Master JEE CLASSES

Kukatpally, Hyderabad.

JEE-ADVANCED-2014-P2-MODEL Max. Marks: 180

PAPER-II
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an
impression at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as :
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
 JEE-ADVANCED-2014-P2-Model
IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 11 – 16) (3 Comprehensions – 2 +2+2 = 6Q) 3 -1 6 18
Sec – III(Q.N : 17 – 20) Matrix Matching Type 3 -1 4 12
Total 20 60
CHEMISTRY:
+Ve - Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 31 – 36) (3 Comprehensions – 2 +2+2 = 6Q) 3 -1 6 18
Sec – III(Q.N : 37 – 40) Matrix Matching Type 3 -1 4 12
Total 20 60
MATHEMATICS:
+Ve - Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 51 – 56) (3 Comprehensions – 2 +2+2 = 6Q) 3 -1 6 18
Sec – III(Q.N : 57 – 60) Matrix Matching Type 3 -1 4 12
Total 20 60
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PHYSICS Max Marks : 60
Section-1
(Only one Option correct Type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and (D). Out of
Which Only One is correct
1. A body of mass ‘m’ is hauled from the earth’s surface by applying a variable force F
varying with height ‘h’ as F 2 ah 1 mg where a is a +ve constant. For first half of
the height ascended, choose the correct statement: (Neglect variations of g with
height)
5mg
A) Work done by F is
2a
mg
B) Increase in gravitational potential energy is
2a
C) Data insufficient
3mg
D) Kinetic energy of the body is
4a
2. A large slab of mass 5kg lies on a smooth horizontal surface with a block of mass 4kg
lying on top of it, between block and slab is 0.25.If the block is pulled horizontally
by a force of F=6N. The work-done by a force of friction on the slab, between the
2
instants t=2s and t=3s is g 10ms (Initial speeds is 0)

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 4kg F

5kg

A) 2.4 J B) 5.55 J C) 4.44 J D) 10 J

3. A small object of mass m slides down very slowly along a rough uneven hilly plane
from a height h and stops after travelling a certain distance BC on a horizontal surface.
The work needed to be done to return the object to its initial position along the same
path very slowly would be

A) zero B) mgh C) 2mgh D) cannot be found

4. A block of mass ‘m’ is kept at point O on a rough horizontal surface whose coefficient
1
of friction varies from O as 0.5 x 3m
5 x

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 If the block is moved by an external force F, the work done by frictional forces during
the first 3m is (neglect the size of the block)
5 2 2
A) mg ln B) mg ln
2 2 3 5

3 2 3 2
C) mg ln D) mg ln
2 5 2 3

5. A book of mass m is projected with a speed V across a horizontal surface. The book
slides until it stops due to frictional force between book and surface. The surface is
now tilted 300 and the book is projected up the surface with the same initial speed V.
When the book has come to rest, how does the decrease in mechanical energy of the
book-earth system compare to that when the book slide over the horizontal surface?
A) It is the same B) It is larger
C) It is smaller D) The relationship can’t be determine
6. The force exerted by a compression device is given by F x kx x l for 0 x l

where l is maximum possible compression and k is a constant. The work required to

compress the device a distance d is maximum when

l l
A) d l/4 B) d C) d D) d l
2 2

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7. The potential energy of a 1 kg particle free to move along the X-axis is given by
x4 x2
v x J . The total mechanical energy of the particle is 2J. Then, the
4 2

maximum speed(in ms-1) is

1 3
A) B) 2 C) D) 2
2 2

8. In the figure shown the system is released from rest. Find the velocity of block A

when block B has fallen a distance l . Assume all pulleys to be mass less and
frictionless.

A
m
P

m
B

gl gl 4 gl gl
A) B) C) D)
2 3 5 5

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9. Consider the following statements regarding potential energy.
(i) Potential energy can be positive or negative.
(ii) A moving body may or may not have potential energy.
(iii) Potential energy can be defined for any type of force.
(iv) Potential energy depends on frame of reference.
( v) Potential energy corresponding to an internal conservative force will increase
when the particle moves opposite to the direction of that conservative force
(vi) Potential energy can be defined as a scalar function of position whose negative
derivative (gradient) gives force
No. of correct statements
A) 3 B) 5 C) 4 D) 6

