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DATE PREPARED: 02/05/23

MATERIAL SAFETY DATA SHEET MSDS No.: CI000E-00

Section 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : RISO INK COLOR <See page 5-8>
MANUFACTURER

NAME: RISO KAGAKU CORPORATION

ADDRESS: 5-34-7 SHIBA, MINATO-KU, TOKYO, 108, JAPAN
TELEPHONE NUMBER: 81 3 5441 6611
DISTRIBUTOR

NAME: RISO EUROPE LIMITED ( SIGNATURE: )

ADDRESS: UNIT 6 MAPLE GROVE BUSINESS CENTRE, LAWRENCE ROAD,
HOUNSLOW, MIDDLESEX. TW4 6DR, U.K.
TELEPHONE NUMBER: 44 20 8572 8777

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE / MIXTURE: Mixture (Preparation)
CHEMICAL NATURE: Water-in-Oil-type emulsion
SYMBOL/R-PHRASE: Not applicable
COMPONENTS: <See page 5-8>

Section 3 - HAZARDS IDENTIFICATION

MOST IMPORTANT HAZARDS:

None.
POTENTIAL HEALTH EFFECTS:

EYE: May cause slight irritation.

SKIN: May cause slight irritation.
INHALATION: Vapour or mist in unusually high concentrations generated from heating this
ink, or from exposure in poorly ventilated areas, may cause irritation to
the nose and throat, headache, and nausea.
INGESTION: May cause abdominal discomfort, nausea.

Section 4 - FIRST-AID MEASURES

EYE: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
SKIN: After contact with skin, wash immediately with plenty of water using a mild
soap.
INHALATION: If you feel unwell, move from the contamination immediately to fresh air and
seek medical advice.
INGESTION: If swallowed, do not induce vomiting and seek medical advice.

Section 5 - FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA: Water, CO2, foam, dry chemical powder, dry sand
SPECIFIC HAZARDS WITH REGARD TO FIRE-FIGHTING MEASURES:

This ink does not act as a source of ignition, but might burn if exposed to
a fire.
HAZARDOUS COMBUSTION PRODUCTS:

CO, CO2, smoke

RISO INK COLOR
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Section 6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Ventilate the area until all released material is properly cleaned up.
METHOD OF CLEANING UP: Shovel up, then wipe up with cloth or paper.
Section 7 - HANDLING AND STORAGE
HANDLING:

TECHNICAL MEASURES: Use only in the well-ventilated areas.

SAFE HANDLING ADVICE: Avoid contact with skin. Use only with cartridge (bottle).
STORAGE:

STORAGE CONDITIONS: Store at 5 - 35 oC and protect from sunlight at all times.

Keep the ink out of reach of children.
PACKAGING MATERIAL: Only original cartridge (bottle).
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING MEASURES:

Good general ventilation should be sufficient for most conditions.

EXPOSURE GUIDELINES: <See page 5-8>
PERSONAL PROTECTIVE EQUIPMENT:

RESPIRATORY PROTECTION : Not normally required

HAND PROTECTION: Recommend the use of gloves in case of contact with skin.
EYE PROTECTION: Not normally required
SKIN AND BODY PROTECTION : Not normally required
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste
ODOUR: Slight petroleum odour
PH: Not applicable
BOILING POINT: • 100 oC
MELTING POINT: • 0 oC
FLASH POINT: Can not established
AUTOIGNITION TEMPERATURE: • 400 oC
EXPLOSION PROPERTIES: Not applicable
OXIDISING PROPERTIES: Not applicable
DENSITY: 1.00 - 1.12
WATER SOLUBILITY: Negligible
Section 10 – STABILITY AND REACTIVITY
STABILITY: This product is considered a stable material under normal storage and
handling conditions.
CONDITION TO AVOID: Avoid exposure to high temperatures.
MATERIALS TO AVOID: Strong oxidising agents
HAZARDOUS DECOMPOSITION PRODUCTS: None

RISO INK COLOR

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MATERIAL SAFETY DATA SHEET MSDS No.: CI000E-00

Section 11 – TOXICOLOGICAL INFORMATION

ACUTE ORAL TOXICITY: LD50•5000mg/kg (rat)
ACUTE EYE IRRITATION: May cause slight irritation.
ACUTE SKIN IRRITATION: May cause slight irritation. P.I.I. • 2.0
MUTAGENICITY: Negative in the Ames test
SKIN SENSITISATION: Frequent or prolonged contact may cause skin sensitisation.
CARCINOGENICITY: Printing inks are listed group 3 (not classifiable as carcinogenic to humans) in
IARC Monograph, 65.
Carbon black is listed group 2B (possibly carcinogenic to humans) in IARC
Monograph, 65.
Petroleum solvent listed group 3 in IARC Monograph,33,45.
Although petroleum solvent is listed in Annex•of Directive 67/548/EEC, it is
justified by Nota L not to classify it as carcinogens because it contains less
than 3% DMSO extract.
Section 12 - ECOLOGICAL INFORMATION
We are not in a position to provide any information as we have not conducted any tests for this purpose
nevertheless we are not aware of any scientific data which evidences negative environmental effects.
Section 13 - DISPOSAL CONSIDERATIONS
METHOD OF DISPOSAL: Burn in an adequate incinerator or bury in landfill in accordance with all
applicable regulations. Any disposal practice must be in compliance with all
EU and Member State (both federal and state) laws.
Material of ink-cartridge (bottle) are polypropylene (PP) and high-density
polyethylene (HDPE).
Section 14 - TRANSPORT INFORMATION
RID/ADR: No classification assigned
ADNR: No classification assigned
IMDG CODE: No classification assigned
ICAO/IATA-DGR: No classification assigned
UN NUMBER: No classification assigned
Section 15 - REGULATORY INFORMATION
Classification and labelling according to EEC directives:
CLASSIFICATION/SYMBOL: No classification assigned
(GOVERNING DIRECTIVE: Dangerous Substances Directive 67/548/EEC, as modified.)
RISK PHRASE: Not applicable
SAFETY ADVICE PHRASE: Not applicable
EINECS(European Inventory of Existing Commercial Chemical Substances):
All chemical substances in these products are listed in EINECS.
IARC (International Agency for Research on Cancer):
Printing inks, carbon black and petroleum solvent (known as mineral oil) are listed in IARC Monograph
(refer to Section 11).
ACGIH (American Conference of Governmental Industrial Hygienists) :
This product contains no chemical substances classifiable as carcinogenic.

