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Heat and Temperature
Temperature is a measure of the amount of energy
possessed by the molecules of a substance. It is a relative measure of how hot or cold a substance is and can be used to predict the direction of heat transfer. Heat is energy in transit. The transfer of energy as heat occurs at the molecular level as a result of a temperature difference. Heat is capable of being transmitted through solids and fluids by conduction, through fluids by convection, and through empty space by radiation. Modes of Heat Transfer
Conduction involves the transfer of heat by the
interactions of atoms or molecules of a material through which the heat is being transferred.
Convection involves the transfer of heat by the
mixing and motion of macroscopic portions of a fluid.
Radiation, or radiant heat transfer, involves the
transfer of heat by electromagnetic radiation that arises due to the temperature of a body. Heat Transfer Rate and Heat Flux
The rate at which heat is transferred is represented
by the symbol Q or q or qx. Common units for heat transfer rate is Btu/hr (W or kW). heat flux is the heat transfer rate per unit area, which has the symbol of Q” or q” or q”x. Units for heat flux are Btu/hr-ft2 (W/m2 or kW/m2 ). The heat flux can be determined by dividing the heat transfer rate by the area through which the heat is being transferred. Quantity Text Notation SI Unit English Unit
heat Q Joule (J) Btu
(heat transfer)
heat rate q Watt (W) Btu/hr
(heat transfer rate) (heat energy rate) (rate of heat flow)
heat flux q” W/m2 Btu/hr-ft2
(heat rate per unit area)
heat rate per unit length q’ W/m Btu/hr-ft
volumetric heat generation q W/m3 Btu/hr-ft3
(rate of heat production per unit volume)
Conversions: 1 Btu = 1054 J
1 kcal = 4184 J Thermal Conductivity
The heat transfer characteristics of a solid material
are measured by a property called the thermal conductivity (k) measured in Btu/hr-ft-oF. It is a measure of a substance’s ability to transfer heat through a solid by conduction. The thermal conductivity of most liquids and solids varies with temperature. For vapors, it depends upon pressure. Convective Heat Transfer Coefficient
The convective heat transfer coefficient (h),
defines, in part, the heat transfer due to convection. It is sometimes referred to as a film coefficient and represents the thermal resistance of a relatively stagnant layer of fluid between a heat transfer surface and the fluid medium. Common units used to measure the convective heat transfer coefficient are Btu/hr ft2 oF. Log Mean Temperature Difference
In heat exchanger applications, the inlet and outlet
temperatures are commonly specified based on the fluid in the tubes. The temperature change that takes place across the heat exchanger from the entrance to the exit is not linear. A precise temperature change between two fluids across the heat exchanger is best represented by the log mean temperature difference (LMTD or ΔTlm) Overall Heat Transfer Coefficient In the case of combined heat transfer, it is common practice to relate the total rate of heat transfer (Q ), the overall cross-sectional area for heat transfer (Ao), and the overall temperature difference (ΔTo) using the overall heat transfer coefficient (Uo). The overall heat transfer coefficient combines the heat transfer coefficient of the two heat exchanger fluids and the thermal conductivity of the heat exchanger tubes. Uo is specific to the heat exchanger and the fluids that are used in the heat exchanger. Bulk Temperature
The fluid temperature (Tb), referred to as the bulk
temperature, varies according to the details of the situation. For flow adjacent to a hot or cold surface, Tb is the temperature of the fluid that is "far" from the surface, for instance, the center of the flow channel. For boiling or condensation, Tb is equal to the saturation temperature. Conduction is the transfer of heat from molecule to molecule within a substance Molecules must be in direct contact with each other • If you put one end of a metal rod over a fire, that end will absorb the energy from the flame. •Molecules at this end of the road will gain energy and begin to vibrate faster •As they do, their temperature increases and they begin to bump into the molecules next to them. •The heat is being transferred from the warmer end to the colder end, and eventually to your finger. Conduction involves the transfer of heat by the interaction between adjacent molecules of a material.
Heat transfer by conduction is dependent upon the
driving "force" of temperature difference and the resistance to heat transfer. The resistance to heat transfer is dependent upon the nature and dimensions of the heat transfer medium.
