SDS no.

143225
Version 1
Revision date 21-Mar-2019
Supersedes Date: None

Safety Data Sheet

EB-89052

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name EB-89052

Product code 143225
Country Limitations This SDS is not for use in the European Union (EU).

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Demulsifier

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Kuwait Drilling Fluids & Oil Service S.A.K
Shuaiba Industrial Area
P.O Box 4544 Safat, 13046
Kuwait

1.4 Emergency Telephone Number

Emergency telephone - Kuwait: +965-98003784; +965-97228726; +965-99366703

2. Hazards Identification
2.1 Classification of the substance or mixture

GHS Classification

Health hazards
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Carcinogenicity Category 2
Specific target organ toxicity - Single exposure Category 3

Environmental hazards
Chronic aquatic toxicity Category 2

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Physical Hazards Not classified

2.2 Label elements

Signal word
WARNING

Hazard Statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
H351 - Suspected of causing cancer
H411 - Toxic to aquatic life with long lasting effects

Precautionary statements
P201 - Obtain special instructions before use
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Supplementary precautionary statements

P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P337 + P313 - If eye irritation persists: Get medical advice/attention
P362 + P364 - Take off contaminated clothing and wash it before reuse
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Contains
Hydrocarbons, C10-C13, aromatics, >1% Naphthalene*

Hydrocarbons C10 aromatics> 1% naphthalene*

Solvent naphtha, petroleum, heavy aromatic

Naphthalene (Impurity)

Benzenesulfonic acid, 4-C10-13-sec-alkyl derivatives

2.3 Other hazards

Not classified as PBT/vPvB by current EU criteria

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Combustible liquid

Repeated exposure may cause skin dryness or cracking

3. Composition/information on Ingredients
3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-%

Hydrocarbons C10 aromatics> 1% naphthalene* 919-284-0 RM1004418 10-30
Hydrocarbons, C10-C13, aromatics, >1% Naphthalene* 926-273-4 RM1004265 10-30
Solvent naphtha, petroleum, heavy aromatic 265-198-5 64742-94-5 5-10

Naphthalene (Impurity) 202-049-5 91-20-3 1-<5

Benzenesulfonic acid, 4-C10-13-sec-alkyl derivatives 287-494-3 85536-14-7 1-<3

Comments
The product contains other ingredients which do not contribute to the overall classification.
*Substances which have an EC Number that begins with the number "9" is a Provisional List Number. The list numbers published
by ECHA do not have any legal significance. The EC substance definition and related classification & labelling has been developed
in the framework of the Regulation (EC) No 1907/2006 (REACH). For information about the related CAS number see section 15 of
this SDS.
The viscosity of this product is high enough that it is not an aspiration risk and the H304 phrase does not apply.
Benzenesulfonic acid, 4-C10-13-sec-alkyl derivatives can use either CAS 85536-14-7, 68584-22-5 or 27176-87-0

4. First Aid Measures

4.1 First aid measures

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If breathing has stopped, begin artificial respiration. Obtain medical
attention.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth
to an unconscious person. Seek medical attention if irritation occurs.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get medical attention if irritation persists.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

General advice The severity of the symptoms described will vary dependant of the concentration and the
length of exposure. If adverse symptoms develop, the casualty should be transferred to
hospital as soon as possible.

Symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

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Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-Fighting Measures

5.1 Extinguishing media

Suitable extinguishing media

Water spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which must not be used for safety reasons

Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

combustible liquid. Vapors are heavier than air and may spread along floors. Vapors may form explosive mixture with air.

Hazardous combustion products

Fire or high temperatures create: Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke).

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up

Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Take precautionary
measures against static discharges. Use non-sparking tools and equipment. After cleaning, flush away traces with water.

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6.4 Reference to other sections

See section 13 for more information.

7. Handling and Storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or
spray mist. Avoid spills and splashing during use.

Hygiene Measures
Use good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face
before breaks and immediately after handling the product Remove contaminated clothing

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Take
precautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid heat, flames
and other sources of ignition. Avoid contact with: Oxidizing agents Strong acids Strong
bases UV or Ionising Radiation.

Storage class Chemical storage.

Packaging materials Use specially constructed containers only.

8. Exposure Controls/Personal Protection

8.1 Control parameters

Exposure limits Hydrocarbons, C10-C13, aromatics, >1% Naphthalene and Hydrocarbons, C10, aromatics,
>1% Naphthalene OEL vapour (Total Hydrocarbons/RCP) – TWA 100 mg/m³ (17ppm)
Above Occupational Exposure Limit (OEL) is a “in-house” calculated value provided from
Suppliers of this component and calculated as per CEFIC/HSPA/UK EH 40 guidelines.

Component Information

Chemical Name Arabic Australia Egypt

Hydrocarbons, C10-C13, aromatics, Not determined Not determined Not determined
>1% Naphthalene*
Hydrocarbons C10 aromatics> 1% Not determined Not determined Not determined
naphthalene*
Solvent naphtha, petroleum, heavy Not determined Not determined Not determined
aromatic
Naphthalene (Impurity) 15 ppm STEL 15ppmSTEL 15 ppm STEL
79 mg/m3 STEL 79mg/m3STEL 79 mg/m3 STEL
10 ppm TWA 10ppmTWA Skin designation
52 mg/m3 TWA 52mg/m3TWA 10 ppm TWA
52 mg/m3 TWA
Benzenesulfonic acid, Not determined Not determined Not determined
4-C10-13-sec-alkyl derivatives
Chemical Name India Indonesian Japan
Hydrocarbons, C10-C13, aromatics, Not determined Not determined Not determined
>1% Naphthalene*
Hydrocarbons C10 aromatics> 1% Not determined Not determined Not determined
naphthalene*
Solvent naphtha, petroleum, heavy Not determined Not determined Not determined

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aromatic
Naphthalene (Impurity) 15 ppm STEL; 75 mg/m3 STEL 10 ppm TWA 10 ppm ACL
10 ppm TWA 15 ppm STEL
50 mg/m3 TWA
Benzenesulfonic acid, Not determined Not determined Not determined
4-C10-13-sec-alkyl derivatives
Chemical Name Kazakhstan Kuwait New Zealand
Hydrocarbons, C10-C13, aromatics, Not determined Not determined Not determined
>1% Naphthalene*
Hydrocarbons C10 aromatics> 1% Not determined Not determined Not determined
naphthalene*
Solvent naphtha, petroleum, heavy Not determined Not determined Not determined
aromatic
Naphthalene (Impurity) 20 mg/m3 MAC 75.0 mg/m3 STEL 15 ppm STEL
15.0 ppm STEL 79 mg/m3 STEL
10 ppm TWA
52 mg/m3 TWA
Benzenesulfonic acid, Not determined Not determined Not determined
4-C10-13-sec-alkyl derivatives
Chemical Name Malaysia Philippines Russia
Hydrocarbons, C10-C13, aromatics, Not determined Not determined Not determined
>1% Naphthalene*
Hydrocarbons C10 aromatics> 1% Not determined Not determined Not determined
naphthalene*
Solvent naphtha, petroleum, heavy Not determined Not determined Not determined
aromatic
Naphthalene (Impurity) 10 ppm TWA 10 ppm TWA 20 mg/m3 MAC
52 mg/m3 TWA 50 mg/m3 TWA
Benzenesulfonic acid, Not determined Not determined Not determined
4-C10-13-sec-alkyl derivatives
Chemical Name Thailand Vietnam Turkey
Hydrocarbons, C10-C13, aromatics, Not determined Not determined Not determined
>1% Naphthalene*
Hydrocarbons C10 aromatics> 1% Not determined Not determined Not determined
naphthalene*
Solvent naphtha, petroleum, heavy Not determined Not determined Not determined
aromatic
Naphthalene (Impurity) Not determined 40 mg/m3 TWA 10 ppm TWA
75 mg/m3 STEL 50 mg/m3 TWA
Benzenesulfonic acid, Not determined Not determined Not determined
4-C10-13-sec-alkyl derivatives

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering Controls
Ensure adequate ventilation Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into
work environment.

Personal protective equipment

Eye protection Use eye protection according to EN 166, designed to protect against liquid splashes Tightly
fitting safety goggles Safety glasses with side-shields
Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training
Use protective gloves made of: Viton
Break through time >480 minutes
Glove thickness 0.71 mm
Be aware that liquid may penetrate the gloves. Frequent change is advisable.

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Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment When workers are
facing concentrations above the exposure limit they must use appropriate certified
respirators Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At
work in confined or poorly ventilated spaces, respiratory protection with air supply must be
used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the
work place.

Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing
before re-use

8.2.3 Environmental exposure controls

Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more
information

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Clear
Odor No information available
Color Amber
Odor threshold Not applicable

Property Values Remarks

pH No information available
pH @ dilution No info available
Melting / freezing point No information available
Boiling point/range No information available
Flash point 68 °C / 154.4 °F ASTM D 93-11
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Insoluble in water
Solubility in other solvents Oil soluble.
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity 32.09 mm2/s @ 40 °C
Dynamic viscosity 31.08 cPs @ 40 °C
log Pow No information available

Explosive properties Vapours may form explosive mixtures with air

Oxidizing properties None known.

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9.2 Other information

Pour point -15°C / 5°F
Molecular weight No information available
VOC content(%) None
Density 0.9833 ± 0.03 g/ml @ 20°C

Comments
The data listed above are typical physical and chemical properties and should not be construed as product specification.

10. Stability and Reactivity

10.1 Reactivity

Combustible liquid.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Hazardous polymerization does not occur.

10.4 Conditions to avoid

Avoid heat, flames and other sources of ignition. Take precautionary measures against static charges.

10.5 Incompatible materials

Oxidizing agents. Strong acids. Strong bases. UV or Ionising Radiation.

10.6 Hazardous decomposition products

See Section 5.2.

11. Toxicological Information

11.1 Information on toxicological effects

Acute toxicity

Product information Prolonged and repeated contact with solvents over a long period may lead to permanent
health problems.

Inhalation Vapors may irritate throat and respiratory system. May cause drowsiness or dizziness.

Eye contact Causes serious eye irritation.

Skin contact Causes skin irritation. Repeated exposure may cause skin dryness or cracking.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause
additional affects as listed under "Inhalation".

Unknown acute toxicity Not applicable.

Toxicology data for the components

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Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Hydrocarbons, C10-C13, aromatics, >1% No data available No data available No data available
Naphthalene*
Hydrocarbons C10 aromatics> 1% naphthalene* > 5000 mg/kg rat > 2000 mg/kg Rabbit > 4688 mg/m³ Rat
Solvent naphtha, petroleum, heavy aromatic > 5000 mg/kg ( Rat ) > 2 mL/kg ( Rabbit ) > 590 mg/m3 ( Rat ) 4 h
Naphthalene (Impurity) = 1110 mg/kg ( Rat ) = 490 > 20 g/kg ( Rabbit ) = 1120 > 340 mg/m3 ( Rat ) 1 h
mg/kg ( Rat ) mg/kg ( Rabbit )
Benzenesulfonic acid, 4-C10-13-sec-alkyl > 300 - 2000 mg/kg (Rat) > 2000 mg/kg (Rat) No data available
derivatives

Sensitization This product does not contain any components suspected to be sensitizing.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity Contains a known or suspected carcinogen.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of Exposure Skin contact. Eye contact. Inhalation.

