Class 9 Science Chapter Wise Topic Wise Notes Chapter 3 Atoms and Molecules
Class 9 Science Chapter Wise Topic Wise Notes Chapter 3 Atoms and Molecules
TOPIC WISE
NOTES
CLASS IX
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INTRODUCTION
An atom is a tiny piece of matter that possesses the characteristics of an element. Some atoms exist
independently of one another by producing ions and molecules. Molecules are produced when one
or more atoms establish chemical bonds. It is the element’s smallest component that shows its
qualities. Molecules can be produced through chemical bonding between two
or more atoms.
Atoms and molecules are responsible for forming tiny sand particles,
gargantuan black holes and everything in between. The atom is the most
fundamental unit of matter, making up everything that we see around us.
It is extremely small, measuring in at less than 0.1 to 0.5 nanometres.
In a chemical reaction, two or more molecules interact to produce new compounds; they are called
reactants, whereas the newly formed compounds are called products.
In a chemical reaction, a chemical change must occur, which is generally observed with physical
changes like precipitation, heat production, colour change, etc.
According to the law of conservation of mass, matter can neither be created nor destroyed in a
chemical reaction. It remains conserved.
Example:
A pure chemical compound containing the same elements combined together in a fixed proportion
by mass is given by the law of definite proportions.
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Class 9th Science (Chemistry)
For e.g., If we take water from a river or from an ocean, both have oxygen and hydrogen in the same
proportion.
The elements are present in chemical compounds in a predetermined mass ratio. The “Law of
Constant Proportions” is this. This “Law of Constant Proportions” is also known as “Proust’s law” or
the “law of defined proportions.” For instance, the oxygen and hydrogen content in pure water is
always 1 : 8.
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Class 9th Science (Chemistry)
Dalton proposed that the concept of atoms could be used to explain the laws of conservation of
mass and definite proportions. He proposed that atoms, which he described as “solid, massy, hard,
impenetrable, moving particle(s)”, are the smallest, indivisible units of matter.
Atom
An atom is the defining structure of an element, which cannot be broken by any chemical means.
an atom is the smallest possible amount associated with a chemical element. For example, an atom
of gold can be called as the smallest quantity of gold you can feasibly have. The word ‘small’ literally
points out to nanoscopically tiny! An atom is thousands of times smaller than a human hair.
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Class 9th Science (Chemistry)
Hence, there is no chance you can see one without the help of a supremely powerful electron
microscope. If you rip apart a variety of things, it would be revealed that all matter present around
us is formed from different types of atoms. For example, living things are usually made from atoms
hydrogen, carbon and oxygen.
Atomic Symbol
The symbols for representing an atom are generated from the first two letters of the element’s
name. The first letter is always in uppercase (capital letter) while the second letter is written in
lowercase. Here are some examples –
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Class 9th Science (Chemistry)
Element Symbol
Hydrogen H
Helium He
Lithium Li
Beryllium Be
Boron B
Carbon C
Nitrogen N
Oxygen O
Fluorine F
Sodium Na
Magnesium Mg
Aluminium Al
Phosphorous P
Sulphur S
Potassium K
Calcium Ca
A symbol gives information on the stoichiometric quantity of the element. e.g., “B” represents one
atom of the element Boron. Likewise, “S” and “Mg” represent one atom of Sulphur and one atom of
Magnesium respectively. As one atom is equal to 6.022 × 10 -23 moles of particles. It can be
interpreted that B has 6.022 × 10-23 moles of particles.
Identity: Every symbol is unique for every unique 118 elements. There should be no
misunderstanding or misinterpretation while assigning or reading the chemical
symbols. Ex- As explained above, “Ca, Cu, C, Cr, Cs, Cl” here even though they have the
same first character, the second character is different. In sequence from left, they stand
for Calcium, Copper, Carbon, Chromium, and Cesium.
• Atomic mass is the total of the masses of the electrons, neutrons, and protons in an atom, or
in a group of atoms, the average mass.
• The mass of an atomic particle is called the atomic mass.
• This is commonly expressed as per the international agreement in terms of a unified atomic
mass unit (AMU).
• It can be best defined as 1/12 of the mass of a carbon-12 atom in its ground state.
Actual masses of the atoms of the elements are very very small.
For Example: The atom of hydrogen has a mass of 1.6727 × 10-27 kg. It is not convenient to use such
small and complicated figures in our calculation, therefore, it was necessary to define atomic masses
in such a way that we get simple figures for them.
Carbon-12 is that atom of carbon which has 6 protons and 6 neutrons in its nucleus
so that so its mass number is 12.
carbon-12 atom has been assigned an atomic mass of exactly 12 atomic mass
units. This means that a carbon-12 atom has been assigned an atomic mass of
exactly 12u.
Carbon-12 atom is taken to be the standard. The atomic masses of all other elements
are determined by comparing the mass of their atom with the mass of a carbon-12 atom.
The atomic mass of an element is relative mass of its atom as compared with the mass of a carbon-
12 atom taken as 12 units.
