Basic Principles of Colour Measurement and Colour
Basic Principles of Colour Measurement and Colour
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Abstract
1. Introduction
Colour and aesthetics are as important as its various physical properties for
textiles/garments, leather, moulded plastics,and products of various other fields.
The ability to integrally colour(dyeing and Printing) textiles, leather, plastic
moulded articles has an important edge over others non polymeric rigid hard
materials like metals etc.
Matching of colours and imitate texture, especially in specific textiles of differ-
ent fibres and blends is crucial in many of its apparel applications. The task becomes
more difficult when colours need to be exactly matched with standard colour yield
desired with endurable criteria for acceptable colour fastness to wash, rubbing, light
1
Colorimetry
and perspiration etc. for different textiles/plastics and polymer products. So,
understanding Theory of colour measurement, quantification, for well defined
applications of different dyes/pigments on different textiles materials has become a
must for the textile or leather dyers/printers and plastics injection moulder/wall
paints etc.
Day by day, more and more concern of consumers on colour matching for
consumers’ textiles and live-style products of apparels and furnishings, bed linen
and auto-mobile (car) Interiors, appliances and along with polymer/plastic
assemblies, are pushing the dyed/printed coloured textile product manufacturer to
develop their products with more precision colour matching with least
meta-merism.
In order to understand the colour we have to know, how the colour is perceived.
The perception of colours [1] involves the interaction of three elements. (i) source
of light, (ii) an object and (iii) human eye.
2. Colour theory
Figure 1.
Schematic display of colour observed from RGB primary colour stimuli with standard illuminant by a standard
observer /detector.
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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• The CIE Theory of Colour -Tristimulus values (X, Y and Z) and CIE L*, a*and
b* values
The CIE Theory of Colour 1931 updated in 1976 [1.2] is in wide commercial use
for textile’s colour communication and hence it has significant importance in
apparel sector and is described below.
3
Colorimetry
Figure 2.
(a): Spectral sensitivity of human eyes of RGB primary Stimulli and (b): Resultant actual measurement of
reflectance values and corresponding Tristimulus values of any object.
Figure 3.
a: CIE 1931 chromaticity diagram showing b: CIE 1931 chromaticity diagram all predominating visible hues
at 380-700 nm (coloured) showing x and y coordinates.
Q l ¼ X l R þ Y l G þ Rl B,
where Rl, Gl, and Bl are the spectral tristimulus values of Ql.
Consequently, the CIE 1931 chromaticity diagram [1–3] is not a perceptually
uniform chromaticity space from which the perception of chromaticity can be
derived, where (Figure 3a and b)
x ¼ X=ðX þ Y þ Z Þ, (1)
y ¼ Y=ðX þ Y þ Z Þ, (2)
z ¼ Z=ðX þ Y þ ZÞ, (3)
and x þ y þ z ¼ 1 (4)
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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Hence there is no need to plot a three dimensial x,y and z diagram, rather the
2 dimensional chromaticity coordinate plot (Figure 3a or b) is sufficient to get x,y
& z values from x vs. y plot of 2 dimensional CIE chromaticity diagram [1–3].
As per 1976 CIE L*a*b* colour space, L*, a* and b* values for comparing colour
differences in betrween two samples of same or similar textile fabrics n be
represented by ∆L*, ∆a* and ∆b* values [1–3].
CIE 1976 lightness/darkness is represented by, L* (L = 0 black and L-100
white), more or less similar to lightness distribution to the Munsell Value scale and,
CIE 1976 scale of redness (a* ve) /greenness (a* ve) is represented by a* and CIE
1976 scale of yellowness (b*+ve) /blueness (b* ve) is represented by b*, and 1976
CIE L*a*b* colour space diagram represent total colour differences value by ∆E or
∆E * (as shown in Figures 4 and 5).
Figure 4.
CIE-L* a* b* system of colour difference plot to determine ∆L*, ∆a* and ∆b* values of a pair.
Figure 5.
Example of metameric match under two different illuminant (day light and Fluoroscent light conditions.
5
Colorimetry
Where, C*1(ab) and C*2(ab) are the chroma values for standard and produced
sample.
