VELAMMAL IIT&NEET ACADEMY

XII IIT GTA-22 P2 Dt: 09.05.24

KEY AND SOLUTIONS
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7
SECTION-I (i)
A. A,B,C A,B,C,D A,C A,C A,B C,D B,C,D
Q. 8 9 10 11
SECTION-I (ii)
A. A C D D
Q. 1 2 3 4 5 6
SECTION-II
A. 21.00 22.50 5.00 40.35 to 40.45 2.00 9.60 to 9.70

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7
SECTION-I (i)
A. A,B,D B,C A,B B,C C,D B,C B,C
Q. 8 9 10 11
SECTION-I (ii)
A. D B A B
Q. 1 2 3 4 5 6
SECTION-II
A. 4.00 13.66 to 13.67 9.00 5.00 -530.00 20.00

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7
SECTION-I (i)
A. B,C A,D A,B,C A,B,C A,C A,B,D A,B,C
Q. 8 9 10 11
SECTION-I (ii)
A. A B B A
Q. 1 2 3 4 5 6
SECTION-II
A. 1.75 1.51 2.82 1.80 5.50 2.00

HINT – SHEET
PART-1 : PHYSICS E
− 52 i3
−2 ⎛ 2R ⎞
Rt
ln =
SECTION-I (i) 5 ⎝ E ⎠ 2
2R
1. Ans ( A,B,C )
5 E − 5Rt
i3 = (1 − e 2L )
2
i 1 – i 2 = i3 ; i1 + i2 = E
; i2 = E − i3 2R
R 2R 2
E − 5Rt
di i3 = (1 − e 2L )
L 3 + i3 .2R = i2 R 5R
dt

di i E i3 E E E − 5Rt
E i2 = − = − + e 2L
L 3 = R( − 3 − 2i3 ) i1 2R 2 2R 10R 10R
dt 2R 2
i3 t
di3 R E − 5Rt
∫ = ∫ dt = (4 + e 2L )
E
− 52 i3 L 10R
0 2R 0
2. Ans ( A,B,C,D ) 4. Ans ( A,C )
Under normal conditions total energy, potential GMx GM R
EI = ; EII =
energy and kinetic energy in ground state and R3 R3 2
first excited state are – 13.6 eV, – 27.2 eV, FI
=
2x
13.6 eV, – 3.4 eV, – 6.8 eV and 3.4 eV FII R
respectively. If potential energy in ground state TI =
2π √ R3
; TII = 2 √
R3
is taken to be zero, then kinetic energy will 4 GM GM
remain unchanged but potential and total 5. Ans ( A,B )
energies are increased by 27.2 eV. Therefore,
the new values are 13.6 eV, 0, 13.6 eV, 23.8
eV, 20.4 eV and 3.4 eV respectively.
3. Ans ( A,C )

mv qB
r= , ω = dθ =
qB dt m

For θ = 2 π , →v is parallel to +ve x-axis.

Δθ 2πm
Δt = =
ω qB
3 3∈0 A
along tangential direction. Ceq = C=
2 2d

dv Kv 3∈0 A
at = =− Q = Ceq V = ( )V
dt m 2d
v t
dv K 6. Ans ( C,D )
∫ =− ∫ dt
v m
v0 0
k
v = v 0 e− m
t

