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Thermodynamics Worksheet

shows thermofynamic problems

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14 views2 pages

Thermodynamics Worksheet

shows thermofynamic problems

Uploaded by

denamout
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Chemistry 1110 Thermodynamics Worksheet

I. Predict whether the following processes absorb heat (are endothermic) or release heat (are
exothermic)
Snow Forming in Clouds Burning a Candle

Baking Bread Water condensing on a cold drink

II. Answer the following questions based on the reaction given:


3H2(g) + N2(g)  2NH3(g) H = -44.5 kcal

A) How much energy is released during the formation of 2.64 g NH3?

B) How many grams N2 would have to react to release 155 kcal of energy?

III. Predict whether the following reactions lead towards more order or more disorder:

Mg(s) + P4(s)  Mg3P2(s) C5H10O(l) + O2(g)  H2O(g) + CO2(g)

H2(g) + N2(g)  NH3(l) C3H5N3O9(s)  H2O(g) + CO2(g) + N2(g) + O2(g)

IV. Predict whether the following processes are spontaneous:

Dissolving sugar (C12H22O11) in water Automobile gasoline evaporating (C8H18) on a hot day

Burning propane gas (C3H8) Charging your cell phone battery

V. Fill in the following chart with the appropriate SIGN of H, S, and G for each process.

Process H S G

Iron rusting: 4Fe(s) + 3O2(g)  2Fe2O3(s) at 30ºC

Combustion of ethanol: C2H5OH(l) + 3O2(g)  2CO2(g) +


3H2O(g)

H2O(l)  H2O(s) at 5°C

Dissolving NH4NO3(s) in water (makes instant cold packs)


VI. Draw two energy diagrams. On the first, show a reaction which is exothermic but very slow.
On the second, show a reaction which is endothermic but very fast.

VII. Write the equilibrium equations for the following reactions:


A) 2CO(g) + O2(g) 2CO2(g)

B) C2H6(g) + 2Cl2(g) C2H4Cl2(g) + 2HCl(g)

C) 3O2(g) 2O3(g)

VIII. Answer the following questions based on the information given:


(a) For the reaction 2CO(g) + O2(g) 2CO2(g), the equilibrium concentrations at a certain temperature
are [CO2] = 0.11 mol/L, [O2] = 0.015 mol/L, [CO] = 0.025 mol/L. What is the value of K at this temperature?

(b) For the reaction N2O4(g) 2NO2(g) the value of K is 7.2x10-3. Calculate the following:

(i) The [N2O4] at equilibrium when [NO2] = 0.0250 mol/L.

(ii) The [NO2] at equilibrium when [N2O4] = 0.0750 mol/L.

IX. Consider the reactions on the left at equilibrium. Will more products or reactants be formed
as a result of the changes shown at right?

2 Fe(s) + 3 H2O(g) Fe2O3(s) + 3 H2(g) Addition of H2(g)

C(s) + H2O(g) CO(g) + H2(g) Increasing pressure

2 H2(g) + O2(g) 2 H2O(g) + heat Addition of a catalyst

NH4Cl(aq) + AgNO3(aq) AgCl(s) + NH4NO3(aq) Addition of NaCl(aq)

N2(g) + H2(g) NH3(g) + heat Addition of heat

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