Unit-1 (Principles of Chemistry)
Unit-1 (Principles of Chemistry)
points)
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Liquid to gas - boiling
Gas to liquid - condensing
Solid to gas - sublimation (eg. dry ice and “pa yote lone” )
Gas to solid - deposition
(solid to liquid)
● When the solid is heated, its particles will gain energy and vibrate
faster
● This would cause the particles to loosen the strong force of
attraction between them
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● The particles are able to move around and the solid melts into a
liquid.
(liquid to solid)
● When the liquid is cooled, the particles will move around more
slowly
● Their force of attraction will hold them in a fixed position and
particles will pace more closely
● The liquid freezes to form a solid
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(gas to solid) and (solid to gas)
Diffusion
● The spreading out of particles in a gas or liquid
● Particles will diffuse from high concentration to where there is
low concentration.
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Practical: showing that particles travel at different speed
Ammonia + hydrogen chloride → ammonium chloride
NH3(g) + HCl(g)→ NH4Cl (s)
Diffusion in liquids
● Diffusion through a liquid is very slow if the liquid is completely
still.
● This is because the particles in a liquid move more slowly than the
particles in a gas.
● The particles in a liquid are also much closer together than those
in a gas and so there is less space for particles to move into without
colliding with another one.
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1.4: know what is meant by the terms:
● solvent: the liquid that the solute dissolves
● Solute: the substance that dissolves in a solvent
● Solution: the liquid formed when solute dissolves in solvent
● saturated solution [2]: The solution that contains as much solute
as possible [1] at a particular temperature [1]
Solubility formula:
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1.7C(will not be included in paper-1): practical: investigate
the solubility of a solid in water at a specific temperature
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How to make the experiment accurate?
● Repeat step 7, again and again, until it gains a constant mass.
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E.g Oxygen gas (O2) E.g Water (H2O) Eg. air, coffee
Filtration
*To separate insoluble solid from liquid
*It can also be used to separate two solids from each other if
one of them is soluble in water.
Residue: the substance left in filter paper
Filtrate: the liquid that comes through the filter paper
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Crystallisation
EXTRA:
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Simple distillation
Process:
- Add the solution into the flask and connected with condenser
- Heat the solution
- The vapour will rise up and pass through the condenser
- The water was collected in the beaker
- The solute is left in the flask
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Fractional distillation
Process:
- Heat the mixture in the flask; ethanol will boil first
- Some water will evaporate too
- But at 78°C, ethanol will no longer condense back in fractionating
column and travel to the condenser
- The water will condense back into the flask
- Almost pure ethanol is produced
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Paper chromatography
- If the ink has the same distance travelled, it means the ink is the
same type.
-
- Spot that moved the farthest has the most soluble colouring.
(the greater the RF value → the more soluble the dye is)
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- Rf value is used to measure how much the ink has travelled from
the pencil line based on the total distance between the pencil line
and the solvent front
- It is a ratio and must be between 0 and 1
(steps)
- Draw a pencil line about 1cm of the bottom of the chromatography
paper
- Put the ink to test on the pencil line (let it dry)
- Suspend the chromatography paper in a beaker that contains a
small amount of solvent so that the bottom of the paper goes into
the solvent.
- Put a lid
- When the solvent has moved up to the top of the paper, draw the
pencil line in the same place again.
- Leave the paper to dry so that all the solvent evaporates.
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To careful:
- Base line has to be above the water level because if it is underwater
ink is most likely to dissolve.
-Base line should be drawn in pencil, not in pen because the ink
from pencil line might mix up with the experimenting ink and
contaminate the results.
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1.15: know the structure of an atom in terms of the
positions, relative masses and relative charges of
subatomic particles
(tip: in the exam, you would be expected to be asked to fill the table
as [1/3] mark Qs.)
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1.16: know what is meant by the terms atomic number,
mass number, isotopes, and relative atomic mass (Ar)
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Summary:
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Chapter 4: The Periodic Table
(Textbook Page 30-37)
*periods: rows
*Groups: columns
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In exam:
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Energy levels or shells
- The electrons move around the nucleus in a series of levels called
energy levels or shells
- Lower energy levels are always filled up before higher ones
- The first level (shell) holds two electrons the most, while the
second and third level hold 8 electrons. (2.8.8.2)
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1.20: understand how to use electrical conductivity and
the acid-base character of oxides to classify elements as
metals or non-metals
Comparison:
Metals Non-metals
can conduct electricity low conductivity of electricity
(because of delocalised (because they have no electrons
electrons) that are free to move) (except
graphite and silicon)
Form basic oxides Form acidic oxides
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More Comparison of their properties:
Metals Non-metals
High melting point and boiling Low melting point and boiling
point. point.
Shiny Not very shiny
Malleable and ductile brittle
Good conductor of heat and Poor conductor of heat and
electricity. electricity. (for heat, diamond is
exception)
Form ionic compounds Form ionic and covalent
compounds.