The relative atomic mass of an element is defined as the weight in grams of the number of atoms of
the element contained in 12.00 g of carbon-12. To calculate the relative atomic mass of chlorine, the
average mass of one atom of chlorine is found by considering 100 atoms of chlorine.
mass of 1 atom of the element
Relative atomic mass =
1
× mass of 1 atom of 6 C12 isotope
2
Gram Atomic Mass of an Element
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Class 9th Science (Chemistry)
Gram atomic mass is the periodic table element’s atomic weight in grams. The molar mass of an
element is the mass of one mole in grams. The mass of one mole of an element is defined as its gram
atomic mass.
It is calculated by taking an element’s atomic weight from the periodic table and converting it to
grams. Thus, when the mass of an element is expressed in grams then it is known as gram atomic
mass. For example, the gram atomic mass of helium is 4g. Similarly, sodium (Na) has an atomic
weight of 22.99u and a gram atomic mass of 22.99 grams. So one mole of sodium atoms weighs
22.99g. This implies that the quantity of the element of the given substance when weighs equal to
its gram atomic mass is called one gram atom.
The gram atomic mass of a material is the amount of that substance in grams that is numerically
equivalent to its atomic mass. If we wish to write a substance’s gram atomic mass, we first write its
atomic mass, then subtract the atomic mass unit u and add grams to the numerical value of the
atomic mass. That is,
Number of gram atoms
Mass of the element (in g) =
Atomic mass of the element (in g)
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Class 9th Science (Chemistry)
MOLECULE
Molecules are made up of one or more atoms that are held together by covalent bonds. Atoms can
be represented as circle shapes with a nucleus in the center, surrounded by one or more
concentric circles representing the shells in which the electrons surrounding the
nucleus of the atom are located, and markings indicating the electron.
Molecules of Elements
A molecule is a collection of two or more chemically bound atoms, whether they are from the same
element or another.
For example, when two hydrogen (H2) atoms and one oxygen (O2) atom interact, one water molecule
is created.
Atomicity: the number of atoms in a molecule of an element is called its atomicity. For example,
helium is monatomic, and oxygen is diatomic.
Molecules of Compounds
Salts and molecular compounds are the two categories into which compounds can be divided.
Covalent bonds hold the atoms together in molecular molecules. Ionic bonds hold it together in salts.
Every compound is composed of one of these two types of bonds.
Molecular Formula
The molecular formula is the expression of the number of atoms of each element in one molecule
of a compound.
The molecular formula definition is the formula showing the actual number of each atom in a
molecule.
When the molar mass value is known, the Molecular Formula is calculated by the empirical formula.
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Class 9th Science (Chemistry)
molar mass
n=
mass of the empirical formula
The molecular formula is often the same as an empirical formula or an exact multiple of it.
Example 1: Caffeine has the following composition: 49.48% of carbon, 5.19% of hydrogen, 16.48%
of oxygen and 28.85% of nitrogen. The molecular weight is 194.19g/mol. Find out the molecular
and empirical formula.
Solution:
8: Carbon
10: Hydrogen
2: Oxygen
4: Nitrogen
CHEMICAL FORMULA
Ion
A charged atom or a group of charged atoms is called ions, It may be positively or negatively charged
Protons are Positively charged, Electrons are Negatively charged, Neutrons are
Neutral.
In an atom, the number of protons is equal to the number of electrons, So the positive and negative
charges are balanced out, Ions are formed when atoms lose or gain electrons.
The negative charge reduces. Thus it becomes positively charged - Cation, because;
The number of positively charged protons becomes more than negatively charged electrons.
The number of negatively charged electrons becomes more than positively charged protons.
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Class 9th Science (Chemistry)
Cation Anion
Positively charged ion is called Cation Negatively charged ion is called anion
It is formed when atom loses electron (and hence It is formed when atom gains electron and
become positively charged) become positively charged
Example - Sodium Ion (Na +) Example - Chloride Ion (Cl -)
Sodium (Na) has 11 protons and 11 electrons. Chlorine (Cl) has 17 protons and 17 electrons.
Overall charge is 0 Overall charge is 0
When sodium loses 1 electron It has 11 protons When chlorine gains 1 electron It has 17
and 10 electrons, Positive charge > Negative protons and 18 electrons, Negative charge >
charge Thus, becomes Cation (Na +) Positive charge Thus, becomes Anion (Cl -)
Each constituent element in a chemical formula is identified by its chemical symbol, along with the
relative number of atoms that make up each element. These ratios are used in empirical equations
to start with a key element and then assign atom counts for the remaining elements in the compound
in relation to the key element.
• Ionic compounds are chemical compounds in which ions are held together by specialised
bonds called ionic bonds.
• An Ionic compound always contains an equal amount of positive and negative charge.
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Class 9th Science (Chemistry)
• For example: In calcium chloride, the ionic bond is formed by oppositely charged calcium and
chloride ions.
• The calcium atom loses 2 electrons and attains the electronic configuration of the nearest
noble gas (Ar). By doing so, it gains a net charge of +2.
The two chlorine atoms take one electron each, thus gaining a charge of -1 (each) and attain the
electronic configuration of the nearest noble gas (Ar).
Valency
The combining capacity of an atom is known as its valency. The number of bonds that an atom can
form as part of a compound is expressed by the valency of the element.
