(Inorganic Chemistry) General Chemistry (Inorganic Chemistry) General Chemistry

DPP-01 (T) 4.8 × 10−10 esu

Only one correct: 6. Match the following

1. A certain positive ion A +2

has 22 neutrons and 18 electrons. What is the mass number of most Column-I Column-II

abundant isotope of A (A) the physical property of metal that allows it to be drawn into wire (P) Element

(A) 42 (B) 38 (C) 40 (D) none (B) a single particle composed of two or more atoms property (Q)Physical

2. Examine the model of vitamin C and determine the molecular formula. In the model shown, the (C) a property that can be observed without changing the chemical (R) Molecule

black sphere = C atom, ∘ sphere = H atom, ∘ Sphere = O atom. formula of a substance

(D) a substance that cannot be broken down into simple substances. (S) Ductility
(T) Malleability
Integer Type
7. From the following:
Sugar solution, air, copper, silver, gold, water, glucose, oxygen gas, hydrogen, ammonia, carbon
dioxide, smoke, dust, brass, soap solution, bronze
(A) C8 H6 O6 (B) C6 H8 O6 (C) C6 H10 O6 (D) none
Estimate total number of –
3. In a scale of 10−18 m, match the particle with respect to their probable size
(i) pure substances = x (ii) Homogeneous mixtures = y (iii) Heterogeneous mixture = z.
List-I List-II
Find x − z + y
(P) Atom (1) 1,000
Fill your answer as sum of digits till you get the single digit answer.
(Q) Nucleus (2) 10,000
8. A certain anion carries −9.6 × 10−19 Coulombs of static electric charge. Calculate the number of
(R) Proton (3) 100,000,000
electronic charges present on it.
Code:
9. Match each description below with the following microscopic picture. More than one picture
(A) P-1 Q-2 R-3
may fit for each description. A picture may be used more than once or not used at all:
(B) P-3 Q-2 R-1
(C) P-1 Q-3 R-2
(D) P − 2 Q-3 R − 1
More than one may be correct:
4. Specie ' X ' with mass number 37 contains 11.1% more neutrons as compared to electrons, then
what is the INCORRECT representation of specie ' X ' ?
(A) 37 −
17 Cl (B) 37
17 Cl (C) 35 −
17 Cl s(D) 35
17 Cl (A) a gaseous compound
Matrix match type (B) a mixture of two gases element
5. Column-I Column-II (C) a solid element
(A) Charge on electron (P) 1.6022 × 10−19 C (D) a mixture of a gaseous element and gases compound
(B) e/me (Q) 1.758820 × 1011 Ckg −1
(C) Mass of proton, mp (R) 1.00867u
(D) Mass of neutron, mn (S) 1.00727u

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10. Complete the following table DPP-02
Element Symbol Protons Neutrons Electrons Mass number Only one correct:
32
S
1. Which species carry the maximum charge?
30 65
20 20 (A) proton (B) β-particle (C) α-particle (D) Hydronium ion
2. The ratio between the neutrons present in nitrogen atom and silicon atoms with mass number
14&28 is
(A) 7: 3 (B) 3: 7 (C) 1: 2 (D) 1: 1
3. Two particles (X) & (Y) have the composition as shown in the table

Particle No. of Electron No. of neutron No. of proton

(𝐗) 18 16 16
(𝐘) 18 18 17

The particle (X) & (Y) are :-

(A) Isotopes of each other (B) Isobar of each
(C) Isotone of each other (D) Isoelectronic ions
4. Ozone is isoelectronic with
(A) NOF (B) NO−
2 (C) Both (A) & (B) (D) None of these
More than one may be correct :
5. Identify those which are isoelectronic with each other
(A) Na+ (B) Mg 2+ (C) Al+3 (D) O2−
6. Identify the element which are isotones of 16
8O

(A) 7N
14
(B) 7N
15
(C) 6C
14
(D) 9 F17
7. N2 is isoelectronic with
(A) CO (B) NO+ (C) C22− (D) CH4

Integer Type :
8. An element has same number of neutrons as total number of protons or total number of
electrons. What will be the neutron excess ?
9. If an element is represented by (A, Z) e.g. Ni60
28 can be written as (60,28) Among the following,

find the total number of possible isotopic pairs formed by the given atoms.
(232,90); (228,88); (228,89); (228,90); (224,88); (216,84); (210,84); (213,84)
10. Find the number of elements which are isodiaphers of
238 234
92 U 90 Th , 90 Th232 , 93 Np237 , 96 Cm
247

