SEC: JR_*CO-SC Date: 31-10-21

Time: 3 Hrs Max. Marks: 186

31-10-21_JR.IIT_STAR CO-SC (MODEL-A)_JEE ADV_WAT-25_SYLLABUS
PHYSICS: PRESENTWEEK (80%): Surface Tension : Definition of surface tension,
Force required to lift objects from surface of liquids, Surface energy,
relation between surface tension and surface energy, Capillarity, Angle
of contact, rising of liquid in a capillary tube, excess pressure inside a
liquid drop, soap bubble,Surface tension, Experiment: Surface tension
of water by capillary rise and effect of detergents

PREVIOUS WEEK (20%): Elasticity & Viscosity: Elastic

behaviour,stress-strain relationship,Hooke's Law,Young's
modulus,bulk modulus, Elasticity experiment: Young's modulus of
elastisity of the material of a metallic wire Viscosity: Viscus force
between two layers,stoke's law terminal velocity,,Experiment: Co-
efficient of viscosity of a given viscous liquid by measuring terminal
velocity of a given spherical body. (exculiding - thermal stess ,
Rynolds number,Poiseuilles equation)

CHEMISTRY: PRESENTWEEK (80%): Oxides and oxo acids of nitrogen, allotropes

of phosphorus, preparation & properties of Phosphine, Oxides,
chlorides and oxoacids of phosporus

PREVIOUS WEEK (20%): Structure and properties of silicates ,

preparation of silicones ,uses .
GROUP 15: General characteristics of elements and their
compounds, Preparation & properties of Nitrogen & Ammonia

MATHEMATICS: 100% Complete Limits

Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. When two soap bubbles of different radii coalesce, some portions of their surfaces
make a common surface. At any point on the circumference of the common surface,
the three surfaces meet at angles  ,  and  . What relation should these angles bear?

A)    B)      C)      D)     
2. Water in a clean aquarium forms a meniscus, as illustrated in the figure.  is surface
tension and  is density of liquid. Calculate the difference in height h between the
centre and the edge of the meniscus.

  2 
A) B) C) D)
g 2 g g 3 g

3. A glass capillary tube is of the shape of truncated cone with an apex angle  so that
its two ends have cross-sections of different radii. When dipped in water vertically,
water rises in it to a height h, where the radius of its cross-section is b. If the surface
tension of water is S, its density is  , and its contact angle with glass is  , the value
of h will be (g is the acceleration due to gravity)

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
2S 2S
A) cos     B) cos    
b g b g

2S 2S
C) cos    /2  D) cos    /2 
b g b g

4. Water is filled up to a height h in a beaker of radius R as shown in the figure. The

density of water is  , the surface tension of water is T and the atmospheric pressure is
p 0 . Consider a vertical section ABCD of the water column through a diameter of the
beaker. The force on water on one side of this section by water on the other side of this
section has magnitude

A) 2p 0 Rh   R 2  gh  2RT B) 2p 0 Rh  R gh 2  2RT

C) p 0 R 2  R gh 2  2RT D) p 0 R 2  R gh 2  2RT

5. A glass tube of uniform internal radius (r) has a valve separating the two identical
ends. Initially, the valve is in a tightly closed position. End 1 has a hemispherial soap
bubble of radius r. End 2 has sub-hemispherical soap bubble as shown in figure.
Just after opening the valve.

A) air from end 1 flows towards end 2. No change in the volume of the soap bubbles

B) air from end 1 flows towards end 2. Volume of the soap bubble at end 1 decreases

C) no change occurs

D) air from end 2 flows towards end 1. Volume of the soap bubble at end 1 increases

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
6. A glass capillary is held at rest by touching its lower end to a liquid bath. Liquid wets
the glass and rises in capillary. Express the surface tension force exerted by liquid on
capillary tube. Given that internal and external radius of capillary tube are Rin =a and
Rout = 1.1a respectively,  is the angle of contact. Take Tsl = surface tension of solid-
liquid interface, Tla = surface tension of liquid-air interface, Tsa = surface tension of
solid-air interface,  is density of liquid and g is acceleration due to gravity.

A) 4.2 aTla  cos  B) 4.2 a  Tsa  Tsl  cos

C) 4.2 a  Tsa  Tsl  Tla cos  D) 2.1 a  Tsa  Tsl  Tla cos 

7. Two light bodies are kept floating on the surface of water very close to each other as
shown below. Water surface takes different shapes depending on the surface nature of
the bodies. Identify true situations from the following arrangement:

both the bodies get pulled towards each

A)
other.

B) both the bodies get repelled.