• It tells us that NaCl is composed of one atom of Sodium (Na) and 1 atom of Chlorine (Cl)
Example 1:
This is because Calcium (Ca) is a metal and Oxygen (O) is a non metal
Example 2:
Molecular mass
The molecular mass of an element is defined as the sum of all the masses of the elements present
inside the molecule. e.g., the molecular mass of water, in which there are two hydrogen atoms and
one oxygen atom present, is 18 (i.e., 2 + 16). Also called its molecular weight.
SI unit of Molecular Mass or Molecular Weight is an atomic mass unit which in short is called a.m.u.
It is sometimes represented by u which represents unified mass.
Make sure to analyse the chemical formula to determine the number of atoms of
each element in the compound.
Multiply the number of atoms present in the compound by the atomic weight of each
element.
Solution:
First Calculate the number of each atom and assign their atomic weight individually.
The sum of atomic masses of all atoms in a formula unit of a compound is called its formula unit
mass. The formula unit mass is used in the case of substances that constitute ions. For example, the
formula unit mass of Sodium Chloride (NaCl) can be calculated as: (1 × 23) + (1 × 35.5) = 58.5u
= 1 × 65 u + 1 × 16 u = 81 u
= 2 × 23 u + 1 × 16 u = 62 u
= 2 × 39 u + 1 × 12 u + 3 × 16 u
= 78 u + 12 u + 48 u = 138 u
Mole Concept
We say that two molecules of carbon combine with one molecule of oxygen to form two molecules
of carbon dioxide.
We can also say that 24u of Carbon molecules combine with 32u of oxygen molecules to form 56u
of carbon dioxide molecules.
Therefore, we can characterise the quantity of a substance by its mass or by its number of molecules.
A chemical equation directly indicates the number of molecules participating in the reaction. Thus,
it is convenient for us to refer to the number of substances in a chemical reaction as numbers of
molecules or atoms.
Molar Mass
A substance is something which has mass and occupies space. The molar
mass/molecular weight is actually the sum of the total mass in grams of the atoms
present to make up a molecule per mole. The unit of molar mass is grams/mole.
mass
Molar mass = = g/mol
mole
The mass of one atom of carbon-12 the atomic mass of carbon-12 is exactly
12 atomic mass units.
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Class 9th Science (Chemistry)
The mass of one mole of carbon-12 atoms is exactly 12 grams; its molar mass is exactly 12 grams per
mole.
Moles
the mole is a fundamental (SI) unit used to measure the amount of substance. This quantity is
sometimes referred to as the chemical amount.
A substance is something that has mass and occupies space. The molar mass/molecular weight is
actually the sum of the total mass in grams of the atoms present to make up a molecule per mole.
The unit of molar mass is grams/mole.
Atoms and Molecules
DPP-01
[Topic: Atoms, Symbols of elements, Atomic mass, Molecules of elements and compounds, Ions,
Writing chemical formula, Molecular mass, Formula unit mass]
41. Write the cations and anions present (if any) in the following compounds:
(a) CH3 COONa
(b) NaCl
(c) H2
(d) NH4 NO3
42. Which of the following symbols of elements are incorrect? Give their correct symbols.
(a) Cobalt- CO
(b) Carbon-C
(c) Aluminium - Al
(d) Helium- He
(e) Sodium -So
DPP-02
1. Which postulate of Dalton's atomic theory is the result of the law of conservation of mass?
2. Which postulate of Dalton's atomic theory can explain the law of definite proportions?
3. What is the full form of IUPAC?
4. Name the scientist who gave the atomic theory of matter.
5. What are building blocks of matter?
6. Name two laws of chemical combination.
7. State the law of conservation of mass.
8. State the law of constant proportions.
DPP-03
(Practice Sheet)
1 What is the fundamental unit of matter?
A. Molecule B. Atom
C. Element D. Compound
2 What is formed when two or more atoms establish chemical bonds?
A. Elements B. Molecules
C. Compounds D. Ions
3 What is the size range of an atom?
A. 1 to 5 nanometres B. 0.5 to 1 nanometre
C. 0.1 to 0.5 nanometres D. 5 to 10 nanometres
4 What is the law that states matter cannot be created nor destroyed in a chemical reaction?
A. Law of Constant Proportions B. Law of Conservation of Energy
C. Law of Chemical Combination D. Law of Conservation of Mass
5 What are the compounds formed in a chemical reaction called?
A. Atoms B. Reactants
C. Elements D. Products
6 Define the Law of Constant Proportions.
7 Write the chemical formulas for the following compounds.
Sodium Chloride, 2. Aluminium Chloride, 3. Calcium Carbonate, 4. Magnesium Hydroxide.
8 Write the valencies for the following atoms.
1. Oxygen, 2. Calcium, 3. Nitrogen, 4. Phosphorous, 5. Chlorine
9 What is the size range of an atom, and why is it considered the most fundamental unit of
matter?
10 Explain the Law of Conservation of Mass and its significance in chemical reactions.
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Class 9th Science (Chemistry)
(Practice Sheet)
1 What did Dalton propose in his Atomic Theory regarding the nature of atoms?
B. Atoms have varying sizes within the same
A. Atoms are continuously divisible.
element.
