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Exercise Thermochem

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Abednego Nugroho
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16 views

Exercise Thermochem

Uploaded by

Abednego Nugroho
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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1A 295 g aluminum engine part at an initial temperature of 3.00°C absorbs 85.0 kJ of heat.

What is the final temperature of the part? ( c of Al = 2.42 J/g * K)

2 A 27.7 g sample of ethylene glycol loses 688 J of heat. What was the initial temperature of the
ethylene glycol if the final temperature is 32.5°C ( c of ethylene glycol = 2.42 J/g *K)

3When 165 mL of water at 22°C is mixed with 85mL of water at 82°C, what is the final
temperature? (assume d of water = 1.00 g/mL)

4An unknown volume of water at 18.2°C is added to 24.4 mL of water at 35.0°C. If the final
temperature is 23.5°C, what was the unknown volume? (assume d of water = 1.00 g/mL)

5A 505 g piece of copper tubing is heated to 99.9°C and placed in an insulated vessel containing
59.8 g of water at 24.8°C. What is the final temperature of the system?

6A 30.5 g sample of an alloy at 93.0°C is placed into 50.0g of water at 22.0°C in insulated coffee
cup. If the final temperature of the system is 31.1°C , what is the specific heat capacity of the
alloy?

7For the following reaction: 1/8 S8 (s) + H2 (g) à H2S (g) ∆H = -20.2 kJ

a. Is this an exothermic or endothermic reaction?


b. What is ∆H for the reverse reaction?
c. What is ∆H when 3.2 mol of S8 reacts?
d. What is ∆H when 20.0g of S8 reacts?

8For the following reaction:

MgCO3(s)→MgO(s)+CO2(g)MgCO3(s)→MgO(s)+CO2(g)

with ∆H = 117.3 kJ

a. Is heat absorbed or released in the reaction?


b. What is ∆H for the reverse reaction?
c. What is ∆H when 5.35 mol of CO2 reacts with excess MgO?
d. What is ∆H when 35.5 g of CO2 reacts with excess MgO?
9. What amount of energy is require to 40.0 grams of liquid water at room
temperature (23.0oC) and change it into 40.0 g of steam at 145.0oC?
Formula q = m C Δ T and q = m H?? and need values for . . .
specific heat(C) Cice= 2.09 J/goC Cliquid= 4.18 J/goC C steam= 1.67 J/goC
and the phase heats (H) Hfus= 6.01 kJ/mol Hvap=40.7 kJ/mol
, 1 calorie is 4.18

10. Ammonia burns in the presence of a platinum catalyst to produce nitric oxide,
NO.
4 NH3 (g) + 5 O2 (g)  4 NO (g) + 6 H2O (g)
What is the heat of reaction at constant pressure? Use the following thermochemical
equations:
N2 (g) + O2 (g)  2 NO (g) H = +180.6 kJ
N2 (g) 3 H2 (g)  2 NH3 (g) H = -191.8 kJ
2 H2 (g) O2 (g)  2 H2O (g) H = -483.7 kJ

11. One liter of water with the temperature of 33oC is heated to 100oC using electric
jug. How log does it take to boil water if the jug uses 2000 Watt electricity. 1
Watts is 1joule/second, 1 calorie is 4.182 joule Cliquid 4.18J/gramoC.
12. Consider the reaction of SO2 + O3 SO3 + O2
o
A rate study of the reaction was conducted at 298 K. The data were obtained and are
shown in the table.

[SO2] (Mol/ L seconds) [O3] Mol/L seconds) Initial rate (mol/ L


seconds)
0.25 0.40 0.118
0.25 0.20 0.118
0.75 0.20 1.062
A) Determine the order of the reaction with respect to SO2 an O3.
B) What is the rate law of this reaction.
C) Can you calculate the value of K?

Given the reaction NO2 +CO NO + CO2

13. The following data were collected. The reaction only depends on NO2.
A) What is the order of the reaction for the disappearance of NO2
B) What is the unit of K (rate constant) an its value
C) Determined the half life (t1/2) of the reaction.

Time [NO2]
(seconds) Mol/Liter
0 0.500
1200 0.444
3000 0.381
4500 340
9000 0250
18000 0.174

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