Chemistry

Assignment -4
Topic: solutions
1. Which of the following statements is incorrect about a solution?
(a) A solution is always a homogeneous mixture
(b) The solute particles in a solution have size less than 10 Å
(c) Brass cannot be called a solution
(d) An ionic compound dissolves in water if the hydration energy is greater than lattice
energy
2. Which of the following concentration terms is affected by change in temperature?
(a) Molarity (b) Molality (c) Mole fraction (d) Weight fraction
3. For an aqueous solution of the same solute, in terms of concentration, at the same
temperature
(a) 1 M = 1 m (b) 1M > 1m (c) 1m > 1 M
(d) Any of these is possible
4. The temperature at which molarity of pure water is equal to its molality is
(a) 273 K (b) 277 K (c) 298 K (d) None of these
5. How many grams of concentrated nitric acid solution should be used to prepare 250
mL of 2-0 M HNO3? The concentrated acid is 70% ΗΝΟ3.
(a) 45.0 g conc. HNO3 (b) 90.0 g conc. HNO3
(c) 70-0 g conc. HNO3 (d) 54.0 g conc. HNO3
6. Molarity of HCl (l) if its density is 1.17 g/cc is
(a) 36.5 (b) 18.25 (c) 32.05 (d) 42.10
7. 6.02 x 1020 molecules of urea are present in 100 mL of its solution. The concentration
of solution is:
(a) 0.02 M (b) 0.01 M (c) 0.001 M (d) 0.1 M
8. The molarity of pure water is
(a) 55.6 (b) 50 (c) 100 (d) 18
9. The number of moles of hydroxide (OH ─) ion in 0.3 litre of 0.005 M solution of
Ba(OH)2 is
(a) 0.0075 (b) 0.0015 (c) 0.0030 (d) 0.0050
22
10. 200 mL of CaCl2 solution is found to contain 3.01 × 10 chloride ions. The molarity
of the solution is
(a) 0.250 M (b) 0.0625 M (c) 0.125 M (d) 0.375 M
11. The amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M
solution in methanol is
(a) 5.625 g (b) 3.275 g (c) 4.575 g (d) 4.125 g
12. Calculate the molarity of a solution of 30 g of Co(NO3)2.6H2O in 4.3 L of solution.
Consider atomic mass of Co = 59 u, N = 14 u, O= 16 u, H = 1 u.
(a) 0.023 M (b) 0.23 M (c) 0.046 M (d) 0.46 M
13. The volume of ethyl alcohol (density 1.15 g/cc) that has to be added to prepare 100 cc
of 0.5 M ethyl alcohol solution in water is
(a) 1.15 cc (b) 2 cc (c) 2.15 cc (d) 2.30 cc
14. What is the molarity of 0.2 N Na2CO3 solution?
(a) 0.1 M (b) 0 M (c) 0.4 M (d) 0.2 M
15. An aqueous solution of urea containing 18 g urea in 1500 cm³ of the solution has a
density equal to 1.052. If the molecular weight of urea is 60, then the molality of the
solution is
(a) 0.200 (b) 0.192 (c) 0.100 (d) 1.200
16. 6.84 g of sucrose is dissolved in 200 g of water, the molality of the solution is
(a) 0.2 m (b) 0.3 m (c) 0.1 m (d) 0.02 m
17. Calculate the mass of urea (NH2CONH2) required in making 2.5 kg 0.25 molal
aqueous solution.
(a) 37.5 g (b) 73.5 g (c) 53.7 g (d) 75.3 g
18. The molality of 90% H2SO4 solution is [density = 1.8 gm/ml]
(a) 1.8 (b) 48.4 (c) 91.83 (d) 94.6
19. 5 litres of a solution contains 25 mg of CaCO3. What is its concentration in ppm?
(mol. wt. of CaCO3 is 100)
(a) 25 (b) 1 (c) 5 (d) 2500
20. The weight percent of sucrose (formula weight = 342 g mol-1) in an aqueous solution
is 3.42. The density of the solution is 1 g mL-1. The concentration of sucrose in the
solution in mol L-1 is
(a) 0.01 (b) 0.1 (c) 1.0 (d) 10
21. 3.0 molal, NaOH solution molarity of the solution is has a density of 1.110 g/ml. The
(a) 3.0504 (b) 3.64 (c) 3.05 (d) 2.9732
22. The mole fraction of the solute in one molal aqueous solution is
(a) 0.027 (b) 0.036 (c) 0.018 (d) 0.009
23. The molality of an aqueous solution in which the mole fraction of the solute is 0.018
will be
(a) 0.5 (b) 1.0 (c) 1.5 (d) 2.0
24. The mole fraction of benzene in a solution containing 39% by mass in an organic
solvent of molecular mass 122 is
(a) 0.5 (b) 0.6 (c) 0.4 (d) 0.35
25. When the concentration is expressed as the number of a moles of the solute per-
kilogram of the solvent, it is known as
(a) Molarity (b) Molality (c) Normally (d) Mole fraction
26. The percentage (by weight) of sodium hydroxide in a 1.25 molal NaOH solution is
(a) 4.76% (b) 1.25% (c) 5% (d) 40%
27. 2.5 litre of 1 M NaOH solution are mixed with another 3 litre of 0.5 M NaOH
solution. Then the molarity of the resulting solution is
(a) 0.80 M (b) 1.0 M (c) 0.73 M (d) 0.50 M
𝑁 𝑁 𝑁
28. 60 mL of 5 H2SO4, 10 mL of 2 HNO3 and 30 mL of 10 HCl are mixed together. The
strength of the resulting mixture is HCl
(a) 0.10 N (b) 0.2 N (c) 0.3 N (d) 0.4 N
29. For converting a 100 ml KCl solution of 0.4 M concentration into a solution of KCl
0.05 M concentration. The quantity of water added is
(a) 900 ml (b) 700 ml (c) 500 ml (d) 300 ml
30. How much volume of 1 M H2SO4 is required to neutralise 20 mL of 1 M NaOH?
(a) 10 mL (b) 20 mL (c) 5 mL (d) 15 mL
31. How many grams of NaOH will be required to neutralize 12-2 g benzoic acid
 (a) 12.2 g (b) 16 g (c) 40 g (d) 4 g
32. A solid dissolves in water if
(a) lattice energy is greater than hydration energy
(b) lattice energy is less than hydration energy
(c) lattice energy is equal to hydration energy
(d) dissolution is exothermic
33. The solubility of a gas in a liquid at any definite temperature depends upon
(a) pressure of the gas
(b) critical temperature of the gas
(c) both critical temperature and pressure
(d) neither pressure nor critical temperature but only on the nature of the solvent
value of Henry's
34. Solubility of a gas in a liquid increases with
(a) increase of pressure and increase of temperature
(b) decrease of pressure and increase of temperature
(c) increase of pressure and decrease of temperature
(d) decrease of pressure and decrease of temperature
35. Which of the following gases does not obey Henry's Law?
(a) O2 (b) N2 (c) CO2 (d) none of these