10. Which of the following forces is a conservative force.

A) F xyz i x2 z j x2 y k N B) F 2 xyz i x2 z j x2 y k N

C) F xyz i xz 2 j x2 y k N D) F xyz i xz 2 j xy 2 k N

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 Section-2
(Paragraph Type)
This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions relate to three
paragraphs with two questions on each paragraph. Each question pertaining to a particular paragraph
should have only one correct answer among the four choices A, B, C and D.
PASSAGE: 01

A block of mass m1 moves with an acceleration a12 relative to the plank 2 as shown in
figure. Assume zero initial velocities of the bodies and observer (assume all
accelerations are along the same direction)
3 m
1
a12

a2
a3
(Observer)

11. What is the work done by the pseudo force as observed by the man on the block
during time t?
ma3 a12 a2 a3 t 2 ma3 a12 a2 a3 t 2
A) B)
2 2
ma3 a12 a2 a3 t 2 ma3 a12 a2 a3 t 2
C) D)
2 2
12 The work done by the inertial force on the block relative to the observer on the ground
during time t.
1 1 1
A) ma3t 2 B) ma3 a12 t 2 C) 0 D) m a12 a2 t 2
2 2 2
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PASSAGE : 02

A particle A is fixed at origin of a fixed coordinate system. Another particle B which

2
is free to move experiences an force F r due to particle A where r is the
r3 r2

position vector of particle relative to A. It is given that the force is conservative in

nature and potential energy at is zero. If has to be removed from the influence of A,

energy has to be supplied for such a process. The ionisation energy E0 is work that has

to be done by an external agent to move the particle from a distance r0 very slowly.

Here r0 is the equilibrium of the particle

13. The potential energy of particle as a function of r

A) B) C) D)
r2 r r2 r r2 r r2 r

14. The ionisation energy E0 of the particle B (magnitude)

2 2 2 2
2
A) B) C) D)
2 4

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PASSAGE : 03
A fixed hemispherical bowl is arranged as shown. A and C are points at the same
horizontal level. B is the bottom most point. A small block of mass m is initially
placed at A. R is the radius of the bowl. (If necessary take g = 10m/s2)

15. If bowl is considered as rough and when block is released from A, it comes to rest at
B. The work done by the friction as it moves from A to B is
mgR mgR
A) – mgR B) C) -2mgR D)
2 2
16 Now consider that bowl is completely smooth and block is released from A. If N is the
normal reaction and is the angle made by the radius vector at any instant with the
vertical axis, which of the following graphs represent the graph of N versus , as it
moves from A to B ?
N N N N

A) cos B) cos C) cos D) cos

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Matching - 1
17. In column-I a force F is given and in column-II work done by that force between two
specified points A and B is given. Match the appropriate column.
Column – I Column-II
A) F 3x 2 y i x3 j P) 2 Rk
From A(0,0,0) to B(1,1,1)
B) F k yi x j Q) -9

From A(0,0) to B(a, a)

yi xj R) ka 2
C) F k moves from
x2 y2 x2 y2
A(0,0) to B(0,0) along a circular path of radius
R in xy plane centered at origin in anti
clockwise direction.
R) zero
xi yj
D) F k 3 3
x2 y2 2
x2 y2 2

A(0,0) to B(0,a) along a circular arc of radius R

centered at origin.
A) A-S, B-P, C-Q, D-R B)A-Q, B-R,C-P, D-S

C) A-R, B-P, C-S, D-Q D) A-P, B-R, C-Q, D-S

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18. Figure shows four situations in which a small block of mass ‘m’ is released from rest
(with respect to smooth fixed wedge) as shown in figure. Column –II shows work
done by normal reaction on the block (with respect to an observer who is stationary on
ground) till block reaches at the bottom of inclined wedge, match the appropriate
column.
Column – I Column-II
P) positive
h V= 2gh

450
A)
Q) negative

B)
R) equal to mgh in
h
magnitude
450

V= 2gh
C)
S) equal to zero
h

V= 2gh
450
D)
A) A-P; B-P; C-Q; D-S B) A-P; B-P; C-S; D-Q
C) A-P; B-Q; C-Q; D-S D) A-P; B-P; C-P; D
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19 A chain of length l and mass m lies on the surface of a smooth sphere of radius
R > l with one end tied to the top of the sphere