Δt

distance, S = ∫ vdt
0
2πm
v0 − K
t qB
S=− [e m ]
K/m 0

mv0 − 2πK vS + v cos θ

S= [1 − e qB ] fobserved = f [ ] = f
K vs + v cos θ
vs + v cos θ
λobserved = ( )
f
 Enthusi
7. Ans ( B,C,D ) 11. Ans ( D )
Momentum along Y-axis will remain conserved p1 = 1.0 atm, V1 = 1.0L, T1 = 122 K
p2 = 1.0 atm, V2 = 2.0L, T2 = 244 K, K = 2T1
So, mu cos θ = 2m Vy p3 = 2.0 atm, V3 = 2.0L, T3 = 444 K, K = 4T1
4u p4 = 0.0157 atm, V4 = 64L, T4 = 122 K, K = T1
⇒ Vy = … (i)
10 For 1 → 2,
Conserving angular momentum about Y-axis 7
Q1 = nCp ΔT = nR (T2 − T1 )
2
7
during collision = × n × R (T1 )
2
mv2 For 2 → 3,
mu sin θℓ = ( + mℓ2 ) ω 5
3 Q2 = nCV ΔT = nR (T3 − T2 )
3u sin θ 9u 2
⇒ω= = … (ii) 5
4ℓ 20ℓ = × n × R (2T1 ) = 5nRT1
2
Velocity of particle just after impact is For 3 → 4,
9u ^ 4u ^ Q3 = 0
Vp = VP ^j + ℓω(−i^) = − i+ j
20 10 For 4 → 1,
for completing full rotation about Y-axis V2
Q4 = nRT ℓn
V1
Wg = Δk 1
= nRT1 ℓn = −nRT1 ℓn64
64
1 4 2 Q− nRT1 ℓn64
⇒ −mg(2ℓ) − mgℓ = 0 − ( mℓ ) ω2 η=1− =1−
2 3 Q+ 7
nRT1 + 5nRT1
2
9 g 20ℓ √ 9 g 6ℓn2 12
⇒ ωmin = √ ⇒ umin = =1− =1− ℓn2
2 ℓ 9 2 ℓ 17 17
2
2 10
10√ gℓ = √2gℓ
PART-1 : PHYSICS
9 3
PART-1 : PHYSICS SECTION-II

SECTION-I (ii) 1. Ans ( 21.00 )

9. Ans ( C )
1
I= E0 E02 . C
2
1 1
570 = E0 × μ20 C 2 Jmax
2 .C
2 4
1 2 m (5) + m (26)
= Jmax . Cμ0 COM of the two dominoes is x0 =
8 2m
x0 = 15.5 mm
2 = 8 × 570 2 × 19 For system to remain in equilibrium the COM of
Jmax =
−7 π
3 × 10 × 4π × 10 upper two dominoes must be over the thickness
38 of third domino.
Jmax = √ = 3.48
π x < x0 < x + 10
or x < 15.5 mm
and 15.5 < x + 10 ⇒ x > 5.5 mm
2. Ans ( 22.50 ) 3. Ans ( 5.00 )
Δ = 70 α
2d sin α + 2d sin Ψ = 70 α
The resistive force is proportional to velocity 10−3 y
10 × 10 – 3 × + 10 × 10 – 3. = 70 α
1 2
ma = –kv y = 5 mm
mdv 4. Ans ( 40.35 to 40.45 )
⇒ + kv = 0
dt
d
⇒ (mv + kx) = 0
dt
d m
⇒ ( v + x) = 0 2GM
dt k For earth, V e = √

m R
⇒ v + x = C (constant) ........(1)
k For Sun + Earth,
If initial velocity is v0 and maximum stopping
GM 3 × 105 GM
Potential energy = ( − − ) m
distance is xmax R 2.5 × 104 R
GM 13GMm
mv0 = (1 + 12) =
C= = xmax .........(2) R R
k
1 13GMm
⇒ xmax = µv0 ........(3) ∴ mv2 =
2 R
m 2GM √
where μ = is the characteristic of the metal v=√ . 13 = √13ve
k R
plate causing the breaking. ∴ ve = 40.4 km/s
Hence µAIv0 = 30 cm and µCuv0 = 20 cm 5. Ans ( 2.00 )
μAl 3 dP
= = −ρg
μCu 2 dy
Now, µv + x = C = µv0
dP = – ρ gdy
⇒ µv1 + 15 = µv0 M ρRT P M0
[ P= RT = ⇒ρ= ]
15 V M0 M0 RT
v 1 = v0 –
μCu P M0
dP = − dy
and x2 = µAlv1 = µAl (v0 − 15 ) RT
μCu
P M0 dy
15 dP = −
and x2 = µAlv1 = µAl(v0 − )
R (T0 − αy)
μCu
P y
μ
⇒ x2 = µAlv0 – Al × 15 dP M
=− 0
dy
μCu ∫
P R
∫ (
T0 − αy
)