CIE 1976 metric Hue-Difference (∆H) for CIELAB system [1–3] was calculated
as follows:
h i1=2
ΔHab ¼ ðΔEab ∗ Þ2 ðΔL ∗ Þ2 ðCab ∗ Þ2 (9)
As per Kubelka Munk Equation [1–3]. Surface colour Strength (K/S value) of
Coloured flat surface is:
Co‐efficient of absorption
K=S ¼
Co‐efficient of scattering
(11)
ð1 Rλ max Þ2
¼ ¼ αCD
2Rλ max
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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Co‐efficient of absorption
K=S ¼
Co‐efficient of scattering
(15)
ð1 Rλ max Þ2
¼ ¼ αCD
2Rλ max
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Colorimetry
and the obtained results of reflectance values at different wave length in visible
region are processed in computer aided colour matching software for matching
X, Y and Z values of produced samples or simply by comaparing the total inte-
grated K/S values at 400–700 nm wavelength (visible range) for ultimate checking
of colour matching of textiles in terms of allowable limits (tolerences) of colour
difference values of ∆ L*, ∆a* and ∆b* values representing 1976 CIE L*a*b*
colour space diagram and in terms of allowable limit of total colour differences
value represented by ∆E / ∆E *.
A textile match however should be ideally be an isomeric match i.e. match under
all illuminant. But in actual practice, when two coloured sample show a match of
colour under one illuminant may not match under other illuminantand this differ-
ence of match under specific two conditions of different illuminant is termed as
illuminant based metameric match. Besides variation of illumainnat, there are other
different types of metamerism for change of conditions of colour measurement, as
follows, arised during colour matching under varying ambience of any one factor or
others [1–3]:
Types of metamerism:
∆L1*, ∆a1*, and ∆b1*are the Delta CIELab* colour coordinates between
Standard and Sample for the first illuminant and ∆L2*, ∆a2*, and ∆b2*are the Delta
CIELab* colour coordinates between Standard and Sample for the second illuminant
Interpretation:
When, MI (metamerism index) is low, the colour difference between the sample
pair (standard vs. produced) is the more closer and similar, for different conditions
of measurement even under different illuminants.
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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The reformulation of batch correction issue for computing the incremental value
of concentration of dyes by each iteration at each stage may be represented by the
following matrix as follows [4]:
• Colorimeter
9
Colorimetry
• Turbidometer
Figure 6.
Major wavelength from incident white light dominating at visible range.
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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This chapter mainly covers the basic principles of analysis of surface colour
parameters vis a vis other appearance properties of the surface of solid textile
materials and associated colour difference parameters by using Reflectance Spec-
trophotometer in terms of specific 1931 CIE and 1976 CIE formulae [1–3] for
determination of all specific Surface colour parameters of textile materials, changes
with or without different chemical processing and computer aided colour match
prediction theories and practices [7, 8].
11
Colorimetry
Figure 7.
Schematic diagram of working of UV–Vis spectrophotometer.
of sample at different wave length. Finally from reflectnace values obtianed for any
sample, it calculates other colour parameters as per CIE 1976 formulae [1–3] and
other formulae as per software inserted/installed for it for the data processing in a
suitable computer system for computer aided colour measuring and also for textile
match prediction system using pre-fed data base of textile dyes.
Usually a double beam UV VIS reflectance spectrophotometer, the incident light
beam is first split into two parts by a half mirror as two light beam called double
beam. One light beam falls /passes on the sample mounted and the other light beam
falls (for reflectance mode) /passes (for transmission mode) through a control
sample panel. This system of double beam eliminates the problems of interference
from control sample and normalises the variations in reflected /transmitted light
intensity readings uncreasing accuracy of the instrument reading, as the final
reflectance/ transmittabce/absorbance values are taken as the differences between
the readings of two reflected/transmitted beams of light intensity recorded.
The semicircular LED Detector inside the integrating sphere measures both the
two reflected/transmitted light intensity alternately and gets its processed in
computerised processor to give final reading. However, in some UV–VIS spectro-
photometer, a second detector is separately installed to measure the intensity of the
two beams separately. Thus, the major instrumental parts of an UV–VIS Double
Beam Reflectance Spectrophotometer are shown in Figure 7 indicating the position
of light source, diffraction grating, monochromator, sample cell/ integrating sphere,
detector and integrator and computerised recorder. The instrument changes the
light source from visible to UV light at about 350 nm by a mechanically moving
mirror, as shown in Figure 7.
