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Data Sheet - CHEMLOK 6108

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0% found this document useful (0 votes)
48 views

Data Sheet - CHEMLOK 6108

Uploaded by

t5j64yydrh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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USA SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product name: CHEMLOK 6108


Product Use/Class: Adhesive

LORD Corporation
111 LORD Drive
Cary, NC 27511-7923 USA

Telephone: 814 868-3180


Non-Transportation Emergency: 814 763-2345
Chemtrec 24 Hr Transportation Emergency No.
800 424-9300 (Outside Continental U.S. 703 527-3887)

EFFECTIVE DATE: 02/05/2020

2. HAZARDS IDENTIFICATION

GHS CLASSIFICATION:
Flammable liquids Category 3
Acute toxicity Inhalation - Dust and Mist Category 4 - 11.2% of the mixture consists of ingredient(s) of unknown
toxicity.
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Skin sensitization Category 1
Carcinogenicity Category 2
Reproductive toxicity Category 2
Specific target organ systemic toxicity (single exposure) Category 3
Specific target organ systemic toxicity (single exposure) Category 2 blood system
Specific target organ systemic toxicity (single exposure) Category 1 Central nervous system, Kidney, Liver,
Respiratory system
Specific target organ systemic toxicity (repeated exposure) Category 2 Ears, blood system
Specific target organ systemic toxicity (repeated exposure) Category 1 Nervous system, Respiratory system,
Hematopoietic System
Hazardous to the aquatic environment - acute hazard Category 2
Hazardous to the aquatic environment - chronic hazard Category 2

GHS LABEL ELEMENTS:


Symbol(s)

Signal Word
DANGER

Hazard Statements
Flammable liquid and vapor.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
May cause harm to breast-fed children.
May cause respiratory irritation.
May cause drowsiness or dizziness.

300000009872
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Product: CHEMLOK 6108, Effective Date: 02/05/2020

May cause damage to organs.(blood system)


Causes damage to organs.(Central nervous system, Kidney, Liver, Respiratory system)
May cause damage to organs through prolonged or repeated exposure.(Ears, blood system)
Causes damage to organs through prolonged or repeated exposure.(Nervous system, Respiratory system,
Hematopoietic System)
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.

Precautionary Statements
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/Bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment.

Response
In case of fire: refer to section 5 of SDS for extinguishing media.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF exposed: Call a POISON CENTER or doctor/physician.
Specific treatment (see supplemental first aid instructions on this label).
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
If skin irritation or rash occurs: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Collect spillage.

Storage
Store in a well-ventilated place. Keep cool.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.

Disposal:
Dispose of contents/container in accordance with waste/disposal laws and regulations of your country or particular
locality.
Other Hazards:
This product contains component(s) which have the following warnings; however based on the GHS classification
criteria of your country or locale, the product mixture may be outside the respective category(s).
Acute: Vapor harmful; may affect the brain or nervous system causing dizziness, headache or nausea. Possible
irritation of the respiratory system can occur causing a variety of symptoms such as dryness of the throat, tightness of
the chest, and shortness of breath. In elevated-temperature applications, product may release vapors that may produce
cyanosis in the absence of sufficient ventilation or adequate respiratory protection. The imide in this product is a
respiratory hazard. Inhalation of product vapors, fumes or particulates during heating should be avoided. May cause
central nervous system depression characterized by the following progressive steps: headache, dizziness, staggering
gait, confusion, unconsciousness or coma.May be harmful if swallowed. Ingestion is not an expected route of entry in
industrial or commercial uses.
Chronic: May affect the gastrointestinal system. Ethylbenzene has been classified by IARC as a possible human
carcinogen (Group 2B) and reported by NTP to show clear evidence for carcinogenicity in animals. IARC has
designated carbon black as Group 2B - inadequate evidence for carcinogenicity in humans, but sufficient evidence in

