Safety Data Sheet

Conforms to SANS ISO 11014: 2010 and ISO 11014: 2009

TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Section 1. Identification
GHS product identifier : TradePro Solvent Based Plaster Primer (USP 1)

Other means of identification : An alkali resistant primer for interior and exterior masonry surfaces.

Relevant identified uses of the substance or mixture and uses advised against

Identified uses : For use on substrates such as interior and exterior cement plaster, concrete
and fibre-cement to protect subsequent coats, such as alkyd paints, against
saponification. As a binding and sealing coat on soft and brittle cement
plaster, porous paper faced board, brickwork, soft board and gypsum
plaster.

Supplier’s details : Kansai Plascon (Pty) Ltd

P.O. Box 4010
Luipaardsvlei
1743

Emergency phone : (011) 951 4500 (within hours of operation)

Facsimile : (011) 955 2841
National Contact Person : Mr C. Costa

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUID- Category 3
substance or mixture SKIN CORROSION/ IRRITATION- Category 2
ACUTE TOXICITY- Category 4
SERIOUS EYE DAMAGE/ IRRITATION- Category 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE- Category 3
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE-
Category 1
ASPIRATION TOXICITY- Category 1
AQUATIC TOXICITY CHRONIC- Category 2

Label elements according to : SANS 10234: 2008

Hazard pictograms :

Signal word : Danger

Hazard statements : H226- Flammable liquid and vapour.

H303- May be harmful if swallowed.
H304- May be fatal if swallowed and enters airways
H315- Causes skin irritation.
H319- Causes serious eye irritiation
H332- Harmful if inhaled

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Conforms to SANS ISO 11014: 2010 and ISO 11014: 2009

TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

H336- May cause drowsiness or dizziness

H372- Causes damage to organs through prolonged or repeated exposure
H411- Toxic to aquatic life with long-lasting effects

Precautionary statements
General : P101- If medical advice is needed, have product container or label at hand.
P102- Keep out of reach of children.
P103- Read label before use.
Prevention : P202- Do not handle until all safety precautions have been read and
understood.
P501: Dispose of contents/containers in accordance with local
regulation.
P233- Keep container tightly closed.
P261- Avoid breathing vapours/spray.
P262- Do not get in eyes, on skin, or on clothing.
P270- Do not eat, drink or smoke when using this product.
P271- Use only outdoors or in a well-ventilated area.
P273- Avoid release to the environment.
P280- Wear protective gloves/protective clothing/eye protection/face
protection.
P285- In case of inadequate ventilation wear respiratory protection.
P235+410- Keep cool. Protect from sunlight
Response : P314- Get medical advice/attention if you feel unwell.
P391- Collect spillage.
P301+330+331- IF SWALLOWED- Rinse mouth. Do NOT induce vomiting.
P303+361+353- IF ON SKIN (or hair)- Take off immediately all
contaminated clothing. Rinse skin with water/ shower.
P304+340: IF INHALED- Remove person to fresh air and keep comfortable
for breathing.
P305+351+338- IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses if present and easy to do – continue
rinsing.
P333+313- If skin irritation or a rash occurs: Get medical advice/attention.
P337+313- If eye irritation persists get medical advice/attention.

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

P361+364- Take off immediately all contaminated clothing and wash it

before reuse.
P362+364- Take off contaminated clothing and wash it before reuse.
P370+380- In case of fire: Evacuate area.
Storage : P410- Protect from sunlight.
P402+404- Store in a dry place. Store in a closed container.
P403+235- Store in a well ventilated place. Keep cool.
Other hazards which do not
Result in classification : None identified

Section 3. Composition/information on ingredients

Subtance/mixture : Mixture
Other means of identification : Solution acrylic
CAS number/other identifiers
CAS number : Not applicable