The diffused reflection shows total effect of incident light including specular
reflection in integrating sphere diffraction, which may be excluded by opening a
port at particular angle without detecting the specular reflections in UV–Vis reflec-
tance spectrophotometer and different types of solid samples with varying surface
and texture show variation in reflectance values, effecting surface colour strength,
as shown in Figure 8.
Sphere Geometries of illumination and viewing in reflectance spectrophotome-
ter [7, 8] is very important here. It is based on mesaurement of Reflectance of dyed
samples of textiles. On a glossy surface there are mirror-like (specular) reflections
and there are more reflections in the case of diffuse light sources. Figure 9 shows
the effect of transmission mode and total reflection mode of integrating sphere of in
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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Figure 8.
Schematic diagram of optical system of UV–Vis reflectance spectrophotometer.
Figure 9.
Schematic diagram of working of integrating shere type optical system in UV–Vis reflectance spectrophotometer.
13
Colorimetry
White calibration: Before Use always this instrument should be callibrated with
standard white tiles equivalent to white surface of saturated dry layer of Magnesium
sulphate, which adjusts computational parameters for any setting disturbances,
so the calculated reflectance values match with calibrated value of white tiles being
100 and the accuracy of reflactance curve is the same as the absolute reflectance
curve do it often.
Absolute certification: The instrument need better to be certified by NABL,
which verifies that the measured colour of the standard white tile is 100 or specified
values by manufacturer, within the tolerance (e.g. within 0.6 ∆E * units) from the
absolute colour of the standard white tile, in perfect agreement between instrument
and laboratories, when checked for certifiocation.
Relative certification: verifies if the measured colour of the standard white
callibrated tile is within the tolerance (e.g. 0.3 ∆E * units) from the initial colour of
the standard white tile in the same instrument, which is very very important for
reproducibility and reliability of colour data produced.
Colour Difference Index (CDI) [10] indicates the combined effects of different
known individual colour difference parameters between any two samples when
dyed with varying conditions of dyeing, indicating dispersion of colour value, to
understand the combined effects of different dyeing variables by a single parame-
ter. For application of same concentration of dye between two sets of dyeing
under any varying conditions of dyeing like pH, taking only the magnitudes of
the respective ΔE, ΔC, ΔH and MI values (irrespective of their sign and
direction) may be considered to calculate CDI values using the following empirical
relationship [10].
ΔE ΔH
Colour Difference Index ðCDIÞ ¼ (22)
ΔC MI
Higher the CDI value dispersion of Colour values are more widely dispersed and
that variable become critical for reproducibility for such dyeing. So, Lower CDI
value below 5.0, is considered as good.
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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Figure 10.
20 standard observer (small area of view) and 100 standard observer (large area of view).
• Standard Observer: There are two angular view areas considered as standard
viewing areas called 20 standard observer (small area of view) and 100
standard observer (large area of view) as shown in Figure 10 [1–3]. As
recommended by CIE, in 1964, the larger area of view of solid samples
mounted for colour measurement on sample port of UV VIs reflectance
spectrophotometer is most widely used for evaluating colour values and for
colour matching of various types of solid samples including textiles. Ordinary
Colorimeters, on the other hand, typically use a 20 Standard Observer (as per
CIE, 1931), which has a smaller area of view and is common for general colour
measurement and colour quality control and evaluation purposes for
comparative purposes and also for printed textiles.
Computer aided Colour Match prediction system (CACMPS) [4, 9] is the com-
bination of specific hardware and software for scientific use for measuring colour of
solid textile surface for given sample as standard for predicting the dyeing recipe or
formulation for the exact shade reproduction in a textile fabric sample to produce.
Hence, this technique is known by names e.g-computer colourant formulation,
computer recipe prediction, Instrumental colour matching system or Computer
aided Colour Match prediction system (CACMPS) using reflectance spectropho-
tometer and associated computerised sytem for storing and analysis of data with
specific software to predict colour matching of textile substrate. A colour matching
computer system consists of the following three basic modules,:
15
Colorimetry
Recipe Generated
Formula#1
Formula # 2
Table 1.