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DPP-03 DPP-04
Only one correct Only one correct
1. Principal, azimuthal and magnetic quantum numbers are respectively related to 1. Which of the following statements regarding subshell filling order for a neutral atom is/are
(A) size, shape and orientation (B) shape, size and orientation correct ?
(C) size, orientation and shape (D) none of these (I) Electrons are assigned to the 4 s subshell before they are assigned to the 3 d subshell
2. Degenerate atomic orbitals have (II) Electrons are assigned to the 4f subshell before they are assigned to the 6 s subshell
(A) equal energy (B) nearly equal energy (III) Electrons are assigned to the 4 d subshell before they are assigned to the 5p subshell
(C) different energy (D) none of the above (A) I only (B) II only (C) I and III (D) I, II and III
3. How many maximum electrons can be described by the quantum numbers n = 5, ℓ = 2 in a 2. Which is a possible set of quantum numbers for the unpaired electron in the orbital box diagram
particular atom?
below ?
(A) 2 (B) 6 (C) 10 (D) 14
[Ar] ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
1
4. If an electron has spin quantum number of + 2 and magnetic quantum number of -1 , then it 3d 4s 4p
cannot be present in – (A) n = 1, ℓ = 1, mℓ = −1, ms = +1/2 (B) n = 4, ℓ = 1, mℓ = −1, ms = +1/2
(A) f-orbital (B) d-orbital (C) p-orbital (D) s-orbital (C) n = 4, ℓ = 2, mℓ = −2, ms = +1/2 (D) n = 4, ℓ = 0, mℓ = 0, ms = +1/2
5. When the quantum number n, l, m, s are represented by 3,3,2, +1/2, the symbolism for the 3. Which element has the following ground state electronic configuration?
electron is – [Ar] ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑ ↑
(A) 3s (B) 3d 3d 4s 4p
(C) 3f (D) impossible set of quantum number (A) Se (B) As (C) S (D) Ge
6. For a 6 s electron the values of n, l, m, s respectively could be: 4. Hund's rule states that the most stable arrangement of electrons (for a ground state electron
(A) 6,4,4, +1/2 (B) 1,0,0, +1/2 (C) 6,1,0, +1/2 (D) 6,0,0, +1/2 configuration)
7. Any p-orbital can accomodate up to (A) has three electrons per orbital, each with identical spins
(A) four electrons (B) Two electrons with parallel spin (B) has mℓ values greater than or equal to +1
(C) Six electrons (D) Two electrons with opposite spin (C) has the maximum number of unpaired electrons, all with the same spin in degenerate orbital
8. Which one of the following sets of quantum numbers (n, l, m, s) represents an impossible (D) has two electrons per orbital, each with opposing spins
arrangement? 5. The Pauli exclusion principle states that
(A) 3,2, −2, +1/2 (B) 4,0,0, +1/2 (C) 3,2, −3, +1/2 (D) 5,3,0, −1/2 (A) no two electrons in an atom can have the same four quantum numbers
9. Which type of orbital is designated by n = 2, ℓ = 3, mℓ = −2 ? (B) electrons can have either ±1/2 spins
(A) 4p (B) 4 d (C) 4f (D) None
(C) electrons with opposing spins are attracted towards each other
Match the column
(D) None of these
10. (' l ' and ' m ' are respectively the azimuthal and magnetic quantum numbers)
6. Choose the correct option for the quantum numbers of the last electron of 3p6 .
Column I Column II 1 1
(A) 4,0,0, +1/2 (B) 3,1, −1, −1/2 (C) 4,1,0, − 2 (D) 3,0,1, 2
(A) Total number of values of (l) for a shell (P) 0,1,2, … … … … … (n − 1)
(B) Values of (l) for a shell (Q) +l, … . . +2, +1,0, −1, −2, … … . −l 7. Select set of quantum number which is possible for maximum number of electrons in an atom
1
(C) Total number of values of (m) for a subshell (R) (2l + 1) (A) n = 5, ℓ = 0, m = 0, s = + 2 (B) n = 5, ℓ = 2, m = 0
(D) Values of (m) for a subshell (S) n