RISO INK COLOR

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MATERIAL SAFETY DATA SHEET MSDS No.: CI000E-00

Section 16 - OTHER INFORMATION

References
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans
Vol.33, 45, 65, IARC (1996)
Threshould limit values for chemical substances and physical agents and biological exposure indices,
ACGIH
The information herein is given in good faith, but no warranty, express or implied,
is made. Please consult RISO EUROPE LIMITED for further information.

RISO INK COLOR

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Section 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMES (ITEM CODE): RISO INK COLOR RED (S-3974E)

RISO INK COLOR BLUE (S-3975E)
RISO INK COLOR GREEN (S-3976E)
RISO INK COLOR YELLOW (S-3978E)
RISO INK COLOR BRIGHT RED (S-3979E)
RISO INK COLOR MEDIUM BLUE (3981E)
RISO INK COLOR RISOFEDERALBLUE (S-3982E)
RISO INK COLOR PURPLE (S-3983E)
RISO INK COLOR BURGUNDY (S-3984E)
RISO INK COLOR FLUORESCENT PINK (S-3988E)
RISO INK COLOR ORANGE (S-3992E)
RISO INK COLOR CRIMSON (S-3993E)

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS:
CAS No. EINECS No. wt%
64742-55-8 265-158-7 < 10
Petroleum solvent
64742-47-8 265-149-8 < 10
Glycerol 56-81-5 200-289-5 < 10
Organic pigment(s) Registered Registered ---
Alkyd resin Registered Registered ---
Water 7732-18-5 231-791-2 ---

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDLINES:
EEC Concentration
CAS No. ACGIH TLV
limits
64742-55-8 --- 5 mg/m3 *1
Petroleum solvent
64742-47-8 C>=10% ; Xn, R65 ---
Glycerol 56-81-5 --- 10 mg/m3
*1 : as mineral oil mists

RISO INK COLOR

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Section 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMES (ITEM CODE): RISO INK COLOR BROWN (S-3977E)

RISO INK COLOR RISOMARINERED (S-3980E)
RISO INK COLOR TEAL (S-3985E)
RISO INK COLOR FLAT GOLD (S-3990E)

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS:
CAS No. EINECS No. wt%
64742-55-8 265-158-7 < 10
Petroleum solvent
64742-47-8 265-149-8 < 10
Glycerol 56-81-5 200-289-5 < 10
Carbon black (pigment) 1333-86-4 215-609-9 <1
Organic pigment(s) Registered Registered ---
Alkyd resin Registered Registered ---
Water 7732-18-5 231-791-2 ---

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDLINES:
EEC Concentration
CAS No. ACGIH TLV
limits
64742-55-8 --- 5 mg/m3 *1
Petroleum solvent
64742-47-8 C>=10% ; Xn, R65 ---
Glycerol 56-81-5 --- 10 mg/m3
Carbon black (pigment) 1333-86-4 --- 3.5 mg/m3
*1 : as mineral oil mists

RISO INK COLOR

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Section 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME (ITEM CODE): RISO INK COLOR HUNTER GREEN (S-3991E)

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS:
CAS No. EINECS No. wt%
64742-55-8 265-158-7 < 10
Petroleum solvent
64742-47-8 265-149-8 < 10
Glycerol 56-81-5 200-289-5 < 10
Carbon black (pigment) 1333-86-4 215-609-9 < 10
Organic pigment(s) Registered Registered ---
Alkyd resin Registered Registered ---
Water 7732-18-5 231-791-2 ---

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDLINES:
EEC Concentration
CAS No. ACGIH TLV
limits
64742-55-8 --- 5 mg/m3 *1
Petroleum solvent
64742-47-8 C>=10% ; Xn, R65 ---
Glycerol 56-81-5 --- 10 mg/m3
Carbon black (pigment) 1333-86-4 --- 3.5 mg/m3
*1 : as mineral oil mists

RISO INK COLOR

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MATERIAL SAFETY DATA SHEET MSDS No.: CI000E-00

Section 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMES (ITEM CODE): RISO INK COLOR GREY (S-3986E)

RISO INK COLOR LIGHT GREY (S-3987E)

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS:
CAS No. EINECS No. wt%
64742-55-8 265-158-7 < 10
Petroleum solvent
64742-47-8 265-149-8 < 10
Glycerol 56-81-5 200-289-5 < 10
Carbon black (pigment) 1333-86-4 215-609-9 <1
Titanium dioxide (pigment) 13463-67-7 236-675-5 < 20
Alkyd resin Registered Registered ---
Water 7732-18-5 231-791-2 ---

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDLINES:
EEC Concentration
CAS No. ACGIH TLV
limits
64742-55-8 --- 5 mg/m3 *1
Petroleum solvent
64742-47-8 C>=10% ; Xn, R65 ---
Glycerol 56-81-5 --- 10 mg/m3
Carbon black (pigment) 1333-86-4 --- 3.5 mg/m3
Titanium dioxide (pigment) 13463-67-7 --- 10 mg/m3
*1 : as mineral oil mists

RISO INK COLOR