C) Both the bodies get repelled

D) Neither repulision nor attraction

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
8. An amount of water is poured on top circular face of a large horizontal glass cylinder.
Excess amount of water spills over the edges and a little amount of water remains
there in a thin uniform layer, a portion of which is shown in the figure. If contact angle
is ‘ ’ and surface tension of water is ‘  ’ the vertical thickness of the water layer far
away from the edge is ‘t’. The point in the plane of the diagram on the liquid where
the liquid protrudes the most is ‘D’. The vertical depth of this point from the
horizontal free surface of the water layer is ‘d’. ‘  ’ is density of water and ‘g’ is
acceleration due to gravity. Mark the Correct relation(s).

2 1  sin   2 1  cos 
A) t  B) t 
g g

2 2 1  cos 
C) d  D) d 
g g

9. In the figure shown, there is a conical shaft rotating on a bearing of very small
clearance t. The space between the conical shaft and the bearing is filled with a
viscous fluid having coefficient of viscosity  . The shaft is having base radius R and
height h. If the external torque applied by the motor is  and the power delivered by
the motor is P working in 100% efficiency to rotate the shaft with constant  then

 2 R 3 R 2  h 2  R 3 R 2  h 2
A) P  B)  
2t 2t

 2 2 R 3 h 2  2 R 3 h 2
C) P  D)  
2t R 2  h 2 2t R 2  h 2

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
10. Pure distilled water is taken in a clean capillary tube of silver. The surface of water is
found to be exactly horizontal. Select the incorrect option(s).

A) In a silver container, the surface tension of water becomes zero.

B) Adhesive force between water and silver molecules is zero.

C) For a molecule of water in contact with silver (at corner), the resultant cohesive
force due to water molecules is 2 times the resultant adhesive force due to molecules
of silver.

D) Angle of contact is zero for water in a silver interface.

11. An elastic rod of length  , Young’s modulus Y and area of cross section A is rotating
with angular velocity  about its centre on a smooth surface. (m = mass of rod)

 3 m 2 
A) The stress at distance from the centre of rod is
4 32 A

m 2  2
B) The elongation in the rod is
12AY

m 2 2  2
C) The elastic potential energy stored in the rod
360A 2 Y

m 2 2  2
D) The elastic potential energy stored in the rod
120A 2 Y

12. When liquid medicine of density  is to be put in the eye, it is done with the help of a
dropper. As the bulb on the top of the dropper is pressed, a drop forms at the opening
of the dropper. We wish to estimate the size of the drop. We first assume that the drop
formed at the opening is spherical because that requires a minimum increase in its
surface energy. To determine the size we calculate the net vertical force due to the
surface tension T when the radius of the drop is R. When the force becomes smaller
that the weight of the drop, the drop gets detached from the dropper (  is the density
of liquid). Select the correct options.

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
A) If the radius of the opening of the dropper is r, the vertical force due to the surface

tension on the drop of radius R (Assuming r << R) is 2 r 2 T / R

1
 3r T 2 4
B) the radius of the drop when it detaches from the dropper is approximately  
 2 g 

C) The radius of the drop when it detaches from the dropper is approximately

1
 3r T 
2 4
 
 4 g 

D) As the drop detaches, it’s surface energy is 8 R 2 T

13. Two vertical plates submerged partially in a wetting liquid form a wedge with a very

small angle  . The edge of this wedge is vertical. The density of the liquid is  , its

surface tension is T, the contact angle is 0 . Choose correct options.

A) The height to which liquid rises as a function of distance x from the edge is

T
2  gx  

B) The pressure just below the surface of liquid near the edge will be less than

atmospheric pressure.

C) A convex meniscus will be formed near the edge.

D) The height to which liquid rises as a function of distance x from the edge is

2T
 gx  

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. When a film of soap solution is created inside a loop formed by rectangular wire frame
and an inextensible light thread AB of length l, the thread assumes shape of a semicircle
and remains equilibrium. By pulling the midpoint of thread with a force F, the thread
can be given shape of two semicircles as shown in figure. If surface tension of soap
F
solution is , find x.
x

15. An air bubble of radius 1 mm is allowed to rise through a long cylindrical column of a
viscous liquid of radius 5 cm and travels at a steady rate of 2.1 cm/s. If the density of
n
the liquid is 1.47 g/cm3, its viscosity is nearly poise. Then find the value of n.
2
Assume
g = 980 cm/sec2 and neglect the density of air.
16. A vertical capillary with inner diameter 0.50mm is submerged into water so that the
length of its part protruding over the water surface in 25mm. The radius of curvature of
the meniscus is x  104 m . Find x to nearest integer.
(Surface tension of water = 73 × 10–3 N/m)
17. There is small hole in a hollow sphere. The water enters in it when it is taken to a depth
of 40cm under water. The surface tension of water is 0.07 N/m. The diameter of hole is
7  10 n m . Find n.
18. A wire of length 1 m and area of cross section 2 ×10–6 m2 is suspended from top of a
roof from one end and a load of 20 N is applied at the other end. If the length of the
wire is increased by 0.5×10–4 m, calculate its Young’s modulus in 1011 N / m2.

