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163 views60 pages

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in

11TH CHEMISTRY PUBLIC QUESTIONS

th
11 CHEMISTRY

n
l.i
da
ka
vi
al
.k

Government Public questions


w

Unitwise
w

March-2019
w

June-2019
September-2020
September-2021
May-2022
july-2022

S.MANIKANDAN.,M.Sc.,B.Ed.,
7708543401
S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 1

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11TH CHEMISTRY PUBLIC QUESTIONS

CONTENTS
S.NO PUBLIC QUESTION PAPERS PAGE
NUMBER

n
1 Preface 3

l.i
2 March 2019 4

da
3 June-2019 8
4 September-2020 12

ka
5 September-2021 16
6 May-2022
vi 20
7 July-2022 24
al
LESSON NAME
.k

1 Basic concepts of chemistry and chemical 28


calculation
w

2 Quantum mechanical model of atom 30


w

3 Periodic classification of elements 32


w

4 Hydrogen 34
5 Alkali and Alkaline earth metals 35
6 Gaseous state 36
7 Thermodynamics 37
8 Physical and chemical equilibrium 39
9 Solutions 41
10 Chemical bonding 43
12 Fundamentals of organic chemistry 45
13 Basic concepts of organic reactions 49
14 Hydrocarbons 50
Haloalkanes and Haloarenes 53
15 Environmental chemistry 57
16 Your hints 58

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 2

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11TH CHEMISTRY PUBLIC QUESTIONS

PREFACE

n
“Praise the lord”

l.i
“Education is not the learning of facts,

da
But the training of the mind to think”
-Albert Einstein

ka
“Education is the movement from darkness to light “
----------------------------------------------------------------------------------------------------------------
vi
Respected Teachers/ Dear students
This guide is based on the six government public 11THchemistry questions. This
al
guide contains more than 200 questions .and 90 one marks. (question and answer)
.k

The questions asked in government public examination are very important so Students
should keep reading this well.
w

The purpose of creating this guide is for students to get higher


w

marks.This guideis also created for slow learning students to pass.


w

You have any doubt of question and answer in this material contact
your chemistry teacher or me
I hope this guide will be very useful for Students and Teachers.
My heartfelt thanks to all the educational webpage.Teachers or students can let me know
their valuable feedback regarding this guide.
God bless all
All the best
S.MANIKANDAN.M.Sc., B.Ed.,
7708543401
NOTE:
Government public question paper march 2019 - mar19
Government public question paper june 2019 - jun19
Government public question paper September 2020 - sep20
Government public question paper September 2021 - sep21
Government public question paper may2022 -may22
Government public question paper july2021 -jul22
Interior page number -ipn

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 3

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11TH CHEMISTRY PUBLIC QUESTIONS

Time allowed : 2.30hours March-2019 Maximum marks : 70


PART-I
Note : i)Answer all the questions.
ii)choose the most appropriate answer from the given four 15 X 1 = 15
alternatives and write the option code and the corresponding answer

n
1.many of the organic compounds are inflammable because of Its :

l.i
a) vander waal‟s force b) co-ordinate nature
c) covalent nature d) ionic nature

da
2.When Δng is negative in chemical equilibrium reaction then :
a) Kp<Kc b) Kp=1/Kc
-ve

ka
c) Kp=Kc(RT) d) Kp > Kc
3.Find A in the following reaction
CaO + 3C __A__+ CO
vi
a) CaC2 b) CO2 c) Ca d) Ca2O
al
4.Splitting of spectral lines in an electric field is called :
a) Compton effect b) stark effect
.k

c) Zeeman effect d) shielding effect


5.Which of the following species does not exert a resonance effect ?
w

a) C6H5NH2 b) C6H5NH3+ c) C6H5OH d) C6H5Cl


w

6.Match the following :


Compound uses
w

1)Chloro picrin i) detection of primary amine


2)Methyl isocyanide ii) DDT
3)Chlolro benzene iii) paint remover
4)Meythylene chloride iv) soil sterilizer
a) (1)- (iv), (2)-(iii) , (3)-(ii), (4)-(i) b) (1)- (iii), (2)-(iv) , (3)-(ii), (4)-(i)
c) (1)- (i), (2)-(ii) , (3)-(iv), (4)-(iii) d) (1)- (iv), (2)-(i) , (3)-(ii), (4)-(iii)
7.use of hot air ballone in meteorological observatory is an application of :
a) Kelvin‟s Law b) Brown‟s Law
c) Boyle‟s Law d) Newton‟s Law
8.what is the pH of rain water ?
a) 5.6 b) 4.6 c) 6.5 d) 7.5
9. which compound is named as “blue john” among the following compounds ?
a) Ca3(PO4)2 b) CaO c) CaH2 d) CaF2
10.The element with positive electron gain enthalpy is _____
a) Argon b) Fluorine
c) Hydrogen d) sodium

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 4

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11TH CHEMISTRY PUBLIC QUESTIONS

11.which of the following molecule does not contain π bond ?


a) CO2 b) H2O c) SO2 d) NO2
12.which of the following compound has same percentage of carbon as that of
ethylene (C2H4) ?
a) benzene b) ethane

n
c) propene d) ethyne

l.i
13.The SI unit of molar heat capacity is : ______
a) JK-1 mol-1 b) KJ mol+1 c) KJ mol-1 d) cm

da
14.What percentage of solution of H2O2 is called as “100-volume‟ H2O2 ?
a) 15% b) 50% c) 20% d) 30%
15.osmotic pressure ( π) of a solution is given by the relation :

ka
a) π RT =n b) V= π nRT
c) π= n RT d) π V=nRT
vi
PART-II
al
Answer any six of the following questions. Question no.24 is compulsory. 6 X 2 = 12
16.State and explaine pauli‟s exclusion principle.
.k

17.Define valency
18.What are ideal gas ?
w

19.State the third law of thermodynamics ?


