MATERIAL SAFETY DATA SHEET

(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)

PRODUCT CODE: P130 Effective Date: 16-September-2002

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Identification of the substance or preparation:
WELLBORE CLEANING SOLVENT P130
Company/undertaking identification: Schlumberger
110 Schlumberger Drive
Sugar Land, Texas 77478, USA

Corporate Emergency Phone: USA 1-281-595-3518

Corporate Non-Emergency Phone: USA 1-281-285-7873

2. COMPOSITION/INFORMATION ON INGREDIENTS
D-LIMONENE; CAS 5989-27-5; 60 - 100%

3. HAZARDS IDENTIFICATION
Emergency Overview
Form: Liquid
Color: Clear colorless
Odor: Aromatic
Main environmental hazards:
Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Main Physical Hazards
Special Precautions: None.
Physical Hazard: Flammable liquid
Main Health Hazards:
HMIS RATING: Health 2 Flammability 2 Reactivity 0
May cause allergic reaction upon repeated skin exposure. May cause skin irritation. May be mildly
irritating to eyes. May be mildly irritating if swallowed. May cause dizziness, nausea, vomiting, diarrhea.
Swallowing large amounts may be harmful.
See Section 11 for a complete discussion of health hazards.

4. FIRST AID MEASURES

Eye contact: Immediately flush eyes with water for 15 minutes while
holding eyelids open. Seek medical attention.
Skin contact: Immediately remove contaminated clothes and shoes.
Wash with soap and water for 15 minutes. Seek
medical attention.
Inhalation: Remove to fresh air. Seek medical attention if irritation
persists or you feel unwell.
Swallowing: DO NOT induce vomiting. Give activated charcoal in
water, or give 2 glasses milk or water. Seek medical
attention at once.
Notes: None.

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PRODUCT CODE: P130 Effective Date: 16-September-2002
5. FIRE FIGHTING MEASURES
Extinguishing media: Alcohol Foam, CO2, Dry Chemical
Further Information: Wear protective fire fighting clothing and avoid
breathing vapors. Use self-contained breathing
apparatus in closed areas.
Flash point: 115ºF
Method: Pensky-Martens CC
Flammability (explosion limits in air):
Lower: 0.7% Upper: 6.1%
Autoflammability (auto-ignition temperature): Not available
Explosive properties (thermal decomposition temperature): > (450ºF)
NFPA Rating: Health 2 Flammability 2 Reactivity 0 Other: None
Combustion products: see Section 10.

6. ACCIDENTAL RELEASE MEASURES

After spillage/leakage: Contain with dikes. Use explosion proof equipment to
recover. Remove all sources of ignition. Soak up
residual on inert absorbant (sand). Put in plastic drum
approved for flammables. Do not allow to enter
waterways.
See Section 8 for protective equipment information.
See Section 13 for disposal information.

7. HANDLING AND STORAGE

Special Precautions: Keep away from heat, sparks, and flame. Keep
container closed when not in use. Use with adequate
ventilation. Do not cut or weld on container.
Packaging requirements: Steel or high density polyethylene (HDPE) container
approved for flammables.
Ventilation: No special requirements.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Respiratory protection: None normally needed. Use NIOSH approved
respirator with organic vapor protection (color coded
black or yellow) if vapors are generated and for
emergencies.
Eye protection: Chemical splash goggles.
Hand protection: Impervious gloves made of: Neoprene
Skin protection: Chemical resistant apron.

Exposure Limit Guidelines (mg/m3)

No components have established exposure limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Liquid
Color: Clear colorless
Odor: Aromatic
pH value: Not applicable

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PRODUCT CODE: P130 Effective Date: 16-September-2002
Boiling point: 309ºF
Pour point: < 194ºF
Vapor pressure: 0.26 kPa (68ºF)
Relative density (specific gravity): 0.84
Bulk Density (solids): Not applicable
Solubility in water: Insoluble
Viscosity: Not determined
Relative Vapor Density (air=1): 4.66
% Volatile: 32.5
Nature: Solvent

10. STABILITY AND REACTIVITY

Stability: Stable.
Conditions to avoid: None known
Materials to avoid: Oxidizers
Hazardous Polymerization: Will not occur.
Dust explosion hazard (solids): No.
Special hazards: None.
Hazardous decomposition products: When heated strongly or burned, oxides of carbon and
harmful organic chemical fumes are released.

11. TOXICOLOGICAL INFORMATION

Eye contact: May be mildly irritating.
Skin contact: Irritant; may cause pain, redness, dermatitis.
Inhalation: May be mildly irritating.
Ingestion: Swallowing large amounts may be harmful. LD50
(oral, rat) > 5g/kg
Carcinogenicity: Not listed by IARC, USA NTP, or USA OSHA.
Mutagenicity: Not known to cause heritable genetic damage.
Teratogenicity: Not known to cause birth defects.
Target organs which may be affected: None known.
Sensitization: May cause allergic reaction upon repeated skin
exposure.
Other: May cause dizziness, nausea, vomiting, diarrhea.

12. ECOLOGICAL INFORMATION

Information on product as a whole:
Main environmental hazards: Very toxic to aquatic organisms. May cause long-term
adverse effects in the aquatic environment.
Degradability: Partially biodegradable.

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PRODUCT CODE: P130 Effective Date: 16-September-2002
13. DISPOSAL CONSIDERATIONS
Product: Ship via permitted waste hauler to permitted
hazardous waste disposal facility for incineration
(preferred) or disposal well injection of all liquids and
landfilling of solids.
Container: Incinerate (preferred) or hazardous waste landfill
unless prohibited by local regulations.
USA EPA RCRA: D001

14. TRANSPORT INFORMATION

CERCLA RQ: Not established.
Department of Transportation (DOT)

Package Size: 0 - 119 gals

Designation: Hazardous Material
Hazard Class: 3 Sub Risk:
Shipping Name: Terpene hydrocarbons, n.o.s., 3, UN 2319, PG III
DOT Label: Flammable Liquid 3

Package Size: > 119 gals

Designation: Hazardous Material
Hazard Class: 3 Sub Risk:
Shipping Name: Terpene hydrocarbons, n.o.s. (contains D-Limonene), 3, UN 2319, PG III,
Marine Pollutant
DOT Label: Flammable Liquid 3, Marine Pollutant

Canadian Shipments
Shipping Name: Terpene hydrocarbons, n.o.s.
Label: Flammable Liquid 3
Classification: 3 Sub Risk:
Package Group: III PIN: UN 2319

15. REGULATORY INFORMATION

Notification/restrictions status:
USA:
All components of this material are on the USA TSCA inventory, or the components are exempt from
inventory reporting.
CANADA:
All components of this material are on the Canada DSL, or the components are exempt from inventory
reporting.

This product contains no chemicals subject to the USEPA reporting requirements of SARA 313.
The USEPA CERCLA Reportable Quantity (RQ) for this product as a whole is: Not established.
Canadian WHMIS classification: B3 ,D2B

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PRODUCT CODE: P130 Effective Date: 16-September-2002
16. OTHER INFORMATION
Sections affected by last revision:
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
TRANSPORT INFORMATION

*Mark of Schlumberger. The information herein is believed to be accurate and is presented in good faith;
however, no warranties or representations are made by Schlumberger regarding the accuracy or
completeness of the information.

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