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. When P4 O 7 react with H 2 O then the no. of mol of +5 oxidation state oxy Acid and +3
oxidation state oxy acid obtained are respectively.

A) 1 mol, 3 mol B) 2 mol, 2 mol

C) 3 mol, 1 mol D) 4 mol, 1 mole

20. The product obtained by the hydrolysis of hypophosphoric acid and

Isohypophosphoric acid are respectively.
A) both gives same product after hydrolysis
B) H3PO 4 and H3PO 2
C) both can give 3 mol H3PO3
D) hydrolysis is not possible.
21. 2NF3  3H 2 O 
high temp
 A  6B
steam

Incorrect statement regarding above Rxn is

A) compound A is anhydride of nitrous acid
B) compound A has two sp 2 hybridized nitrogen atom
C) A is monobasic acid
D) The first step of this reaction is elimination of F ion
22. Which of the following compound does not give oxyacid of central atom on
hydrolysis?

A) SiCl4 B) NCl3 C) PCl3 D) PCl5

23. Heating of ammonium dichromate produces:

A) NH3 , Cr2O3 and H 2 O B) N 2 , Cr2O3 and H 2 O

C) NO, CrO3 and H 2O D) N 2O, CrO3 and H 2O

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. Consider the following reactions:
 zB2
A x  yB2 
limited
sup ply of air
compound ' p ' 
excess air
 compound 'Q '

If atomic number of elements A and B are 15 and 8 respectively, then according to the
given information the correct statement(s) is /are:

A) (B–A–B) bond angle in compound ‘Q’ > (B–A–B) bond angle in compound ‘P’

B) (A–B) bond length in compound ‘Q’ < (A–B) bond length in compound ‘P’

C) Value of x + y + z is 9

D) compound ‘P’ is P2 O5 and compound ‘Q’ is P4 O10 .

25. Correct statement(s) about hydrolysis of H 5 P3O10 is/are:

A) H 4 P2O6 can be formed by its partial hydrolysis

B) Hydrolysis is proceeded by SN AE mechanism

C) Complete hydrolysis produces H3PO 4

D) H 5 P3O10 is obtained by hydrolysis of H 3P3O9

26. Select the correct statement about silicates:

A) Cyclic silicate having three Si atoms contains six Si–O–Si linkages.

1
B) 2 over oxygen atoms of per tetrahedron unit are shared in double chain silicate
2

C) (Si 2 O5 ) n2n  is formula of double chain silicate

D) SiO 44 units polymerize to form silicate because Si atom has less tendency to form

 - bond with oxygen

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
27. Which is true about N 2O5 ?

A) It is anhydride of HNO3

B) In solid state it exists as NO 2 NO3

C) It is structurally similar to P2 O5

D) It can be prepared by heating HNO3 over P2 O5

28. Orthophosphoric acid 

gentle heat
220ºC
X

What is /are correct about X?

A) It is a tetrabasic acid

B) It contains one P–O–P bond

C) It is a dibasic acid

D) on hydrolysis it produces metaphosphoric acid

29. Identify the correct statement(s):

A) P4 O10 is used as a drying agent

B) P4 O10 contains p  d back bonding

C) in P4 O10 each P atom is bonded to three oxygen atoms

D) P4 O10 hydrolyse in water forming phosphorus acid

 H2O [O]
30. 2P   Q  R

If P is parent phosphoric acid then according to given information the correct

statement is/ are:

A) Q is Pyro form and R is hypo form of given present oxy acid P

B) Number of H – atoms present in each given oxy acid is equal to its basicity

C) In P, Q, R oxy acids, oxidation state of central atom remains same.

D) All given oxy acids have p  d bond(s) in their structure.

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
31. The correct statement(s) regarding PCl5 is/are:

A) In solid phase, hybridization of P –atom in cation is sp3

B) In vapour phase, all P – Cl bond lengths are equal

C) In vapour and solid phase, central atom has no lone pair

D) In solid phase, anion has only one type of bond angle

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. Hydrolysis of NCl3 gives NH3 and X. What is the basicity of X?

33. How many following Ammonium salts will evolve N 2 gas on heating?

(NH 4 ) 2 CO3 , (NH 4 ) 2 Cr2 O 7 , NH 4 NO 2 NH 4 ClO 4 , NH 4 Cl, (NH 4 ) 2 S, (NH 4 ) 2 C2 O 4

34. How many following ammonium salts will evolve NH3 gas on heating?

(NH 4 ) 2 CO3 , (NH 4 ) 2 Cr2 O 7 , CH 3COONH 4 , NH 4 ClO 4 ,

NH 4 Cl, (NH 4 ) 2 S, (NH 4 ) 2 C 2 O 4 , (NH 4 ) 2 SO 4 , NH 4 NO3

35. SiCl 4 

H2O
 X 
1000
Y

In the above reaction, how many oxygen atom(S) is/are present in X and Y?

