PC2174A 2022 Tutorial 02
PC2174A 2022 Tutorial 02
Tutorial 2
3. In a very simple model of a crystal, point-like atomic ions are regularly spaced along an infinite
one-dimensional row with spacing R. Alternate ions carry equal and opposite charges ±e. The
potential energy of the ith ion in the electric field due to another ion, the jth, is
qi qj
Uij = ,
4πϵ0 rij
where qi , qj are the charges on the ions, rij is the distance between them and ϵ0 is a constant known
as permittivity of vacuum. Write down a series giving the total contribution Ui of the ith ion to the
overall potential energy. Show that the series converges, and, if Ui is written as
αe2
Ui = ,
4πϵ0 R
find a closed-form expression for α, known as the Madelung constant for this unrealistic lattice.