3 P0 0
= 30 – × 15 = 7.5 cm M0 g
2
αy αR
⇒ P = P0 ( 1 − )
x1 + x2 = 15 + 7.5 = 22.5 cm T0
 Enthusi
6. Ans ( 9.60 to 9.70 ) The modulus of elasticity in tension will then be
Since the transverse fibers do not affect the according to Hooke's law
σ Fp 4kℓΔx 4kℓ
bending of the web, we can only deal with the E= = Δx = =
ε 2
πd Δx πd 2
S ℓ
elongation of the radial fibers.
4 × 0.17 × 106 × 0.1
If a part of the fiber has a length ℓ and a E= 22
7
× (0.15 × 0.15) × 10−12
stiffness k, then it is extended by Δx = F/k by a 0.68 × 105
=
−12
= 9.62 × 1017 Pa
force of magnitude F. The radial fiber consists 0.07065 × 10
of 4 such parts, therefore it is lengthened by the PART-2 : CHEMISTRY
force FΔΧ = 4Δx. The total stiffness of the SECTION-I (i)

radial fiber will then be (similarly to four 2. Ans ( B,C )

springs suspended in series Coordination entity Wavelength of light
k absorbed (nm)
K=
4 [CoCl(NH3)5]2+ (P) 535
[Co(NH3)5(H2O)]3+ (Q) 500
[Co(NH3)6]3+ (R) 475
In the middle of the web at point O, the spider [Co(CN)6]3 – (S) 310
acts on the web with its weight, which is in [Cu(H2O)4]2+ (T) 600
balance with the six elastic forces Fp 3. Ans ( A,B )
mg = 6Fpcosα, (A)
k
Fp = K (y − 4ℓ) = (√(4ℓ)2 + h2 − 4ℓ)
4
h h (B)
cos α = = ,
y 2 2
√
(4ℓ) + h
k 2 h
mg = 6 (√(4ℓ) + h2 − 4ℓ)
4 2
√
(4ℓ) + h2
2
2mg√(4ℓ) + h2
k= (C)
2
3h (√(4ℓ) + h2 − 4ℓ)
2mg 4ℓ
k= ×
3h √
1+h2
4ℓ ( − 1)
(4ℓ)2
(D)
2mg 1 2mg 2 × 16ℓ2
= = ×
3h 1 h2 3h h2
( 1+ 2 (4ℓ)2
− 1)

64 mgℓ
=
3 h3
64 0.01 × 10 × 0.1 × 0.1
= × = 0.17 × 106 N/m
3 125 × 10 −9
6. Ans ( B,C ) 11. Ans ( B )
PA = 235 yA – 125 xB yA p-orbital having 4e – (according to value of 's')
= yA [235 – 125 (1 – xA)] PART-2 : CHEMISTRY
= yA [235 – 125 + 125 xA] SECTION-II
PA = yA [110 + 125 xA] 2. Ans ( 13.66 to 13.67 )
P A = PT × yA (i) Ag2SO3 + H+ → 2Ag+ + SO2 + H2O
⇒ PT = (P°A – P°B) xA + P°B (ii) FeSO4 solution absorbs NO and becomes
∴ P°B = 110 brown because of the formation of
P°A – P°B = 125 [Fe(NO)]2+SO42–.
P°A = 235.
(iii) Being covalent do not dissociate
7. Ans ( B,C ) (iv) Ammonium hydroxide in presence of
(A) Coagulation value.
ammonium chloride is group reagent of IIIrd
1
(B) Coagulation power ∝ group.
Coagulation value
(C) Hardy Schultz rule (v) 2[Cr(OH)4]– (green colouration) + 3H2O2 +
(D) Definition of protective colloid.
2OH–
PART-2 : CHEMISTRY
→ 2CrO42– + 8H2O
SECTION-I (ii) (vi) Red colour solution or precipitate is
8. Ans ( D ) produced when reagent reacts in alkaline
−2 × 96500 × 0.059
ΔG = – nFEcell = KJ mol–1. solution.
1000
9. Ans ( B ) (vii) HO.SO2.NH2 + HNO2
−0.059 [M 2+ ]A → N2 + 2H+ + SO42– + H2O
0.059 = log
2 0.001
[M 2+ ]A (viii) Fe2+ + [Fe(CN)6]3–
1
or, = or, [M2+]A = 10 – 5 = s(say) → Fe3+ + [Fe(CN)6]4–
0.001 100
MX2(s) ⇌ M2+(aq) + 2X – (aq) 4Fe3+ + [Fe(CN)4]4–
s 2s → Fe4[Fe(CN)6]3 ↓(Turnbull's blue)
Ksp = 4s3 = 4 × 10 – 15 (ix) 4Cr(OH)3↓ + 5O22–
10. Ans ( A ) → 4CrO42– (yellow solution) + 6H2O
n=2→ℓ= 0 1 2 3 a2 + b 2 25 + 16
a=5 b=4 = = 13.67
s p d f 3 3
No change in the volue of m 3. Ans ( 9.00 )
∴ total orbitals associated to 2nd shell = 16 x = 5, y = 4
The value of s = + 1 , + 1 , − 1 , − 1 Tollen's test : (i), (ii), (iv), (vi), (vii)
4 2 2 4 Fehling test : (i), (ii), (iv), (vi)
∴ total no of e– associated to 2nd shell =16 × 4
= 64
 Enthusi
4. Ans ( 5.00 ) PART-3 : MATHEMATICS
SECTION-I (i)