A case study of colour match prediction from the database of direct dye for cotton.
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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After that, the associated Computer aided colour match prediction software
takes over the rest part of the work of calculations and comparison of colour data to
show the measured values and calculated colour values using stored colour database
of specific dyes for specific type of textile substrate. Table 1 shows Computer aided
colour match prediction system (CACMPS) generated dyeing recipe and its dye cost
and estimated approxmiation of Colour difference values with least metameric ratio
for cotton fabric sample to be dyed to match against given standard samples using
direct dye data base stored.
The above shown formulae of colour match prediction generated against standard
shade C5, has generated two possible recipes, and is difficult to decide which one we
should accept and proceed for bulk dyeing. From the Point of least metamerism,
formulation-1 and from the point of least cost Formula 2 are respectively found
better after 4 trial run in Computer aided colour match prediction system (CACMPS)
within DE limit to 1.00. Thus, computer predicted formulation 2 is least cost and
formulation 1 is least metameric in nature, as shown in output result generated here.
The practical aspects of data base generating match generation using a data base,
setting up proper DE or multiple colour tolerance & above all accurate spectropho-
tometer measurement depends on following factors.
17
Colorimetry
The calibration dyeing for preparation of dyestuff data base for dyeing specific
textile fabrics with selected type and class of dyes is an essential pre requisite. After
selection of substrate and class of dyes and dye manufacturer/suppliers), to run a
computer aided colour measuring and matching system, preparation of dyestuff
data base ton store using selective class and type of dyes, the control bleached
cotton/ otherwise textile fabric sample are to be dyed with each selected dye at 5-8
different concentration levels of dyes (say, within 0.1 / 0.5 to 4%) and those
samples dyed are to be subjected to measure their reflectance values at
different wavelength and their individual values or their integrated sum of these
REflectance / tristimulus colour values are to be stored for futurev uses to form a Dye
class wise/company wise data bank or data base of all different type of dyes for
specific substrate / substance following a particular standard process of dyeing in a
separate file of the computerised processor or computer to use at every re-call.
Samanta et al. [9, 10] mentioned the cares necessary for accuracy in colour measure-
ment of textiles including nos. of folding etc. and orientation of samples and measure
of colour difference index values etc. Randall and Stutts [11] specifies how to prepare
reliable samples of calibration dyeing for creating dyestuff data base in computer
aided colour matching system as a most important step. For optimum efficacy in
computer aided colour matching system, the laboratory dyeing machine and process
must be highly controlled in terms of dyeing process variables and all these must be
standardised before callibration dyeing be carried out accurately, which is to be
assured by the lab dyers /colourist to store precision colour data/ dyestuff database
separately for company wise /substrate wise for separate class of dyes.
3.3 Checking of linearity / non-linearity for plots of K/S vs. dye conetrations in
dyestaff data base
The accuracy of computer aided colour matching system depends on the correct
dyestuff data base preparation as discussed in calibration dyeing in item 3.1 above.
The accuracy of dyestuff data base can be checked by checking linearity of K/S vs.
Dye Concentrations curve pattern for each individual dye applied on same substrate
under standardised control dyeing conditions. Sometimes, this linear relation does
not exist and then the deviation from linearity is to be eliminated, before such
dyestuff data base are stored for future use of colour matching functions. The
deviation from linearity of plot between K/S vs. dye concentration are due to
(i) inherent variation in dye uptake rate or variation in exhaustion rate of the
dye for higher percentage of dyes (ii) unknown interference of dyes with given
dye bath auxialaries (iii) variation in dyeing conditions /stirring rate (iv)
weighing/solubilisation/dilution error (v) impurities/agglomeration of few
dyestuff itself, where these said reasons causes a variation of dyeing with increase in
dye concentration [9] showing non linearity/deviation from linearity in observed.
Dye uptake.