D. Atoms can be created in chemical
C. Atoms are indestructible and indivisible.
reactions.
2 According to Dalton, what is the key factor that determines the identity of an element?
A. Number of neutrons B. Atomic mass
C. Number of electrons D. Number of protons
3 What information does the atomic symbol of an element provide?
A. Number of electrons B. Atomic mass
C. Identity of the element D. Number of protons
4 What is the significance of the symbols representing elements?
A. Represents the number of moles B. Indicates the mass of the element
C. Provides information on stoichiometric D. Represents the number of neutrons
quantity
5 What is the relative atomic mass of an element?
A. The weight of one mole of the element B. The mass of one atom of the element
C. The mass of an atom relative to carbon- D. The average mass of isotopes of the
12 element
6 Why is the atomic mass of carbon-12 taken as the standard for defining atomic masses of
other elements?
7 Define the gram atomic mass of an element and provide an example.
8 How is the gram atomic mass of an element calculated?
9 What did Dalton propose about the nature of atoms in his Atomic Theory?
10 Define an atom and explain why atoms are not visible to the naked eye.
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Class 9th Science (Chemistry)
(Practice Sheet)
1 What holds atoms together in a molecule?
A. Ionic bonds B. Covalent bonds
C. Metallic bonds D. Hydrogen bonds
2 What is the smallest unit of measurement that a substance can be divided into while still
remaining the same substance?
A. Atom B. Element
C. Molecule D. Compound
3 Which of the following elements is diatomic?
A. Argon B. Helium
C. Oxygen D. Sulphur
4 How many atoms does a tetra-atomic element comprise?
A. 1 B. 2
C. 3 D. 4
5 In which type of bond are atoms held together in salts?
A. Covalent bonds B. Metallic bonds
C. Ionic bonds D. Hydrogen bonds
6 What is the molecular formula of a compound?
7 Which type of formula shows the actual number of each atom in a molecule?
8 What is a molecule, and how is it formed?
9 Explain the difference between salts and molecular compounds in terms of their bonds.
10 Differentiate between covalent bonds and ionic bonds in compounds.
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Class 9th Science (Chemistry)
(Practice Sheet)
1 What is a charged atom or group of charged atoms called?
A. Neutron B. Electron
C. Ion D. Proton
2 Which term is used for a positively charged ion?
A. Neutron B. Anion
C. Cation D. Electron
3 What happens when an atom gains an electron?
A. It becomes a cation B. It becomes an anion
C. It loses a proton D. It becomes neutral
4 What is the combining capacity of an atom known as?
A. Charge B. Atomic mass
C. Valency D. Ionization energy
5 In a chemical formula, which element is usually written first?
A. Nonmetal B. Metal
C. Anion D. Cation
6 What does the chemical formula NaCl represent?
7 How is an ionic bond formed in an ionic compound?
8 What is the unit of molecular mass?
9 What is valency?
10 Define formula unit mass and explain its significance in ionic compounds.
EXEMPLAR SOLUTION
Chapter 3
Atoms and Molecules
(a) (i)
(b) (i) and (iv)
(c) (ii) and (iii)
(d) (ii) and (iv)
Soln:
Answer is (d) (ii) and (iv)
Explanation:
Number of moles = Mass of water
Molar mass of water
Number of moles = 20
Soln:
Answer is d) Atoms aggregate in large numbers to form the matter that we can see, feel or touch
Explanation:
Atoms aggregate in large numbers to form the matter But we cannot see the matter with our naked eyes.
Answer is (b) N2
Explanation:
Chemical formula of Nitrogen is N but Nitrogen exist in molecule of two ions hence chemical symbol of Nitrogen
is written as N2.
Soln:
Answer is (d) Na
Explanation:
Sodium word is derived from Latin word Natrium hence the chemical name of sodium is Na.
Soln:
Answer is (c) 2 moles of CaCO3
Explanation:
Soln:
Answer is (d) 18g of CH4
Explanation:
Number of atoms = Mass of
substance × Number of atoms in the molecule/ Molar mass × NA
(a) 18 g of water =18 x3/18 ×NA = 3 NA
(b) 18 g of oxygen = 18 x2 /32 × NA = 1.12 NA
(c) 18 g of CO2 = 18 x3/44 × NA = 1.23 NA
(d) 18 g of CH4 =18 x5 /16 × NA = 5.63 NA
Note: NA = 6.023×1023
Soln:
Answer is (c) 1g H2
Note: NA = 6.023×1023
Explanation:
Soln:
Explanation:
Soln:
Explanation:
Soln:
Answer is (c) when energy is either given to, or taken out from the system
11. Which of the following represents a correct chemical formula? Name it.
(a) CaCl
(b) BiPO4
(c) NaSO4
(d) NaS
Soln:
Explanation:
Bismuth phosphate is right because Both ions are trivalent Bismuth phosphate(Bi3+- Trivalent anion. anion is an
ion that is negatively charged).