Routes of entry Skin contact. Eye contact. Inhalation. Ingestion.

Specific target organ toxicity - Category 3

Single exposure
Specific target organ toxicity - Not classified.
Repeated exposure

Target organ effects Central nervous system.

Aspiration hazard The viscosity of this product is high enough that it is not an aspiration risk and the H304
phrase does not apply.

Other information Key literature references and sources for data. See Section 16 for more information.

12. Ecological Information

12.1 Toxicity

Toxic to aquatic life with long lasting effects

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Toxicology data for the components

Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Hydrocarbons, C10-C13, aromatics, 3.0 mg/l LL50 rainbow trout No information available 1.1 mg/l EL50 water flea (Daphnia
>1% Naphthalene* (Oncorhynchus mykiss) 96 h (ECHA magna) 48 h (ECHA Data)
data) 361 mg/l EC50 Skeletonema 72 h
> 1000 mg/l LC50 Scopthalmus (SLB Data)
Maximus 96h (SLB Data)

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Hydrocarbons C10 aromatics> 1% 2-5 mg/l LC 50 (96h) 3-10 mg/l EC 50 (48h) 11 mg/l EC50 (72h)
naphthalene*
Solvent naphtha, petroleum, heavy = 45 mg/L LC50 Pimephales = 2.5 mg/L EC50 Skeletonema = 0.95 mg/L EC50 Daphnia magna
aromatic promelas 96 h = 1740 mg/L LC50 costatum 72 h 48 h
Lepomis macrochirus 96 h = 41
mg/L LC50 Pimephales promelas
96 h = 2.34 mg/L LC50
Oncorhynchus mykiss 96 h = 19
mg/L LC50 Pimephales promelas
96 h
Naphthalene (Impurity) = 31.0265 mg/L LC50 Lepomis = 0.4 mg/L EC50 Skeletonema = 2.16 mg/L LC50 Daphnia magna
macrochirus 96 h 0.91 - 2.82 mg/L costatum 72 h 48 h = 1.96 mg/L EC50 Daphnia
LC50 Oncorhynchus mykiss 96 h = magna 48 h 1.09 - 3.4 mg/L EC50
1.6 mg/L LC50 Oncorhynchus Daphnia magna 48 h
mykiss 96 h 5.74 - 6.44 mg/L LC50
Pimephales promelas 96 h = 1.99
mg/L LC50 Pimephales promelas
96 h
Benzenesulfonic acid, > 1 - 10 mg/L LC50 Lepomis = 36 mg/L EC50 Desmodesmus > 1 - 10 mg/L EC50 Daphnia magna
4-C10-13-sec-alkyl derivatives macrochirus (Bluegill sunfish) 96h subspicatus 72 h 48h

12.2 Persistence and degradability

See component information below.

Chemical Name Persistence and degradability

Hydrocarbons, C10-C13, aromatics, >1% Readily biodegradable
Naphthalene*
Hydrocarbons C10 aromatics> 1% Inherently biodegradable, fulfilling criteria
naphthalene*
Solvent naphtha, petroleum, heavy Inherently biodegradable, not fulfilling criteria
aromatic
Naphthalene (Impurity) Readily biodegradable
Benzenesulfonic acid, 4-C10-13-sec-alkyl Readily biodegradable
derivatives

12.3 Bioaccumulative potential

See component information below.

Chemical Name Bioaccumulation

Hydrocarbons, C10-C13, aromatics, >1% No information available
Naphthalene*
Hydrocarbons C10 aromatics> 1% Does not bioaccumulate
naphthalene*
Solvent naphtha, petroleum, heavy Material may have some potential to bioaccumulate
aromatic
Naphthalene (Impurity) Not likely to bioaccumulate
Benzenesulfonic acid, 4-C10-13-sec-alkyl Material may have some potential to bioaccumulate
derivatives

12.4 Mobility

Mobility
See component information below.

Chemical Name Mobility

Hydrocarbons, C10-C13, aromatics, >1% Insoluble in water
Naphthalene*

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Hydrocarbons C10 aromatics> 1% Practically insoluble

naphthalene*
Solvent naphtha, petroleum, heavy Insoluble in water
aromatic
Naphthalene (Impurity) Practically insoluble
Benzenesulfonic acid, 4-C10-13-sec-alkyl Miscible in water
derivatives

Mobility in soil
See component information below.

Chemical Name Mobility in soil

Hydrocarbons, C10-C13, aromatics, >1% Not expected to adsorb on soil
Naphthalene*
Hydrocarbons C10 aromatics> 1% After release, adsorbs onto soil
naphthalene*
Solvent naphtha, petroleum, heavy After release, adsorbs onto soil
aromatic
Naphthalene (Impurity) Adsorbs on soil
Benzenesulfonic acid, 4-C10-13-sec-alkyl No information available
derivatives

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

12.7 Other information

Key literature references and sources for data. See Section 16 for more information.

13. Disposal considerations

13.1 Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations.

products

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

14. Transport information

14.1. UN number

UN/ID No. (ADR/RID/ADN/ADG) UN3082

UN No. (IMDG/ANTAQ) UN3082
UN No. (ICAO/ANAC) UN3082

14.2. UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hydrocarbons, C10-C13, aromatics, >1% naphthalene)

14.3 Hazard class(es)

ADR/RID/ADN/ADG Hazard class 9

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IMDG/ANTAQ Hazard class 9

ICAO/ANAC Hazard class/division 9

14.4 Packing group

ADR/RID/ADN/ADG Packing group III
IMDG/ANTAQ Packing group III
ICAO/ANAC Packing group III

14.5 Environmental hazard

Yes

14.6 Special precautions

Hazard identification no (ADR) 90

EmS (IMDG) F-A, S-F
Emergency Action Code (EAC) •3Z
Tunnel restriction code (E)

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC Code
Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This safety data sheet complies with the requirements of:

The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

Australian Standard for the Uniform Scheduling of Drugs and Poisons

Solvent naphtha, petroleum, heavy aromatic

Schedule 7
Naphthalene (Impurity)
Schedule 6

International inventories

USA (TSCA) Complies

Canada (DSL) Complies
Philippines (PICCS) Does not comply
Japan (ENCS) Does not comply
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies

This SDS is not for use in the European Union (EU).

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CAS Number 64742-94-5 can be used to identify the substance given a list number in section 3 in areas not subject to the REACH
regulation.

16. Other Information

Prepared by Kuwait Drilling Fluids & Oil Services S.A.K.C

Revision date 21-Mar-2019

Version 1

This SDS has been revised in the New issue.

following section(s)

Key literature references and sources for data

www.ChemADVISOR.com
Supplier
National Chemical Inventories
National regulatory information
National occupational exposure limits

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS
information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate
agreement between the parties.
This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

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SDS no. PID17519KW
Version 6
Revision date 08-May-2019
Supersedes date 29-Dec-2016

Safety Data Sheet

SI-4583

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name SI-4583

Product code PID17519KW
Country Limitations This SDS is not for use in the European Union (EU).

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Scale Inhibitor.

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Kuwait Drilling Fluids & Oil Service S.A.K
Shuaiba Industrial Area
P.O Box 4544 Safat, 13046
Kuwait

[email protected]
1.4 Emergency Telephone Number

Emergency telephone - Kuwait: Talal Dardari +965-98003784; Sudhir Kumar +965-97228726; Hani Al-Aradi +965-97235102;
Mohammed A. Yassien +965-99366703

2. Hazards identification
2.1 Classification of the substance or mixture

Classification according to (EC) No. 1272/2008

Health hazards
Serious eye damage/eye irritation Category 1

Environmental hazards Not classified

Physical Hazards Not classified

2.2 Label elements

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

Signal word
DANGER

Hazard statements
H318 - Causes serious eye damage

Precautionary Statements - EU (§28, 1272/2008)

P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/ physician

Contains
Etidronic acid

2.3 Other data

Not classified as PBT/vPvB by current EU criteria

3. Composition/information on ingredients
3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC-No. CAS No Weight-% Classification Classification (Reg. REACH

(67/548) 1272/2008) registration
number
Etidronic acid 220-552-8 2809-21-4 1-5 Xn; R22 Met.Corr.1(H290) No data available
Xi; R41 Acute Tox.4(H302)
Eye Dam.1(H318)

Comments
The product contains other ingredients which do not contribute to the overall classification.

4. First aid measures

4.1 First-Aid Measures

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by
mouth to an unconscious person. Get medical attention if symptoms occur.

Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.

Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses.
Continue to rinse for at least 15 minutes. Seek medical attention at once.

4.2 Most important symptoms and effects, both acute and delayed

General advice The severity of the symptoms described will vary dependant of the concentration and the
length of exposure. If adverse symptoms develop, the casualty should be transferred to
hospital as soon as possible.

Main symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Treat symptomatically.
Notes to physician

5. Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Water spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which must not be used for safety

reasons None known.

5.2 Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

Heating of containers may cause pressure rise, with risk of bursting.

Hazardous combustion products

Fire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Oxides of phosphorus, Phosphines.

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental release measures

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6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up

Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush
away traces with water.

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors
or spray mist. Avoid spills and splashing during use.

Safe handling instructions

Use good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and
face before breaks and immediately after handling the product Avoid contact with skin, eyes and clothing.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
direct sunlight. Avoid contact with: Alkalis Oxidizing agents Acids Metals

Storage class Packaging Chemical storage.

materials Use specially constructed containers only.

7.3 Specific end uses

See Section 1.2.

8. Exposure controls/personal protection

8.1 Control parameters

Chemical Name EU OEL Austria Australia Denmark

Etidronic acid Not determined Not determined Not determined Not determined
Chemical Name Malaysia France Germany Hungary
Etidronic acid Not determined Not determined Not determined Not determined

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Chemical Name New Zealand Italy Netherlands Norway

Etidronic acid Not determined Not determined Not determined Not determined
Chemical Name Poland Portugal Romania Russia
Etidronic acid Not determined Not determined Not determined 2 mg/m3 MAC
Chemical Name Spain Switzerland Turkey UK
Etidronic acid Not determined Not determined Not determined Not determined

Predicted No Effect Concentration (PNEC)

Etidronic acid
Fresh water 0.136 mg/L
Sea water 0.014 mg/L
Fresh water sediment 59 mg/kg
Sea sediment 5.9 mg/kg
Soil 96 mg/kg
Impact on sewage treatment 20 mg/L
8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the
chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional
hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory
protection will vary from workplace to workplace and should be assessed by the user in each situation.

Engineering measures to reduce exposure

Ensure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.

