DPP - Daily Practice Problems

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CHEMISTRY SYLLABUS : Hydrocarbons-3-(Aikynes)

[2 7]
Max. Marks : 120 Time : 60 min.
GENERAL INSTRUCTIONS
•
The Daily Practice Problem Sheet contains 30 MCQ's. For each question only one option is correct. Darken the correct drcle/
bubble in the Response Grid provided on each page.
•
You have to evaluate your Response Grids yourself with the help of solution booklet.
•
Each correct answer will get you 4 marks and 1 mark shall be deduced for each incorrect answer. No mark will be given/ deducted
if no bubble is filled. Keep a timer in front of you and stop immediately at the end of 60 min.
• The sheet follows a particular syllabus. Do not attempt the sheet before you have completed your preparation for that syllabus.
Refer syllabus sheet in the starting of the book for the syllabus of all the DPP sheets.
• After completing the sheet check your answers with the solution booklet and complete the Result Grid. Finally spend time to
analyse your performance and revise the areas which emerge out as weak in your evaluation.

DIRECTIONS (Q.1-Q.21) : There are 21 multiple choice Q.3 Chloroform is heated with Ag powder in laboratory what
questions. Each question has 4 choices (a), (b), (c) and (d), will be the product ?
out of which ONLY ONE choice is correct. (a) Acetylene (b) AgzO
Q.l The product formed by the addi ti on ofHBr to propyne in (c) CH2CI2 (d) CH4
the presence of �02 is - Q.4 What happens when 2- butyne reacts with Hz in presence
(a) CH3CH2CH -Br (b) CH2 - CH2 -CH2 ofLiAIH4 ?
I I I (a) CH3 -C-H
Br Br Br II
(c) CH3 -CH-Br (d) All of these CH3 -C-H
I (b) CH3 - C - H
CH2Br
II
Q.2 On passing vinyl acetylene into cone.
HCI in the presence H -C-CH3
of cuprous and ammonium chlorides, the following is (c) CH3 - CHz- CHz- CH3
produced- (d) CH2 = C H
(a) Neoprene (b) Isoprene I
(c) Chloroprene (d) None of these CH=CH2

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Q.5 What happens when 2- butyne reacts with N a+ Liq. NH3 ? CH
(a) CH3 - C -H (b) CH3 - C - H
Q.12 Ill reacts with acetic acid in presence ofHg2+ to give :
II II CH
CH3 - C - H H - C - CH3
(a) CH3
=f H
(b) CH (CH 3 COO )2
(c) CH3-C�-C�-CH3 (d) I I
CH2

CH = CH2
CH(CH3C00h CH(CH 3 C00h
Q.6 What happens when 2- butyne reacts with� in presence (c) CH3 (d) none of the above
ofNickle boride or Lindlar's catalyst (Pd/CaC03-PbO) ?
�
I
(a) CH3 - -H (b) CH3 - TI - H CH2CCH3COO)
Q.13 What is the chief product of reaction between �-butylene
CH3 - C - H H - C - CH3 chloride and ale. KOH/Na� ?
(c) CH3 - C�-C�-C�(d) CH2 = C H (a) 1 ,2-butadieoe (b) I ,3-butadiene
I (c) 2-butyne (d) 1-butyne
CH=CH2 Q.14 Acetylene magnesium chloride reacts with ethyl bromide,
Q.7 What will be the product ofchlorine water and acetylene ? what will be the product ?
(a) Dichloropropanol (b) Dichloroethanal (a) 1-butyne (b) 2-butyne
(c) Propanol (d) 2-Chloroethanol (c) 1,2-butadiene (d) 1 ,3-butadiene
2 Q.l5 When sodium fumarate is electrolysed, which alkyne is
Q.8 CH3 - C = CH + dil. �SO4 + Hg+ �X, what is the 'X' ?
formed at anode?
(a) Acetal (a) Propyne (b) Butyne (c) Ethyne (d) None
(b) Acetone Q.16 Order of acidity of �0, NH3 and acetylene is­
(c) Butanone (a) NH3 > CH= CH > �0
(d) Propylidine hydrogen sulphate (b) �O>NH3>HC=CH
Q.9 Product formed by the oxidation of acetylene in the (c) �O > HC = CH> NH3
presence of alkaline KMn04 is (d) NH3 > �0 > HC =CH
Q.17 Westrosol has the following formula
(a) Glyoxal (b) Oxyrane
(c) C02 + �0 (d) Oxalic acid (a) CHC12 (b) CHC1 2
I I
Q.lO When acetylene and sulphur react in the presence of hot
CHC 12 CH2Cl
iron pyrite, product formed is
(a) Pyrrole (b) Benzene (c) CHCI (d) CHCl
(c) Toluene (d) Thiophene II II
CHCI CC12
Q.ll The product ofreaction between one mole ofacetylene and
two moles ofHCHO in the presence ofCu is - Q.18 CH = CCOOH Product is
(a) HOC�-C=C-Cf40H (a) CH2 = C - COOH (b) CH3-C�OOH
(b) �C=CH-C=C-�OH I II
(c) HC = C-C�OH OH 0
(d) None of these (c) OHC-C�-COOH (d) OH-CH=CH-COOH