Soln:
Answers are
(a) Copper (II) bromide- CuBr2
(b) Aluminium (III) nitrate = Al(NO3)3
(c) Calcium (II) phosphate - Ca3(PO4)2
(d) Iron (III) sulphide - Fe2S3
(e) Mercury (II) chloride - HgCl2
(f) Magnesium (II) acetate- Mg(CH3COO)2
13. Write the molecular formulae of all the compounds that can be formed by the combination of
following ions Cu2+, Na+, Fe3+, C1–SO4 -2 , PO4 -3
Soln:
Answers are
CuCl2/ CuSO4/ Cu3 (PO4) 2
NaCl/ Na2SO4/ Na3 PO4
FeCl3/ Fe2(SO4) 3 / FePO4
14. Write the cations and anions present (if any) in the following compounds
(a) CH3COONa
b) NaCl
(c) H2
(d) NH4NO3
Soln:
a) In CH3COONa-CH3COO is anion and Na is cation.
b) In NaCl-Cl anion Na is cation
c) In H2 both the ions are cations as they share electrovalent bond between them
d) In NH4NO3- NO3 is anion NH4 is cation
15. Give the formulae of the compounds formed from the following sets of elements
(a) Calcium and fluorine
(b) Hydrogen and sulphur
(c) Nitrogen and hydrogen
(d) Carbon and chlorine
(e) Sodium and oxygen
(f) Carbon and oxygen
Soln:
16. Which of the following symbols of elements are incorrect? Give their correct symbols
(a) Cobalt CO
(b) Carbon c
(c) Aluminium AL
(d) Helium He
(e) Sodium So
Soln:
Cobalt CO is wrong, correct symbol is Co
Carbon c is wrong, correct symbol is C
Alluminium AL is wrong, correct symbol is Al
Helium He is the right symbol
Sodium So is wrong, correct symbol is Na
17. Give the chemical formulae for the following compounds and compute the ratio by mass of the
combining elements in each one of them. (You may use appendix-III).
(a) Ammonia
(b) Carbon monoxide
(c) Hydrogen chloride
(d) Aluminium fluoride
(e) Magnesium sulphide
Soln:
Sl. No. Compounds Chemical formula Ratio by mass of the
combining elements
(a) Ammonia NH3 N:H=14:3
(b) Carbon monoxide CO C:O= 12:16=3:4
(c) Aluminium fluoride HCl H:Cl= 1:35.5
(d) Aluminium fluoride AlF3 Al:F=27:57=9:19
(e) Magnesium sulphide MgS Mg:S= 24:32=3:4
18. State the number of atoms present in each of the following chemical species
(a) CO3-2
(b) PO4-3
(c) P2 O5
(d) CO
Soln:
(a) CO3-2- 1+3=4
(b) PO4-3 -1+4=5
(c) P2 O5 – 2+5=7
(d) CO – 1+1=2
Soln:
Mass of 1 mole of a substance is equal to its relative atomic or molecular mass in grams.
Mass of one mole (Avogadro Number) of neutrons =1g
Mass of one neutron = 1/ Avogadro number(NA) g
Mass of one molecule of water = Molar mass / NA = 18/ NA g
The molar mass of water is
18.015 g/mol. This was
calculated by multiplying the atomic weight of hydrogen (1.008) by two and adding the result to the weight
for one oxygen (15.999)
Mass of one molecule of water = Molar mass / NA = 18/ NA g
Avogadro number(NA) =6.022 x 1023mol¯1
There are 8 neutrons in one atom of oxygen
Number of neutrons in oxygen= number of oxygen - Atomic number of oxygen
Oxygen's atomic weight= 15.9994
increases with an increase in temperature.
Therefore the mass is 16
Therefore number of neutrons= 16 - 8 = 8
Mass of one neutron = 1/ Avogadro number(NA) g
Mass of 8 neutrons = 8/ Avogadro number(NA) g
Fraction of mass of water due to neutrons = 8/18 g
20. Does the solubility of a substance change with temperature? Explain with the help of an
example.
Soln:
Solubility is the ability of a solute to get dissolved in 100g solvent. Solubility of a given solute to
dissolve in specific solvent depends on the temperature. With Increase in temperature solubility of
liquids and solids increase. In the same way solubility of gases decreases with increase in temperature.
a) Monoatomic are inert gases that do not combine and exist as monoatomic gases
b) Diatomic- (a) 2- diatomic- NO2 = 1+ 2 = 3., HCl = 1+ 1 = 2
c) Triatomic-N2O = 2 + 1 = 3., NO2 = 1+ 2 = 3, O3 = 3
d) Tetraatomic- H2O2 = 2 + 2 = 4, P4O10 = 4 + 10 = 14, P4 = 4, CH4 = 1+ 4= 5
e) Octa atomic- C2H6 = 2 + 6 = 8
f) Polyatomic.
22. You are provided with a fine white coloured powder which is either sugar or salt. How would
you identify it without tasting?
To examine if the fine white coloured powder is sugar pr salt we can conduct two experiments.
Soln:
1. Heating: Upon heating sugar melts to liquid form because sucrose has a decomposition point and
melting point at temperatures between 190 to 192 degrees Celsius. This will turn sugar to light brown colour.
Upon heat further sugar gets charred to black colour.
Salt has a melting point of 841 degrees Celsius and 1545.8 degrees Fahrenheit. If we don’t heat it to that
point nothing change is observed.