Ingredient name CAS number % SANS 10234

Classification
Medium Aliphatic 64742-88-7 10.0-20.0 Acute Tox. 4, H332
Petroleum Solvent Acute Tox. 5, H303
Asp. Tox 1, H304
Skin Irrit. 2, H315
Eye Irrit. 2B, H320
Aquatic Chronic 2, H411
Flam. Liq. 3, H226
Hydrocarbon blend (C9- 64771-72-8 <10.0 Flam. Liq. 3, H226
C11 n-Parrafins) Asp. Tox 1, H304
STOT SE 3, H336
Aquatic Chronic 3, H412
Heavy Aromatic 64742-94-5 <10.0 Acute Tox. 4, H332
Petroleum Solvent Acute Tox. 5, H303
Asp. Tox 1, H304
Skin Irrit. 2, H315
Eye Irrit. 2B, H320
Aquatic Chronic 2, H411
Flam. Liq. 3, H226
White Spirit, Mineral 64742-88-7 <10.0 Asp. Tox. 1, H304
Turpentine Flam. Liq. 3, H226
Aquatic Chronic 2, H411
Eye Irrit. 2B, H319
STOT RE 1, H372
Skin Irrit. 2, H315
STOT SE 3, H336
Solvent naphtha 64742-94-5 <2.0 Flam. Liq. 3, H226
(petroleum), heavy Asp. Tox. 1, H304
arom.

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section. Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper
and lower eyelids. Check for and remove any contact lenses. Get medical
attention if irritation persist.

Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical attention if symptoms occur.

Skin contact : Wash contaminated skin with soap or a recognised skin cleaner and plenty
of water. Avoid the use of solvents. Remove contaminated clothing and
shoes. Get medical attention if symptoms persist.

Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in
a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Do
not induce vomiting unless directed to do so by medical personnel. Get
medical attention if symptoms occur.

Most important symptoms/ effects, acute and delayed

Potential acute health effects

Eye contact : Highly irritating and risk of irreversible damage.
Inhalation : Harmful if inhaled. Irritating and narcotic. Can affect central nervous system.
Skin contact : Irritating if in contact with skin. Risk of dermatitis.
Ingestion : Harmful. May cause lung damage if swallowed.

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include pain or irritation, watering or redness.
Inhalation : Adverse symptoms may include nausea or vomiting, headache,
drowsiness/fatigue or dizziness/vertigo.
Skin contact : Adverse symptoms may include irritation or redness.
Ingestion : May cause damage to organs through prolonged or repeated exposure.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if

large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable
training.

See toxicological information (Section 11)

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire such as
foam, CO2 or dry powder. Use fog to cool and control.

Unsuitable extinguishing media : Do NOT use water jets.

Specific hazards arising

from the chemical : In a fire or if heated, a pressure increase will occur and the container may
burst. Can form explosive vapour/air mixture. Static discharge hazard.
Flammable with toxic fumes. Cool containers in case of fire.

Hazardous thermal
decomposition products : Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions

For fire-fighters : Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training.

Special protective
equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self
contained breathing apparatus (SCBA) with a full face-piece operated in
positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency
personnel : No action shall be taken involving any personal risk or without suitable
training. Evacuate surrounding areas. Keep unnecessary and unprotected
personnel from entering. Do not touch or walk through spilled material. Put
on appropriate personal protective equipment.

For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the product
has caused environmental pollution (sewers, waterways, soil or air). Water
polluting material. May be harmful to the environment if released in large
quantities.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water
and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

an inert dry material and place in an appropriate waste disposal container.

Dispose of via a licensed waste disposal contractor.

Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into
an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Dispose of via a licensed
waste disposal contractor. Note: see section 1 for emergency contact
information and section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe
handling : Put on appropriate personal protective equipment (see Section 8). Eating,
drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face
before eating, drinking and smoking. Remove contaminated clothing and
protective equipment before entering eating areas. Do not get in eyes or on
skin or clothing. Do not ingest. Avoid breathing vapor or mist. Keep away
from ignition sources. No open flames. No smoking. Avoid free fall of liquid
– use earthing.

Conditions for safe storage,

Including any
Incompatibilities :Store in accordance with local regulations. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials (see section 10) and food and drink. Keep
container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabelled containers. Use appropriate
containment to avoid environmental contamination. Do not reuse container.

Section 8. Exposure controls/personal protection

Occupational exposure limits :

Ingredient name Exposure limits

Hydrocarbon blend (C9-C11 n-Parrafins) ACGIH:
TWA: 350 mg/m3
Heavy Aromatic Petroleum Solvent ACGIH TLV:
TWA: 525 mg/m3
TWA: 100ppm
White Spirit, Mineral Turpentine OHSA:
TWA: OEL: RL 100ppm
TWA: OEL: RL 575mg/m 3
STEL: OEL: 125 RL
STEL: OEL: RL 720mg/m 3
Solvent naphtha (petroleum), heavy arom. ACGIH:
TWA: 100 ppm
TWA: 525 mg/m³

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Recommended monitoring
Procedures : If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective equipment.