Therefore, this linearization is to be ultimately done by statistical best fit
linearization process or elimination of one or two concentrations of dyes(where /
from which point the said linearization is originated/deviated) for particular dye or
by empirical modifications of the equation of K-M functions (K/S value). before
storing dyestuff database to be used for colour match prediction of coloured textiles
easily. For this type of special cases, the dye absorption co-efficient/difussion coef-
ficient of the dye is to be determibned and to be checked at about five to eight level
of dye concentrations to check the dyeing absorption/diffusion rate and then line-
arization can be made either eliminating few dye concentrations where dyeing rate
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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Colour Matching of textiles is very much dependant on the Pigment /dye Data-
base created –dye class based and type of fibre/fabric based and dye company based
to be pre-up-loaded in spectro. To match full strength of colour, Light and dark i.e.
white and black reduction are very important.
Pigments /dyes should be thoroughly dispersed and uniformly dyed, which is
Very difficult with powder pigments, but much easier with Master batch mass
pigmentation to produce coloured textiles.
There are so many variations in measuring surface colour of textiles. A mea-
surement is never perfect. The effect of variability of colour measurement is
reduced by using multiple measurements and taking avrages at 10 points atlesat.
How many measurements should I make for averaging is a good question and Rule
of thumb is 10 times atleast for each variability parameter of dyeing for
standardising dyeing process variables. For any variable instrumental factors also,
measure each spot of colour value for 10 times to take average of it. But for sample
uniformity for data base storing data, one should repeat colour measurements at
several locations — more than 10 to 100, depending CV % of K/S values or reflec-
tance values of coloured textile surface. One can follow ASTM standard E 1345-
90 to determine how many measurements are necessary in each case.
Some more Practical Aspects of variability in colour mesurement of textile
surface [9] are:
b. Back ground opaqueness of the sample (No. of Folds are to be kept Constant
say usually 4 fold).
d. Variation in texture or surface roughness may vary K/S values for change in
scattering (Any chemical/ physical intervention/Treatment before dyeing
may change surface texture)
e. Variation of colour and texture in two sides of the fabric sample (K/S -surface
colour strength in one face of fabric may sometimes differ from other face
due to the said effect).
f. Any Fabric or Dyeing Defects/Stains in the fabric sample (Any defect of the
fabric may cause colour variation).
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Colorimetry
g. Dull shade / Fluorescent colour & bright shade etc. some times behave differently.
h. Blended fabric may pose problem with change of Blend % of each component
of fibres.
• Improper Cleanliness of dyeing machinery parts, like steam pipes and dye bath
• In-compatable colour mixing and variation of dyeing time and other process
variables
• Inventory and logistics issues are there also for variation of colour and its
measurement.
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Basic Principles of Colour Measurement and Colour Matching of Textiles and Apparels
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6. Purity/ Quality test of incoming newer batch of dyes with the help of this
computer aided colour measuring system.
where x, y and Y are the colorimetric values for the sample under illuminant
D65, and xn and yn are the chromaticity coordinates of the light source/illuminant
used. A value for WI of 100 represents a perfect reflecting white diffuser,
equivalent to surface of saturated paste of Magnesium sulphate.
X, Y and Z are the CIE tri-stimulus values of the sample and L* is the lightness/
darkness indicator, b* is the blueness/yellowness indicator.
21
Colorimetry
0:8477
Yellowness Index ðYIÞðASTM‐E313=1973Þ ¼ 100 ½1–ðB=GÞ ¼ 100 1
Y
(25)
Where, X, Y and Z are the CIE tri-stimulus values of the sample, L* is the
lightness/darkness indicator, b* is the blueness/yellowness indicator and
B = Z/1.181 = 0.847 Z, G = Y = L2 /100.
Brightness Index (BI) as per ISO-2469/2470-1977method [13] can be calculated
by following formula:
Brightness index ¼
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6. Concluding remarks
Acknowledgements
The author is thankful to the Principal RBGC, Kolkata for her encouragement
and support.
Author details
Pubalina Samanta
Department of Fashion and Apparel Design, Rani Birla Girls’ College, Kolkata,
West Bengal, India
© 2022 The Author(s). Licensee IntechOpen. This chapter is distributed under the terms
of the Creative Commons Attribution License (http://creativecommons.org/licenses/
by/3.0), which permits unrestricted use, distribution, and reproduction in any medium,
provided the original work is properly cited.
23
Colorimetry
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