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Product: CHEMLOK 6108, Effective Date: 02/05/2020

experimental animals. In 2006 IARC reaffirmed its 1995 finding that there is "inadequate evidence" from human
health studies to assess whether carbon black causes cancer in humans. Further, epidemiological evidence from well-
conducted investigations has shown no causative link between carbon black exposure and the risk of malignant or
non-malignant respiratory disease in humans. The nitrogen substituted aromatic in this product gave positive results
for mutagenicity in an Ames Assay study while two other mutagenicity studies proved negative. Repeated or
prolonged skin contact may cause allergic reactions with susceptible persons.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS Number Range


Xylene 1330-20-7 60 - 65 %
Ethyl benzene 100-41-4 10 - 15 %
Nitrogen substituted aromatic PROPRIETARY 5 - 10 %
Carbon black 1333-86-4 1-5%
Zinc compound PROPRIETARY 1-5%
Imide PROPRIETARY 1-5%
Toluene 108-88-3 0.1 - 0.9 %
Any "PROPRIETARY" component(s) in the above table is considered trade secret, thus the specific chemical and its exact concentration is being
withheld.

4. FIRST AID MEASURES

FIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids
open while flushing. Get prompt medical attention.

FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated
clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur.

FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult,
give oxygen. Get immediate medical attention.

FIRST AID - INGESTION: If swallowed, do not induce vomiting. Call a physician or poison control center immediately
for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing.

5. FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNSUITABLE EXTINGUISHING MEDIA: Not determined for this product.

SPECIFIC HAZARDS POSSIBLY ARISING FROM THE CHEMICAL: Flammable liquid and vapor. Keep containers
tightly closed. Isolate from heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers
may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. WARNING: Due to the
combustible nature of the dried film of this product and the potential for smoldering or fire, the accumulation and buildup of
the dried film on spray booth walls and floors, spindles, fixtures and other surfaces should be avoided, and any buildup
should be removed. Keep the dried film accumulations away from sparks, friction, impact, high heat (>235 F/>112 C) or
other sources of ignition. These conditions could cause the dried film to ignite very readily and quickly, and the resulting
smoldering or fire may be difficult to extinguish. During removal of accumulation/buildup of this product, take precautions
to avoid heat, friction and impact during the cleaning process. Use paint stripper, brass brush, or plastic scraper for cleaning.
In the event of smoldering or a fire involving the dried product, Cold Fire®** fire suppressing agent is preferred as the
extinguishing medium. If Cold Fire® is not available, use water spray as the extinguishing medium. Take efforts to ensure
that these agents reach the base of the smoldering or fire. Lord Corporation will not be responsible for personal injuries,
property damage or any other damages arising from the accumulation (buildup, cleaning/removal or any related smoldering
or fire) resulting from the use of this product. Refer to the Chemlok® Safe Handling Guide for additional information.
**NOTE: LORD Corporation has determined Cold Fire® fire suppressing agent to be effective in extinguishing fires
involving dried Chemlok® adhesives. LORD does not recommend any particular equipment or system for use in delivering
or applying Cold Fire® products. Customer is responsible for determining that Cold Fire® products and any delivery

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Product: CHEMLOK 6108, Effective Date: 02/05/2020

equipment or system is appropriate and effective for customer's specific needs. During a fire, irritating and/or toxic gases and
particulate may be generated by thermal decomposition or combustion.

SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS: Wear full firefighting
protective clothing, including self-contained breathing apparatus (SCBA). Water spray may be ineffective. If water is
used, fog nozzles are preferable.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Remove all


sources of ignition (flame, hot surfaces, and electrical, static or frictional sparks). Avoid breathing vapors. Use self-contained
breathing equipment. Avoid contact. See Section 5 for cautionary information on the dried residue of this product.

ENVIRONMENTAL PRECAUTIONS: Do not contaminate bodies of water, waterways, or ditches, with chemical or
used container.

METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP: Keep non-essential personnel a safe
distance away from the spill area. Notify appropriate authorities if necessary. Contain and remove with inert absorbent
material and non-sparking tools. Avoid contact. Before attempting cleanup, refer to hazard caution information in other
sections of the SDS form.

7. HANDLING AND STORAGE

HANDLING: Keep closure tight and container upright to prevent leakage. Ground and bond containers when transferring
material. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not
handle until all safety precautions have been read and understood. Empty containers should not be re-used. Use with
adequate ventilation. Because empty containers may retain product residue and flammable vapors, keep away from heat,
sparks and flame; do not cut, puncture or weld on or near the empty container. Do not smoke where this product is used or
stored. See Section 5 for cautionary information on handling of the dried residue of this product.

STORAGE: Do not store or use near heat, sparks, or open flame. Store only in well-ventilated areas. Do not puncture, drag,
or slide container. Keep container closed when not in use. Refer to OSHA 29CFR Part 1910.106 "Flammable and
Combustible Liquids" for specific storage requirements.

INCOMPATIBILITY: Strong oxidizers, acids, bases, water.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

COMPONENT EXPOSURE LIMIT


Chemical Name ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- Skin
TWA STEL TWA CEILING
Xylene 100 ppm 150 ppm 435 mg/m3 N.E. N.A.
100 ppm
Ethyl benzene 20 ppm N.E. 435 mg/m3 N.E. N.A.
100 ppm
Nitrogen substituted aromatic N.E. N.E. N.E. N.E. N.A.
Carbon black 3 mg/m3 N.E. 3.5 mg/m3 N.E. N.A.

Zinc compound N.E. N.E. N.E. N.E. N.A.


Imide N.E. N.E. N.E. N.E. N.A.
Toluene 20 ppm N.E. N.A.
200 ppm 300 ppm
N.A. - Not Applicable, N.E. - Not Established, S - Skin Designation

Engineering controls: Sufficient ventilation in pattern and volume should be provided in order to maintain air
contaminant levels below recommended exposure limits. Caution: Solvent vapors are heavier than air and collect in lower
levels of the work area. Sufficient ventilation (using explosion-proof equipment) should be provided to prevent flammable
vapor/air mixtures from accumulating.

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Product: CHEMLOK 6108, Effective Date: 02/05/2020

PERSONAL PROTECTION MEASURES/EQUIPMENT:


RESPIRATORY PROTECTION: Use a NIOSH approved chemical/mechanical filter respirator designed to
remove a combination of particulates and organic vapor if occupational limits are exceeded. For emergency
situations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved
air-supplied respirator. For respirator use observe OSHA regulations (29CFR 1910.134) or use in accordance with
applicable laws and regulations of your country or particular locality.

SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact.

EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where
splashing may occur.

OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is
likely. Remove and wash contaminated clothing before reuse.

HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any
chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or
stored. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Typical values, not to be used for specification purposes.


ODOR: Solvent VAPOR PRESSURE: N.D.
APPEARANCE: Black VAPOR DENSITY: Heavier than Air
PHYSICAL STATE: Liquid LOWER EXPLOSIVE LIMIT: 1 %(V)
FLASH POINT: 80 °F, 26 °C Setaflash UPPER EXPLOSIVE LIMIT: 7 %(V)
Closed Cup
BOILING RANGE: 136 - 141 °C EVAPORATION RATE: Slower than n-butyl-
acetate
AUTOIGNITION TEMPERATURE: N.D. DENSITY: 0.97 g/cm3 - 8.10 lb/gal
DECOMPOSITION TEMPERATURE: N.D. VISCOSITY, DYNAMIC: ≥375 mPa.s @ 25 °C
ODOR THRESHOLD: N.D. VISCOSITY, KINEMATIC: ≥387 mm2/s @ 25 °C
SOLUBILITY IN H2O: Insoluble VOLATILE BY WEIGHT: 76.60 %
pH: N.A. VOLATILE BY VOLUME: 85.37 %
FREEZE POINT: N.D. VOC CALCULATED: 6 lb/gal, 719 g/l
COEFFICIENT OF WATER/OIL N.D.
DISTRIBUTION:

LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

10. STABILITY AND REACTIVITY

HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions.