Personal protective equipment

Eye protection Tightly fitting safety goggles. Safety glasses with side-shields.
Hand protection Use protective gloves made of: Neoprene Nitrile PVC Be aware that liquid may penetrate
the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient
ventilation wear suitable respiratory equipment, Respirator with combination filter for
vapor/particulate, Type A/P2, At work in confined or poorly ventilated spaces, respiratory
protection with air supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at
the work place.

Safe handling instructions Wash hands before eating, drinking or smoking, Remove and wash contaminated
clothing before re-use.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance No information available
Odor Odorless
Color Light yellow
Odor threshold Not applicable

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Property Values Remarks

pH 4.5 - 5.0
pH @ dilution
Melting / freezing point < -6 °C / 21.2 °F
Boiling point/range No information available
Flash point No information available
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
log Pow Not determined

Explosive properties Not applicable

Oxidizing properties None known.

9.2 Other information

Pour point No information available
Molecular weight No information available
VOC content(%) None
Density 1.00 - 1.15 g/ml @ 20°C

10. Stability and reactivity

10.1 Reactivity

No specific reactivity hazards associated with this product.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Not known.

10.4 Conditions to avoid

Keep away from direct sunlight.

10.5 Incompatible materials

Alkalis. Oxidizing agents. Acids. Metals.

10.6 Hazardous decomposition products

See Section 5.2.

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11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.

Eye contact Causes serious eye damage.

Skin contact Prolonged contact may cause redness and irritation.

Ingestion Ingestion may cause stomach discomfort.

Unknown acute toxicity Not applicable.

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Etidronic acid = 2400 mg/kg ( Rat ) > 7940 mg/kg ( Rabbit ) No data available

Sensitization This product does not contain any components suspected to be sensitizing.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity This product does not contain any known or suspected carcinogens.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of exposure Eye contact.

Routes of entry No route of entry noted.

Specific target organ toxicity (single Not classified

exposure)
Specific target organ
toxicity (repeated exposure)

Aspiration hazard

12. Ecological information

12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that
large or frequent spills can have a harmful or damaging effect on the environment.
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.

Toxicity to algae
This product is not considered toxic to algae.

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Toxicity to fish
This product is not considered toxic to fish.

Toxicity to daphnia and other aquatic invertebrates

This product is not considered toxic to invertebrates.

Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Etidronic acid = 360 mg/L LC50 Oncorhynchus No information available = 527 mg/L EC50 Daphnia magna
mykiss 96 h = 868 mg/L LC50 48 h
Lepomis macrochirus 96 h

12.2 Persistence and degradability

Product is biodegradable.

12.3 Bioaccumulative potential

The product does not contain any substances expected to be bioaccumulating.

12.4 Mobility in soil

Mobility
Soluble in water.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

13. Disposal considerations

13.1 Waste treatment methods

Waste from residues / unused Dispose of in accordance with local regulations.

products

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not product specific, but
application specific Waste codes should be assigned by the user based on the application
for which the product was used. The following Waste Codes are only suggestions: EWC
waste disposal No: 07 01 04 Waste Code: 7152 Organic waste without halogen.

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14. Transport information

14.1. UN number
Not regulated

14.2. UN proper shipping name

The product is not covered by international regulation on the transport of dangerous goods

14.3 Hazard class(es)

ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated

14.4 Packing group

ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated

14.5 Environmental hazard

No

14.6 Special precautions

Not applicable

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC
Code Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Australian Standard for the Uniform Scheduling of Drugs and Poisons

Etidronic acid
Schedule 4
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation
(EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC
and 2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

International inventories

USA (TSCA) Complies

European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies.
Philippines (PICCS) Complies

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Japan (ENCS) Complies

China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies

This SDS is not for use in the European Union (EU).

15.2 Chemical Safety Report

No information available

16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam

Supersedes date 29-Dec-2016

Revision date 08-May-2019

Version 6

This SDS has been revised in the All sections No changes with regard to classification have been made.
following section(s)

Text of R phrases mentioned in Section 3

R22 - Harmful if swallowed
R41 - Risk of serious damage to eyes

Full text of H-Statements referred to under sections 2 and 3

H318 - Causes serious eye damage

H290 - May be corrosive to metals
H302 - Harmful if swallowed

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information,
Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose;
any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
maximum extent permited by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate
agreement between the parties.

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SDS no. PID17550
Version 4
Revision date 17-Apr-2019
Supersedes date 20-Oct-2014

Safety Data Sheet

KI-3978

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name KI-3978

Product code PID17550
Country Limitations This SDS is not for use in the European Union (EU).

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended use Corrosion inhibitor

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Kuwait Drilling Fluids & Oil Service S.A.K
Shuaiba Industrial Area
P.O Box 4544 Safat, 13046
Kuwait

[email protected]
1.4 Emergency Telephone Number

Emergency telephone - Kuwait: Talal Dardari +965-98003784; Sudhir Kumar +965-97228726; Hani Al-Aradi +965-97235102;
Mohammed A. Yassien +965-99366703

2. Hazards identification
2.1 Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Health hazards
Skin corrosion/irritation Category 1 Subcategory 1B
Serious eye damage/eye irritation Category 1

Environmental hazards Not classified

Physical Hazards Not classified

2.2 Label Elements

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Signal word
DANGER

Hazard statements
H314 - Causes severe skin burns and eye damage

Precautionary Statements - EU (§28, 1272/2008)

P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/
shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/ physician
P501 - Dispose of contents/container in accordance with local regulations.

Supplementary precautionary statements

P264 - Wash face, hands and any exposed skin thoroughly after handling
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363 - Wash contaminated clothing before re-use

Contains
Ethanol, 2,2'-oxybis-, reaction products with ammonia, morpholine derivs. residues

benzododecinium chloride

Benzyl(tetradecyl)dimethyl Ammoniums chloride

Ethylene Glycol

2.3 Other data

Not classified as PBT/vPvB by current EU criteria

3. Composition/information on ingredients
3.1 Substances

Not Applicable

3.2 Mixtures

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 KI-3978
Safety data sheet number PID17550
Revision date 17/Apr/2019

Component EC-No. CAS-No Weight % - Classification Classification (Reg. REACH

range (67/548) 1272/2008) registration
number
Ethanol, 2,2'-oxybis-, 272-712-1 68909-77-3 10-<20 Xi; R36 Eye Irrit. 2 (H319) 01-2119560595-31-x
reaction products with R52/53 Aquatic Chronic 3 (H412) xxx
ammonia, morpholine
derivs. residues
benzododecinium 205-351-5 139-07-1 5-10 Xn; R21/22 Acute Tox. 4 (H302) No data available
chloride C; R34 Acute Tox. 4 (H312)
N; R50 Skin Corr. 1B (H314)
Aquatic Acute 1
Benzyl(tetradecyl)dime 205-352-0 139-08-2 1-5 Xn; R21/22 (H400)
Acute Tox. 4 (H302) No data available
thyl Ammoniums C; R34 Acute Tox. 4 (H312)
chloride N; R50 Skin Corr. 1B (H314)
Aquatic Acute 1
Ethylene Glycol 203-473-3 107-21-1 1-5 Xn; R48/22 (H400)
Acute Tox. 4 (H302) No data available

STOT Rep. Exp. Cat 2

(H373)

Comments
The product contains other ingredients which do not contribute to the overall classification.

4. First aid measures

4.1 First Aid

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If not breathing, give artificial respiration. Seek medical attention at
once.

Ingestion Do NOT induce vomiting. Get immediate medical attention. Rinse mouth. Risk of product
entering the lungs on vomiting after ingestion. Never give anything by mouth to an
unconscious person.

Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.

Eye contact Remove contact lenses. Immediately flush eyes with water for 15 minutes while holding
eyelids open. Seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.

Main symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

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Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-fighting measures
5.1 Extinguishing media

Suitable extinguishing media

Water spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which shall not be used for safety reasons

Do not use water jet.

5.2 Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

None known.

Hazardous combustion products

Fire or high temperatures create:, Carbon oxides (COx), Nitrogen oxides (NOx).

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Keep people away from and upwind of spill/leak. Do not get on skin or clothing. Wash thoroughly after handling. Do not breathe
vapors or spray mist. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and materials for containment and cleaning up

Methods for Containment

Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

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 KI-3978
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Methods for cleaning up

Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local/national regulations (see Section 13).

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills and
splashing during use. Do not breathe vapors or spray mist.

Hygiene measures
Use good work and personal hygiene practices to avoid exposure Wash hands and face before breaks and immediately after
handling the product. When using do not smoke, eat or drink. Remove contaminated clothing.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid excessive heat
for prolonged periods of time. Keep away from direct sunlight Avoid contact with: Acids
Strong oxidising agents Reducing agents Nitrites

Storage class Corrosive storage.

Packaging material Use specially constructed containers only

7.3 Specific end uses

See Section 1.2.

8. Exposure controls/personal protection

8.1 Control parameters

Component EU OEL - Third List Austria Australia Denmark

Ethanol, 2,2'-oxybis-, reaction products with Not determined Not determined Not determined Not determined
ammonia, morpholine derivs. residues
benzododecinium chloride Not determined Not determined Not determined Not determined
Benzyl(tetradecyl)dimethyl Ammoniums Not determined Not determined Not determined Not determined

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 KI-3978
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chloride
Ethylene Glycol 40 ppm STEL 20 ppm STEL 40ppmSTELvapour 10 ppm TWA
104 mg/m3 STEL 52 mg/m3 STEL 104mg/m3STELvapour 26 mg/m3 TWA
20 ppm TWA 10 ppm TWA 10mg/m3TWAparticulate 10 mg/m3 TWA
52 mg/m3 TWA 26 mg/m3 TWA 20ppmTWAvapour Potential for cutaneous
Possibility of significant 52mg/m3TWAvapour absorption
uptake through the skin skin notation

Component Malaysia France Germany Hungary

Ethanol, 2,2'-oxybis-, reaction products with Not determined Not determined Not determined Not determined
ammonia, morpholine derivs. residues
benzododecinium chloride Not determined Not determined Not determined Not determined
Benzyl(tetradecyl)dimethyl Ammoniums Not determined Not determined Not determined Not determined
chloride
Ethylene Glycol 39.4 ppm Ceiling aerosol 40ppmSTEL 10 ppm TWA 52mg/m3TWA
100 mg/m3 Ceiling 104mg/m3STEL 26 mg/m3 TWA 104mg/m3STEL
aerosol 20 ppmTWA
52 mg/m3TWA

Component New Zealand Italy Netherlands Norway

Ethanol, 2,2'-oxybis-, reaction products with Not Determined Not determined Not determined Not determined
ammonia, morpholine derivs. residues
benzododecinium chloride Not Determined Not determined Not determined Not determined
Benzyl(tetradecyl)dimethyl Ammoniums Not Determined Not determined Not determined Not determined
chloride
Ethylene Glycol 50 ppm Ceiling mist and Not determined 104mg/m3STEL 10 mg/m3 TWA dust
vapour 52 mg/m3 20 ppm TWA total dust
127 mg/m3 Ceiling mist 10 mg/m3 and vapor
and vapour 52 mg/m3 TWA
104 mg/m3 STEL dust
40 ppm STEL
25 ppm Ceiling (vapor)
Skin