Column I Column II
Gravitational potential energy
Rg l
A) of the chain with reference level P) 1 cos
l R
at the centre of the sphere
The chain is released and slides
2Rg l l
B) down, its KE when it has slid by Q) sin sin sin
l R R
an angle
The initial tangential acceleration mR 2 g l
C) R) sin
(just after it is released) l R
The magnitude of radial
acceleration ar of any element of 2
mR g l l
D) the chain when it had slid down S) sin sin sin
l R R
by angle

A) A – S, B – R , C – P, D – Q B) A – Q, B – S, C – P, D – R
C) A – R, B – S, C – P, D – Q D) A – R, B – S, C – Q, D – P

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20. A block of mass m is stationary with respect to a rough wedge as shown in figure.
Starting from rest work done on block in time t :
If m 1kg , 300 , a 2m / s 2 , t 4s and g 10 m / s 2

Column - I Column - II

A) By gravity P) 144 J

B) By normal reaction Q) 32 J

C) By friction R) 56 J

D) By all the forces S) 48 J

T) none

A) A - T; B - P; C - Q; D – S B) A - Q; B - P; C - S; D – T

C) A - T; B - Q; C - S; D – P D) A - T; B - P; C - S; D – Q

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CHEMISTRY Max Marks : 60
Section-1
(One or more options correct type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and (D). Out of
Which Only One is correct
21. The statement that is not true for the long form of the periodic table:
A) It reflects the sequence of filling electrons in the order of sublevels s, p, d and f.
B) It helps to predict the stable valence states of elements
C) It reflects trends in physical and chemical properties of elements
D) It helps to predict the relative ionicity of bond between any two elements
22. Which of the following represent correct order of first ionization enthalpy for Ca, Ba,
Se, S and Ar?
A) Ca < Ba < S < Se < Ar B) Ca < S < Ba < Se < Ar

C) S < Se < Ca < Ba < Ar D) Ba < Ca < Se < S < Ar

23. If 1.96 104 kJ energy is supplied to 1 mole Li g it ionises to Li 3 . If I.E1 for Li is

520kJ mol 1 and IE for H is 2.18×10-18 J atom-1. The IE 2 for Li will be

-1
A) 7270 kJ mol B) 11.81 103 kJ mol-1
3 -1 4 -1
C) 6.54 10 kJ mol D) 3.32 10 kJ mol

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24. The correct order of decreasing electronegativities values among Be(I), oxygen (II),
Nitrogen(III) and magnesium (IV) is:
A) II > III > I > IV B) III > I V > II > I
C) II > III > IV > I D) II > I > III > IV
25. The first and second ionization potentials of an element M (atomic weight = 25) are

800 and 1500 kJ mol-1 respectively. Calculate the percentage of M+2 (g) ions formed if

5 g of M(g) absorbs 250 kJ of energy.

A) 70 B) 40 C) 60 D) 30

26. Which of the following order is correct regarding the atomic radii?

A) Cr > Mn > Fe B) V < Nb < Ta

C) Sc < Y < La D) Ce < Eu < Lu

27. The correct order of size is:

A) Cr+3 < Cr +4 < Cr+5 B) C 4 < N 3 < O 2

C) Fe> Fe+2 > Fe+3 D) He+< Li+2 < Be+3

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28. Given that
i) IP2 order of C < N < F < O
ii) First negative electron gain enthalpy of S > Se > Te > O
iii) First ionisation enthalpy of Sc > Y > La
iv) Electron gain enthalpy with sign Ne > Ar> Kr> Xe
Number of correct statements are
A) 1 B) 2 C) 3 D) 4
29. In which of the following the order is not correct, according to the property indicated
against it?
A) Na>Mg>Al – Second ionization potential
B) P < S < Cl non metallic character
C) F2>Cl2>Br2>I2 Oxidising power
D) P2 O5 SO 3 Cl 2 O7 Acidic nature