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Q.19 When acetylene is passed into methanol at 160-200°C in the Q.24 In the given reaction
presence ofa small amount ofpotassium methoxide under (OJ
A B
pressure, the following is formed-
(a) Polyvinyl alcohol (b) Divinyl ether Which are correct ?
(c) Dimethyl etJ1er (d) Methyl vinyl ether (l) A = Acetaldehyde (2) B = aceti·c acid
(3) A = Acetone (4) B = ethyl alcohol
Q.20 Acetylene and ethylene react with alk KMn04 to give
respectively DIRECTIONS (Q.25-Q.27) : Read the passage given below and
(a) Oxalic acid and formic acid answer the questions that follows :
(b) Acetic acid and ethylene glycol
Acetylene and other terminal alkynes ( 1-alk:ynes) are weakly acidic
(c) Ethyl alcohol and ethylene glycol in character. The acetylenic hydrogen of such alkynes can be
(d) None replaced by copper ( 1) and silver (I) ions. They react with
Q.21 Which is the most suitable reagent among the following to ammonical solutions ofcuprous chloride and silver nitrate to form
the corresponding copper and silver alkyuides.
distinguish compOtmd (3) from the rest ofthe compounds?
Docopper acetytide (Red pp1)
(I) CH3C =CCH3 (2) CH3 C�-C�CH3 CH=CH+2([Cu(NH3h]Cl---t Cu-C=C-Cu +
(3) CH3CHzC=CH (4) CH3CH=CHz
2NH4Cl + 2NH3
(a) Br in CC14 (b) Br in CH3COOH
2 2
(c) Alkaline K.Mn04 (d) Tollen's reagent CH = CH +2[Ag(NH3)2]N03 ---1 Ag- C = C -Ag +
Oisitver acetylide (while ppl)

DIRECTIONS (Q.22-Q.24) : In the following questions, more 2NH4N03

than one of tbe answers given are correct. Select the correct This reaction can be used to distinguish between 2-alkynes and
answe.-s and mark it according to tbe following codes: 1 -a1kynes. 1-Aikynes will give this test while 2-alkynes, will not
Codes : give this test.
(a) l , 2 and 3 are correct (b) I and 2 are correct Q.25 Which of the following acid is dibasic ?
(c) 2 and 4 are correct (d) 1 and 3 are correct
(a) CH3- CH = CH-CH3 (b) (CH3)2C = CH2
(c) CH3- C = CH (d) CH = CH
Q.22 The triply bonded carbon atoms -
Q.26 Acetylenic hydrocarbons are acidic because-
(I) Are sp hybridised (a) Sigma electron density of C - H bond in acetylene
3
(2) Are sp hybridised is nearer a carbon which bas 50% s-cbaracter
(3) Have two pi bonds and one sigma bonds (b) Acetylene has only one hydrogen atom at each carbon
(4) Have three sigma bonds and one pi bond atom
(c) Acetylene contains least number of hydrogen atoms
Q.23 Acetylene can be prepared from -
among the possible acetylenic hydrocarbons
(l) Potassium ftunarate (2) Calcium carbide (d) Acetylene belongs to the class ofalkynes with formula
(3) Ethylene bromide (4) Aluminium carbide en �n - 2