Component Poland Portugal Romania Russia

Ethanol, 2,2'-oxybis-, reaction products with Not determined Not determined Not determined Not determined
ammonia, morpholine derivs. residues
benzododecinium chloride Not determined Not determined Not determined Not determined
Benzyl(tetradecyl)dimethyl Ammoniums Not determined Not determined Not determined Not determined
chloride
Ethylene Glycol 50 mg/m3 STEL NDSCh Skin 40ppmSTEL 10 mg/m3 STEL aerosol
15 mg/m3 TWA NDS 40 ppm STEL VLE-CD 104mg/m3STEL and vapor
104 mg/m3 STEL 20ppmTWA 5 mg/m3 TWA aerosol
VLE-CD 52mg/m3TWA and vapor
20 ppm TWA indicative
limit value
52 mg/m3 TWA
indicative limit value

Component Spain Switzerland Turkey UK

Ethanol, 2,2'-oxybis-, reaction products with Not determined Not determined Not determined Not determined
ammonia, morpholine derivs. residues
benzododecinium chloride Not determined Not determined Not determined Not determined
Benzyl(tetradecyl)dimethyl Ammoniums Not determined Not determined Not determined Not determined
chloride
Ethylene Glycol 40 ppm STEL 20 ppm STEL 40 ppm STEL 40 ppm STEL vapour
104 mg/m3 STEL 52 mg/m3 STEL 104 mg/m3 STEL 104 mg/m3 STEL
Skin Skin Skin vapour
20 ppm TWA VLA-ED 10 ppm TWA MAK 20 ppm TWA 30 mg/m3 STEL
52 mg/m3 TWA VLA-ED 26 mg/m3 TWA MAK 52 mg/m3 TWA calculated particulate
Skin

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10 mg/m3 TWA
particulates
20 ppm TWA vapour
52 mg/m3 TWA vapour

Derived No Effect Level (DNEL)

Long term exposure systemic effects

Ethanol, 2,2'-oxybis-, reaction products with ammonia, morpholine derivs. residues

Dermal 6.67 mg/kg
Inhalation 25.52 mg/m³
Predicted No Effect Concentration (PNEC)
Ethanol, 2,2'-oxybis-, reaction products with ammonia, morpholine derivs. residues
Fresh Water 0.045 mg/l
Sea Water 0.0045 mg/l
Fresh water sediment 0.796 mg/kg
Sea sediment 0.0769 mg/kg
Soil 0.133 mg/kg
Impact on Sewage Treatment 100 mg/l
Intermittent release 0.45 mg/l

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering measures to
reduce exposure
Ensure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.

Personal protective equipment

Eye protection Chemical splash goggles and face shield.
Hand protection Impervious gloves made of:, Neoprene, Nitrile, Be aware that liquid may penetrate the
gloves. Frequent change is advisable.
Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators, Respirator with combination filter for vapor/particulate,
Type A/P3, At work in confined or poorly ventilated spaces, respiratory protection with air
supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at
the work place.

Hygiene measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothing
before re-use.

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 KI-3978
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9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance No information available
Odour Ammoniacal
Colour Dark Amber
Odor threshold Not applicable

Property Values Remarks

pH 10.8
pH @ dilution
Melting/freezing point No information available
Boiling point/range No information available
Flash Point > 70 °C / 158 °F
Evaporation rate No information available
Flammability (solid, gas) Not Applicable
Flammability Limits in Air
Upper flammability Limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature Not Applicable
Decomposition temperature No information available
Kinematic viscosity No information available
Viscosity, dynamic 8 cPs
Log Pow Not determined

Explosive properties Not Applicable

Oxidizing properties None known.

9.2 Other information

Pour point No information available
Molecular weight No information available
VOC content(%) none
Density VALUE 1.016 ± 0.03 g/ml @ 20°C

10. Stability and reactivity

10.1 Reactivity

Corrosive.

10.2 Chemical stability

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 KI-3978
Safety data sheet number PID17550
Revision date 17/Apr/2019

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Not known.

10.4 Conditions to avoid

Avoid excessive heat for prolonged periods of time. Keep away from direct sunlight.

10.5 Incompatible materials

Acids. Strong oxidising agents. Reducing agents. Nitrites.

10.6 Hazardous decomposition products

See Section 5.2.

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Inhalation Vapours are corrosive. After 24-36 hours, injured persons may develop serious shortness of
breath and lung oedema. Vapours irritate the respiratory system, and may cause coughing
and difficulties in breathing.

Eye contact Causes serious eye damage. May cause irreversible damage to eyes.

Skin contact Causes severe skin burns. Components of the product may be absorbed into the body
through the skin.

Ingestion Harmful if swallowed. Can burn mouth, throat, and stomach.

Unknown acute toxicity Not Applicable.

Component LD50 Oral LD50 Dermal LC50 Inhalation

Ethanol, 2,2'-oxybis-, reaction products with = 1500 mg/kg ( Rat ) No data available No data available
ammonia, morpholine derivs. residues
benzododecinium chloride = 400 mg/kg ( Rat ) No data available No data available
Benzyl(tetradecyl)dimethyl Ammoniums chloride No data available No data available No data available
Ethylene Glycol 4000 - 10200 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) = 9530 No data available
µL/kg ( Rabbit )

Sensitisation This product does not contain any components suspected to be sensitizing.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity This product does not contain any known or suspected carcinogens.

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Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of exposure Skin contact. Eye contact.

Routes of entry Skin contact. Eye contact. Ingestion. Inhalation.

Specific target organ toxicity (single Not classified

exposure)
Specific target organ toxicity Not classified.
(repeated exposure)

Aspiration hazard Not Applicable.

12. Ecological information

12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that
large or frequent spills can have a harmful or damaging effect on the environment.
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebrates
Ethanol, 2,2'-oxybis-, reaction OECD; Acute LC50; 96 hours OECD; Acute ErC50 (growth rate); OECD; Acute EC50; 48 hours
products with ammonia, morpholine Semi-static; Fish > 45 g/l 72 hours Static; Algae; 45 mg/kg Static, Daphnia; > 100 g/l
derivs. residues OECD 201 Algae, Growth Inhibitor
Test; Chronic NOECr; 72 hours
Static; Algae; 3.2 mg/l
benzododecinium chloride = 1 mg/L LC50 Salmo gairdneri 15 No information available No information available
min 0.223 - 0.46 mg/L LC50
Lepomis macrochirus 96 h = 1.3
mg/L LC50 Poecilia reticulata 96 h =
2.4 mg/L LC50 Oryzias latipes 96 h
0.823 - 1.61 mg/L LC50
Oncorhynchus mykiss 96 h
Benzyl(tetradecyl)dimethyl = 1 mg/L LC50 Salmo gairdneri 15 No information available No information available
Ammoniums chloride min 0.223 - 0.46 mg/L LC50
Lepomis macrochirus 96 h = 1.3
mg/L LC50 Poecilia reticulata 96 h =

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 KI-3978
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2.4 mg/L LC50 Oryzias latipes 96 h

0.823 - 1.61 mg/L LC50
Oncorhynchus mykiss 96 h
Ethylene Glycol = 16000 mg/L LC50 Poecilia 6500 - 13000 mg/L EC50 = 46300 mg/L EC50 Daphnia
reticulata 96 h 14 - 18 mL/L LC50 Pseudokirchneriella subcapitata 96 magna 48 h
Oncorhynchus mykiss 96 h = 27540 h
mg/L LC50 Lepomis macrochirus 96
h 40000 - 60000 mg/L LC50
Pimephales promelas 96 h = 41000
mg/L LC50 Oncorhynchus mykiss
96 h = 40761 mg/L LC50
Oncorhynchus mykiss 96 h

12.2 Persistence and degradability

This product is expected to be readily biodegradable.

12.3 Bioaccumulative potential

The product does not contain any substances expected to be bioaccumulating.

12.4 Mobility in soil

Mobility
Soluble in water.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

13. Disposal considerations

13.1 Waste treatment methods

Waste from residues / unused Dispose of in accordance with local regulations.

products

Contaminated packaging Empty containers should be transported/delivered using a registered waste carrier for local
recycling or waste disposal.

EWC waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application

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for which the product was used. The following Waste Codes are only suggestions: EWC
waste disposal No: 07 01 04

14. Transport information

14.1 UN number

UN/ID No. (ADR/RID/ADN/ADG) UN1760

UN No. (IMDG) UN1760
UN No. (ICAO) UN1760

14.2 Proper shipping name

CORROSIVE LIQUID, N.O.S. (Benzododecinium Chloride, Benzyl(tetradecyl)dimethyl Ammoniums Chloride)

14.3. Hazard class(es)

ADR/RID/ADN/ADG Hazard class 8
IMDG Hazard class 8
ICAO Hazard class/division 8

14.4 Packing group

ADR/RID/ADN/ADG Packing Group III
IMDG Packing group III
ICAO Packing group III

14.5 Environmental hazard

No

14.6 Special precautions

Hazard ID 80
EmS (IMDG) F-A, S-B
Emergency action code 2X
Tunnel restriction code (E)

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC Code
Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Australian Standard for the Uniform Scheduling of Drugs and Poisons

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benzododecinium chloride
Schedule 6
Schedule 5
Benzyl(tetradecyl)dimethyl Ammoniums chloride
Schedule 6
Schedule 5
Ethylene Glycol
Schedule 6
Schedule 5
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)
No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

International inventories

USA, Toxic Substances Control Act inventory (TSCA) Complies

European Union - EINECS and ELINCS Complies
Canada, Domestic Substance List (DSL) Complies
Philippines (PICCS) Does not Comply
Inventory - Japan - Existing and New Chemicals list Does not Comply
China (IECSC) Complies
Australia (AICS) Complies
Korea (KECL) Does not Comply
Inventory - New Zealand - Inventory of Chemicals (NZIoC) Complies

This SDS is not for use in the European Union (EU).

15.2 Chemical Safety Report

No information available

16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam

Supercedes date 20/Oct/2014

Revision date 24/Jun/2016

Version 3

The following sections have been The following sections have been revised:, 3. Composition/information on Ingredients, 8.
revised: EXPOSURE CONTROLS / PERSONAL PROTECTION, 9. Physical and chemical
properties, 13. Disposal considerations, 14. Transport information, 15. Regulatory
Information, Section 16: Other information.