Appropriate engineering
controls : No special ventilation requirements. Good general ventilation should be
sufficient to control worker exposure to airborne contaminants. If this
product contains ingredients with exposure limits, use process
enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure below any recommended or statutory limits.

Environmental exposure
controls : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the end of
the working period. Appropriate techniques should be used to remove
potentially contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers are close to
the workstation location.

Eye/face protection : Avoid direct contact. Never touch eyes with dirty hands or gloves. Safety
eyewear complying with an approved standard should be used when a
risk assessment indicates this is necessary to avoid exposure to liquid
splashes, mists, gases or dusts.

Hand protection : Avoid direct contact. Chemical-resistant, impervious gloves complying

with an approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is necessary.

Body protection : Personal protective equipment for the body should be selected based on
the task being performed and the risks involved and should be approved
by a specialist before handling this product.

Other skin protection : Avoid direct contact. Appropriate footwear and any additional skin protection
Measures should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this
product.

Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator with organic vapour
filter cartridge (e.g. A1B1E1 type) complying with an approved standard if
a risk assessment indicates this is necessary e.g. in case of insufficient
ventilation. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of
the selected respirator.

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Section 9. Physical and chemical properties

Physical state : Viscous Liquid

Colour : Off white

Odor : No data available.

Odor threshold : No data available.

pH : Not applicable.

Melting point : No data available.

Boiling point : No data available.

Flash point : 38 °C

Evaporation rate : No data available.

Flammability (solid, gas) : Not applicable.

Lower and upper explosive

(flammable) limits : Not applicable.

Vapor pressure : No data available.

Vapor density : No data available.

Relative density : 1.25 (typical)

Solubility : Soluble in organic solvents, insoluble in water.

Partition coefficient,
n-octanol/water : No data available.
Auto-ignition temperature : No data available.

Decomposition temperature : No data available.

Viscosity : 70 - 80 KU

Section 10. Stability and reactivity

Reactivity : Inert - no reaction with fire-fighting water.

Chemical stability : Stable under normal conditions.

Possibility of hazardous
reactions : Under normal conditions of storage and use, hazardous reactions will not
occur.

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Conditions to avoid : Could generate static – Use earthing. Avoid all possible sources of ignition
(spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.

Incompatible materials : Any reactive substances – oxidisers in particular.

Hazardous decomposition
products : Under normal conditions of storage and use, hazardous decomposition
products should not be produced.

Section 11. Toxicological information

Acute Toxicity
Product/ingredient Result Species Dose Exposure
name
White Spirit, Oral LD50 Rat >2 000 mg/kg 14 days, no death
Mineral occured
Turpentine Dermal LD50 Rabbit >2 000 mg/kg 14 days, no death
occurred
Inhalation LC50 Rat 10 4 hrs
mg/l -20mg/l

Irritation/Corrosion
Product/ingredient Result Species Score Exposure Observation
name
Solvent naphtha Skin - Mild irritant Rabbit - 24 hours 500 -
(petroleum), microliters
heavy arom.

Specific target organ toxicity (single exposure)

Name Category Route of exposure Target Organs
Hydrocarbon blend (C9-C11 Category 3 Not determined Not determine
n-Parrafins)

Specific target organ toxicity (repeated exposure)

Name Category Route of exposure Target Organs
None

Aspiration hazard
Name Result
Medium Aliphatic Petroleum Solvent ASPIRATION HAZARD - Category 1
Heavy Aromatic Petroleum Solvent ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum), heavy arom. ASPIRATION HAZARD - Category 1

Information on the likely

routes of exposure : Inhalation, skin contact

Potential acute health effects

Eye contact : Highly irritating and risk of irreversible damage.
Inhalation : Harmful if inhaled. Irritating and narcotic. Can affect central nervous system.
Skin contact : Irritating if in contact with skin. Risk of dermatitis.
Ingestion : Harmful. May cause lung damage if swallowed.

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include pain or irritation, watering or redness.
Inhalation : Adverse symptoms may include nausea or vomiting, headache,
drowsiness/fatigue or dizziness/vertigo.
Skin contact : Adverse symptoms may include irritation or redness.
Ingestion : May cause damage to organs through prolonged or repeated exposure.

