SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.

Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT-BTs JEE-MAIN Date: 11-01-2024
Time: 09.00Am to 12.00Pm GTM-11 Max. Marks: 300
KEY SHEET
PHYSICS
1) 1 2) 3 3) 1 4) 3 5) 4
6) 1 7) 2 8) 4 9) 4 10) 3
11) 2 12) 3 13) 2 14) 3 15) 4
16) 2 17) 4 18) 3 19) 1 20) 3
21) 4 22) 4 23) 5 24) 5 25) 3
26) 3 27) 7 28) 2 29) 54 30) 2

CHEMISTRY
31) 2 32) 4 33) 3 34) 1 35) 4
36) 3 37) 3 38) 2 39) 1 40) 1
41) 3 42) 2 43) 2 44) 1 45) 3
46) 1 47) 4 48) 4 49) 1 50) 2
51) 600 52) 12 53) 2 54) 2 55) 5
56) 84 57) 5 58) 5 59) 25 60) 3

MATHEMATICS
61) 1 62) 2 63) 1 64) 1 65) 2
66) 2 67) 3 68) 3 69) 3 70) 3
71) 4 72) 3 73) 2 74) 4 75) 1
76) 1 77) 3 78) 2 79) 3 80) 2
81) 7 82) 9 83) 2 84) 55 85) 5
86) 1 87) 4 88) 2 89) 300 90) 1002

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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

SOLUTIONS
PHYSICS
1. G    M 1 L3T 2 
 c    LT 1 
 h   ML2T 1 
x y z
 M o LT
1 o
   M 1 L3T 2   LT 1   ML2T 1 
x  z  0 3x  y  2 z  1
2 x  y  z  0
1 3 1
x  ,y   ,z 
2 2 2
1
 x  y x
   16
 z 
2. t is independent of 
3.

u2 u2
Rmax  Rmin 
g/ 2 2g
Rmax
2 2
Rmin
l010a.e  kx  kx 
4. L  10 log dB  10[log10a  log e  kx ]  10  a  dB
l0  2.3 
20  2t
7. a
2
a  10  t
v 2

 dv   10  t dt
0 0
2
 t2 
v  10t  
 2 0
 20  2  18m / s
9. By equation of continuity
1 A  A2VB
AV
VB  4VA  16 m / s
Bernoulli’s theorem at point A and B
1 1
PA  VA2  PB  VB2
2 2
1 1
2.8  105   900   4   PB   900  16 
2 2

2 2
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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

PB  172  10 N / m
3 2
 172kNm2   43  4 kNm2  K0  4
q q 3q
10.  Curved surface =  (1  cos  ) 
0 2 0 4 0


11. At t  , i 
2R
 3
At t  0, i  
R 4R
R R
2
R
R
2
 4R 2
Ratio = 
2 R 3 3
12. Conceptual
dl
dl  10000;V  30
14. Sol.  5000;V  15 dt
dt
L  3 mH for 4  6ms
V
L  3 mH , For 0  2ms
dl
dt
 
15. M  iA(  K )  4 (0.5) 2 K
 
M   K
     
T  M  B     K   10 i  10 J
 
2
mR 1 1
 2  0.5  
2
l
2 2 4
T 10
   40 rad / s 2
I 1
4
L L
 bx 
0  dm  x 0  a  L  dx.x
16. xcm  L  L
 bx 
0 dm a  a  L  dx
17. i  iz  iL
iz  i  iL
19.

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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

E  1 107  200 109

20. n   11011
hc 6.6 1034  3 108
1011
Number of electrons ejected = 3  108
10
q
v 
4 0 r


10 8
1.6 1019   9 109
 3V
4.8 102
3
21. For minima the minimum path difference is , then
2
3
 2 
2
 y2  y 
2
7
y
12
22. n  2 r
n2
 2 a0
z
4
2  2 a0
1
23. If the time of penetration is  t
Then resistance force
mv0
F
t
For reaction at the end
3a a
F  Mg 
4 2
mv0 3a Mga
 
t 4 2
3 mv0
t 
2 Mg
24. Impulse =change in momentum=J
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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S
Initially mass m is at rest .
 it will gain the momentum J.
At maximum compression the block and car will move with same velocity and
J2
momentum J.  KE of system at this instant 
2  5m 
J2
Initial KE=  From conservation of energy
2m
J2 1 2 J2 1 4J 2
 kx   kx 2 
m 2 2  5m  2 2  5m 
4J 2 2J
or x  
5mk 5mk
3RT 3R  373 3R  T
25. Vms  V   3V 
M M M
T T
 3 3  T  3  373  1119 K
373 373
T  o C   846o C
F sin 
26. area AB  tan 
F cos 
area AB
27. By MEC,
KEi  PEi  KE f  PE f
2
GMm 11 GMm 1  R 
0  0  K 
2R 8 R 2 2
7GMm
K
R3
13.6 nh
28. E  2 &L
n 2
29. K1  K 2  5.5MeV
And P1  P2
30. I A  I cm  md 2

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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