All heat transfer problems involve the temperature
difference, the geometry, and the physical properties of the object being studied. In conduction heat transfer problems, the object being studied is usually a solid.
There are several ways to correlate the geometry,
physical properties, and temperature difference of an object with the rate of heat transfer through the object.
In conduction heat transfer, the most common means
of correlation is through Fourier’s Law of Conduction.
The law, in its equation form, is used most often in its
rectangular or cylindrical form (pipes and cylinders). Sample Prob. 1000 Btu/hr is conducted through a section of insulating material as shown in the figure, that measures 1 ft2 in cross-sectional area. The thickness is 1 in. and the thermal conductivity is 0.12 Btu/hr-ft-°F. Compute the temperature difference across the material. A concrete floor with a conductivity of 0.8 Btu/hr-ft- °F measures 30 ft by 40 ft with a thickness of 4 inches. The floor has a surface temperature of 70°F and the temperature beneath it is 60°F. What is the heat flux and the heat transfer rate through the floor? Solution: 1.
Principles of Heat Transfer, 7th Edition by Kreith, Manglik, and Bohn
Heat Transfer, 10th Edition by J. P. Holman Equivalent Resistance Method It is possible to compare heat transfer to current flow in electrical circuits. The heat transfer rate may be considered as a current flow and the combination of thermal conductivity, thickness of material, and area as a resistance to this flow. The temperature difference is the potential or driving function for the heat flow, resulting in the Fourier equation being written in a form similar to Ohm’s Law of Electrical Circuit Theory. If the thermal resistance term Δx/k is written as a resistance term where the resistance is the reciprocal of the thermal conductivity divided by the thickness of the material, the result is the conduction equation being analogous to electrical systems or networks. The electrical analogy may be used to solve complex problems involving both series and parallel thermal resistances. A typical conduction problem in its analogous electrical form is given in the following example. Where the "electrical" Fourier equation may be written as follows. Sample Prob. A composite protective wall is formed of a 1 in. copper plate, a 1/8 in. layer of asbestos, and a 2 in. layer of fiberglass. The thermal conductivities of the materials in units of Btu/hr-ft-oF are as follows: kCu = 240, kasb = 0.048, and kfib = 0.022. The overall temperature difference across the wall is 500°F. Calculate the thermal resistance of each layer of the wall and the heat transfer rate per unit area (heat flux) through the composite structure. Solution: Seatwork #1 Prob #1 A wall 2 cm thick is to be constructed from material that has an average thermal conductivity of 1.3 W/m◦C. The wall is to be insulated with material having an average thermal conductivity of 0.35 W/m◦C, so that the heat loss per square meter will not exceed 1830W. Assuming that the inner and outer surface temperatures of the insulated wall are 130x◦C and 3x◦C, calculate the thickness of insulation required. Cylindrical Coordinates Heat transfer across a rectangular solid is the most direct application of Fourier’s law. Heat transfer across a pipe or heat exchanger tube wall is more complicated to evaluate. Across a cylindrical wall, the heat transfer surface area is continually increasing or decreasing. Figure below shows the cross-sectional view of a pipe constructed with homogeneous material. The surface area (A) for transferring heat through the pipe (neglecting the pipe ends) is directly proportional to the radius (r) of the pipe and the length (L) of the pipe. A = 2πrL
As the radius increases from the inner wall to the
outer wall, the heat transfer area increases. The development of an equation evaluating heat transfer through an object with cylindrical geometry begins with Fourier’s law that; From the discussion, it is seen that no simple expression for area is accurate. Neither the area of the inner surface nor the area of the outer surface alone can be used in the equation. For a problem involving cylindrical geometry, it is necessary to define a log mean cross-sectional area (Alm). Substituting the expression 2πrL for area in the equation allows the log mean area to be calculated from the inner and outer radius without first calculating the inner and outer area. This expression for log mean area can be inserted into Fourier’s equation, allowing us to calculate the heat transfer rate for cylindrical geometries. Sample Prob. A stainless steel pipe with a length of 35 ft has an inner diameter of 0.92 ft and an outer diameter of 1.08 ft. The temperature of the inner surface of the pipe is 122oF and the temperature of the outer surface is 118oF. The thermal conductivity