Revision date: 24/3/2023 Revision: 1

SAFETY DATA SHEET

PX 3495
Conforms to UNGHS Rev.4(2011)

SECTION 1: identification of the hazardous chemical and of the supplier

Product identifier
Product name PX 3495

Recommended use of the substance or mixture and restrictions on use

Identified uses Octane Improver. For industrial use only.

Details of the supplier of the safety data sheet

Manufacturer Dorf Ketal Chemicals (I) Pvt. Ltd.
Dorf Ketal Tower-2. Kanchpada,
Ramchandra Lane,
Malad (W).Mumbai 400064.
Ph.: +91-22-28813654 / +91-22-28828374.
Fax: +91-22-28882366.
Email: [email protected].

Emergency telephone number

Emergency telephone For Chemical Emergency ONLY (in the case of fire, leak, spill, exposure or accident) call
CHEMTREC at +1(703) 527- 3887 or CHEMTREC India at 000-800-100-7141. For ALL other
emergencies call DORF KETAL Emergency Control Room +91 7405056503 , +91 2838
660532 & +91 260 2668784.

SECTION 2: Hazard identification

Classification of the substance or mixture

Classification
Physical hazards Not Classified

Health hazards Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 STOT RE 2 - H373

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

Label elements

Pictogram

Signal word Danger

Hazard statements H301+H311+H331 Toxic if swallowed, in contact with skin or inhaled.

H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.

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Precautionary statements P260 Do not breathe vapour/ spray.

P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P314 Get medical advice/ attention if you feel unwell.
P330 Rinse mouth.
P361+P364 Remove/ Take off immediately all contaminated clothing and wash it before
reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/ container in accordance with national regulations.

Contains N-methylaniline

Supplementary precautionary P261 Avoid breathing vapour/ spray.

statements P264 Wash contaminated skin thoroughly after handling.
P271 Use only outdoors or in a wellventilated area.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
P311 Call a POISON CENTER or doctor/ physician.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P391 Collect spillage.
P405 Store locked up.

Other hazards
This product does not contain any substances classified as PBT or vPvB (persistent, bioaccumulative and toxic, or very
persistent and very bioaccumulative).

SECTION 3: Composition and information of the ingredients of the hazardous chemical

Substances

N-methylaniline ≥99%
CAS number: 100-61-8
M factor (acute) = 1 M factor (chronic) = 1

Classification
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT RE 2 - H373
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The full text for all hazard statements is displayed in Section 16.
Product name PX 3495

SECTION 4: First-aid measures

Description of first aid measures

General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical
personnel.

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Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When
breathing is difficult, properly trained personnel may assist affected person by administering
oxygen. Get medical attention. Place unconscious person on their side in the recovery
position and ensure breathing can take place.

Ingestion Get medical attention immediately. Rinse mouth thoroughly with water. Give a few small
glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be
dangerous. Never give anything by mouth to an unconscious person. Place unconscious
person on their side in the recovery position and ensure breathing can take place. Keep
affected person under observation.

Skin contact It is important to remove the substance from the skin immediately. Remove contamination
with soap and water or recognised skin cleansing agent. Get medical attention.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical
attention if any discomfort continues.

Protection of first aiders It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation.

Most important symptoms and effects, both acute and delayed

Inhalation Toxic if swallowed, in contact with skin or inhaled.

Eye contact May cause damage to organs through prolonged or repeated exposure.

Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Fire-fighting measures

Extinguishing media
Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry
powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
This product is toxic.

Hazardous combustion None known.

products

Advice for fire-fighters

Protective actions during Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of
firefighting gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Cool
containers exposed to heat with water spray and remove them from the fire area if it can be
done without risk. Cool containers exposed to flames with water until well after the fire is out.
If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping
the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and
keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate
authorities.

Special protective equipment Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus
for firefighters (SCBA) and appropriate protective clothing. Fire-fighter's clothing will provide a basic level of
protection for chemical incidents.

Hazchem code 3X

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SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be
taken without appropriate training or involving any personal risk. Do not touch or walk into
spilled material. Avoid inhalation of vapours and spray/mists. Use suitable respiratory
protection if ventilation is inadequate. Avoid contact with skin and eyes.

Environmental precautions
Environmental precautions Inform respective authorities in case of seepage into water course or sewage system. Do not
allow to enter sewers/ surface or ground water.

Methods and material for containment and cleaning up

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills
immediately and dispose of waste safely. Provide adequate ventilation. Small Spillages:
Collect spillage. Large Spillages: Absorb spillage with non-combustible, absorbent material.
The contaminated absorbent may pose the same hazard as the spilled material. Collect and
place in suitable waste disposal containers and seal securely. Label the containers containing
waste and contaminated materials and remove from the area as soon as possible. Flush
contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.
Dangerous for the environment. Do not empty into drains. For waste disposal, see Section 13.

Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimise spills. Keep container tightly sealed
when not in use. Avoid the formation of mists. This product is toxic. Immediate first aid is
imperative. Avoid discharge to the aquatic environment. Do not handle until all safety
precautions have been read and understood. Do not handle broken packages without
protective equipment. Do not reuse empty containers.

Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash
occupational hygiene contaminated clothing before reuse.

Conditions for safe storage, including any incompatibilities

Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Keep only in the
original container. Keep container tightly closed, in a cool, well ventilated place. Keep
containers upright. Protect containers from damage.

Storage class Toxic storage.

Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.

SECTION 8: Exposure controls and personal protection

Control parameters
Occupational exposure limits
No exposure limits known for ingredient(s).

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Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Ensure the ventilation system is
controls regularly maintained and tested. Good general ventilation should be adequate to control
worker exposure to airborne contaminants. Observe any occupational exposure limits for the
product or ingredients.