(3) 1. Ans ( B,C )

0
3
Required Area = 2 ∫ 2 (x + ) dx = 2√3
2
−3/2

2. Ans ( A,D )
1
(3)
A = ∫ [−ℓny) − (ey − e] dy = 2
0

3. Ans ( A,B,C )
dx x3
(4) 3x2 = x3 = t
dy x3 − y
dt t
= ⇒ tdt = ydt + xdy
dy t−y
5. Ans ( -530.00 )
t2 c
= t. y +
dG = V.dP – S.dT ; at const. volume 2 2

P1 P ⇒ x6 = 2x3y + c
Δ G = V. Δ P – (10 + 10 – 2 T).dT = 2 ⇒
T1 T2
P2 = 1 × 400/300 4. Ans ( A,B,C )
T2 T2 n4 + 3n2 + 10n + 10
Δ G = 24.6 × 4
− 1) × 100 − [10 × 100 + 10−2 × ( 2 − 1 )]
2n (n4 + 4)
(
3 2 2

1
Δ G = 24.6 × × 100 – [1000 + 10 – 2 × 3n2 + 10n + 6
3 1
= +
160000 90000 2n 2n (n2 + 2n + 2)(n2 − 2n + 2)
( − )]
2 2
1 1 4n2 + 8n + 8 − n2 + 2n − 2
= 24.6 × × 100 – 1000 – 350 = – 530 J = +
3 2n 2n (n2 + 2n + 2)(n2 − 2n + 2)
6. Ans ( 20.00 )
1 1 1
AB A+ + B – =
2 n
+
n−2 2
−
n−2 2
2 (n − 2n + 2) 2 (n + 2n + 2)
s ≈0
∞
8
n4 + 3n2 + 10n + 10
B – + H+ −−
10
→ HB ∴ ∑
2n . (n4 + 4)
10 – 3
n=2
≈0 s
2 × 10 – 10 = s × [B – ] ....... (1) =∑
∞
1
∞
+∑(
1
− n
1
)
n
2 n−2 2
2 (n − 2n + 2) 2 (n + 2n + 2)
2
s s2 n=2 n=2
108 = ⇒ 10 8
=
[B− ] × 10−3 2 × 10−10 × 10−3
1 6 11
⇒ s2 = 2 × 10 – 5 ⇒ s = √20 × 10 – 3 = +
2 10
=
10
5. Ans ( A,C ) 6. Ans ( A,B,D )
Equation of tangent at P is 2x + y + 1 = 0 Let (x2 – 4x + 6) = t
f(t) = t2 – (k + 2)t + k + 5 = 0
Apply conditions of location of roots on
equation f(t) = 0.
for exactly 4 real solution k ∈ (4, 5)
for exactly 3 real solutions k = 5
for exactly are real solution k ∈ ϕ
for no real solutions k ∈ ( – ∞ , 4)
7. Ans ( A,B,C )
N will be the mid point of PT a (x + x3
+ 2 5
x +. . .) + b (x − x3
+ x5
+. . .)
3 15 3 5
⇒ T is (0, –1) +c (x + x3
+ 9x5
+. . .)
6 5!
lim =3
Image of Q(8, 3) w.r.t. to tangent at P lies on PM. x→0 x5
(a + b + c)x + ( 3a − b
+ c
)x
3
Image Q' of Q(8, 3) w.r.t. 2x + y + 1 = 0 3 6
2a b 9c 5
x−8 y−3 −2[16 + 3 + 1] + ( 15 + 5
+ 5!
) x +. . .
= =
2 1 5 ⇒ lim =3
x→0 x5
⇒ x = –8, y = –5 a+b+c= ...(1)
Q'(–8, –5) 2a – 2b + c = 0 ...(2)
⇒ PM will be y = –5 2a b 3c
+ + =3 ...(3)
15 5 40
⇒ axis of parabola will be y = –1 ⇒ a = 30, b = 10, c = – 40
PQ is a focal chord of parabola equation of PQ is 2a + b + c = 60 + 10 – 40 = 30
4x – 3y – 23 = 0 focus will be point of intersection PART-3 : MATHEMATICS
axis & PS SECTION-I (ii)