of the stainless steel is 108 Btu/hr-ft-oF. Calculate the heat transfer rate through the pipe. Calculate the heat flux at the outer surface of the pipe. Solution: A 10 ft length of pipe with an inner radius of 1 in and an outer radius of 1.25 in has an outer surface temperature of 250°F. The heat transfer rate is 30,000 Btu/hr. Find the interior surface temperature. Assume k = 25 Btu/hr-ft-°F. Solution: The evaluation of heat transfer through a cylindrical wall can be extended to include a composite body composed of several concentric, cylindrical layers, as shown in the figure. Sample Prob. A thick-walled nuclear coolant pipe (ks = 12.5 Btu/hr- ft-°F) with 10 in. inside diameter (ID) and 12 in. outside diameter (OD) is covered with a 3 in. layer of asbestos insulation (ka = 0.14 Btu/hr-ft-oF) as shown in the figure. If the inside wall temperature of the pipe is maintained at 550°F, calculate the heat loss per foot of length. The outside temperature is 100°F. Solution: Seatwork #1 Prob. #2 A thick-walled tube of stainless steel with thermal conductivity k = 19 W/moC has inner diameter of 10 cm and outer diameter of 30 cm is covered with 5 cm layer of asbestos insulation with thermal conductivity k = 0.2 W/moC. If the inside of the pipe and outside of insulator temperature is maintained at 60xoC and 10xoC respectively. Determine the heat loss per meter length of pipe and the tube-insulation interface temperature. Convection involves the transfer of heat by the motion and mixing of "macroscopic" portions of a fluid (that is, the flow of a fluid past a solid boundary). The term natural convection is used if this motion and mixing is caused by density variations resulting from temperature differences within the fluid. The transfer of heat from a hot water radiator to a room is an example of heat transfer by natural convection. The term forced convection is used if this motion and mixing is caused by an outside force, such as a pump and blower. The transfer of heat from the surface of a heat exchanger to the bulk of a fluid being pumped through the heat exchanger is an example of forced convection. Heat transfer by convection is more difficult to analyze than heat transfer by conduction because no single property of the heat transfer medium, such as thermal conductivity, can be defined to describe the mechanism. Heat transfer by convection varies from situation to situation (upon the fluid flow conditions), and it is frequently coupled with the mode of fluid flow. In practice, analysis of heat transfer by convection is treated empirically (by direct observation). Convection heat transfer is treated empirically because of the factors that affect the stagnant film thickness: Fluid velocity
Fluid viscosity
Heat flux
Surface roughness
Type of flow (single-phase/two-phase)
Convection involves the transfer of heat between a surface at a given temperature (Ts) and fluid at a bulk temperature (Tb). The exact definition of the bulk temperature (Tb) varies depending on the details of the situation. For flow adjacent to a hot or cold surface, Tb is the temperature of the fluid "far" from the surface. For boiling or condensation, Tb is the saturation temperature of the fluid. For flow in a pipe, Tb is the average temperature measured at a particular cross-section of the pipe. The basic relationship for heat transfer by convection has the same form as that for heat transfer by conduction: Newton’s law of cooling The convective heat transfer coefficient (h) is dependent upon the physical properties of the fluid and the physical situation. Typically, the convective heat transfer coefficient for laminar flow is relatively low compared to the convective heat transfer coefficient for turbulent flow. This is due to turbulent flow having a thinner stagnant fluid film layer on the heat transfer surface. Values of h have been measured and tabulated for the commonly encountered fluids and flow situations occurring during heat transfer by convection. Sample Prob. Many applications involving convective heat transfer take place within pipes, tubes, or some similar cylindrical device. In such circumstances, the surface area of heat transfer normally given in the convection equation varies as heat passes through the cylinder. In addition, the temperature difference existing between the inside and the outside of the pipe, as well as the temperature differences along the pipe, necessitates the use of some average temperature value in order to analyze the problem. This average temperature difference is called the log mean temperature difference (LMTD), described earlier. Overall Heat Transfer Coefficient
Many of the heat transfer processes encountered in