30. Linus Pauling wanted to determine the electron gain enthalpy (electron affinity) of an
unknown element X. He took one mole of atoms of X and found that on absorption of
410 kJ of energy half of X-atoms transfer one electron to the other half. To convert all
the resulting X ions to X+ ions, an additional energy of 735 kJ was required. What
was the electron gain enthalpy of X as obtained by Linus Pauling?
-1
A) -270 kJ mol B) 325 kJ mol-1 C) -540 kJ mol-1 D) 650 kJ mol-1
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 Section-2
(Paragraph Type)
This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions relate to three
paragraphs with two questions on each paragraph. Each question pertaining to a particular paragraph
should have only one correct answer among the four choices A, B, C and D.
Comprehension: 1
-1
The first i H1 and the second i H 2 ionisation enthalpies in kJ mol and the electron
gain enthalpy in kJ mol-1 of a few elements (two metals of same group and two non-
metals of same group along with a another non metal) are given below:
Elements i H1 i H2 eg H
(P) 520 7300 -60
(Q) 419 3051 -48
(R) 1681 3374 -333
(S) 1008 1846 -295
(T) 2372 5251 +48
Answer the following questions.
31. Which one of the above elements is least reactive non metal and most reactive metal
respectively?
A) (R) and (Q) B) (S) and (T) C) (T) and (Q) D) (T) and (P)
32. Which one of the above elements is most reactive non metal and least reactive metal
respectively?
A) (P) and (Q) B) (R)and (P) C) (R) and (T) D) (S) and (P)

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Comprehension: 2
E.N is the tendency of an atom to attract the shared electron pair towards it in a

covalent bond. Since it is a relative property it has no units. Hence various scales are

proposed such as Mullikan scale, Pauling scale, Allred-Rochowe scale. The most

accepted is of Pauling based on bond energy data and more particularly on Ionic-

covalent bond resonance energy .While Mulliken scale is applicable to mono valent

elements says that E.N is the average of I.P and E.A. Electro negativity on Mulliken

scale is 2.8 times more than that of calculated from Pauling scale.

33. H – H, X – X, and H – X bond energies are 104 kcal/mol 38 kcal/mol and 135

kcal/mol respectively. Electro negativity of ‘X’ is.

A) 3.76 B) 3.21 C) 2.85 D) 1.72

34. If electron affinity of ‘X’ is 333 kJ/mol then Ionization energy of ‘X’ is:

A) 1712 kJ/mol B) 874 kJ/mol

C) 1012 kJ/mol D) 2045 kJ/mol

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Comprehension: 3
In an universe other than earth all the quantum numbers have same value as on earth

except ‘ ’ and ‘s’. Azimuthal quantum number can have values from 0 to (n + 1) in

1 1
integral step and s (spin quantum no.) has values of – , 0 & . If all rules like
2 2

Aaufbau rule, Hund’s rule and Paulis exclusion rule follow in other universe also.
35. Configuration of element with atomic number 29 will be

A) 1s3, 1p9, 2s3, 1d 14 B) 1s3, 2s3, 2p9, 3s3, 3p9, 4s2

C) 1s2, 1p6, 2s2, 1d 10, 2p9 D) 1s3 ,1p6 , 2p9 , 2s2 ,1d10

36. No. of elements in third period of another universe will be

A)27 B)12 C)36 D)42

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 Section-3
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
37. Consider Slater rules for given code type question
Column -1 Column -2
P) Screening constant for Na 1) 8.8

Q) Screening constant for Na+ 2) 2.2

R) Zeff for Na 3) 4.15
S) Zeff for Na+ 4) 6.85

P Q R S
A) 1 3 2 4

B) 3 1 2 4

C) 4 1 2 3

D) 1 3 4 2

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38. Match the column -1 with column-2
Column-1 Column-2
P 1 Magnitude of Electron gain enthalpy for
halogens

Q 2 First ionisation enthalpy order for second

*
P.P * period elements of long form of periodic
* *

table.
Atomic number

R 3 Electro negativity order for halogens

S 4 First ionisation enthalpy of alkali metals

(P.P=Periodic property, Graphs are not up to the scale, use them to predict order)

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 P Q R S
A) 2 4 1 3
B) 3 1 2 4
C) 3 1 4 2
D) 1 3 2 4
39.
Column-1 Column-2
P (Xe) 4f25d 06s 2 1 d-block 6th group
Q (Rn) 5f36d 17s 2 2 f-block-6th period
R (Kr) 4d10 5s 2 3 Radioactive element
S (Ar) 3d54s 1 4 d-block- 5th period
P Q R S
A) 3 1 4 2
B) 2 3 1 4
C) 2 3 4 1
D) 4 3 2 1