CHEMISTRY
31.
 CH 3 3 C  CH3 3 C OH
CO2 Et

CH 3 MgBr
etherH 2O


H 2 SO4 , 00 C

COCH 3

 CH3 3 C  CH3 3 C


AlCl3
CH 3COCl


32. Glucose, Fructose and Mannose produces same osazone.

33. At C1 and C3 carbon dotted line species must be on the same side and opposite to C2
carbon species.
34.
Cl Br
Cl
HBr (Electrophilic addition)

A) Cl Br
HBr
peroxide (free radical addition)

Anhy HI
SN 2 OH I
B)
cone
HI I
OH
1
SN
SOCl2 CH 3  CO  Cl
O

C) CH 3  C  OH
Re dp Cl  CH 2  CO  OH
Cl2

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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

CH 3 CH 3 CH 3
D)

H OH 
Na
 H ONa 
CH3Cl
SN 2
H OMe

14CH 3 14CH 3 14CH 3

CH 3 CH 3
Red p
I H 
MeONa
SN 2
 H OMe
I2

SN 2 14CH 3 14CH 3

35. cyclohexanol is more soluble in water. 1-hexanol can form inter molecular H-bond

with water
36.
OH



H 2O / H
 
OH O O
CHO
H HO
H OH

37. Reaction is Benzoin condensation.

38. In case of NI 3 , the lone pair moment adds on the resultant of the N  I moments but in
case of NF3 , the lone pair moment on N partly cancels the resultant N  F moments.
39. NaCl reacts with conc. H 2 SO4 to give colourless fumes of HCl which on treatment with
MnO2 get oxidized to yellowish green coloured Cl2 gas.
40. Only 10 aliphatic amines are prepared. 3, 4 cannot be prepared because of steric
hinderence.
41.
42. N 2 H 4 is not a chelating and ambident ligand.
43. Total 3 isomers 2 are cis and 1 are trans
2MnO2  2 K 2CO3  O2  2 K 2 MnO4  CO2
44.
X Y 
2 KMnO4  Cl2  2 K 2 MnO4  2 KCl
Z 
45. 2CuSO4  4 KI  Cu2 I 2  I 2  2 K 2 SO4
KI  I 2  KI 3
46. Both NO2 and NO3 gives brown gas with H 2 SO4 .

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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S
47.
Y Y

Z Z
P Y P Z

Z Z

Y Y
Non zero zero
48. The   bonding molecular orbital possess two nodal palnes.
34.5
49. V.P  with  in temperature. T f  i.K f .m  1 2   1000  3
46  500
50.
N 2  3H 2  2 NH 3

Initial: 1 3 0

Af eq 1  x 3  3x 2x
Out of 4 moles 2 moles are reacted
1  x  3  3x  2  x  0.5
1 p
Total moles at eq  1  x  3  3x   2 x  3 PNH 3   p 
3 3
Q1 T1 Q T Q  Q2 T1  T2
51.    1 2  1 2  1 
Q2 T2 Q1 T1 Q1 T1
w T1  T2 w 1000  800
     w  600 J
Q1 T1 3000 1000
2.303 a
52. When t  t114 , a  a 0 / 4 t1/ 4  log 0
K a0 / 4
When t  t1/10 , a  a0 / 10 then
2.303 a0 t1/ 4 2.303 K
t1/10  log  20  log 4   20
K a0 / 10 t1/10 K 2.303  log10
log 4 2 log 2 2  0.3  20
  20   20   12
log10 log10 1
cell constant 1.15
53. conductivity (K)    5  10 3 s cm 1
Resistance 230
K 1000 5  103 103
Equivalent conductivity   eq     2 ohm 1cm 2 eq 1
normality 2.5
103 
2 2
0.059  Fe 2  0.059
54. EE  0
log  1.67  log
103    0.1
4 4
n  H    PO2  4
0.059
E  1.67  log107  1.67  0.103  1.567  2
4
55.  NH 2 S  Fe3  FeS  S  NH 4
HI  Fe 3  FeI 2  I 2 Sn 2  Fe 3  Fe 2  Sn 4

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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S
3
CN   Fe 3  Fe  CN 3  
excess
CN 
  Fe  CN 6 
yellow ppt
3
NaNO2  Fe  NO reaction SO2  Fe 3  Fe 2  SO42
S 2O32  Fe 3  Fe 2  S 4O62 SCN   Fe 3  Fe  SCN 3
Blood red
3 
NaIO3  Fe  H  No reaction
56. Equivalents of Na2C2O4  Equivalents of KMnO4
= total equivalents of KMnO4  excess equivalents of KMnO4 reacted with H 2C2O4
1000  W  2
 45  0.02  5  10  0.1 2  W=0.1675gm
134
0.1675
% purity =  100  83.75%  84%
0.2
57. Conceptual
58. a, b, c, e, f are true.
1.86  1 1000
59. T f  K f .molality  M  acid observed   120
0.155  100
Eq. acid = Eq. base
0.75 1 Normal 150
 1000  25   M  acid  Normal  150  i=   1.25
M acid 5 observed 120
i  1      0.25  %  25
  .. ..
60. O H ,  N HCOR,  CH  CH  COOH ,  N H 2 ,  N O


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 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S