engineering facilities involve a combination of both conduction and convection. For example, heat transfer in a steam generator involves convection from the bulk of the reactor coolant to the steam generator inner tube surface, conduction through the tube wall, and convection from the outer tube surface to the secondary side fluid. In cases of combined heat transfer for a heat exchanger, there are two values for h. There is the convective heat transfer coefficient (h) for the fluid film inside the tubes and a convective heat transfer coefficient for the fluid film outside the tubes. The thermal conductivity (k) and thickness (Δx) of the tube wall must also be accounted for. An additional term (Uo), called the overall heat transfer coefficient, must be used instead. It is common practice to relate the total rate of heat transfer (Q) to the cross-sectional area for heat transfer (Ao) and the overall heat transfer coefficient (Uo). The relationship of the overall heat transfer coefficient to the individual conduction and convection terms is shown in the figure below. An example of this concept applied to cylindrical geometry is illustrated by the figure below, which shows a typical combined heat transfer situation. Referring from the figure representing flow in a pipe, heat transfer by convection occurs between temperatures T1 and T2; heat transfer by conduction occurs between temperatures T2 and T3; and heat transfer occurs by convection between temperatures T3 and T4. Thus, there are three processes involved. Each has an associated heat transfer coefficient, cross- sectional area for heat transfer, and temperature difference. ΔTo can be expressed as the sum of the ΔT of the three individual processes.
If the basic relationship for each process is solved for its
associated temperature difference and substituted into the expression for ΔTo above, the following relationship results. This relationship can be modified by selecting a reference cross-sectional area Ao.
Solving for results in an equation in the form .
˙Q = Uo Ao ΔT where: Equation for the overall heat transfer coefficient in cylindrical geometry is relatively difficult to work with. The equation can be simplified without losing much accuracy if the tube that is being analyzed is thin-walled, that is the tube wall thickness is small compared to the tube diameter. For a thin-walled tube, the inner surface area (A1), outer surface area (A2), and log mean surface area (A1m), are all very close to being equal. Assuming that A1, A2, and A1m are equal to each other and also equal to Ao allows us to cancel out all the area terms in the denominator of the equation. This results in a much simpler expression that is similar to the one developed for a flat plate heat exchanger .
The convection heat transfer process is strongly
dependent upon the properties of the fluid being considered. Correspondingly, the convective heat transfer coefficient (h), the overall coefficient (Uo), and the other fluid properties may vary substantially for the fluid if it experiences a large temperature change during its path through the convective heat transfer device. This is especially true if the fluid’s properties are strongly temperature dependent. Under such circumstances, the temperature at which the properties are "looked-up" must be some type of average value, rather than using either the inlet or outlet temperature value. For internal flow, the bulk or average value of temperature is obtained analytically through the use of conservation of energy. For external flow, an average film temperature is normally calculated, which is an average of the free stream temperature and the solid surface temperature. In any case, an average value of temperature is used to obtain the fluid properties to be used in the heat transfer problem. The following example shows the use of such principles by solving a convective heat transfer problem in which the bulk temperature is calculated. Water flows through a cast steel pipe (k= 50 W/m K) with an outer diameter of 104 mm and 2 mm wall thickness. Calculate the Heat loss by convection and conduction per meter length of uninsulated pipe when the water temperature is 15oC, the outside air temperature is - 10oC, waterside heat transfer convective coefficient is 30 kW/m2K and outside heat transfer convective coefficient is 20 W/m2K. Calculate the corresponding heat loss per meter of pipe when it is lagged with insulation having an outer diameter of 300 mm and thermal conductivity of k = 0.05 w/mK. How much can be save for insulating 100 m of pipe in one month continuous operation, assuming that energy costs Php 10.85 per kWh? Seatwork A 50-cm-diameter pipeline in the Arctic carries hot oil where the outer surface is maintained at 3xoC and is exposed to a surrounding temperature of −1xoC.Aspecial powder insulation 5 cm thick surrounds the pipe and has a thermal conductivity of 7mW/moC. The convection heat-transfer coefficient on the outside of the pipe is 9 W/m2oC. Estimate the energy loss from the pipe per meter of length.