SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : MasterEmaco N 303 grey
Product code : 000000000051519434
Manufacturer or supplier's details
Company : Master Builders Solutions Saudi Arabia
for Manufacturing LLC.
Address : Dammam 2nd Industrial Area
AL Khobar 31952
Telephone : +966966138121140
Emergency telephone : ChemTel: +1-813-248-0585
Telefax : +966966138121822
Recommended use of the chemical and restrictions on use
Recommended use : Product for construction chemicals
2. HAZARDS IDENTIFICATION
GHS Classification
Skin corrosion/irritation : Category 2
Serious eye damage/eye irri- : Category 1
tation
Specific target organ toxicity - : Category 3 (respiratory tract irritation)
single exposure
GHS label elements
Hazard pictograms :
Signal Word : Danger
Hazard Statements : H318 Causes serious eye damage.
H315 Causes skin irritation.
H335 May cause respiratory irritation.
Precautionary Statements :
Prevention:
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P261 Avoid breathing dust.
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
P264 Wash face, hands and any exposed skin thoroughly after
handling.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physi-
cian.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P332 + P313 If skin irritation occurs: Get medical advice/ atten-
tion.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.
Other hazards which do not result in classification
If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature : modified cement mortar
Components
Chemical name CAS-No. Concentration (%
w/w)
Cement, portland, chemicals 65997-15-1 >= 7 - < 75
Quartz (SiO2) 14808-60-7 >= 0 - < 5
4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.
Do not leave the victim unattended.
If inhaled : If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact : If skin irritation persists, call a physician.
If on skin, rinse well with water.
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
If on clothes, remove clothes.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Most important symptoms : Causes skin irritation.
and effects, both acute and Causes serious eye damage.
delayed May cause respiratory irritation.
Notes to physician : Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Unsuitable extinguishing : High volume water jet
media
Specific hazards during fire : Do not allow run-off from fire fighting to enter drains or water
fighting courses.
Specific extinguishing meth- : Collect contaminated fire extinguishing water separately. This
ods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for fire-fighters essary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- : Use personal protective equipment.
tive equipment and emer- Avoid dust formation.
gency procedures Avoid breathing dust.
Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for : Keep in suitable, closed containers for disposal.
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
containment and cleaning up
7. HANDLING AND STORAGE
Advice on protection against : Avoid dust formation.
fire and explosion Provide appropriate exhaust ventilation at places where dust
is formed.
Advice on safe handling : Avoid formation of respirable particles.
Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Further information on stor- : Containers should be stored tightly sealed in a dry place.
age conditions
Further information on stor- : No decomposition if stored and applied as directed.
age stability
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Breathing protection if dusts are formed.
Filter type : Particle filter with medium efficiency for solid and liquid parti-
cles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection : Choose body protection according to the amount and concen-
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
tration of the dangerous substance at the work place.
Protective measures : Avoid contact with the skin, eyes and clothing.
Avoid inhalation of dusts.
In order to prevent contamination while handling, closed work-
ing clothes and working gloves should be used.
Handle in accordance with good building materials hygiene
and safety practice.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : powder
Color : dark gray
Odor : odorless
Odor Threshold : Not determined due to potential health hazard by inhalation.
pH : alkaline
Melting point : Not applicable
Flash point : Not applicable
Flammability (solid, gas) : not flammable
Self-ignition : not self-igniting
Density : Method: Calculation method
Bulk density : approx. 1.250 - 2.800 kg/m3
Solubility(ies)
Water solubility : slightly soluble
Decomposition temperature : No decomposition if stored and handled as pre-
scribed/indicated.
Viscosity
Viscosity, dynamic : Not applicable
Explosive properties : Not explosive
Not explosive
Oxidizing properties : not fire-propagating
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
Self-heating substances : No data available
Metal corrosion rate : No corrosive effect on metal.
10. STABILITY AND REACTIVITY
Reactivity : No decomposition if stored and applied as directed.
Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous reac- : No decomposition if stored and applied as directed.
tions
Conditions to avoid : See SDS section 7 - Handling and storage.
Incompatible materials : Strong bases
Strong acids
Hazardous decomposition : No hazardous decomposition products if stored and handled
products as prescribed/indicated.
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Product:
Remarks : Chromate in this product has been reduced. Sensitization due
to chromate within stated shelf-live is unlikely.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
STOT-single exposure
May cause respiratory irritation.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information
Product:
Remarks : No data available
12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Ecotoxicology Assessment
Acute aquatic toxicity : This product has no known ecotoxicological effects.
Chronic aquatic toxicity : This product has no known ecotoxicological effects.
Persistence and degradability
Product:
Biodegradability : Remarks: Not applicable for inorganic substances.
Components:
Quartz (SiO2):
Biodegradability : Remarks: Not applicable
Bioaccumulative potential
No data available
Mobility in soil
Product:
Distribution among environ- : Remarks: Following exposure to soil, adsorption to solid soil
mental compartments particles is probable, therefore contamination of groundwater
is not expected.
The substance will not evaporate into the atmosphere from
the water surface.
Other adverse effects
Product:
Results of PBT and vPvB : This substance/mixture contains no components considered
assessment to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
0.1% or higher.
Additional ecological infor- : No data available
mation
13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
16. OTHER INFORMATION
Full text of other abbreviations
AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
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SAFETY DATA SHEET
MasterEmaco N 303 grey
Version Revision Date: SDS Number: Date of last issue: 06.04.2020
1.1 31.12.2020 000000264790 Date of first issue: 06.04.2020
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
formation System
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
UN / EN
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