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40. Match the elements with respective periodic property given in the column-1 with their
gradation given in column-2

Coloumn-I Coloumn-II

( i ) Basic nature of their oxides

Li Be (i)Increases
P ( ii ) Metallic character
B ( iii ) atomic radius
C 1 (ii)Increases
(iii)Decreases

Na ( i ) Electro positivecharacter
Mg (i)Decreases
Q 2 (ii)Decreases
( ii ) IP1 non metallic character
Al Si (iii)Increases
( i ) magnitudeofelectron gain enthalpy (i)Increases
R
F Cl 3 (ii)Decreases
( ii ) Atomic size ( iii ) oxidi sin g power
Br I (iii)Decreases
( i ) magnitude of electron gain enthalpy (i)Decreases
S
O S 4 (ii)Decreases
( i ) Acidic nature of oxides ( iii ) Electro negetivity
Se Te (iii)Decreases
P Q R S
A) 4 1 2 3
B) 2 1 4 3
C) 3 2 1 4
D) 4 2 1 3

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MATHS Max Marks : 60
Section-1
(Only one Option correct Type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and (D). Out of
Which Only One is correct
41. The number of value(s) of ' a ' for which the function f ( x) sin( ax) tan( 2 ax) will not
be a periodic will be ___
A) 0 B) 1 C) 2 D) None of These
1 3
42. If fractional part of and x 2 for some x 2, 3 are equal then the value of x 4
x x
is
A) 3 B) 7 C) 5 D) 0
1
43. The function f ( x) x ln x is
A) a constant function in its domain
B) has domain (0, )

C) a periodic function in its domain

D) All of the above
44. The fundamental period of f (x) sin 96 x cos 96 x is

A) B) 2 C) D) None of these
2
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 xe x x
45. If f x x
, then f ( x) is
e 1 2

A) an even function B) an odd function

C) neither odd nor even function D) both odd and even function
46. If domain of f(x) is [1, 3], then the domain of f log 2 x 2 3 x 2 is

3
A) 5, 4 1,2 B) 13, 2 ,5
5
C) 4,1 2,7 D) 3,2
0 0 0
47. The fundamental period of f x sin x cos x tan x is

A) 2 B) C) /2 D) Indeterminate

48. If f ( x) x , then domain of f ( x ) is

A) 0, B) ,0 C) 0 D) None of these
3
49. The domain of f x log10 x 3 x is
4 x2

A) (1, 2) A) 1,0 1, 2 C) 1,0 2, D) 1,0 1,2 2,

The domain of the function f x log10 1 log10 x 2 5 x 10 is

50.
A) 0, B) (0, 5) C) ,0 D) None of these

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 Section-2
(Paragraph Type)
This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions relate to three
paragraphs with two questions on each paragraph. Each question pertaining to a particular paragraph
should have only one correct answer among the four choices A, B, C and D.
Paragraph for Question Nos. 51 & 52

x, if x 2013
Let us define a new function of Rg ( x) or Rg ( x) , then
4026 x, if x 2013

51. The solution of the equation Rg ( x 2013) 2014x 2013 is

A) 0 B) 2 C) 5 D) None of These
52. The maximum value of Rg ( x) is

A) 0 B) 2013 C) 1 D) Can’t Say

Paragraph for Question Nos. 53 & 54
Any function f ( x) is said to be an EVEN FUNCTION, if f ( x) f ( x) .

Any function f ( x) is said to be an ODD FUNCTION, if f ( x) f ( x) .

Any function f ( x) can be expressed as the sum of an even and an odd function
f ( x) f ( x) f ( x) f ( x)
as f ( x) ,
2 2

f ( x) f ( x) f ( x) f ( x)
Where is EVEN and is ODD.
2 2

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53.. If f (x) a e x be x
c is an even function, then the best possible relation between a, b, c
can be
A) a b 0 B) a b C) a b c c 0 D) b a c c 0

2018 x 1
54. The function f x x is
2018 x 1

A) Odd B) Even C) Both (A) & (B) D) Neither (A) nor (B)
Paragraph for Question Nos. 55 & 56
An even periodic function f : R R with period 4 is such that
max . | x |, x 2 0 x 1
f ( x)
x 1 x 2