Text of R phrases mentioned in Section 3

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R36 - Irritating to eyes

R34 - Causes burns
R50 - Very toxic to aquatic organisms

R21/22 - Harmful in contact with skin and if swallowed

R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Full text of H-Statements referred to under sections 2 and 3

H314 - Causes severe skin burns and eye damage

H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H319 - Causes serious eye irritation
H400 - Very toxic to aquatic life
H373 - May cause damage to organs through prolonged or repeated exposure
H412 - Harmful to aquatic life with long lasting effects

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS
information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate
agreement between the parties.

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SDS no. PID13263
Version 6
Revision date 10-May-2020
Supersedes date 10-Jun-2017

Safety Data Sheet

MB-5011

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name MB-5011

Product code PID13263
Norway Pr. no. 110718

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Microbiocide

Uses advised against Consumer use

1.1 Details of the supplier of the safety data sheet

Supplier
Kuwait Drilling Fluid & Oil Services Co
PO Box - 3046 Safat Kuwait
Shuaiba Industrial Area
Kuwait

[email protected]

1.2 Emergency Telephone Number

Emergency telephone - +965 98003784, +965 97228726

2. Hazards identification
2.1 Classification of the substance or mixture

Classification according to (EC) No. 1272/2008

Health hazards
Acute oral toxicity Category 4
Acute inhalation toxicity - vapor Category 4
Skin corrosion/irritation Category 1 Subcategory 1B
Respiratory sensitization Category 1
Skin sensitization Category 1
Specific target organ toxicity Category 3
(single exposure)

Environmental hazards Not classified

Physical Hazards Not classified

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2.2 Label elements

Signal word
DANGER

Hazard statements
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H332 - Harmful if inhaled
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 - May cause respiratory irritation
H371 - May cause damage to organs

Precautionary Statements - EU (§28, 1272/2008)

P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/
shower
P304 + P341 - IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P501 - Dispose of contents/container in accordance with local regulations.

Supplementary precautionary statements

P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P285 - In case of inadequate ventilation wear respiratory protection
P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Contains
Glutaraldehyde

Methanol

2.3 Other data

Not classified as PBT/vPvB by current EU criteria

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3. Composition/information on ingredients
3.1 Substances

Not Applicable

3.2 Mixtures

Component EC-No. CAS-No Weight % - Classification Classification (Reg. REACH

range (67/548) 1272/2008) registration
number
Glutaraldehyde 203-856-5 111-30-8 5-10 T; R23/25 Met. Corr. 1 (H290) 01-2119455549-26-x
C; R34 Acute Tox. 3 (H301) xxx
R42/43 Skin Corr. 1B (H314)
N; R50 Skin Sens. 1 (H317)
Aqute Tox. 3 (H331)
Resp. Sens 1 (H334)
Aquatic Acute 1 (H400)
Methanol 200-659-6 67-56-1 0-0.1 F;R11 Flam. Liq. 2, H225 01-2119433307-44-X
T; R39/23/24/25 - Acute Tox. 3, H301 XXX
R23/24/25 Acute Tox. 3, H311
Acute Tox. 3, H331
STOT SE 1, H370

Comments
The product contains other ingredients which do not contribute to the overall classification.

4. First aid measures

4.1 First-Aid Measures

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If not breathing, give artificial respiration. Seek medical attention at
once.

Ingestion Do NOT induce vomiting. Get immediate medical attention. Rinse mouth. Risk of product
entering the lungs on vomiting after ingestion. Never give anything by mouth to an
unconscious person.

Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.

Eye contact Remove contact lenses. Immediately flush eyes with water for 15 minutes while holding
eyelids open. Seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.

Main symptoms

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Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-fighting measures
5.1 Extinguishing media

Suitable extinguishing media

Water spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which shall not be used for safety reasons

None known.

5.2 Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

None known.

Hazardous combustion products

Fire or high temperatures create:, Carbon oxides (COx).

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Do not get on skin or clothing. Wash thoroughly after handling. Do not breathe vapors or spray mist. Use personal protective
equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and materials for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up

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Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local/national regulations (see Section 13).

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills and
splashing during use. Do not breathe vapors or spray mist. Persons susceptible to allergic reactions should not handle this product.

Safe handling instructions

Use good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face
before breaks and immediately after handling the product Remove contaminated clothing.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid heat, flames
and other sources of ignition. Avoid contact with: Alkalis

Storage class Corrosive storage.

Packaging material Use specially constructed containers only.

7.3 Specific end uses

See Section 1.2.

8. Exposure controls/personal protection

8.1 Control parameters

Component EU OEL Austria Australia Denmark

Glutaraldehyde Not determined 0.05 ppm STEL Not determined 0.2 ppm Ceiling
0.2 mg/m3 STEL 0.8 mg/m3 Ceiling
0.05 ppm TWA
0.2 mg/m3 TWA
Methanol 200 ppm TWA 800 ppm STEL 250ppmSTEL 200 ppm
260 mg/m3 TWA 1040 mg/m3 STEL 328mg/m3STEL 260 mg/m3
Possibility of significant 200 ppm TWA 200ppmTWA
uptake through the skin 260 mg/m3 TWA 262mg/m3TWA
skin notation

Component Malaysia France Germany Hungary

Glutaraldehyde 0.05 ppm Ceiling 0.2ppmSTEL 0.05 ppm TWA Not determined

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0.21 mg/m3 Ceiling 0.8mg/m3STEL 0.21 mg/m3 TWA

0.1 ppmTWA
0.4 mg/m3TWA
Methanol 200 ppm TWA 1000ppmSTEL 200 ppm TWA 260mg/m3TWA
262 mg/m3 TWA 1300mg/m3 STEL 270 mg/m3 TWA
Skin notation 200 ppmTWA
260 mg/m3TWA

Component New Zealand Italy Netherlands Norway

Glutaraldehyde 0.05 ppm STEL Not determined Not determined 0.2 ppm Ceiling; 0.8
sensitiser mg/m3 Ceiling; 0.25
mg/m3 Ceiling (activated
Alkyls)
Sensitizing substance
Methanol 250 ppm STEL Not determined 133 mg/m3 100 ppm TWA
328 mg/m3 STEL 100 ppm GW 130 mg/m3 TWA
200 ppm TWA 100 ppm STEL
262 mg/m3 TWA 130 mg/m3 STEL
Possibility of significant Skin
uptake through the skin

Component Poland Portugal Romania Russia

Glutaraldehyde 0.6 mg/m3 STEL Not determined Not determined 5 mg/m3 MAC
0.4 mg/m3 TWA Allergenic substance
Methanol 300 mg/m3 STEL NDSCh Skin 5ppmSTEL 15 mg/m3 STEL vapor
100 mg/m3 TWA NDS 250 ppm STEL VLE-CD 200ppmTWA Skin
200 ppm TWA indicative 260mg/m3TWA 5 mg/m3 TWA vapor
limit value
260 mg/m3 TWA
indicative limit value

Component Spain Switzerland Turkey UK

Glutaraldehyde 0.05 ppm VLA-EC 0.1 ppm STEL Not determined 0.05 ppm STEL
0.2 mg/m3 VLA-EC 0.42 mg/m3 STEL 0.2 mg/m3 STEL
0.05 ppm MAK 0.05 ppm TWA
0.21 mg/m3 MAK 0.2 mg/m3 TWA
Methanol Skin 800 ppm STEL Skin 250 ppm STEL
200 ppm TWA VLA-ED 1040 mg/m3 STEL 200 ppm TWA 333 mg/m3 STEL
266 mg/m3 TWA VLA-ED Skin 260 mg/m3 TWA Skin
200 ppm TWA MAK 200 ppm TWA
260 mg/m3 TWA MAK 266 mg/m3 TWA

Derived No Effect Level (DNEL)

Short term exposure local effects

Glutaraldehyde
Inhalation 0.5 mg/m³
Methanol
Inhalation 260 mg/m³
Long term exposure local effects
Glutaraldehyde
Inhalation 0.25 mg/m³
Methanol
Oral 8 mg/kg bw/day
Dermal 40 mg/kg bw/day
Inhalation 260 mg/m³
Short term exposure systemic effects

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Methanol
Oral 8 mg/kg bw/day
Dermal 40 mg/kg
Inhalation 260 mg/m³
Long term exposure systemic effects

Methanol
Dermal 40 mg/kg
Inhalation 260 mg/m³
Predicted No Effect Concentration (PNEC)
Glutaraldehyde
Fresh water 0.0025 mg/L
Sea water 0.006 mg/L
Fresh water sediment 0.527 mg/kg
Sea sediment 0.0527 mg/kg
Soil 0.03 mg/kg
Impact on sewage treatment 0.8 mg/L
Methanol
Fresh water 20.8 mg/l
Sea water 2.08 mg/l
Fresh water sediment 77 mg/kg
Sea sediment 7.7 mg/kg
Soil 3.18 mg/kg
Impact on sewage treatment 100 mg/l
Intermittent release 1540 mg/l

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering measures to reduce exposure

Ensure adequate ventilation. Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into
work environment.

Personal protective equipment

Eye protection Chemical splash goggles and/or face shield.
Hand protection Impervious gloves made of:, Butyl, Rubber, Neoprene, Be aware that liquid may penetrate
the gloves. Frequent change is advisable.
Respiratory protection In case of inadequate ventilation wear respiratory protection, Respirator with combination
filter for vapor/particulate, Type A2/P3, At work in confined or poorly ventilated spaces,
respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at
the work place.

Safe handling instructions Wash hands before eating, drinking or smoking, Remove and wash contaminated clothing
before re-use.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

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Physical state Liquid

Appearance No information available
Odor Mild Fruity
Color Colorless
Odor threshold Not applicable

Property Values Remarks

pH 4.6 ± 1.00
pH @ dilution
Melting/freezing point No information available
Boiling point/range No information available
Flash point > 100 °C / > 212 °F
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not Applicable
Flammability Limits in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature Not Applicable
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Log Pow Not determined

Explosive properties Not Applicable

Oxidizing properties None known.

9.2 Other information

Pour point No information available
Molecular weight No information available
VOC content(%) None
Density 1.021 ± 0.030 g/ml @ 25°C

10. Stability and reactivity

10.1 Reactivity

Corrosive.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Not known.

10.4 Conditions to avoid

Avoid heat, flames and other sources of ignition.

10.5 Incompatible materials

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Alkalis.

10.6 Hazardous decomposition products

See also section 5.2.

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Inhalation Vapours are corrosive. After 24-36 hours, injured persons may develop serious shortness of
breath and lung oedema. Vapours irritate the respiratory system, and may cause coughing
and difficulties in breathing.

Eye contact Causes burns. May cause irreversible damage to eyes.

Skin contact Causes burns. May cause an allergic skin reaction. Components of the product may be
absorbed into the body through the skin.

Ingestion Causes burns. Harmful if swallowed. Can burn mouth, throat, and stomach. May cause
drowsiness or dizziness.

Unknown acute toxicity Not Applicable.