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(C) n = 3, m = 0, s = − 2
1
(D) n = 5, m = 0, s = + 2
1
DPP-05
8. Statement-1 : For n = 2 the values of ℓ may be 0,1 and m may be 0, ±1. 1. Consider the ground state of Cr(Z = 24). The numbers of electrons with the azimuthal quantum
Statement-2 : For each value of n, there are 0 to (n − 1) possible values of ℓ, for each value of ℓ number l = 1 and 2 respectively are
there are 0 to ±ℓ values of m. (A) 16 and 4 (B) 12 and 5 (C) 12 and 4 (D) 16 and 5
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for 2. The total number of electrons in Cr atom for which m = 0
statement-1. (A) 1 (B) 8 (C) 12 (D) 16
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation 3. How many maximum possible set(s) of quantum no. are possible for 6th electron of Fe
for statement-1. (A) 1 (B) 3 (C) 6 (D) 10
(C) Statement-1 is true, statement-2 is false. 4. The maximum no. of electron in phosphorous atom for which n + l + m = 3 will be –
(D) Statement-1 is false, statement-2 is true. (A) 6 (B) 5 (C) 4 (D) 3
Match the column: 5. Which of the following have maximum number of unpaired electron –
9. Column-I Column-II (A) Na+ (B) N3− (C) Fe3+ (D) Cr 3+
(A) No. of electrons in Na(11) having m = 0 (P) 7 MATCH THE COLUMN
(B) No. of electrons in S(16) having (n + ℓ) = 3 (Q) 15 6. Match the column:
(C) No. of maximum possible electrons having (R) 8 Column – I Column – II
s = +1/2 spin in Cr (24) (A) Fe+2 (P) Set of quantum no. for last e−
(S) 12 1
n = 2, ℓ = 1, m = 1, s = +
2
Subjective
(B) Mn+4 (Q) Magnetic moment (μ) = zero.
10. Imagine a universe in which the four quantum no. can have the same possible values as in our
(C) Zn +2
(R) Spin multiplicity (SM) = 4
universe except that azimuthal quantum no. (1) can have integral values from 0,1,2 … . n + 1
(D) Na +
(S) Total no. of exchange pair in 3d-subshell = 10
(a) Find the no. of electron n = 1 & 2 shell.
(T) Paramagnetic
(b) Predict the electronic configuration for elements with atomic no. 15&25 using aufbau
Subjective
(n + l) rule.
7. H-atom have infinite shells, write total number of shells which does not contain f-subshell.
8. Calculate Zeff for last valence shell electron in fluorine (F).
9. In multielectronic atom, maximum number of degenerated orbitals present in 3rd shell
10. Calculate Zeff for 3 s electron in vanadium(23).

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ANSWER KEY ANSWER KEY

DPP-1 DPP-2
1. (C) 2. (B) 3. (B) 4. (B,C,D) 5. A-PT, B-Q, C-S, D-R 1. (C) 2. (C) 3. (D) 4. (C) 5. (A,B,C,D) 6. (B,C,D)

6. A − S, B − R, C − Q, D − P 7. (A, B, C) 8. 0 9. 5 10. (1)

7. 10, OMR Ans. 1

8. 6
9. (A) ii, iii, iv ; (B) vi ; (C) v ; (D) iii , ii
10. Element Symbol Protons Neutrons Electrons Mass number
Sulphur 32
S 16 16 16 32
Zinc 65
Zn 30 35 30 65
Calcium 40
Ca 20 20 20 40

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ANSWER KEY ANSWER KEY
DPP-3 DPP-4
1. A 2. A 3. C 4. D 5. D 6. D 7 D 1. C 2. B 3. A 4. C 5. A 6. B 7. (D)
8. C 9. D 10. (A) → S; (B) → P; (C) → R; (D) → Q 8. A 9. (A) −P; (B) −R; (C) – Q
10. (a) 18,32
(b) atomic number 15 = 1 s2 1p6 2 s2 1 d5 atomic number 25 = 1 s2 1p6 2 s2 1 d10 2p5

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ANSWER KEY
DPP-05
1. B 2. C 3. C 4. B 5. C
6. A → S, T; B → R, T; C → Q; D → P, Q
7. 3 8. σ = 3.8 Zeff = 5.2
9. 5 10. σ = 11.25 Zeff = 11.75

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