55. The value of { f (5.12)} is (where {.} denotes fractional part of x) is:

A) { f (3.26)} B) { f (7.88)} C) { f (2.12)} D) { f (5.88)}

56. The number of solutions of f ( x) | 3sin x | for x (-6,6) are

A) 5 B) 3 C) 7 D) 9

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 Section-3
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
57. Here [ ] represents Greatest Integer Function, { } denote fractional part Function
Column – I Column – II
(Function) (fundamental Period)
4
P f x ecos x
x x cos2 x 1 1
3

Q f x cos 2 2x sin 2 2x 2 1
4

R f x sin 3 x tan x 3 1
2

S f x 3x 3x a b where a, b R 4 1

P Q R S
A) 4 3 4 1
B) 4 3 1 3
C) 2 1 4 3

D) 2 1 1 4

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58. Match the following
Here [ ] represents Greatest Integer Function

COLUMN – I COLUMN - II
P Odd function 1 x x x R

Q Even function 2 log x 1 x2 x R

R Neither even nor odd 3 1 x

x log x 1,1
1 x

S Periodic function 4 2x / 2
x R
1 2x / 2

P Q R S
A) 2 3 1, 4 1
B) 2 3 1 3
C) 4 1 1, 4 3
D) 2 1 1 1

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59. Column-B discusses about the nature of functions given in Column-A.

Column-A Column-B
e2 x 1 1) Periodic Function
P) f : R R, f ( x )
ex

Q) f : R R, f ( x) x sin x 2) Even Function

R) f : R R, f ( x ) sin x cos x 3) Odd Function

S) f : R R, f ( x) sin 6 x cos6 x 4) Neither even nor

odd function

P Q R S
A) 4 1,3 1 3
B) 2 3 1,4 1,2
C) 2 1,3 1,4 1,2

D) 4 3 1 3,4

space for rough work Page Page 31

60. Column-B consists of period of functions given in Column-A.

Column-A Column-B
P) f ( x) sin 2017 (2016 x) cos2017 (2016 x) 1)
2

Q) f ( x) sin 2016 (2017 x) cos 2017 (2016 x) 2)

R) f ( x) sin 2017 (2016 x) cos 2016 (2017 x) 3) 2
S) f ( x) sin 2016 (2017 x) cos 2016 (2017 x) 4)
3

P Q R S
A) 1,2,3,4 2,3 1,2,3 1,2,3
B) 1,2,3,4 1,2,3 1,2,3 1,2,3,4
C) 2,3,4 2,3 1,2,3 2,3
D) 1,2,3,4 2,3 2,3 2,3

space for rough work Page Page 32

 Master JEE CLASSES
Kukatpally, Hyderabad.
JEE-ADVANCED-2014-P2-MODEL
Max.Marks:180
KEY SHEET

PHYSICS

1 B 2 B 3 C 4 C 5 C

6 D 7 C 8 D 9 B 10 B

11 C 12 C 13 B 14 C 15 A

16 A 17 B 18 B 19 C 20 D

CHEMISTRY

21 A 22 D 23 A 24 A 25 D

26 C 27 C 28 D 29 A 30 B

31 C 32 B 33 A 34 A 35 A

36 B 37 A 38 B 39 C 40 D

MATHS

41 B 42 C 43 A 44 A 45 B

46 A 47 B 48 C 49 D 50 B

51 B 52 B 53 B 54 B 55 B

56 C 57 A 58 A 59 B 60 D

Page 1
 SOLUTIONS

PHYSICS
1. Wc Wnc Wext KE

2. with F=6N both blocks more together, W f f .S

3. from A to C , W f mgh

From C to A , mgh W f WF O

4. Wf fdr

dW
6. 0
dx
7. Work done by conservative force is independent of path followed
10. Apply W-E theorem
12. Apply W pseudo concept

14. du F .dr , Apply work energy theorm

15. When it moves from A to B and surface is rough from W - E theorem

Wnet KE
Wf Wg Wnet

Wf mgR 0 Wf mgR

16. A to B surface is rough, B to C smooth let it reach a point P above C, when pushed
from A. So from W - E theorem Wnet KE KE f KEi

motion from A to point (beyond C)