Component LD50 Oral LD50 Dermal LC50 Inhalation

Glutaraldehyde = 252 mg/kg ( Rat ) = 560 µL/kg ( Rabbit ) = 0.1 mg/L ( Rat ) 4 h
Methanol = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 83.2 mg/L ( Rat ) 4 h

Sensitization May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause
allergic skin reaction.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity This product does not contain any known or suspected carcinogens.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of exposure Skin contact. Eye contact. Inhalation. Ingestion.

Routes of entry Skin contact. Skin absorption. Eye contact. Ingestion. Inhalation.

Specific target organ toxicity Category 3

(single exposure)
Specific target organ toxicity Not classified.
(repeated exposure)

Target organ effects Respiratory system.

Aspiration hazard Not Applicable.

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12. Ecological information

12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that
large or frequent spills can have a harmful or damaging effect on the environment.
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebrates
Glutaraldehyde 7.8 - 13 mg/L LC50 Oncorhynchus = 0.84 mg/L EC50 Desmodesmus = 14 mg/L EC50 Daphnia magna 48
mykiss 96 h 7.8 - 22 mg/L LC50 subspicatus 96 h = 0.61 mg/L EC50 h 0.56 - 1.0 mg/L EC50 Daphnia
Lepomis macrochirus 96 h = 5.4 Desmodesmus subspicatus 72 h magna 48 h
mg/L LC50 Pimephales promelas
96 h 2.6 - 4.8 mg/L LC50
Oncorhynchus mykiss 96 h
Methanol = 15400 mg/L (LC50; Lepomis No information available No information available
macrochirus)

12.2 Persistence and degradability

Readily biodegradable.

12.3 Bioaccumulative potential

The product does not contain any substances expected to be bioaccumulating.

12.4 Mobility in soil

Mobility
Soluble in water.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

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13. Disposal considerations

13.1 Waste treatment methods

Waste from residues / unused Dispose of in accordance with local regulations.

products

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used. The following Waste Codes are only suggestions: EWC
waste disposal No: 07 01 04 Waste Code: 7152 Organic waste without halogen.

14. Transport information

14.1 UN Number

UN/ID No. (ADR/RID/ADN/ADG) UN3265

UN No. (IMDG) UN3265
UN No. (ICAO) UN3265

14.2 Proper shipping name

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Glutaraldehyde)

14.3 Hazard class(es)

ADR/RID/ADN/ADG Hazard class 8
IMDG Hazard class 8
ICAO Hazard class/division 8

14.4 Packing group

ADR/RID/ADN/ADG Packing group III
IMDG Packing group III
ICAO Packing group III

14.5 Environmental hazard

No

14.6 Special precautions

Hazard identification no (ADR) 80

EmS (IMDG) F-A, S-B
Emergency action code 2X
Tunnel restriction code (E)

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Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC Code
Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Australian Standard for the Uniform Scheduling of Drugs and Poisons

Glutaraldehyde
Schedule 6
Schedule 5
Methanol
Schedule 6
Schedule 5
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)
No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

International inventories

USA (TSCA) Complies

European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies

Contact [email protected] for REACH information.

15.2 Chemical Safety Report

No information available

16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam

Supersedes date 10-Jun-2017

Revision date 10-May-2020

Version 6

The following sections have been This SDS have been made in a new database and therefore a new layout. No changes with
revised: regard to classification have been made.

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Text of R phrases mentioned in Section 3

R11 - Highly flammable
R34 - Causes burns
R50 - Very toxic to aquatic organisms

R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed

R23/25 - Toxic by inhalation and if swallowed
R39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R42/43 - May cause sensitization by inhalation and skin contact

Full text of H-Statements referred to under sections 2 and 3

H302 - Harmful if swallowed

H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H332 - Harmful if inhaled
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 - May cause respiratory irritation
H371 - May cause damage to organs
H225 - Highly flammable liquid and vapor
H290 - May be corrosive to metals
H301 - Toxic if swallowed
H311 - Toxic in contact with skin
H331 - Toxic if inhaled
H400 - Very toxic to aquatic life
H370 - Causes damage to organs

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS
information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate
agreement between the parties.

Page 13 / 13
SDS no. PID13113
Version 7
Revision date 31-May-2019
Supersedes Date: 07-Jan-2015

Safety Data Sheet

MB-5029

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name MB-5029

Product code PID13113
Country Limitations This SDS is not for use in the European Union (EU).

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Microbiocide

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Kuwait Drilling Fluid & Oil Services
Co PO Box - 3046 Safat Kuwait
Shuaiba Industrial Area
Kuwait

[email protected]

1.4 Emergency Telephone Number

Emergency telephone - +965 98003784, +965 97228726

2. Hazards Identification
2.1 Classification of the substance or mixture

GHS Classification

Health hazards
Acute toxicity - Inhalation (Dusts/Mists) Category 3
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Skin sensitization Sub-Category 1A
Reproductive toxicity Category 2

Environmental hazards
Chronic aquatic toxicity Category 2

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Physical Hazards Not classified

2.2 Label elements

Signal word
DANGER

Hazard Statements
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H331 - Toxic if inhaled
H361 - Suspected of damaging fertility or the unborn child
H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements
P201 - Obtain special instructions before use
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician

Supplementary precautionary statements

P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P284 - Wear respiratory protection
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P311 - Call a POISON CENTER or doctor/physician
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention
P362 + P364 - Take off contaminated clothing and wash it before reuse
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Contains
Tetrakis(hydroxymethyl)phosphonium sulfate

Nonylphenol, branched, ethoxylated

Quaternary ammonium compounds, benzyl-C12-14(even numbered)-alkyldimethyl, chlorides*

2.3 Other hazards

Not classified as PBT/vPvB by current EU criteria

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3. Composition/information on Ingredients
3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-%

Tetrakis(hydroxymethyl)phosphonium sulfate 259-709-0 55566-30-8 10-<20
Nonylphenol, branched, ethoxylated NLP 68412-54-4 1-<3
500-209-1
Quaternary ammonium compounds, benzyl-C12-14(even 939-350-2 RM1003944 1-<3
numbered)-alkyldimethyl, chlorides*

Comments
The product contains other ingredients which do not contribute to the overall classification.
*Substances which have an EC Number that begins with the number "9" is a Provisional List Number. The list numbers published
by ECHA do not have any legal significance. The EC substance definition and related classification & labelling has been
developed in the framework of the Regulation (EC) No 1907/2006 (REACH). For information about the related CAS number see
section 15 of this SDS.

4. First Aid Measures

4.1 First aid measures

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If not breathing, give artificial respiration. Seek medical attention at
once.

Ingestion Do NOT induce vomiting. Get immediate medical attention. Rinse mouth. Risk of product
entering the lungs on vomiting after ingestion. Never give anything by mouth to an
unconscious person.

Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.

Eye Contact Remove contact lenses, if worn. Immediately flush eyes with water for 15 minutes while
holding eyelids open. Seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.

Symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Please see Section 11. Toxicological Information for further information.

Skin contact
Please see Section 11. Toxicological Information for further information.
Eye contact

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4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-Fighting Measures

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing media appropriate for surrounding material.

Extinguishing media which must not be used for safety

reasons None known.

5.2. Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

None known.

Hazardous combustion products

Fire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Sulphur oxides, Oxides of phosphorus,
Phosphines, Hydrogen gas, Halogenated compounds.

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate personnel to safe areas. Do not get on skin or clothing. Wash thoroughly after handling. Do not breathe vapors or
spray mist. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up

Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and
place in container for disposal according to local/national regulations (see Section 13).

6.4 Reference to other sections

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See section 13 for more information.

7. Handling and Storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Do not get in eyes, on skin or on clothing. Do not
breathe vapors or spray mist. Avoid spills and splashing during use. Persons susceptible to allergic reactions should not handle
this product. Not to be used by pregnant workers and workers who have recently given birth or who are breastfeeding.

Hygiene Measures
Use good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and
face before breaks and immediately after handling the product Remove contaminated clothing

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid excessive heat
for prolonged periods of time. Avoid contact with: Strong acids Strong bases Strong
oxidizing agents Strong reducing agents

Storage class Toxic storage.

Packaging materials Use specially constructed containers only.

8. Exposure Controls/Personal Protection

8.1 Control parameters

Component Information

Chemical Name Arabic Australia Egypt

Tetrakis(hydroxymethyl)phosphoniu Not determined Not determined Not determined
m sulfate
Nonylphenol, branched, ethoxylated Not determined Not determined Not determined
Quaternary ammonium compounds, Not determined Not determined Not determined
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*
Chemical Name India Indonesian Japan
Tetrakis(hydroxymethyl)phosphoniu Not determined Not determined Not determined
m sulfate
Nonylphenol, branched, ethoxylated Not determined Not determined Not determined
Quaternary ammonium compounds, Not determined Not determined Not determined
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*
Chemical Name Kazakhstan Kuwait New Zealand
Tetrakis(hydroxymethyl)phosphoniu Not determined Not determined Not determined
m sulfate
Nonylphenol, branched, ethoxylated Not determined Not determined Not determined
Quaternary ammonium compounds, Not determined Not determined Not determined
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*
Chemical Name Malaysia Philippines Russia
Tetrakis(hydroxymethyl)phosphoniu Not determined Not determined Not determined
m sulfate
Nonylphenol, branched, ethoxylated Not determined Not determined Not determined
Quaternary ammonium compounds, Not determined Not determined Not determined
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

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Chemical Name Thailand Vietnam Turkey

Tetrakis(hydroxymethyl)phosphoniu Not determined Not determined Not determined
m sulfate
Nonylphenol, branched, ethoxylated Not determined Not determined Not determined
Quaternary ammonium compounds, Not determined Not determined Not determined
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the
chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional
hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory
protection will vary from workplace to workplace and should be assessed by the user in each situation.

Engineering Controls
Ensure adequate ventilation

Personal protective equipment

Eye protection Eye protection must conform to standard EN 166 Chemical splash goggles and/or face
shield
Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training
Impervious gloves made of: Nitrile PVC
Break through time >480 minutes
Glove thickness 1.23 mm
Be aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection Positive-pressure supplied air respirators may be required for high airborne contaminant
concentrations. Respiratory protection must be provided in accordance with current local
regulations. Respirator with combination filter for vapour/particulate (EN 141) Type A/P3. At
work in confined or poorly ventilated spaces, respiratory protection with air supply must be
used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the
work place.

Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated
clothing before re-use

8.2.3 Environmental exposure controls

Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for
more information

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Clear
Odor No information available
Color Colorless
Odor threshold Not applicable

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Property Values Remarks

pH No information available
pH @ dilution 4.0 ± 1.00 @ 10%
Melting / freezing point No information available
Boiling point/range No information available
Flash point >100°C/>212°F ASTM D 93-11
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature Not applicable
Decomposition temperature No information available
Kinematic viscosity >1 cSt @20°C
Dynamic viscosity >1 cSt @20°C
log Pow Not determined

Explosive properties Not applicable

Oxidizing properties None known.

9.2 Other information

Pour point -10°C
Molecular weight No information available
VOC content(%) None
Density 1.05 ± 0.03 g/ml at 20 °C

Comments
The data listed above are typical physical and chemical properties and should not be construed as product specification.