MATHEMATICS
61. f  x has minimum value at x  1
62. x  v  2 xdx  dv
2

1 ev v 2
f t    dv
2  v 2  2v  2 2


1 v 1 2v  2 1 ev
 e  dv 
2  v  2v  2  v  2v  2 2
2 2 2 v 2  2v  2

t
1  1 1
2 2
ex et
 f t    4     
2  x  2 x  2  0 2  t  2t  2 2 
2 4 2

2 5
e 1 et t e 7e 1
f 1   f t  
1
 f 1 1   f 1  f 1 1  
 t 4  2t 2  2 
2
10 4 25 50 4

x2 y 2
63.   1, x 2  y 2  8 x  0
9 4

x2 x2  8x 6
 1  13 x 2  72 x  36  0  x  6,
9 4 13

But x  6 is acceptable


A 6, 2 3  B  6, 2 3 
Equation of circle is x 2  y 2  12 x  24  0
dy  x  2    y  2 
64. 
dx  x  2    y  2 
Put x  2  h, y-2=k
dk h  k dv 1  v
 met k=vh  v+h 
dh h  k dh 1  v
1V 1
 dv   dh
1V 2
h
1
 tan 1  v   log 1  v 2   log h  c
2
1  y  2  1   y  2 2 
tan    log 1    log  x  2   c ______ 1

 x2 2   x  2 
2

 3, 2   0  0  c  c  0
Also (1) passes through  P  2, 3
1 1  1  1
tan 1    log 1  2   log p 2 tan 1    log 1  p 2 
 p 2  p   p
The equation of the circle is  x  h    y  k   k 2
2 2
65.
If passes through  1,1 then  1  h   1  k   k 2
2 2

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1
h 2  2h  2k  2  0    0  4  4  2 k  2   0 k 
2
2 2
66. e
2
67. A  x  y  z  12, x  1, y  1, z  1 11C2  55

No. of ways of getting one correct  7C1 6!1  

1 1 1 1 1 1
68.       7C1  265 
 1! 2! 3! 4! 5! 6! 
No. of ways of getting two correct  7C2 5!1        7C2  44 
1 1 1 1 1
 1! 2! 3! 4! 5! 
No. of ways of getting three correct  7C2 4!1       7C3  9 
1 1 1 1
 1! 2! 3! 4! 
Required no. of ways  7C1  265   7C2  44   7C3  9 
 e x  1   1  cos x 
2 2
e x  cos x 1 3
69. Lt  Lt       1 
x2 x 0  2 2
2 2
 x   x 
x 0

71. n  S   55 n  A   5C2  1  1  3  or 1  2  2    1500

1500 12 1
p   p  2
55 25  
n x n x 200  25  300  10
72. x 1 1 2 2   16
n1  n2 500
n1  12  d12   n2  22  d 22 
d1  x1  x  9, d 2  x2  x  6  
2
 67.2
n1  n2
74. Lt f  x   f  0 
x 0

5  a  10  a  5
75. Total non empty subsets – Subsets with product is odd.
1
76. Area  PR  QS
2
x 2  4 x  30
77. Let f  x   3  2  3  x  7  37
x  8 x  18

f  x1   f  x2   3 , but x1  x2

 f is not one-one
m 3
78. tan 600   m  0 or 3
1  3m
y  2  3  x  3  y  3 x  2  3 3  0
79.
r

C1C2  2r
2  r  2 r  r 2  4r  4  0

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 11

 SRI CHAITANYA IIT ACADEMY, INDIA 11‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐11_KEY &SOL’S
80. f  x   tan  2 x  3  tan  2 x  2   tan 1  2 x  4   tan 1  2 x  3
1 1

 tan 1  2 x  5   tan 1  2 x  4   tan 1  2 x  6   tan 1  2 x  5 

 tan 1  2 x  6   tan 1  2 x  2 
 r 3
81. Focus of parabola is  3, 5  let  be angle between focal orders then tan  
2 s11 5
15
tan  
8

82.
lt
e x0
 2  2 cos x cos 2 x   x  3  e    e
3 3 9

x2
4 1  2x 1   x 1
83. e 2 x  4e x  58  x
 2x  0  e  2 x   4  e  x   58  0
e e  e   e 
 x 1 
 e  x  p   p  2  4 p  58  0 p  4 p  60  0
2 2
 p  10  p  6   0
 e 
85. PA  PB is minimum when R lies on AB  PA  PB  AB  5
1
86. a .b  a .c  0 , b.c=
2
1 0
2
a b  a c 1 a  b  a  c  11 2 1  1  1 1  1
0
2
87.
D

 /4

B A 2
 2

a 2b 3c
88.   116  0 , both roots are common    a  3, b  4, c  5
3 8 15
ABC is right angle triangle
89. a 1  r  r 2   70
4 a , 5ar , 4 ar 2  A.P
1
5r  2  2r 2  r  2,
2
If r  2, a  10
 2x  x 
2

1  x 
1000
90. 1   3   ...........
 1  x  1 x  
2
 x 
 1  x 
1000
1  
 1 x 
2
 1 
 1  x   1  x 
1000 1002
 
1 x 

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 12