JEE

Prayas JEE 90 Days Crash Course 2025

Chemistry
DPP: 3
Atomic Structure

−−
Q1 When electron jumps from the fourth orbit to (D) λ = √
h

m
the second orbit in He ion, the radiation
+

emitted out will fall in Q6 In H-atom, if ' x ' is the radius of the first Bohr
(A) ultraviolet region orbit, de Broglie wavelength of an electron in
(B) visible region 3
rd
orbit is
(C) infrared region (A) 3πx

(D) radio wave region (B) 6πx

(C) 9x

Q2 The wavelength of radiation emitted out in 2

(D) x

the transition n to n in Li ion is

2+ 2
= 4 = 1

(A) 135R

16 Q7 If the uncertainty in position of a moving particle

(B) 16

135R
is 0 then find out ΔP
(C) 16R

135
(A) 0 (B) 1
(D) 135
(C) Infinite (D) None of these
16R

Q3 Number of possible spectral lines in the Brackett Q8 Which of the following is the correct form
series in the hydrogen spectrum, when electrons of Schrodinger wave equation? .
(A)
2 2 2

present in the ninth excited state return to the ∂ ψ ∂ ψ ∂ ψ 16π

2
m
+ + + (E − V )ψ = 0
2 2 2 2
∂ x ∂ y ∂ z h
ground state, is
(B)
2 2 2
∂ ψ ∂ ψ ∂ ψ 2
8π m
+ + + (E − V )ψ = 0
(A) 36 (B) 45 ∂x
2
∂y
2
∂z
2
h
2

(C)
2 2 2

(C) 5 (D) 6
∂ψ ∂ψ ∂ψ 2
4π m
+ + + (E − V )ψ = 0
2 2 2 2
∂x ∂y ∂z h

(D)
2 2 2
∂ ψ ∂ ψ ∂ ψ 2 2
8π m
Q4 An α-particle is accelerated through a potential ∂x
2
+
∂y
2
+
∂z
2
+
2
(E − V )ψ = 0
h

difference of V volts from rest. The de Broglie's

Q9 Which of the following radial distribution graphs
wavelength associated with it is:
corresponds to l = 2 for H atom for the least
(A) −−−
150
o

√
V
A
value of n for which l = 2 is allowed?
(B)
o
0.286
A
(A)
√V

(C)
o
0.101
A
√V

(D)
o
0.983
A
√V

Q5 If wavelength is equal to the distance travelled

by the electron in one second, then: (B)
(A) λ =
h

(B) λ =
h

m
−
−
(C) λ = √
h

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–
(D) √2 h

2π

Q14 The orbital diagram in which the Aufbau principle

is violated
(A)

(C) (B)

(C)

(D) (D)

Q15 Which of the following electron configurations is

correct for iron, (atomic number 26)?
(A) [Kr]4s1 3d6
(B) [Kr]4s1 3d7
(C) [Ar]4s2 3d6
Q10 Which one of the following set of quantum (D) [Kr]4s2 3d6
numbers is not possible for electron in the
ground state of an atom with atomic number 19 ?
(A) n = 2, l = 0, m = 0

(B) n = 2, l = 1, m = 0

(C) n = 3, l = 1. m = −1

(D) n = 3, l = 2, m = +2

Q11 The angular momentum of an electron in 2p

- orbital is:
(A) h

2π

(B) h

√2 π

(C) 2h

(D) None of these

Q12 How many electrons in an atom can have

n = 4, l = 2, m = −2 and s = +
1

2
?
(A) 1 (B) 2
(C) 5 (D) 10

Q13 The orbital angular momentum of 3p electron is :

–
(A) √3 h
–
(B) √6 h

(C) zero

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Answer Key
Q1 (B) Q9 (C)

Q2 (B) Q10 (D)

Q3 (D) Q11 (B)

Q4 (C) Q12 (A)

Q5 (D) Q13 (D)

Q6 (B) Q14 (B)

Q7 (C) Q15 (C)

Q8 (B)

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