Eye/face protection Unless the assessment indicates a higher degree of protection is required, the following
protection should be worn: Tight-fitting safety glasses.

Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the
glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material. To protect hands from chemicals, wear gloves that are proven to be
impervious to the chemical and resist degradation. Considering the data specified by the
glove manufacturer, check during use that the gloves are retaining their protective properties
and change them as soon as any deterioration is detected. Frequent changes are
recommended.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke
when using this product.

Respiratory protection Ensure all respiratory protective equipment is suitable for its intended use. Check that the
respirator fits tightly and the filter is changed regularly. Gas and combination filter cartridges
suitable for intended use should be used. Full face mask respirators with replaceable filter
cartridges suitable for intended use should be used. Half mask and quarter mask respirators
with replaceable filter cartridges suitable for intended use should be used.

Environmental exposure Keep container tightly sealed when not in use. Emissions from ventilation or work process
controls equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to
the process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Yellow to Amber

Relative density 0.97 – 1.00 (ASTM D 1298) @ 15.6°C

Other information Water Content :- ≤ 0.10 % (ASTM D 1364)

Purity :- ≥99% (DKTRndWI249)

SECTION 10: Stability and reactivity

Reactivity See the other subsections of this section for further details.

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

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Possibility of hazardous No potentially hazardous reactions known.

reactions

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

Materials to avoid Oxidising materials.

Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should not
products be produced.

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity - oral
Summary Toxic if swallowed.

ATE oral (mg/kg) 100.0

Acute toxicity - dermal

Summary Toxic if in contact with skin.

ATE dermal (mg/kg) 300.0

Acute toxicity - inhalation

Summary Toxic if inhaled.

ATE inhalation (vapours mg/l) 3.0

Skin corrosion/irritation
Summary Based on available data the classification criteria are not met.

Serious eye damage/irritation

Summary Based on available data the classification criteria are not met.

Respiratory sensitization
Summary Based on available data the classification criteria are not met.

Skin sensitization
Summary Based on available data the classification criteria are not met.

Germ cell mutagenicity

Summary Based on available data the classification criteria are not met.

Carcinogenicity
Summary Based on available data the classification criteria are not met.

Reproductive toxicity
Summary Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposure

Summary Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposure

Summary May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard
Summary Based on available data the classification criteria are not met.

SECTION 12: Ecological Information

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Acute aquatic toxicity

Summary Very toxic to aquatic life.

Acute toxicity - fish LC₅₀, 96 hours: 0.164 mg/l, Fish

Acute toxicity - aquatic LC₅₀, 48 hours: 0.08 mg/l, Daphnia magna

invertebrates

Chronic aquatic toxicity

Summary Very toxic to aquatic life with long lasting effects.

Persistence and degradability

Persistence and degradability The degradability of the product is not known.

Bioaccumulative potential
Bioaccumulative potential No data available on bioaccumulation.

Mobility in soil
Mobility No data available.

Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal information

Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way. When handling waste, the safety precautions applying to handling of the product should
be considered. Care should be taken when handling emptied containers that have not been
thoroughly cleaned or rinsed out. Empty containers or liners may retain some product
residues and hence be potentially hazardous.

Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a
licensed waste disposal contractor. Waste, residues, empty containers, discarded work
clothes and contaminated cleaning materials should be collected in designated containers,
labelled with their contents. Incineration or landfill should only be considered when recycling is
not feasible. Disposal of this product, process solutions, residues and by-products should at
all times comply with the requirements of environmental protection and waste disposal
legislation and any local authority requirements.

SECTION 14: Transportation information

UN number
UN No. (Road/Rail) 2294

UN No. (IMDG) 2294

UN No. (IATA) 2294

UN proper shipping name

Proper shipping name (N-METHYLANILINE) ENVIRONMENTALLY HAZARDOUS
(Road/Rail)

Proper shipping name (N-METHYLANILINE), MARINE POLLUTANT

(IMDG)

Proper shipping name (IATA) (N-METHYLANILINE) ENVIRONMENTALLY HAZARDOUS

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Transport hazard class(es)

Road/Rail class 6.1

Road/Rail classification code T1

Road/Rail label 6.1

IMDG class 6.1

Transport labels

IATA class/division 6.1

Packing group
Road/Rail packing group III

IMDG packing group III

IATA packing group III

Environmental hazards

Environmentally hazardous substance/marine pollutant

Special precautions for user

IMDG Code segregation None
group

EmS F-A, S-A

Hazard Identification Number 60

(Road/Rail)

Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

Safety, health and environmental regulations specific for the substance or mixture
Chemical safety assessment No chemical safety assessment has been carried out.

SECTION 16: Other information

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Abbreviations and acronyms

used in the safety data sheet

IATA: International air transport association.

ICAO: Technical instructions for the safe transport of dangerous goods by air.
IMDG: International maritime dangerous goods.
CAS: Chemical abstracts service.
ATE: Acute toxicity estimate.
LC₅₀: Lethal concentration to 50 % of a test population.
LD₅₀: Lethal dose to 50% of a test population (median lethal dose).
EC₅₀: 50% of maximal effective concentration.
PBT: Persistent, bioaccumulative and toxic substance.
vPvB: Very persistent and very bioaccumulative.

Classification abbreviations Acute Tox. = Acute toxicity

and acronyms STOT RE = Specific target organ toxicity-repeated exposure
Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)

Training advice Only trained personnel should use this material.

Revision date 24/3/2023

Revision 1

SDS number 4853

Hazard statements in full H301 Toxic if swallowed.

H311 Toxic if in contact with skin.
H331 Toxic if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

File Name: PX 3495_302637_SDS_VN_en_MAR-24-2023

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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