Form positive ions in their Form negative ions in their
compounds compounds
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Chapter 5 and 6
● Mole = Volume/ molar volume (this can only be done with gases)
(if volume is cm³, molar volume is 24000cm³)
(if volume is dm³, molar volume is 24dm³)
Do past papers
Preview (important)
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Chapter 7: Ionic bonding
(Textbook Page 75-84)
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Group Charge
1 1+
2 2+
3 3+
5 3-
6 2-
7 1-
Positive charges
Name Charge
Sliver (Ag) 1+
Copper (Cu) 2+
Iron (Fe) 2+ or 3+
Lead (Pb) 2+
Zinc (Zn) 2+
More charges
Hydrogen (H + ) 1+
Hydroxide (OH - ) 1-
Ammonium (NH4 + ) 1+
Carbonate (CO3 2- ) 2-
Nitrate (NO3 - ) 1-
Sulfate (SO4 2- ) 2-
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combinations of elements from Groups 1, 2, 3 and 5, 6, 7
only outer electrons need be shown
Another example:
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1.41: understand ionic bonding in terms of electrostatic
attractions
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1.41: understand why compounds with giant ionic lattices
have high melting and boiling points
Why do giant ionic lattices have high melting and boiling points? [3]
- Because of strong electrostatic force of attraction[1] between
oppositely charged ions[1] holding lattice together
- A lot of energy is needed to overcome those strong bonds [1]
•Soluble in water
•InSoluble in organic solvents.
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1.43: Don't conduct electricity in solid state but can conduct when
they are molten or aqueous because the ions can move around.
Summary:
Bonding, definition, structure, m.p and b.p, electricity conductivity,
physical properties.
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● inorganic molecules including water, ammonia and carbon
dioxide
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attraction can be used to represent all forces between
molecules
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1.50: explain how the structures of diamond, graphite
and C60 fullerene influence their physical properties,
including electrical conductivity and hardness
Diamond
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diamond and explain, in terms of its
bonding, why diamond has a high
melting point.[4]
- It has giant covalent structure
- Made with covalent bonds only
- (idea that) covalent bonds are broken
- (Covalent bonds) are strong/require a lot
of energy to break them
EXTRA:
Graphite
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(yes) - Because delocalized electrons of graphite are
free to move around
Melting and boiling point - Very high melting and boiling points because
(very high) of very strong carbon-carbon covalent bonds
- So a lot of energy is required to break those
bonds
EXTRA:
- Insoluble in all solvents
Solubility - Because it takes a lot of energy to break all the
(no) strong covalent bonds
Density - Less dense than a diamond because the layers
(less dense than diamond) of molecules are far apart
C60 fullerene
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Physical property - Easy to break down
(is soft) - Because Intermolecular forces of attraction between
layers are weaker and not much energy is needed to
overcome them
Electricity conductivity - don't conduct electricity
(no) - because electrons cannot jump from molecule to
molecule
Melting and boiling - Low high melting and boiling points because only
point (low) weak intermolecular forces of attraction between
molecules must be broken.
- No covalent bonds breaking
- So less energy is needed
EXTRA: - C60 fullerene has been suggested as being useful in
the treatment of cancer.
Unique points - They can act as hollow cages to trap other molecules
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[paper 2 only]
Chapter 9: Metallic bonding
(Textbook Page 98-100)
Example:
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1.54C: explains typical physical properties of metals,
including electrical conductivity and malleability
Structure
- All have giant structures and have no individual molecules
- Electron sea model
Electrical conductivity
- Conduct electricity
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Alloy
Why is metal alloy harder than pure metals? [3]
- The different metals have slightly different sizes of atoms
- This breaks up the regular lattice arrangement
- It is more difficult for the layers of ions to slide over each
other
[paper 2 only]
Chapter 10: Electrolysis
(Textbook Page 101-113)
1.57C: know that anion and cation are terms used to refer
to negative and positive ions respectively
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Key terms:
Electrolysis: It is a chemical change caused by passing an electric
current through a compound which is either molten or in solution.
Electrolyte : It is a liquid or solution that undergoes electrolysis.
-Contain ions.
Electrodes properties: (electrodes used: platinum or carbon)
1. Must conduct electricity
2. Must be inert (unreactive)
Catre
Cathode → reduction
Anode→ oxidation
(step-by-step)
- In a liquid or an aqueous solution, there are ions with charges.
- In this case, there are Pb 2+ and Br - ions and they can move
around freely
- The electrodes to which electricity is connected will attract those
ions (opposite charges attract)
-This means Br - ions will lose electrons to the anode (because
opposite charges attract) and become bromine gas (Br2).
- The Pb 2+ ions will gain electrons from the cathode which would
discharge them and become molten pure lead.
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- The electrons lost from the Br - ions will go to the Pb 2+ ions
(from anode to cathode)
- Electricity is needed to charge the electrodes to attract the ions
and make them discharge.
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