2. Electric conductivity:
If we dissolve the given substance in water we can check for electric conductivity to check whether the
substance is sugar or salt. If it is salt it conducts electricity. Because salt (NaCl) has positive sodium ions
and negative chloride ions hence salt conducts electricity. But sugar don’t conduct electricity as sugar has
only positive ions.
23. Calculate the number of moles of magnesium present in a magnesium ribbon weighing 12 g.
Molar atomic mass of magnesium is 24g mol–1.
Soln:
Number of moles = weight
atomic weight
= 12 = 0.5 moles
24
Long Answer Questions
24. Verify by calculating that (a) 5 moles of CO2 and 5 moles of H2O do not have the same mass. (b) 240 g
of calcium and 240 g magnesium elements have a mole ratio of 3:5.
Soln:
(a) Molar mass of CO2 =12 + 2 x 16= 12 + 32 = 44 g mol-1
5 moles of CO2 have mass = 44 x 5 = 220 g
It is verified that 5 moles of CO2 and 5 moles of H2O are not same.
(b) Number of moles = w/ atomic weight
Atomic weight of Ca= 40 amu
Number of moles in 240g Ca metal 240/ 40 = 6
Number of moles in 240g of Mg metal 240/ 24 = 10
Atomic weight of Mg = 24amu
Ratio 6:10
25. Find the ratio by mass of the combining elements in the following compounds. (You may use
Appendix-III) (a) CaCO3 (d) C2H5OH (b) MgCl2 (e) NH3 (c) H2SO4 (f) Ca(OH)2
Soln:
a) CaCO3
Ca: C : O × 3
40 : 12 : 16 × 3
40: 12 : 48
10 : 3 : 12
(b) MgCl2
Mg : Cl × 2
24: 35.5 × 2
24: 71
(c) H2SO4
Hx2:S:O×4
2: 32 : 16 × 4
2 : 32 : 64
1: 16: 32
(d) C2H5OH
C×2:H×6:O
12 × 2 : 1 × 6 : 16
24 : 6 : 16
12 : 3 : 8
(e) NH3
N:H×3
14 : 1 × 3
14: 3
(f) Ca(OH)2
Ca : O × 2 : H × 2
40 : 16 × 2 : 1 × 2
40 : 32 : 2
20 : 16 : 1
26. Calcium chloride when dissolved in water dissociates into its ions according to the following
equation. CaCl2 (aq) → Ca2+ (aq) + 2Cl– (aq) Calculate the number of ions obtained from CaCl2
when 222 g of it is dissolved in water.
Soln:
1 mole of calcium chloride = 111g
Therefore 222g of CaCl2 is equivalent to 2 moles of CaCl2
Since 1 formula unit CaCl2 gives 3 ions,
therefore, 1 mol of CaCl2 will give 3 moles of ions 2 moles of CaCl2 would give 3×2=6 moles of ions.
No. of ions = No. of moles of ions × Avogadro number
= 6 × 6.022 ×1023
= 36.132×1023
=3.6132 × 1024 ions
27. The difference in the mass of 100 moles each of sodium atoms and sodium ions is 5.48002 g. Compute
the mass of an electron.
Soln:
Sodium atom and ion differ by one electron. For 100 moles each of sodium atoms and ions there would be a
difference of 100 moles of electrons.
Mass of 100 moles of electrons= 5.48002 g
Mass of 1 mole of electron = 5.48002 / 100 g
Mass of one electron = 5.48002 /100 × 6.022 ×1023
= 9.1 ×1028 g
= 9.1×10-31 kg
28. Cinnabar (HgS) is a prominent ore of mercury. How many grams of mercury are present in 225 g of
pure HgS? Molar mass of Hg and S are 200.6 g mol–1 and 32 g mol–1 respectively.
Soln:
Molar mass of HgS = The molar mass of Hg + the molar mass of S
= 200.6 + 32 = 232.6 g mol–1
1molecule of HgS contains 1 atom of Hg
232.6 g of HgS contains 200.6 g of Hg
Therefore, Mass of Hg in 225 g of HgS = 200.6 X 225 = 194.04g
232.6
29. The mass of one steel screw is 4.11g. Find the mass of one mole of these steel screws. Compare this value
with the mass of the Earth (5.98 × 1024kg). Which one of the two is heavier and by how many times?
Soln:
One mole of screws weigh = 2.475 ×1024g
= 2.475×1021 kg
= 2.4 ×10
Mass of earth is 2.4×103 times the mass of screws
The earth is 2400 times heavier than one mole of screws
30. A sample of Vitamin C is known to contain 2.58 ×1024 oxygen atoms. How many moles of oxygen atoms
are present in the sample?
Soln:
We know,
1 mole = 6.022 x 1023
The number of moles= Given number of particles
Avogadro Number
n= 2.58x1024
6.022x1023
n= 4.28 mol
31. Raunak took 5 moles of carbon atoms in a container and Krish also took 5 moles of sodium atoms in
another container of same weight.
(a) Whose container is heavier?
(b) Whose container has more number of atoms?