Potential Chronic health effects

General : Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Acute toxicity estimates

No data available.

Section 12. Ecological information

Toxicity
Product/Ingredien Result Species Exposure
t name
Hydrocarbon Acute EC50: 2990 ppm Aquatic Toxicity: Bluegill 24 hours
blend (C9-C11 n- sunfish
Parrafins)
White Spirit, Acute LC/EC50 8.1 mg/l Fish, (Salmon) 96 hours
Mineral Acute LC/EC50 6.0 mg/l Aquatic Organisms, (Daphnia 48 hours
Turpentine Magna)
Acute LC/EC50 9.4 mg/ml Aquatic Organisms, (Green 8 hours
algae)

Persistence and degradability

Product/Ingredien Aquatic half-life Photolysis Biodegradability
t name
Hydrocarbon - - Not readily
blend (C9-C11 n- biodegradable
Parrafins)

Bioaccumalitive potential
Product/Ingredien LogPow BCF Potential
t name
Hydrocarbon 3.3 and 5.25 190 to 5800 -
blend (C9-C11 n-
Parrafins)

Mobility in soil
Soil/ water partition coefficient
(KOC) : No data available.
Mobility : No data available.

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

PBT/vPvB data : P: No data available. B: No data available. T: No data available.

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : This material and its container must be disposed of in a safe way. The
generation of waste should be avoided or minimized wherever possible.
Significant quantities of waste product residues should not be disposed of
via the foul sewer but processed in a suitable effluent treatment plant.
Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor – potential for spontaneous combustion. Take care with
used containers. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority
requirements. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. Care should be
taken when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.

Section 14. Transport information

Transportation - road Transportation- Transportation- Air -

- SANS 10228:2012 Maritime - IMO/ IMDG IATA
UN number 1263 1263 1263
UN proper shipping Paint related material Paint related material Paint related material
name
Transport hazard 3 3 3
class(es)

Packing group III III III

Marine pollutant No No No
Additional information No data available Emergency schedules Passenger and Cargo
(EmS) Aircraft
F-A, S-F Quantity limitation:
450 L
Packaging instructions:
964
Cargo Aircraft Only
Quantity
limitation: 450 L
Packaging instructions:
964

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Limited Quantities -
Passenger Aircraft
Quantity
limitation: 30 kg
Packaging instructions:
Y964
Transport in bulk No data available No data available No data available
according to Annex II
of MARPOL 73/78 and
the IBC code

Section 15. Regulatory information

Safety, health and
environmental regulations
specific for the product : Relevant information regarding authorization: Occupational Health
and Safety Act 1993 Regulation for Hazardous Chemical Substances.
Relevant information regarding restrictions: None known.
EU regulations: Regulation EC 1272/2008 [EU-GHS/CLP] and EU
directives 67/548/EEC or EC 1999/45/EC
Other National regulations: None. Standards used for PPE
recommendations in Section 8: NIOSH-National Institute for
Occupational Health and Safety (USA) EN 166- European standard
which concerns the area of eye protection. EN 374-3 European
standards for permeation and penetration. EN 141/EN 143 European
standards for gas mixtures to remove specified gases and vapours or
combined filters for removing solids, and/or liquid particles and
specified gases and vapours.

Section 16. Other information

History

Date of printing : 17/07/2017

Date of previous issue : Not applicable
Key to abbreviations : ATE = Acute Toxicity Estimate
BCP Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution
from Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine
pollution)
RID = The Regulations concerning the International Carriage of Dangerous
Goods by Rail
UN = United Nations

References : Supplier safety data sheets

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TRADEPRO SOLVENT BASED PLASTER PRIMER (USP 1)

Further information:
This information is based upon the present state of our knowledge. This SDS has been compiled and is
solely intended for this product.

Notice to readers:
Employers should use this information only as a supplement to other information gathered by them, and
should make independent judgement of suitability of this information to ensure proper use and protect
the health and safety of employees.
This information is furnished without warranty, and any use of the product not in conformance with
this Safety Data Sheet, or in combination with any other product or process, is the responsibility of the
user.

Legal disclaimer:
The above information is believed to be correct but does not purport to be all inclusive and shall be
only used as a guide. This company shall not be held liable for any damage resulting from handling or
from contact with the above product.

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