[If answer is 6 and 4, represent as 64]

36. In silica, SiO 2 , each silicon atom is bonded to how many oxygen atom?

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
 2 x  x ln 2  
1/ x 2

37. The value of the limit, lim   is

x0  3  x ln 3 
x

 ln2/3  ln3/2  ln 6 
 2 
ln 6 
   
 3  2 
A) 6  2 
B) 6  2 
C)   D)  
 3  2
 1 

38. The value of lim
x1
 x  x1 is (where [.] Greatest Integer Function)
A) 0 B) 1 C) does not exist D) None of these
1
4  x2 1
39. lim  tan 1 x is equal to
x1 
 
1 1
1 1 
A)  B) C) e 
D) e 
 
40. If ,  ,  where      (in order) are three roots of a cubic equation f  x  0 which
are in arithmetic progression with common difference 3 and the leading coefficient of
1
  x 
cubic is 2, then the value of lim 1  f  x   is equal to
x   x   

A) e3 B) e3 C) e6 D) e6
 1 
n

  1  1  
n 1n  n  2 ....n  n1 
n 2
41. lim n  
n 

  2  2   2  

1
A) e B) e2 C) e 2 D) 1

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
 1 
  sin x  n 1 x   p
x 
 x 
  x 

  
42. The value of lim lim 1  sin 1  sin 2 .....1  sin n     7 n   is e
 
q
(where p & q are
n  x 0  7  7   7  r1 
 
coprime), then which of the following is/are correct?
A) p  q  7 B) p  q  5 C) q  p  5 D) q  p  7

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
  
43. If   ,   R and    ,   R  2n  , n  I  are functions satisfying


 2 



1  x  sin 2   1  x 2  sin    x  x 2   0 , then which of the following is/are CORRECT?

 1 1  1
A) lim   sin     sin    2 B) ln    is an odd function
 0  
 e

 2  
 n 1 
 
  2   
1 1
1
C) lim
 0 
 r

  n, n  N D) lim   sin     sin   
 r 1   

 0 e

44. Let f be a biquadratic function of x given by f  x  Ax 4  Bx3  Cx 2  Dx  E , where

1
 f x x
A,B,C,D,E  R and A  0 . If lim    e3 , then which of the following is/are true?
x0  3 
 2 x 

A) A  4B  0 B) A  3B  0 C) f 1  8 D) f 1  4

 x3 1 
45. If xlim   ax 2  bx  c  4 then which of the following is/are correct?
   x 1 

A) a  b  c B) a  b  c C) a  b  c  7 D) a  b  c  5

 
 2 x ,  sin x 1, 0 x
1  x  1  2 where [k]
46. Consider, f  x   and g  x  
 x  2  x, 1  x  3 
 x  cos  x  2 ,

 x
 2
denotes greatest integer function of k then which of the following statement(s) is/are
CORRECT?
A) lim g  f  x  1 B) lim g  f  g ( x)  0
x1 
x
2

f  g  x  1 g  f  x  1
C) lim  D) lim 
x 2 
f  x 2 2 x 0 
 f  x 2
2
2

47. Which of the following limit vanishes?

A) lim  x x  x x 
x 1
B) lim x 2 ln
x0 x0 x

10 x  2 x  5 x  1
C) lim x ln x1 D) lim
x 0 x 0 x  tan x

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Narayana IIT Academy 31-10-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-25_Q’P
1
p cos x  xe x
48. If lim 1
 0 , then which of the following is/are INCORRECT about
x0
1  sin x  q cos x.e x

p,q?

A) p  0, q  R B) p  4 , q  2 C) p  2, q  R D) p  0, q  2

49. A right angled triangle has one leg of length 1 unit, another leg of length x units and
hypotenuse is of length y units. The angle opposite to the side of length x units is 
then:
A) y 3  x3  sec3   tan 3  B) lim  y  x   0

2

C) lim  y 2  x 2   1 D) lim  y 3  x3   1
 
2 2

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.

  12 sin xx    22 sin xx   ...   n 2 sin x x   
 
      
50. If L  lim nlim        where [.] denotes the greatest
x 0    
3
  n 


  


3
integer function. Then  ____
L

2 x3   tan 1 x
3
1
51. The number of possible value(s) of k for which xlim  ,
 8 3 1 1 2
x cot kx  k 2 x 6 sin 3  3kx3
 x
is

 n   1 
52. If f  x  nlim  r cos r
  r 1
x , then the value of
 
 x0 
lim 1 cos x2 f  x  cos x1  is

 

(where [.] is greatest integer function)

lim  x cos x    x sin x  is

x 1/ x
53.
x 0


54. The value of xlim

 3 x3  2 x2  x2   x  is equal to k
, then k 

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