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Q.27 Acetylene gives - (c) Statement-! is false, Statement-2 is True.
(a) White ppt with AgN03 and red ppt with Cu2Cl2 (d) Statement- I is True, Statement-2 is False.
(b) White ppt with C�Cl2 and red ppt with AgN03 28. Statement 1 : Acetylene racts with sodamide to evolve �
(c) White ppt with both gas.
(d) Red ppt with both Statement-2 Acetylene is a weaker acid than ammonia.
:

DIRECTIONS (Q. 28-Q.30) : Each of these questions contains 29. Statement-I : The reaction rates ofalkynes with electrophiles
two statements: Statement-! (Assertion) and Statement-2 are slower than those of allcenes.
(Reason). Each ofthese questions has four alternative choices, Statcmcnt-2 : The steric and electronic factors play their
only one of which is the correct answer. You have to select the part in diminishing the reactivity of al kynes towards
correct choice.
electrophiles.
(a) Statement-! is True, Statement-2 is True; Statement-2 is a
30. Statement-I : 1-Alkynes are considered as weak acids.
correct explanation for Statement-1.
(b) Statement-! is True, Statement-2 is True; Statement-2 is NOT Statement-I : Hydrogen atom attached to the triply bonded
a correct explanation for Statement- ! . carbon atom can be easily removed by strong base.

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DAILY P RACTICE PROBLEM SHEET 27 - CHEMISTRY

Tota l Questions 30 Tota l Marks 120
Attempted Correct
Incorrect Net Score
Cut-off Score 32 Qual ifying Score 56
Success Gap = Net Score - Qual ifying Score
N et Score = (Correct x 4} - ( Incorrect x 1)

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DPP/ C ( 27 ) ------� s7
DAILY PRACTICE
PROBLEMS
CH EMISTRY
SOLUTIONS (2 7)
(I ) (c) The product fonned by the addition ofHBr to propyne (10) (d) In the presence ofhot iron pyrite, thiophene is formed
in the presence ofHz02 is C�CH(Br)CJ-l2Br, contrary as a product, when NH3 is taken in place of sulphur,
to Markownikoffs rule. pyrrole is formed.
Cu