STABILITY: Product is stable under normal storage conditions.

CONDITIONS TO AVOID: High temperatures. Sources of ignition.; For dried product issues, refer to Section 5 of the
(M)SDS.

INCOMPATIBILITY: Strong oxidizers, acids, bases, water.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide, chlorine, hydrogen chloride,
Oxides of nitrogen, Phosgene

11. TOXICOLOGICAL INFORMATION

EXPOSURE PATH: Refer to section 2 of this SDS.

SYMPTOMS: Refer to section 2 of this SDS.

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Product: CHEMLOK 6108, Effective Date: 02/05/2020

TOXICITY MEASURES:
Chemical Name LD50/LC50
Xylene Oral LD50: Rat 3,500 mg/kg
Dermal LD50: Rabbit > 4,350 mg/kg
Inhalation LC50: Rat 29.08 mg/l /4 h
Ethyl benzene Oral LD50: Rat 3,500 mg/kg
Dermal LD50: Rabbit 15,400 mg/kg
Inhalation LC50: Rat 17.4 mg/l /4 h
Nitrogen substituted aromatic Oral LD50: rat 1,100 mg/kg

Carbon black Oral LD50: Rat > 15,400 mg/kg


Dermal LD50: Rabbit > 3 g/kg
GHS LC50 (vapour): Acute toxicity point estimate 55 mg/l
Zinc compound Oral LD50: Rat > 5,000 mg/kg

Imide Oral LD50: Rat 1,370 mg/kg


Inhalation LC50: Rat 55 mg/m3 /4 h
Toluene Oral LD50: Rat 2,600 mg/kg
Dermal LD50: Rabbit 12,000 mg/kg
Inhalation LC50: Rat 12.5 mg/l /4 h

Germ cell mutagenicity: No classification proposed


Carcinogenicity: Category 2 - Suspected of causing cancer.
Components contributing to classification: Ethyl benzene.
Reproductive toxicity: Category 2 - Suspected of damaging fertility or the unborn child. May cause harm to breast-
fed children.
Components contributing to classification: Xylene. Ethyl benzene. Zinc compound. Toluene.

12. ECOLOGICAL INFORMATION

ECOTOXICITY:
Chemical Name Ecotoxicity
Xylene Fish: Pimephales promelas 13.4 mg/l96 h flow-through
Oncorhynchus mykiss 2.661 - 4.093 mg/l96 h Static
Oncorhynchus mykiss 13.5 - 17.3 mg/l96 h
Lepomis macrochirus 13.1 - 16.5 mg/l96 h flow-through
Lepomis macrochirus 19 mg/l96 h
Lepomis macrochirus 7.711 - 9.591 mg/l96 h Static
Pimephales promelas 23.53 - 29.97 mg/l96 h Static
Cyprinus carpio 780 mg/l96 h semi-static
Cyprinus carpio > 780 mg/l96 h
Poecilia reticulata 30.26 - 40.75 mg/l96 h Static
Invertebrates: water flea 3.82 mg/l48 h
Gammarus lacustris 0.6 mg/l48 h

Ethyl benzene Fish: Oncorhynchus mykiss 11.0 - 18.0 mg/l96 h Static


Oncorhynchus mykiss 4.2 mg/l96 h semi-static
Pimephales promelas 7.55 - 11 mg/l96 h flow-through
Lepomis macrochirus 32 mg/l96 h Static
Pimephales promelas 9.1 - 15.6 mg/l96 h Static
Poecilia reticulata 9.6 mg/l96 h Static
Invertebrates: Daphnia magna 1.8 - 2.4 mg/l48 h
Plants: Pseudokirchneriella subcapitata 4.6 mg/l72 h
Pseudokirchneriella subcapitata > 438 mg/l96 h
Pseudokirchneriella subcapitata 2.6 - 11.3 mg/l72 h Static
Pseudokirchneriella subcapitata 1.7 - 7.6 mg/l96 h Static

Nitrogen substituted aromatic N.D.


