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REVIEWER IN MATSCI (LEC 1,2,3) 4.
Processing- method to develop the
material. Created by: BRUHH Cedweak 5. Characterization- those 4 components Topic1: INTRODUCTION TO MATERIAL define the characteristics of a material. SCIENCE AND ENGINEERING II. Why study material science Material Science- It tackles relationships 1. Material Selection- selecting between the structures and properties of proper material depending on a a material. criterion. Material Engineering- designing, 2. New Material Fabrication- The engineering structure of a material to need to consider any produce pre-determined set of properties. deterioration of material properties that may occur during service I. COMPONENTS OF MATERIAL SCIENCE operation. AND ENGINEERING 3. Material Investigation- consider 1. Structure- refers to the level of the efficiency, the cost, the safety arrangement of its component. of a material. a. Subatomic level- electrons, protons, neutrons III. CLASSIFICATION OF MATERIALS b. Atomic level- elements in Solid materials are group into 3 basic periodic table & atomic categories. structure A. METALS- compounds with one or c. Microscopic level- large group more metallic elements atoms that are bonded • Relatively strong, stiff, ductile together. • Resistant to fracture d. Macroscopic Level- can be • Good Conductors viewed by naked eye. 2. Property- is a material trait in terms of the Ex: METAL ALLOYS kind and magnitude of response to a B. CERAMICS- compounds between specific imposed stimulus. metallic and non-metallic a. Mechanical Property- relates elements to deformation to an applied • Relatively strong, stiff, hard force (strength and toughness, • EXTREMELY BRITTLE elastic modulus) b. Electrical Property- electrical • Insulative to heat and conductivity and dielectric electricity. constant Ex: Porcelain, Clay c. Thermal Property- Heat capacity of a material. C. POLYMERS- Organic compounds d. Magnetic Property- response based on non-metallic elements. of a material to a magnetic • Not strong, stiff field. • EXTREMELY DUCTILE e. Optical Property- response of • Can easily be DEFORMED. a material to EM wave LIGHT. Ex: Plastic, Rubber f. Deteriorative Property- chemical reactivity of a material. 3. Performance- Function or application of its properties. D. COMPOSITES- composed of two human body to replace damaged or or more individuals, any of the deceased body parts. three. C. SMART MATERIALS- called smart • Combination of the because it can sense change to its combined best environment and then respond to these characteristic of each changes in a pre-determined manner. material. - has a sensor and an actuator. D. NANOMATERIALS- NANO prefix due to Ex: Cement, Fiber Glass the structural entities are in the order of IN-DEPTH DISCUSSION OF BASIC NANOMETER. MATERIALS
METALS- composed of metallic elements
such as Iron, aluminum, copper, titanium, gold and nickel.
CERAMICS- most frequently composed
from oxides, nitride, carbides.
- Alumina, Silica, and Silicon nitride.
- More resistant to high temperature and harsh environments
POLYMER- includes plastic and rubber
materials.
- Based on carbon, hydrogen, and
other non-metallic elements - Has a carbon atom backbone. - Polyethylene, PVC, nylon, Polycarbonate - EXTREMELY DUCTILE AND PLIABLE
COMPOSITES- the design goal is to
achieve a combination of properties that is displayed by a single material.
- Fiberglass, combination of glass
and polymer IV. CLASSIFICATION OF ADVANCED MATERIALS A. SEMICONDUCTORS- possess electrical properties that are between conductor and insulators. - Extremely sensitive to concentration of impurity atoms. - Revolutionized electronics and computer industry. B. BIOMATERIALS- employed in components that are implanted to a Topic2: ATOMIC STRUCTURE AND discrete orbitals. ( BASTA MAY RING INTERATOMIC BONDING DAW AROUND THE NUCLEUS NA NAGDEDETERMINE SA ENERGY I. ATOMIC STRUCTURE LEVEL NG ISANG ELECTRON) Atoms are consisting of very small nucleus composed of protons and V. QUANTUM NUMBERS neutrons that are encircled by electrons. PRINCIPAL QUANTUM NUMBER (n) Sub-atomic Charge Mass(kg) - Relates to the distance of electron Electrons -1.609x10-19C 9.11x10-31 to the nucleus. Protons +1.609x10-19C 1.67x10-27 - Para syang ring na may values 1, 2, Neutrons Chargeless 1.67x10-27 3 or K, M, N, L
AZIMUTHAL QUANTUM NUMBER (l)
II. CHARACTERIZATION OF ATOMS 1. ATOMIC NUMBER (Z)- represents the - Relates to the shape of the number protons in the nucleus which is subshell. equal to the electrons outside the nucleus. - Denoted as s, p, d, f.