CH3-C=CH HBr
CH3-CH=CHBr (11) (a) CH2 =0+ H - C = C - H + CH2=0 ---- ---7

Peroxide HOCHz - C = C -CHpH

2-butyne- 1,4 diol.
CH3 - CHIBr
HBr CH
1 (12) (a) Ill +CH3COOH
Peroxide
CH
CH2Br CH 2
CH3COOH
(2) (c) On passing vinyl acetylene into cone. HCI in the II
Hg2+
presence of cuprous and ammounium chlorides,
chloroprene is formed and the reaction proceeds by
(13) (c) 2-Butyne is the chiefproduct according to Saytzeft's
I , 4-addition followed by rearrangement under the rule.
influence of the cataiyst. CH3CH(CI)CH(CI)CH3 �CH3C = CCH3
C� = CH-C CH + HCI � [CHzCI-CH=C = CHz]
=
(14) (a) HC = C-MgCI + C2H5 Br -------7
�CHz= C -CH=CHz HC = C-C2H5 + Mg (Cl) Br
I ( 15) (c) In Kolbe's synthesis, sodium or potassium salt of
Cl maleic acid or fumaric acid on electrolysis gives
Chloroprene (2-chlorobuta-1, 3-dienc) acetylene or ethyne at anode.
HCC13 + 6Ag + Cl3HC ---,--- � HC = CH
---:-:- �0, NH3
6 A gCI
H-
{3) {a) -
(16) (c) The order of acidity of and acetylene
acetylene depends upon the relative basicity ofOH, N 2 and
HC = c-. The decreasing nature ofbasic character is
(4) (b) 2-Butyne mainly forms trans-2-butene on
NHz >HC= C > OH-, hence the decreasing order of
- -
hydrogenation with LiAlfl.t.
acidity is �0 HC CH NH3.
> = >
(5) (b) Reaction is called as 'Birch reduction'. (17) (d) Acetylene adds up two molecules of chlorine to give
(6) {a) 2-Butyne forms cis-2.-butene with Lindlar's catalyst. tertachloroethane, known as westron industrially. This
(7) (b) Chlorine water (HO 0 -CIEB) reacts with acetylene on dehydrochlorination with lime water gives
tricihloroethene, commerically called westrosol
and gives dichloroethanal
Cl Cl-C-H
OH H-C H-C-Cl
I II
H�c e G:l
+ H O - CI� I
H-C Ill +2Cl2 � I
Lime water
-HCI
CI-C-CI
Ill
I-1 - C II H-C H-C -CI
H-C I
Cl
Trichloroethene

I (Westrosol)
Cl Westron

(18) (c) CH=C-7-COOH H+ -ow

e G:l
OH H -C = O �H-COOH -GHC-CH2-COOH
HO-C! I
H-C-OH �
I
H-C -Cl T
-H20 OH(Enol form) (Keto fom1)
I I
H -C-C I (19) (d) When acetylene is passed into methanol at 160-200°C
in the presence ofa small amount ( 1 -2%) ofpotassium
Cl
I
Cl methoxide and under pressure just high enough to
prevent boiling, methyl vinyl ether is fonned.
(8) (b) In dil �S04alkyne is hydrolysed tQ form ketone, The mechanism is believed to involve nucleophi ldic
here acetone will be the main product.
HC CH + CH3 0-� C-H = CH OCH3
attack in the first step.
(9) (d) This is the exceptional case ofO)(idation in which triple =
CHJOH
bonded carbon is not separated. The product is oxalic
acid.
CHz = CHO CH3 + CH30-
Methyl vinyl ether
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58 DPP/ C (27)
(20) (a) Acetylene and ethylene react with alk. KMnO4 to give (25) (d) Acetylene contains two acidic hydrogen atoms.
oxalic acid and formic acid respectively.
(26) (a)
CH COOH
alk. KMn04 (27) (a) AgC = CAg is white and CuC = CCu is red.
Ill +4 [0] I
CH COOH (28) (d)
acetylene oxalic acid (29) (a) The low reactivity of alkynes towards electrophilic
CH2 addition reactions is believed to be due to following
alk. KMn04
II + 4 [0] 2HCOOH two factors.
CH2
(I) The bridged intermediate cation formed by the
ethylene formic acid
initial attack ofelectrophile on the triple bond is
(21) (d) Terminal alkynes (= C-H) give white precipitate with
less stable because it is a highly strained system.
Tollen's reagent (ammoniacal AgN03)
(22) (d) Each triply bonded carbon is sp hybridised & has 2n (2) In acetylenic carbon atoms, the n: electrons are
& l cr bonds. more tightly held by the carbon nuclei and hence
(23) (a) Potassium fumarate on electrolysis, CaC2 on they are less easily available for reaction with
hydrolysis and ethylene bromide on elimination give electrophiles.
acetylene. Aluminium carbide on hydrolysis produces
methane. Thus both the above factors, steric and elctronic,
H2S04 ,HgS04 play their part in diminishing the reactivity of
(24) (b) CH=CH CH3CHO
60°C A
alkynes towards electrophiles.
(30)
� CH3 COOH
(a)
B