any?’ R.M. PUBLIC SCHOOL =” —_— PRE BOARD 1 (2024-25) Class: 12" Seduce M.Marks:70 Subject: Chemistry (See2) ‘Timi General Instructions: Qu 1. Question paper consists of 70 marks. 2. Section A consists of 16 Multiple Choice questions carrying | marks each. 3. Seetion B consists of 5 short answer questions carrying 2 marks each 4. Seetion C consists of 7 short answer questions carrying 3 marks each S. Section D consists of 2 case-based questions carrying 4 marks cach 6. Section F consists of 3 long answer questions carrying 5 marks each 7. All questions are compulsory SECTION A Multiple choice questions (16%1=16 Marks) 1. The colligative property used for the determination of molar mass of polyme 1d proteins is: a) Osmotic pressure b) Depression in freezing point ©) Relative lowering of vapour pressure d) 2. Low concentration of oxygen in the blood tissues of people li a) High atmospheric pressure / b) Low temperature ©) Low atmospheric pressure 4) Both low temperature and high atmospheric pressure 3. The correct cell to represent the following reactis Zn +2Ag’ Zn?" +2Ag tion in Boiling point ing in high altitude is due to is a) 2Ag | Ag’ || Zn | Zn?” b) Ag’ | Ag || Zn?" | Zn c) Ag | Ag* || Zn | Zn? ~d) Zn| Zn” || Ag’ | Ag 4, The unit of conductivity are . a) ohm 'em b) ohm ‘em? c) ohm! d) ohm “em?equiv | 5. The order of reaction Ha (g) + Ch (g) "¥ 2HCI(g) is a)2 b)I 0 43 6. Which of the following is affected by catalyst? a) AH b) AG ©) Ea - das 7. The most common and stable oxidation of lanthanoid is w a) +2 = b) 43 4 446 oe Bly 8. The compound {CO(SO,)(NHs\yIBrand [CO(Br}(NHs4] SOx represent: C0" + 4) Optical Isomerism ) Linkage Isomerism ony ft c) lonisation Isomerism 4) Coordination Isomerism be 9. Which of the following options are correct for [Fe(CN)«}”’complex? a) d?sp* hybridis: b) sp'd? hybridisation +) paramagnetic d) diamagnetic 10. The IUPAC name of compound shown below is a) 2-bromo4-Chlorocyclohex-|-ene it b) 6 bromo-2-Chlorocyclohexane cosy ¢) 3 bromo-3-Chlorocyclohexane Jt 4d) 1 bromo-3-Chlorocyclohexane anr \ HL CURCH CCH eanmot be prepared by Mu a) PhCOCII, + CH\CHs MeX €) PhCOCH» CH + CHAMeX. 12. Acid catalysed of alkene is an example of a) Free radial substitution, bb) Nucleopilic substitution 4) Eletrophilic addition ~<}-Eleetrophitie substitution 13. The compound which is most difficult to protonate is by HCHO PhCH(CH) CHDX d) CIACILCOCHL, + PhMgX ¢) Nucleophilic addition A. 0. d ~ HC CH a OC b) OL Oo pro HH Wc CH n Reasoning Questions Directions: QNo. 14 to 16 are Assertion Reasoning Based questions. These consist of two statements, Assertion (A) and Reason(R). Answer these questions selecting the appropriate option given below ) Both A and R are true and R is the correct explanation of A. b) Both A and R are true and R is not the correct explanation of A. ©) Ais true R is false d) A is false R is true. 14. Assertion (A): P-Chlorobenzoie acid is stronger acid than benzoic acid. Reason (R): Chlorine has electron-donating resonance (+R) effect. 15, Assertion: Nitration of benzoic acid gives M-nitrobenzoie acid Reason(R): Carboxyl group increases the electron density at m-position 16, Assertion(A): Hydroxy ketones are not directly used in Grignard reaction. Reaction(R): Grignard reagent react with hydroxyl group SECTION B Very Short answer questions (5*2=10 Marks) 17. What is Henry’s law? Give one application of it 18. In an aqueous solution how does specific conductivity of electrolytes change with. Coy 19, What do you mean by Chelating ligand? Give examples, 20. Write the product formed when chlorobenzene undergoes ni 21. A small amount of ethanol is usually added to chloroform bottles? Why od SECTION C Short answer questions (7*3=21 Marks) 22. a) How do you convert 2-bromo-butane fo but-2-ene. b) What is the reagent used for de-hydrogenation of alkyl halide? 23. Explain the following with an example. a) Kolbe’s reaction. b) Reimer-Tiemann reaction ¢) Williamson ether synthesis 24. Complete the following synthesis by giving missing starting material, reagent or products i CH: CHCHs tno, —— KOH, heat o COOH sock Heat COOHH:NCONHNH, ) ColsCHO) + 25, a) What do you mean by rate of r b) Calculate the overall order of a reaction which has Rate - K[A}'2[B]°/2 26. Boiling point of water at 750mmHg is 99.63°C. How much sugar is to be added 10 500g of water such that it boils at 100°C. 7 { order reaction time required for completation of 99.9% is 10 times of half tim tM following expression 27. Show that ina of the reaction 28, How do you determine the standard electrode potential of a system Mg” | Mz? SECTION D Long answer questions (3*5=15 Marks) 29. Define Kohlrausch’s law. How does it help in +a) Calculation of XY for weak electrolyte and +b) degree of dissociation of'a weak electrolyte, ~¢) State Faraday law of electrolysis 4d) What are primary cells? How do they differ form secondary cells 30, a) Give the preparation of Potassium Permanganate trom Pyrolusite ore. sb) Describe the preparation of Potassium dichromate from chromite ore. ¢) What are lanthanoids? Give their general electronic configurations. What is lanthanoid contraction d) Name an important alloy of lanthanoid metals? C**iwo #31. An organic compound contains 69.77 carbon. 11.63% hydrogen a the compound is 86. It does not reduce Tollen’s reagent but forms an addition compound with sodium hydrogen sulphite and gives positive lodeform test. On vigrous oxidation it gives ehtanoic acid and Propanoie acid. What \d rest oxygen. The molec jar mass of the possible structure of the compound. SECTION E Case Based questions (2*4=8 Marks) 32. Phenols and carboxylic acids are acidic in nature. Both dissolve in NaOH solution and tun Blue litmus, fed. However carboxylic acid are much stronger acid than Phenols and decompose NaHiCOy with the evoluti mn of CO) but Phenols do not. Both electron-donating and electron-with drawing substituents Influence the acid strength of alphetic acids formic acid has reducing properties and also does not show reactions with alkyl group. *phoic Questions. bevy a) Why Carboxylic acids do not give the characteristic reactions Blcrca tote b) Fluorine is more electronegative than Chlorine even than P-fluorobenzoic acid is weaker acid than p- chlorobenzoic acid. Explain, ¢) Formic acid reduces Tollens’ reagent but acetic acid does not? Explai ethylene glycol in water is commonly used as an antifreeze solution in car radiators, 12.4g of this, Substance is dissolve in 100g of water. (Kf and Kb for water are 1.86 km’ and 0.52 km ' respectively) Questions. a) What is the mole fraction of ethylene glycol in the solution. b) What is the molarity of the solution, ©) What is the freezing point of the solution, 4d) Is it advisable to keep t 33. is substance in car radiators in summer.