EGYPTIAN CHINESE UNIVERSITY

FACULTY OF ENGINEERING AND TECHNOLOGY

ENERGY AND RENEWABLE ENERGY ENGINEERING
PROGRAM

Thermodynamics
Assoc. Prof. Mohamed Nawar
Mech. Power Eng. Dpt.
Faculty of Eng. Mattria
Helwan University

Assoc. Prof. Mohamed Nawar, 2023, Cairo, Egypt

Course Contents:
1. Basic Concepts of Thermodynamics
2. Energy
3. Properties of Pure Substances
4. Energy Analysis of Closed Systems
5. Mass and Energy Analysis of Control Volumes
6. The Second Law of Thermodynamics
7. Entropy

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Basic concepts of
thermodynamics
 SYSTEMS AND CONTROL VOLUMES
• System: A quantity of matter or a region in space chosen for study.
• Surroundings: The mass or region outside the system
• Boundary: The real or imaginary surface that separates the system from
its surroundings.
• The boundary of a system can be fixed or movable.
• Systems may be considered to be closed or open.
• Closed system (Control mass): A fixed amount of mass, and no mass
can cross its boundary

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• Open system (control volume): A properly
selected region in space.
• It usually encloses a device that involves mass
flow such as a compressor, turbine, or nozzle.
• Both mass and energy can cross the boundary of
a control volume.
• Control surface: The boundaries of a control
volume. It can be real or imaginary.

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 PROPERTIES
• Property: Any characteristic of a
system.
• Some familiar properties are
pressure P, temperature T, volume
V, and mass m.
• Properties are considered to be
either intensive or extensive.
• Intensive properties: Those that
are independent of the mass of a
system, such as temperature,
pressure, and density.
• Extensive properties: Those
whose values depend on the size—
or extent—of the system.
• Specific properties: Extensive
properties per unit mass.

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 STATE AND EQUILIBRIUM
• Thermodynamics deals with equilibrium
states.
• Equilibrium: A state of balance.
• In an equilibrium state there are no
unbalanced potentials (or driving forces)
within the system.
• Thermal equilibrium: If the temperature
is the same throughout the entire system.
• Mechanical equilibrium: If there is no
change in pressure at any point of the
system with time.
• Chemical equilibrium: If the chemical
composition of a system does not change
with time, that is, no chemical reactions
occur.

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 PROCESSES AND CYCLES
Process: Any change that a system undergoes from one equilibrium state to
another.
Path: The series of states through which a system passes during a process.
To describe a process completely, one should specify the initial and final states, as
well as the path it follows, and the interactions with the surroundings.
Quasistatic or quasi-equilibrium process: When a process proceeds in such a
manner that the system remains infinitesimally close to an equilibrium state at
all times.

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• Process diagrams plotted by employing
thermodynamic properties as
coordinates are very useful in visualizing
the processes.
• Some common properties that are used
as coordinates are temperature T,
pressure P, and volume V (or specific
volume v).
• The prefix iso- is often used to designate
a process for which a particular property
remains constant.
• Isothermal process: A process during
which the temperature T remains
constant.
• Isobaric process: A process during
which the pressure P remains constant.
• Isochoric (or isometric) process: A
process during which the specific
volume v remains constant.
• Cycle: A process during which the initial
and final states are identical.

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 TEMPERATURE AND THE ZEROTH LAW OF
THERMODYNAMICS
• The zeroth law of
thermodynamics: If two
bodies are in thermal
equilibrium with a third
body, they are also in
thermal equilibrium with
each other.
• By replacing the third
body with a thermometer,
the zeroth law can be
restated as two bodies are
in thermal equilibrium if
both have the same
temperature reading even
if they are not in contact.
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 Temperature Scales
P versus T plots
• All temperature scales are based on
some easily reproducible states such as of the
the freezing and boiling points of water: experimental
the ice point and the steam point. data obtained
• Ice point: A mixture of ice and water from a constant-
that is in equilibrium with air saturated volume gas
with vapor at 1 atm pressure (0°C or thermometer
32°F). using four
• Steam point: A mixture of liquid water different gases
and water vapor (with no air) in
equilibrium at 1 atm pressure (100°C or at different (but
212°F). low) pressures.
• Celsius scale: in SI unit system
• Fahrenheit scale: in English unit
system
• Thermodynamic temperature scale: A
temperature scale that is independent of
the properties of any substance.
• Kelvin scale (SI) Rankine scale (E)
• A temperature scale nearly identical to
the Kelvin scale is the ideal-gas
temperature scale. The temperatures
on this scale are measured using a
constant-volume gas thermometer.
A constant-volume gas thermometer would
read -273.15°C at absolute zero pressure. 11
 Temperature Scales

Comparison of temperature scales.

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 Comparison of magnitudes of
various temperature units.

• The reference temperature in the original Kelvin scale was the ice point,
273.15 K, which is the temperature at which water freezes (or ice melts).
• The reference point was changed to a much more precisely reproducible
point, the triple point of water (the state at which all three phases of water
coexist in equilibrium), which is assigned the value 273.16 K.

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 PRESSURE
Pressure: A normal force exerted by a
fluid per unit area

Some
basic
pressure
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gages.
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• Absolute pressure: The actual pressure at a given position. It is
measured relative to absolute vacuum (i.e., absolute zero pressure).
• Gage pressure: The difference between the absolute pressure and
the local atmospheric pressure. Most pressure-measuring devices are
calibrated to read zero in the atmosphere, and so they indicate gage
pressure.
• Vacuum pressures: Pressures below atmospheric pressure.

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Variation of Pressure with Depth

In a room filled with gas, the pressure variation

with height is negligible.

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Pressure in a liquid at rest increases linearly with distance
from the free surface.

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