Soln:
No of Moles 2 - - 0.5
No of particles - 3.011x1023 - 0
Soln:
33. The visible universe is estimated to contain 1022 stars. How many moles of stars are present in the
visible universe?
Soln:
Number of moles of stars = 1022
6.023 ×1023
= 0.0166 moles
34. What is the SI prefix for each of the following multiples and submultiples of a unit?
(a) 103
(b) 10–1
(c) 10–2
(d) 10–6
(e) 10–9
(f) 10–12
Soln:
a) 103 = 1000= kilo
(b) 10–1 =1/10= 0.1= deci
(c) 10–2 =1/100 = 0.01= centi
(d) 10–6 = 0.000 001= micro
(e) 10–9 =0.000 000 001 = nano
(f) 10–12=0.000 000 000 001 = pico
Soln:
(a) 5.84 × 10–3 mg = 5.84 ×10–9 kg
(b) 58.34 g =5.834 ×10–2 kg
(c) 0.584g =5.84 ×10–4 kg
(d) 5.873×10-21g=5.873 ×10–24 kg
36. Compute the difference in masses of 103 moles each of magnesium atoms and magnesium ions.
(Mass of an electron = 9.1×10–31 kg)
Soln:
Mg2+ ion and Mg atom differ by two electrons.
103 moles of Mg2+ and Mg atoms would differ by
103 × 2 moles of electrons
Mass of 2 ×103 moles of electrons = 2×103 × 6.023 ×1023 × 9.1 ×10–31 kg
2×6.022 × 9.1×10–5kg
109.6004 ×10–5 kg
1.096 × 10–3kg
Soln:
Soln:
39. A gold sample contains 90% of gold and the rest copper. How many atoms of gold are present in one
gram of this sample of gold?
Soln:
Soln:
While forming some compounds, atoms gain or lose electrons, and form electrically charged particles called ions.
Compounds that are formed by the attraction of cations and anions are called as ionic compounds.
Ex : 2Na + Cl2 → 2Na+ Cl- → 2NaCl (sodium chloride- common salt.)
Sodium is a group 1 metal, thus forms a +1 charged cation. Chlorine is a non-metal, and has the ability to form a -
1 charged anion.
Compounds formed due to bonding of uncharged ions are called as molecular compounds and the bonding
between them is called covalent bonding. Molecular compounds are formed by sharing of electrons between the
two atoms and the elements are held together by covalent bonds.
Ex: 2C + O2 → 2CO ( Carbon monoxide)
41. Compute the difference in masses of one mole each of aluminium atoms and one mole of its ions. (Mass
of an electron is 9.1×10–28 g). Which one is heavier?
Soln:
Mass of one mole of Aluminium atom = {13 × mass of each electron + 13 × mass of each proton + 14 × mass of
each neutron} × Avogadro's constant.
We know, if atoms convert into ions, only transfer of electrons takes place, in Al+3 ion, Aluminium atom loss
three electrons,
So,
Mass of Al+3 ={10× mass of each electron +13 × mass of each proton + 14 × mass of each neutron} Avogadro's
constant
Now,
You see mass of aluminium atom is greater than aluminium ion by 3 electrons
Difference in mass =Mass of Aluminium atom -mass of aluminium ion
= 3 × mass of each electron x Avogadro's constant .
= 3 × 9.1 × 10-28x 6.023 x 1023
=27.3 x 10-28 x 6.023 x 1023 g
=164.4 x 10-5 g
= 1.644 x 10-3 g
= 0.0016 g
42. A silver ornament of mass ‘m’ gram is polished with gold equivalent to 1% of the mass of silver.
Compute the ratio of the number of atoms of gold and silver in the ornament.
Soln:
Mass of silver = m g
Mass of gold = m /100g
Number of atoms of silver = Mass/ Atomic mass X NA
= m /108NA Number of atoms of gold
= m/ 100 X197
Ratio of number of atoms of gold to silver = Au : Ag
= m/ 100 X 197 X NA : m/ 108 NA
= 108 : 100×197
= 108 : 19700 =
1 : 182.41
43. A sample of ethane (C2H6) gas has the same mass as 1.5 ×1020 molecules of methane (CH4). How many
C2H6 molecules does the sample of gas contain?
Soln:
Soln:
Answers
a) Law of conservation of mass
b) Ions
c) 310
Explanation
3 × atomic mass of Ca+ 2 × atomic mass of phosphorus + 8 × atomic mass of oxygen) = 310
Soln:
b) Six : Helium (He); Neon ( Ne); Argon (Ar); Krypton (Kr); Xenon (Xe); Radon (Rn).
47. Write the formulae for the following and calculate the molecular mass for each one of them.
(a) Caustic potash
(b) Baking powder
(c) Lime stone
(d) Caustic soda
(e) Ethanol
(f) Common salt
Soln:
The formulae for the following and calculate the molecular mass for each one of them.
48. In photosynthesis, 6 molecules of carbon dioxide combine with an equal number of water
molecules through a complex series of reactions to give a molecule of glucose having a molecular
formula C6 H12 O6 . How many grams of water would be required to produce 18 g of glucose?
Compute the volume of water so consumed assuming the density of water to be 1 g cm-3.