10. Stability and Reactivity

10.1 Reactivity

No specific reactivity hazards associated with this product.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Hazardous polymerization does not occur.

10.4 Conditions to avoid

Avoid excessive heat for prolonged periods of time.

10.5 Incompatible materials

Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents.

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10.6 Hazardous decomposition products

See Section 5.2.

11. Toxicological Information

11.1 Information on toxicological effects

Acute toxicity

Inhalation Toxic by inhalation.

Eye contact Causes serious eye damage.

Skin contact Irritating to skin. May cause an allergic skin reaction.

Ingestion may cause stomach discomfort.
Ingestion

Unknown acute toxicity Not applicable.

Toxicology data for the components

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Tetrakis(hydroxymethyl)phosphonium sulfate 575 mg/kg ( Rat ) > 2000 mg/kg (Rat) 0.591 mg/l (Rat)
Nonylphenol, branched, ethoxylated No data available No data available No data available
Quaternary ammonium compounds, 397.5 mg/Kg (Rat) 2848 mg/Kg (Rabbit) No data available
benzyl-C12-14(even numbered)-alkyldimethyl,
chlorides*

Sensitization May cause allergic skin reaction.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity This product does not contain any known or suspected carcinogens.

Reproductive toxicity H361d - Suspected of damaging the unborn child.

Routes of Exposure Ingestion. Skin contact. Eye contact. Inhalation.

Routes of entry Ingestion. Skin absorption. Eye contact. Inhalation.

Specific target organ toxicity - Not classified

Single exposure
Specific target organ toxicity - Not classified.
Repeated exposure

Aspiration hazard Not applicable.

Other information Key literature references and sources for data. See Section 16 for more information.

12. Ecological Information

12.1 Toxicity

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_____________________________________________________________________________________________

Toxic to aquatic life with long lasting effects

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Toxicology data for the components

Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Tetrakis(hydroxymethyl)phosphoniu < 1 mg/l No information available No information available
m sulfate
Nonylphenol, branched, ethoxylated No information available No information available No information available
Quaternary ammonium compounds, < 1 mg/l Fish 96h < 0.1 mg/l Algae 72h < 1 mg/l Daphnia 48h
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

12.2 Persistence and degradability

The product contains nonylphenol ethoxylate which can be transformed into persistent (not readily degradable) nonylphenols
when degraded.

Chemical Name Persistence and degradability

Tetrakis(hydroxymethyl)phosphonium Readily biodegradable
sulfate
Quaternary ammonium compounds, Readily biodegradable
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

12.3 Bioaccumulative potential

See component information below.

Chemical Name Bioaccumulation

Tetrakis(hydroxymethyl)phosphonium Does not bioaccumulate
sulfate
Quaternary ammonium compounds, Bioconcentration factor (BCF) 79 Not likely to bioaccumulate
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

12.4 Mobility

Mobility
Soluble in water. See component information below.

Chemical Name Mobility

Tetrakis(hydroxymethyl)phosphonium Soluble in water
sulfate
Quaternary ammonium compounds, 455 g/l@10 °C
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

Mobility in soil
See component information below.

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Chemical Name Mobility in soil

Tetrakis(hydroxymethyl)phosphonium Distribution among environmental compartments
sulfate
Quaternary ammonium compounds, No information available
benzyl-C12-14(even
numbered)-alkyldimethyl, chlorides*

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

12.7 Other information

Key literature references and sources for data. See Section 16 for more information.

13. Disposal considerations

13.1 Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations.

products

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

14. Transport information

14.1. UN number

UN/ID No. (ADR/RID/ADN/ADG) UN2810

UN No. (IMDG/ANTAQ) UN2810
UN No. (ICAO/ANAC) UN2810

14.2. UN proper shipping name

TOXIC LIQUID, ORGANIC, N.O.S. (Tetrakis(hydroxymethyl)phosphonium sulphate)

14.3 Hazard class(es)

ADR/RID/ADN/ADG Hazard class 6.1
IMDG/ANTAQ Hazard class 6.1
ICAO/ANAC Hazard class/division 6.1

14.4 Packing group

ADR/RID/ADN/ADG Packing group III
IMDG/ANTAQ Packing group III
ICAO/ANAC Packing group III

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14.5 Environmental hazard

Yes

14.6 Special precautions

Hazard identification no (ADR) 60

EmS (IMDG) F-A, S-A
Emergency Action Code (EAC) 2X
Tunnel restriction code (E)

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC
Code Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This safety data sheet complies with the requirements of:

The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

International inventories

USA (TSCA) Complies

Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies

This SDS is not for use in the European Union (EU).

CAS Number 68424-85-1 can be used to identify the substance given a list number in section 3 in areas not subject to the
REACH regulation.

16. Other Information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Poh Yue Cheong

Supersedes Date: 07-Jan-2015

Revision date 31-May-2019

_____________________________________________________________________________________________

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 MB-5029 SDS no. PID13113
Revision date 31-May-2019
_____________________________________________________________________________________________

Version 7

This SDS has been revised in This SDS have been made in a new database and therefore a new layout. No changes
the following section(s) with regard to classification have been made.

Key literature references and sources for data

www.ChemADVISOR.com
Supplier
National Chemical Inventories
National regulatory information
National occupational exposure limits

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measurements,testsordataderivedfrom supplier’sownstudyorfurnishedby others.InprovidingthisSDS information,
Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose;
any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
maximum extentpermitedbylaw,supplier’swarrantyobligationsandbuyer’ssoleremediesareasstatedinseparate agreement
between the parties.
This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

_____________________________________________________________________________________________

Page 12 / 12
SDS no. PID13068
Version 8
Revision date 01/Aug/2020
Supersedes date 04/Sep/2017

Safety Data Sheet

KI-3023

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name KI-3023

Product code PID13068
Country Limitations This SDS is not for use in the European Union (EU).

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Corrosion inhibitor

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Kuwait Drilling Fluids & Oil Service S.A.K
Shuaiba Industrial Area
P.O Box 4544 Safat, 13046
Kuwait

1.4 Emergency Telephone Number

Emergency telephone - Kuwait: +965-98003784; +965-97228726; +965-99366703

2. Hazards Identification
2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Health hazards
Aspiration toxicity Category 1
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 1 Subcategory 1C
Serious eye damage/eye irritation Category 1
Skin sensitisation Category 1
Carcinogenicity Category 2
Specific target organ toxicity - Repeated exposure Category 2

Environmental hazards

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 KI-3023
Safety data sheet number PID13068
Revision date 01/Aug/2020

Chronic aquatic toxicity Category 2

Physical Hazards Not classified

2.2 Label elements

Signal word
DANGER

Hazard statements
H304 - May be fatal if swallowed and enters airways
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H332 - Harmful if inhaled
H351 - Suspected of causing cancer
H373 - May cause damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28,1272/2008)

P201 - Obtain special instructions before use
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Supplementary precautionary statements

P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P284 - Wear respiratory protection
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P314 - Get medical advice/attention if you feel unwell
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Contains
Fuels, diesel

Lubricating Oil

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Fatty acids C18 unsaturated, reaction products with tetraethylenepentamine

Hydrocarbons, C9, aromatics*

2.3 Other hazards

Not classified as PBT/vPvB by current EU criteria

3. Composition/information on ingredients
3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-% Regulation (EC) No REACH

1272/2008 registration
number
Fuels, diesel 269-822-7 68334-30-5 60-100 Flamm. Liquid (H226) 01-2119484664-2
Asp. Hazard 1 (H304) 7-xxxx
Skin Irrit. 2 (H315)
Acute Tox. 4 (H332)
Carc. 2 (H351)
STOT RE 2 (H373)
Aquatic Chronic 2 (H411)
Lubricating Oil Not Listed Proprietary 5-10 Carc. 1B (H350) No data available
Fatty acids C18 unsaturated, 629-725-6 1226892-45-0 5-10 Skin Corr. 1C (H314) 01-2119487006-3
reaction products with Skin Sens. 1A (H317) 8-xxxx
tetraethylenepentamine Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Hydrocarbons, C9, 918-668-5 RM1003765 1-5 Asp. Tox. 1 (H304) 01-2119455851-3
aromatics* Flam. Liquid 3 (H226) 5-xxxx
STOT SE 3 (H335)
STOT SE 3 (H336)
Aquatic Chronic 2 (H411)
EUH066

Comments
The product contains other ingredients which do not contribute to the overall classification.

The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as
measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions
— Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London.
The producer of "Lubricating oils" declares that it contains less than 3% DMSO extractable material by IP-346

*Substances which have an EC Number that begins with the number "9" is a Provisional List Number. The list numbers published
by ECHA do not have any legal significance. The EC substance definition and related classification & labelling has been developed
in the framework of the Regulation (EC) No 1907/2006 (REACH). For information about the related CAS number see section 15 of
this SDS.

CAS Number 61790-69-0 can be used to identify substance 1226892-43-8 in areas not subject to the REACH regulation.

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4. First aid measures

4.1 First aid measures

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If breathing has stopped, begin artificial respiration. Seek medical
attention at once.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs
spontaneously, minimize the risk of aspiration by properly positioning the affected person.
Risk of product entering the lungs on vomiting after ingestion. Never give anything by mouth
to an unconscious person. Get immediate medical attention.

Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.

Eye Contact Remove contact lenses, if worn. Immediately flush eyes with water for 15 minutes while
holding eyelids open. Immediate medical attention is required.

4.2. Most important symptoms and effects, both acute and delayed

General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.

Symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Please see Section 11. Toxicological Information for further information.

Skin contact
Please see Section 11. Toxicological Information for further information.
Eye contact

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Water spray, dry chemical, carbon dioxide (CO 2), or foam.

Extinguishing media which must not be used for safety reasons

Do not use water jet, Do not use a solid water stream as it may scatter and spread fire.

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5.2. Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

Vapours heavier than air. Development of hazardous combustion gases or vapours possible in the event of fire.

Hazardous combustion products

Fire or high temperatures create: Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke), Nitrogen oxides
(NOx), Sulphur oxides, Aldehydes.

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Keep people away from and upwind of spill/leak. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for containment
Prevent further leakage or spillage if safe to do so. Dyke far ahead of liquid spill for later disposal.

Methods for cleaning up

Take precautionary measures against static discharges. Absorb with earth, sand or other non-combustible material and transfer to
containers for later disposal. After cleaning, flush away traces with water.

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

Handling
Do not handle until all safety precautions have been read and understood. Handle in accordance with good industrial hygiene and
safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use.
Persons susceptible to allergic reactions should not handle this product.

Hygiene Measures

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Use good work and personal hygiene practices to avoid exposure When using do not smoke, eat or drink. Wash hands and
face before breaks and immediately after handling the product Remove contaminated clothing

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure
limits. Take precautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid heat, flames
and other sources of ignition. Avoid contact with: Strong oxidising agents Strong acids
Strong bases Halogens

Storage class Packaging materials Corrosive storage.