1
W f ( AB ) Wg KEP KE A 0 mV A2
2
Hence W f ( AB) mgR

1 2
Given mv A mgR, let y be the position of point P above horizontal level AC, where the
2
body finally reaches
mgR mgy mgR
y 0
it reaches to a height of R above B
20. apply work energy theorm
A - T; B - P; C - S; D – Q
Page 2
 CHEMISTRY
23. Solution:
Li g Li +3g +3e H=1.96 10 4 kJ mol -1

Li g Li +g +e IE1 =520 kJ mol -1

Li g Li +2g +e IE 2 =a kJ mol-1

Li g2 Li +2g +e IE 3 =b kJ mol-1

also b E1 for Li 2
E1 for H Z 2
18
=2.18 10 32 6.023 1023 J mol-1

=11.81 10 6 J mol-1 =11.81 103 kJ mol -1

For the above eq

1.96 10 4 520 a 11.81 10 3

a=7270 kJ mol-1

24. Conceptual

25. M M e

5
number of moles = 0.2
25
Energy required to form M+ ions
= 0.2 x 800
= 160 KJ mol-1
Remaining energy = 90 KJ moles
This is used to convert M+ to M+2
Number of moles of M+2 formed
90
= 0.06
1500
0.06
% M+2 = x 100 = 30%
0.2
26. Conceptual
27. Conceptual
28. Conceptual
29. Ne> Ar> Kr>Xe>Rn>Ne (NCERT)

Page 3
 1 1 1
30. X X e; I.E...(a)
2 2 2
1 1 1
e X X ; Heg.....(b)
2 2 2
1 1 1
X X X ; (I.E. Heg ) 410kJ
2 2 2

I.E. Heg = 820kJ

1 1
X X 2e; H 735kJ …..(c)
2 2
(a)-(b) = (c)
1 1
I.E. Heg 735
2 2

I.E. Heg =1470

I.E. Heg = 820kJ

_____________________________
(-) - 2 H eg = 650 Heg = -325 kJmol-1.
32. Hint: (1) The element (E) having very high ionisation enthalpy and positive electron
gain enthalpy would be a noble gas, i.e., least reactive.
(2) The element (B) would be most reactive metal as it has low ionisation enthalpy and
low negative electron gain enthalpy. Probably it is an alkali metal.
(3) The element (C) would be most reactive non-metal as it has high negative value of
electron gain enthalpy. Probably it is a halogen.
(4) The element (D) would be least reactive non-metal.
(5) The element (A) has low first ionisation enthalpy but very high second ionisation
enthalpy. It would be least reactive alkali metal, i.e., lithium which forms covalent
MX ]

1
33. E1H X B.E H 2 B.E of X 2
2
104 38
71 k .mol
2
1
EH X EHX

=135-71 = 64 k. mol

Page 4
 XA XB 0.208 64 8

XA 0.208 8 2.1 3.764

333 x
34. 3.76
544

x 1712 kJ

35 and 36.

n=1 n=2 N =3 n=4

=0 1s =0 2s =0 3s =0 4s

=1 1p =1 2p =1 3p =1 4p

=2 1d =2 2d =2 3d =2 4d

=3 2f =3 3f =3 4f

=4 3g =4 4g

=5 4h

Electronic configuration 1s, 1p, 2s, 1d, 2p, 3s, 3d, 3p, 4s, 3d
For third period 3s3, 3d15, 3p9
number of element = 27
(a)
1s3, 1p9, 2s3, 1d14
37. Zeff for Na 11 8 0.85 2 1

Zeff for Na 11 7 0.35 0.85 2

38. Conceptual
39. P= Ce58 Q) Pa91 R) Cd 48 S) Cr24
40. Conceptual
MATHS
42. x 1,0,1

43. f ( x) x logx e e Domain is 0,1 1,

Page 5
44. Sol: For odd values of n , fundamental period is 2
For n 2, fundamental period is indeterminate

For even values of n( 2), fundamental period is

2
46. f ( x) c

47. 00 is not defined

3
49. f x log10 x3 x is defined 4 x2 0, x3 x 0 x 2, x 1 x x 1 0
4 x2
f ( x) f ( x) f ( x) f ( x)
53. Sol: f ( x)
2 2

a b a b
f ( x) ex e x
c ex e x

2 2

56. Conceptual
57. Conceptual
58. x x is neither even nor odd function. It is a periodic function with period ‘1’

log x 1 x 2 is odd function

x
1 x 22
xlog , x
are even functions
1 x 2
1 2

Page 6