MAGNETIC QUANTUM NUMBER (ml)
2. ATOMIC MASS (A)- represent the sum of number of protons and neutrons. - Determines energy state of the subshell. 3. ISOTOPE- elements with the same - s has 1, p has 3, d has 5, and f has atomic number and different atomic 7. mass. SPIN QUANTUM NUMBER (ms)
4. ATOMIC WEIGHT- correspond to the - Orientation of electron either
weighted average of the atomic masses of upward or downward direction the atom’s natural occurring isotopes. VI. ELECTRON DRIVING ATOMIC WEIGHT UNIT- PRINCIPLES 1 mol is equal to 6.022x1023 atoms. PAULI’S EXCLUSION PRINCIPLE It is called Avogadro’s numbers. - No electron can be identified by the same set of quantum numbers. III. BUILDING BLOCK OF AN ATOM - Dapat hindi sila same ng orientation ng electron charge. ISOBARS- elements with same atomic mass but different atomic number AUFBAU PRINCIPLE ISOMERS- elements with the same molecular - Electrons fills the lowest energy formula but different structures. level before filling the higher energy level. ISOTONES- elements with the same number of neutrons but different number of protons. HUND’S RULE ISOTOPES- elements with the same atomic - Every orbital in a particular sublevel number but different atomic mass. is initially occupied by a single electron before any orbital is double IV. BOHR ATOMIC MODEL occupied. - States that electrons are assumed to revolve around the atomic nucleus in - Kada box ng s p d f nilalagyan muna - Attractive bonding fore between ng isa equally, then mag dodoble. positive and negative ions termed VII. ELECTRON CONFIGURATION as Coulombic force. - Structure of an atom that represent Example: Sodium (Na) + Chloride (Cl) = the way states are occupied. NaCl { USE DIAGONAL line method} B. COVALENT BONDING Remember :s can store 2 electrons - Chemical bonding that is most commonly occurring for non- P can store 6 electrons metallic elements D can store 10 electrons - Chemical bond that results from sharing of valence electron. F can store 14 electrons Ex: Hydrogen and Carbon forming VIII. PERIODIC TABLE Hydrocarbons compounds. GROUP IA- Alkali Metals C. METALLIC BONDING GROUP IIA- Alkaline Earth Metal - Found in Metal and alloys obviously. GROUP IIIB- IIA- Transition Metals - Valence electrons are not bound GROUP IIIA- VIA- Semi Metals to any particular atom. - Form “Sea of electrons” or “ GROUP VIIA- Halogens Electron Cloud” GROUP 0: Noble Gasses
ELECTROPOSITIVE ELEMENTS
- Elements under metal
classification - Gives up electron to form positive ions.
ELECTRONEGATIVE ELEMENTS
- Elements above metal
classification - Accepts electron to form negative ions.
IX. INTERATOMIC BONDING
A. IONIC BONDING - Found in compounds of metallic and non-metallic elements. - Occurs between positive and negative ions.
Industrial process for OXICONAZOLE
Dr krishnasarma Pathy
step-I 2,2’4’-tri-choloroacetophenone,Imidazole reacted in presence of acetonitrile to
form 1-(2,4-dichlorophenacyl)-imidazole (I).Which is then reacted with hydroxylamine.
hydrochloride to give (Z)-1-(2,4-dichlorophenyl)-2-(1H-imidazol-1-yl) ethanone oxime
(II). It is further reacted with 2,4-Dichlorobenzyl chloride in presence of sodium hydride
to give (III) Oxiconazole and finally salt formation with nitric acid
A Comparative Study of Mechanical Properties of Zinc Acrylate Epoxy nanocomposites Reinforced by AL2O3 and Cloisite®30B and Their Mixture: Tensile Strength and Fracture Toughness: A Comparative Study of Mechanical Properties of Zinc Acrylate Epoxy nanocomposites Reinforced by AL2O3 and Cloisite®30B and Their Mixture: Tensile Strength and Fracture Toughness