7.3 Specific end uses Use specially constructed containers only

See Section 1.2.

8.1 Control parameters 8. Exposure controls/personal protection

Exposure Limits

Hydrocarbons, C9, aromatics OEL vapour (Total Hydrocarbons/RCP) – TWA 19ppm

(100 mg/m³)
Above Occupational Exposure Limit (OEL) is a “in-house” calculated value
Component Information provided from Suppliers of this component and calculated as per CEFIC/HSPA/UK
EH 40 guidelines.
Chemical Name EU OEL - Third List Austria Australia Denmark
Fuels, diesel Not determined Not determined Not determined Not determined
Lubricating Oil Not determined Not determined Not determined Not determined
Fatty acids C18 unsaturated, reaction Not determined Not determined Not determined Not determined
products with tetraethylenepentamine
Hydrocarbons, C9, aromatics* Not determined Not determined Not determined Not determined
Chemical Name Malaysia France Germany Hungary
Fuels, diesel Not determined Not determined Not determined Not determined
Lubricating Oil Not determined Not determined Not determined Not determined
Fatty acids C18 unsaturated, reaction Not determined Not determined Not determined Not determined
products with tetraethylenepentamine
Hydrocarbons, C9, aromatics* Not determined Not determined Not determined Not determined
Chemical Name New Zealand Italy Netherlands Norway
Fuels, diesel Not determined Not determined Not determined Not determined
Lubricating Oil Not determined Not determined Not determined Not determined
Fatty acids C18 unsaturated, reaction Not determined Not determined Not determined Not determined
products with tetraethylenepentamine
Hydrocarbons, C9, aromatics* Not determined Not determined Not determined Not determined
Chemical Name Poland Portugal Romania Russia
Fuels, diesel 0.5 mg/m3 TWA NDS Skin Not determined Not determined
100 mg/m3 TWA total
Hydrocarbons aerosol
and vapor
Lubricating Oil Not determined Not determined Not determined Not determined
Fatty acids C18 unsaturated, reaction Not determined Not determined Not determined Not determined
products with tetraethylenepentamine

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Hydrocarbons, C9, aromatics* Not determined Not determined Not determined Not determined
Chemical Name Spain Switzerland Turkey UK
Fuels, diesel Not determined Not determined Not determined Not determined
Lubricating Oil Not determined Not determined Not determined Not determined
Fatty acids C18 unsaturated, reaction Not determined Not determined Not determined Not determined
products with tetraethylenepentamine
Hydrocarbons, C9, aromatics* Not determined Not determined Not determined Not determined

Derived No Effect Level (DNEL)

Long term exposure systemic effects

Fatty acids C18 unsaturated, reaction products with tetraethylenepentamine
Dermal 4.2 mg/kg
Inhalation 29 mg/m³
Hydrocarbons, C9, aromatics*
Dermal 25 mg/kg
Inhalation 150 mg/m³
Predicted No Effect Concentration (PNEC)
Fatty acids C18 unsaturated, reaction products with tetraethylenepentamine
Fresh Water 30.7 µg/L
Sea Water 3.07 µg/L
Freshwater sediment 119.8 mg/kg
Sea sediment 11.98 mg/kg
Soil 9.44 mg/kg
Impact on sewage treatment 2.3 mg/L
Intermittent release 6.12 µg/L
8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering Controls
Ensure adequate ventilation. Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into
work environment.

Personal protective equipment

Eye protection Eye protection must conform to standard EN 166. Chemical splash goggles and face shield.
Hand protection Wear gloves according to EN 374 resistant to the solvent(s) in use
Use protective gloves made of: Nitrile
Break through time >480 minutes
Glove thickness 0.38 mm
Be aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of inadequate ventilation wear respiratory protection, Respirator with combination
filter for vapour/particulate (EN 141), Type A/P3, At work in confined or poorly ventilated
spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at
the work place.

Hygiene Measures Wash hands before eating, drinking or smoking, Remove and wash contaminated
clothing before re-use.

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8.2.3 Environmental exposure controls

Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more
information

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Clear
Odour Hydrocarbon odor.
Colour Amber
Odour threshold Not applicable

Property Values Remarks

pH No information available
pH @ dilution
Melting / freezing point No information available
Boiling point/range No information available
Flash point 72 °C / 161.6 °F Closed cup
Evaporation rate No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapour pressure No information available
Vapour density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Insoluble in water
Solubility in other solvents Oil soluble.
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity <10 cSt @38°C
Dynamic viscosity 12 cPs @20°C
log Pow Not determined

Explosive properties Not applicable

Oxidising properties None known

9.2 Other information

Pour point < -8 °C
Molecular weight No information available
VOC content(%) None
Density 0.84 ± 0.03 g/ml @ 25°C
0.85 ± 0.05 g/cm3 @ 20°C
Comments
The data listed above are typical physical and chemical properties and should not be construed as product specification.

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10. Stability and reactivity

10.1 Reactivity

Corrosive.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerisation
Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Avoid heat, flames and other sources of ignition. Take precautionary measures against static charges.

10.5 Incompatible materials

Strong oxidising agents. Strong acids. Strong bases. Halogens.

10.6 Hazardous decomposition products

See Section 5.2.

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Product information Prolonged and repeated contact with solvents over a long period may lead to permanent
health problems.

Inhalation Harmful by inhalation. Vapors may irritate throat and respiratory system. May cause
damage to organs through prolonged or repeated exposure. May cause additional affects
as listed under "Ingestion".

Eye contact Causes burns. May cause irreversible damage to eyes.

Skin contact Causes burns. May cause an allergic skin reaction. Repeated exposure may cause skin
dryness or cracking.

Ingestion May be fatal if swallowed and enters airways. Potential for aspiration if swallowed.
Aspiration may cause pulmonary edema and pneumonitis. Can burn mouth, throat, and
stomach.

Unknown acute toxicity Not applicable.

Toxicology data for the components

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Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Fuels, diesel = 7500 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 4.6 mg/L ( Rat ) 4 h
Lubricating Oil > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 2.18 mg/L ( Rat ) 4 h
Fatty acids C18 unsaturated, reaction products 2500 mg/kg (rat) No data available No data available
with tetraethylenepentamine
Hydrocarbons, C9, aromatics* 3492 mg/kg (Rat) >3160 mg/kg (Rabbit) >6193 mg/m³ 4hrs (Rat)

Sensitisation May cause allergic skin reaction.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity Contains a known or suspected carcinogen.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of exposure Ingestion. Skin contact. Eye contact. Inhalation.

Routes of entry Ingestion. Skin contact. Skin absorption. Inhalation.

Specific target organ toxicity - Not classified

Single exposure
Specific target organ toxicity - Category 2.
Repeated exposure

Target organ effects Respiratory system. Lungs.

Aspiration hazard May be fatal if swallowed and enters airways.

12. Ecological information

12.1 Toxicity

Toxic to aquatic life with long lasting effects

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Toxicology data for the components

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Fuels, diesel = 35 mg/L LC50 Pimephales No information available No information available
68334-30-5 ( 60-100 ) promelas 96 h
Lubricating Oil > 5000 mg/L LC50 Oncorhynchus No information available > 1000 mg/L EC50 Daphnia
( 5-10 ) mykiss 96 h magna 48 h
Fatty acids C18 unsaturated, reaction < 1 mg/L LC50 (Fish) = 96 h < 1 mg/L (Green Algae) = 72 h < 1 mg/L EC50 (Daphnia Magna)
products with tetraethylenepentamine = 48 h
1226892-45-0 ( 5-10 )

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Hydrocarbons, C9, aromatics* 1 - <10 mg/l 96 hrs 1 - <10 mg/l 1 - <10 mg/l 48 hrs
RM1003765 ( 1-5 ) Oncorhynchus Daphnia Magna
mykiss

12.2 Persistence and degradability

See component information below.

Chemical Name Persistence and degradability

Hydrocarbons, C9, aromatics* Readily biodegradable
RM1003765

12.3 Bioaccumulative potential

See component information below.

Chemical Name Bioaccumulation

Hydrocarbons, C9, aromatics* Does not bioaccumulate
RM1003765

12.4 Mobility in soil

Mobility
Insoluble in water.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

13. Disposal considerations

13.1 Waste treatment methods

Waste from residues / Dispose of in accordance with local regulations.

unused products

Contaminated packaging Empty containers should be transported/delivered using a registered waste carrier for
local recycling or waste disposal.

EWC Waste Disposal No According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific Waste codes should be assigned by the user based on the application
for which the product was used The following Waste Codes are only suggestions: EWC
waste disposal No: 07 01 04

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14. Transport information

14.1. UN number

UN/ID No. (ADR/RID/ADN/ADG) UN3267

UN No. (IMDG) UN3267
UN No. (ICAO/ANAC) UN3267

14.2. UN proper shipping name

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Fatty acids C18 unsat, rxn pdcts with tetraethylenepentamine)

14.3. Hazard class(es)

ADR/RID/ADN/ADG Hazard class 8
IMDG Hazard class 8
ICAO Hazard class/division 8

14.4 Packing group

ADR/RID/ADN/ADG Packing Group III
IMDG Packing group III
ICAO Packing group III

14.5 Environmental hazard

Yes

14.6 Special precautions

Hazard ID 80
EmS (IMDG) F-A, S-B
Emergency Action Code (EAC) 2X
Tunnel restriction code (E)

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC
Code Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Che micals

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Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation
(EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC
and 2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

International inventories

USA, Toxic Substances Control Act inventory (TSCA) Does not Comply
European Union - EINECS and ELINCS Complies
Canada (DSL) Does not Comply
Philippines (PICCS) Does not Comply
Inventory - Japan - Existing and New Chemicals list Does not Comply
China (IECSC) Complies
Australia (AICS) Does not Comply
Korea (KECL) Does not Comply
Inventory - New Zealand - Inventory of Chemicals (NZIoC) Does not Comply

Europe - REACH
All products supplied from the European Economic Area (EEA) are compliant with the REACH Regulation EC 1907/2006.For
products supplied from the EEA, Schlumberger and/or its suppliers have pre-registered and is registering all of the substances
that it and/or its suppliers manufactures in or imports into the EEA that are subject to Title II of the REACH Regulation. All
products supplied from outside the EEA are subject to REACH only if imported into the EEA. The importer of the products must
comply with REACH for each imported substance. Contact [email protected] for REACH information.

This SDS is not for use in the European Union (EU).

CAS Number 64742-95-6 can be used to identify the substance given a list number in section 3 in areas not subject to the
REACH regulation.

15.2 Chemical Safety Report

No information available

16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam

Supercedes date 04/Sep/2017

Revision date 01/Aug/2020

Version 8

This SDS has been revised in the All sections There have been changes with regard to classification.
following section(s)

Full text of H-Statements referred to under sections 2 and 3

H304 - May be fatal if swallowed and enters airways

H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction

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