Carbon black N.D.
Zinc compound N.D.
Imide Invertebrates: Daphnia magna (Water flea) 31.6 mg/l48 h

Toluene Fish: Pimephales promelas 15.22 - 19.05 mg/l96 h flow-through


Pimephales promelas 12.6 mg/l96 h Static

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Product: CHEMLOK 6108, Effective Date: 02/05/2020

Oncorhynchus mykiss 5.89 - 7.81 mg/l96 h flow-through


Oncorhynchus mykiss 14.1 - 17.16 mg/l96 h Static
Oncorhynchus mykiss 5.8 mg/l96 h semi-static
Lepomis macrochirus 11.0 - 15.0 mg/l96 h Static
Oryzias latipes 54 mg/l96 h Static
Poecilia reticulata 28.2 mg/l96 h semi-static
Poecilia reticulata 50.87 - 70.34 mg/l96 h Static
Invertebrates: Daphnia magna 5.46 - 9.83 mg/l48 h Static
Daphnia magna 11.5 mg/l48 h
Plants: Pseudokirchneriella subcapitata > 433 mg/l96 h
Pseudokirchneriella subcapitata 12.5 mg/l72 h Static

PERSISTENCE AND DEGRADABILITY: Not determined for this product.

BIOACCUMULATIVE: Not determined for this product.

MOBILITY IN SOIL: Not determined for this product.

OTHER ADVERSE EFFECTS: Not determined for this product.

13. DISPOSAL CONSIDERATIONS

DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local
environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and
disposal facility. Waste streams, including the dried adhesive residue, resulting from the use of this product should be tested
for RCRA characteristics, including ignitability, to determine any applicable waste classifications.

14. TRANSPORT INFORMATION

US DOT Road
Proper Shipping Name: Adhesives
Hazard Class: 3
SECONDARY HAZARD: None
UN/NA Number: 1133
Packing Group: III
Emergency Response Guide Number: 128

IATA Cargo
PROPER SHIPPING NAME: Adhesives
Hazard Class: 3
HAZARD CLASS: None
UN NUMBER: 1133
PACKING GROUP: III
EMS: 3L

IMDG
PROPER SHIPPING NAME: Adhesives
Hazard Class: 3
HAZARD CLASS: None
UN NUMBER: 1133
PACKING GROUP: III
EMS: F-E

The listed transportation classification applies to non-bulk shipments. It does not address regulatory variations due to
changes in package size, mode of shipment or other regulatory descriptors. For the most accurate shipping information,
refer to your transportation/compliance department.

15. REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS: AS FOLLOWS:

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Product: CHEMLOK 6108, Effective Date: 02/05/2020

SARA SECTION 313


This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372.:
Chemical Name CAS Number Weight % Less Than
Xylene 1330-20-7 65.0 %
Ethyl benzene 100-41-4 15.0 %
Zinc compound PROPRIETARY 5.0 %
Toluene 108-88-3 0.9 %

TOXIC SUBSTANCES CONTROL ACT:

INVENTORY STATUS
The chemical substances in this product are on the TSCA Section 8 Inventory.

EXPORT NOTIFICATION
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
None

16. OTHER INFORMATION

Under HazCom 2012 it is optional to continue using the HMIS rating system. It is important to ensure employees have
been trained to recognize the different numeric ratings associated with the HazCom 2012 and HMIS schemes.
HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 3 PHYSICAL HAZARD: 0
* - Indicates a chronic hazard; see Section 2

Revision: Section 2, Section 3, Section 8, Section 11, Section 12

Effective Date: 02/05/2020

DISCLAIMER

The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of
handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by
use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and
regulations.

Page: 8

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