⇒ focus S is (5, –1) Point M lies on directrix of 8. Ans ( A )

parabola N will be mid point of M & S Graph of f(x)
⇒ M is (–3, –5)
⇒ directrix is x = –3
Normal at other end of focal chord at P will be
parallel to tangent at P. −1
Range : [ , 3]
4
Circle described on focal radii as diameter touches
9. Ans ( B )
tangent at vertex of parabola.
Graph of f(x)

−1
Range : [ , 3]
4
 Enthusi
10. Ans ( B ) PART-3 : MATHEMATICS
d esin x
(A) f(x) = SECTION-II
dx x
esin x 1. Ans ( 1.75 )
f(x) = ∫ dx
x If the one of the digit first or last is zero then
4 2 4 2
2esin x esin(x )
⇒∫ . dx = ∫ d (x2 )
1 x 1 x2 number of numbers is 8 × 7 = 56.
x2 = t If none of the first and last digit is zero then
16
= [f(t)]1 number of numbers are 2 × 8 × 7 × 7
= f(16) – f(1) Hence total numbers = 8 × 7 + 2 × 8 × 7 × 7 = 840
⇒ k = 16 2. Ans ( 1.51 )
(B) xf ′ (x) = esin x a = −√2, b = √ 2

xf ′′ (x) + f ′ (x) = esin x . sin x √ 2

area = − ∫ (x4 − 2x2 ) dx

= g(x) −√ 2
√ 2
11. Ans ( A )
= −2 ∫ (x4 − 2x2 ) dx
esin x
(A) d f(x) = 0
dx x √ 2
esin x
f(x) = ∫ dx = 2 ∫ (2x2 − x4 ) dx
x
4 2 4 2
2esin x esin(x ) 0
⇒∫ . dx = ∫ d (x2 ) 16√2
1 x 1 x2 ∴ Area = = 1.51
x2 = t 15
16
= [f(t)]1 3. Ans ( 2.82 )
= f(16) – f(1)
⇒ k = 16
(B) xf ′ (x) = esin x
xf ′′ (x) + f ′ (x) = esin x . sin x
= g(x)
π /2
esin x
(C) I = ∫ x cos x . dx
x
0
2 2
sin x = t h−k h+k
( ) = ( ) +2
cos x dx = dt √ 2 √ 2
1 ∴ xy = – 1
= ∫ et dt = e1 − 1 Hence locus is rectangular hyperbola
0 with length of latus rectum = 2 2 √
π
λ =
2
4. Ans ( 1.80 ) 6. Ans ( 2.00 )
a b
n A =[
1 ]
lim n ∑
n→∞ c d
3n + 8rn + 4r2
2
r =1 a b a c ⎡
a2 + b 2 ac + bd ⎤
T
AA = [ ] [ ] =
n
c d b d ⎣
ac + bd c2 + d 2 ⎦

1 ⎛ 1 ⎞
= n→∞
lim ∑

r=1
n ⎝
3 + 8 ( nr ) + 4( nr )
2 ⎠ ∴ a2 + b2 = 1, c2 + d2 = 1, ac + bd = 0

1 1
1 dx 1 dx Let a = cos θ , b = sin θ , c = cos ϕ , d = sin ϕ
= ∫ = ∫
2
4 x2 + 2x + 1 − 1 4
0 4 0 (x + 1)2 − (
1
)
2 π
∴ cos θ cos ϕ + sin θ sin ϕ = 0, ∴ θ – ϕ =
2
Thus
⇒ |a| + |b| + |c| + |d| = 2 (|cos θ |+ | sin θ |

5. Ans ( 5.50 ) since |cos θ | + |sin θ | ≤ √ 2

2 2 2 2
N1 σ 1 + N2 σ 2 + N1 d 1 + N2 d 2
σ12 2 =
N1 + N2 greatest value of 2 (|a| + |b|) = 2√2
Here σ12 2 = combined variance

N1 = N2 = 5, σ1 2 = 4, σ2 2 = 5, d1 = – 1, d2 = 1