Soln:
Chapter 3
Atoms and Molecules
Questions:
Q.3 Which postulate of Dalton's atomic theory is the result of the law of
conservation of mass?
Ans.: The postulate of Dalton’s atomic theory that is the result of the
law of conservation of mass are following:
‘Atoms are indivisible particles, which cannot be created or destroyed in
a chemical reaction.’
‘The relative number and kinds of atoms are constant in a given
compound.’
Q.4 Which postulate of Dalton's atomic theory can explain the law of
definite proportions?
Ans.: The postulate of Dalton's atomic theory that explains the law of
definite proportions is ’The relative number and kinds of atoms are
constant in a given compound.’
Questions:
Q. 1 Define the atomic mass unit.
Ans.: One atomic mass unit is a mass unit equal to exactly one twelveth
(1/12th) the mass of one atom of carbon-12. The relative atomic masses
of all elements have been found with respect to an atom of carbon-12.
Questions:
Na2O
AlCl3 Or AlCl3
(i) Al2(SO4)3
(ii) CaCl2
(iii) K2SO4
(iv) KNO3
(v) CaCO3
Ans.:
(i) The name of this compound is Aluminium sulphate.
(ii) The name of this compound is Calcium chloride.
(iii) The name of this compound is Potassium sulphate.
(iv) The name of this compound is potassium nitrate.
(v) The name of this compound is Calcium carbonate.
Q. 1 Calculate the molecular masses of H2, O2, Cl2, C02, CH4, C2H6,
C2H4, NH3, CH3OH (Atomic masses: H = 1; 0 = 16; Cl = 35.5; C = 12;
N = 14)
Ans.: The molecular mass of a substance is the sum of the atomic masses
of all the atoms in a molecule of the substance. It is therefore the relative
mass of a molecule expressed in atomic mass units (u).
(vii) C2H4 molecule has two carbon atoms and four hydrogen atoms.
C2H6 molecule has two carbon atoms and four hydrogen atoms.
Molecular mass of C2H4 = Mass of 2C atoms + Mass of 4 H atoms
= 2 X 12 + 4 X 1 = 24 + 4 = 28 u
(viii) NH3 molecule has one nitrogen atom and three hydrogen atoms.
Atomic mass of Nitrogen = 14 , Atomic mass of hydrogen = 1 u
Molecular mass of NH3 = Mass of N atom + Mass of 3H atoms
= 14 + 3 X 1 = 14 + 3 = 17 u
(ix) CH3OH molecule has one carbon atom, four hydrogen atoms and
one oxygen atom.
Atomic mass of carbon = n 12 u, Atomic mass of hydrogen = 1 u and
Atomic mass of oxygen = 12 u.
Molecular mass of CH3OH = Mass of C + Mass of 4 H + Mass of 0
= 12 + 4 X 1 + 16 = 12 + 4 + 16 = 32 u
Exercise
Questions:
= 40% …….(i)
= 60% …….(ii)
Thus, the percentage composition of the compound is: Boron = 40%;
Oxygen = 60%
Q. 2 When 3.0 g of carbon is burnt in 8.00 g of oxygen, 11.00 g of carbon
dioxide is produced. What mass of carbon dioxide will be formed when
3.00 g of carbon is burnt in 50.00 g of oxygen? Which law of chemical
combination will govern your answer?
Ans.: Answer will be governed by the law of constant proportions which
states that the mass of reactant must be equal to the mass of the product
formed during a reaction
Now, since carbon and oxygen combine in the fixed proportion of 3 : 8 by
mass to produce 11 g of carbon dioxide,
𝐶 + 𝑂2 = 𝐶𝑂2
3 + 8 = 11 (by ratio proportion)According to the question, the
equation formed will be:-
𝐶 + 2𝑂2 = 𝐶𝑂2 + 𝑂2
3 +50 = 11 + 42 53 = 53Therefore, the same mass of carbon
dioxide (11 g) will be obtained even if we burn 3 g of carbon in 50 g of
oxygen. The extra oxygen (50 – 8 = 42 g oxygen) will remain unchanged.
Q.5 Give the names of the elements present in the following compounds:
(a) Quick lime
(b) Hydrogen bromide
(c) Baking soda
(d) Potassium sulphate
Ans.:
(a) Calcium oxide, CaO is also known as quick lime. The elements present
in quick lime are: Calcium (Ca) and Oxygen (O).
(b) The chemical formula of hydrogen bromide is HBr. The elements
present in hydrogen bromide are: Hydrogen (H) and Bromine (Br).
(c) Baking soda is sodium hydrogen carbonate, and its chemical formula
is NaHCO3. The elements present in baking soda are: Sodium (Na),
Hydrogen (H), Carbon (C) and Oxygen (O).
(d) The chemical formula of potassium sulphate is K2SO4. The elements
present in potassium sulphate are: Potassium (K), Sulphur (S) and Oxygen
(O).
Ans: The molar masses of all these substances will be equal to the
respective molecular masses expressed in g/mol. Now:\(a) Molar mass of
ethyne, C2H2 = Mass of C × 2 + Mass of H × 2
= 12 × 2 + 1 × 2
= 24 + 2
= 26 g/mol
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