20.What is called bond length ? Name the techniques through which the length of a bond
w

can be determined .
w

21.Describe the reaction involved in the detection of nitrogen in an organic compound by


lassaigne method.
22.How is alkane prepared from grignard reagent ?
23.Define- acid rain
24.Which is the suitable method for detection of nitrogen present in food and fertilizers?
PART-III
Answer any six of the following questions. Question no.33 is compulsory 6 X 3 = 18
25.Calculate the equivalent mass of H2SO4
26.Explain diagonal relationship .
27.How is Tritium prepared ?
28.Define –Le-Chatelier principle.
29.State the term “isotonic solution”
30.Both C2H2 and CO2 have the same structure. Explain why.
31.Write note on Williamson‟s synthesis.
32.Explain why Ca(OH)2 is used in white washing .
33.Give the structural formula for the following compounds.
a)m-dinitrobenzene b)p-dichlorobenzene c)1,3,5,Tri-methyl Benzene

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 5

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11TH CHEMISTRY PUBLIC QUESTIONS

PART-IV
Answer all the questions. 5 X 5 = 25
34. a) i) calculate oxidation number of oxygen in H2O2
ii) Write the de-broglie equation.
(OR)

n
b) i)State and explain Dobereiner”s “triad”

l.i
ii) complete the following equation
Na2O2 + ?  Na2SO4+ H2O2

da
35. a) i) Among the alkaline earth metals BeO is insoluble in water but other

ka
oxides are soluble .why ?
ii) State Diffusion law.
(OR)
vi
b) i) calculate the entropy change during the melting of one mole of ice into
water at 00c. enthalpy of fusion of ice is 6008 J mol-1.
al
[𝐶𝑎𝑂 (𝑆) ][𝐶𝑂2(𝑔) ]
ii) Write the balanced chemical equation for the Kc=
.k

[𝐶𝑎𝐶𝑂 3(𝑆) ]
36. a) i) NH3 and HCl do not obey Hentry‟s law. Why ?
w

ii) Write the structure of the following compounds.


(A) NH3 (B) BF3
w

(OR)
b) i) Identify the cis and trans isomers for the following compounds
w

a) b)

ii) Explain with example the positive mesometric effect.

37. a) i) Write the IUPAC names for the following compounds.

(A) (B)
ii) What are nucleophiles and electrophiles ? give one example each
(OR)
b) i) How will you get the following products with the given reactants ?
(A) Acetylene  Benzene
(B) Phenol  Benzene
(C) Benzene Tolune
S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 6

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11TH CHEMISTRY PUBLIC QUESTIONS

ii) Write any two different components you get during fractional distillation of
coal tar at any two different temperatures.
38.a) i) A compound having the empirical formula C6H6O has the vapour density
47. Find its molecular formula.
ii) The simple aromatic hydrocarbon compound (A) reacts with bromine to

n
give (B).compound (A) reacts with Raney Ni and gives (C). Identify

l.i
(A) , (B) and (C).
(OR)

da
b) i) C(s) + O2(g)  CO2(g)
Calculate the standard entropy change for the above reaction, given the
standard entropies of CO2(g), C(s), O2(g) are 213.6,5.740 and 205 JK-1

ka
respectively.
ii) Identify the compound (A) and (B) vi
al
.k
w
w
w

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 7

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11TH CHEMISTRY PUBLIC QUESTIONS

Time allowed : 2.30hours Maximum marks : 70


JUNE-2019
PART-I
Note : i) Answer all the questions.
ii) choose the most appropriate answer from the given four 15 X 1 = 15

n
alternatives and write the option code and the corresponding answer .

l.i
1.The oxidation number of carbon in CH2F2 is ______

da
a) +4 b) -4 c) 0 d)+2
2.The energy of an electron in the third orbit of hydrogen atom is –E . The

ka
energy of an electron in the first orbit will be _____
𝐸 𝐸
a) -3E b) - c) - d) -9E
3 9
3.The effective nuclear charge experienced by the d1 electron in the given
vi
electronic configuration, (1s)2 (2s,2p)8 (3s,3p)8 (3d)1 (4s)2 is :
al
a) 4 b) 3 c) 2.1 d) 6.9
4.The type of H-bonding present in orthonitro phenol and p-nitro phenol are ___respectively.
.k

a) Inter molecular H-bonding and intra molecular H-bonding


b) Intra molecular H-bonding and inter molecular H-bonding
w

c) Intra molecular H-bonding and no H-bonding


w

d) Intra molecular H-bonding and intra molecular H-bonding


5.When CaC2 is heated in atmospheric nitrogen in an electric furnace, the
w

compound formed is __________


a) Ca(CN)2 b) CaNCN c) CaC2N2 d) CaNC2
6.When an ideal gas undergoes unrestrained expansion, no cooling occurs
because the molecules ________
a) are above the inversion temperature b) exert no attraction force on each other
c) do work equal to the loss in kinetic energy d) collide without loss of energy
7.Among the following statements, which one is /are correct ?
i) During cyclic process the amount of heat absorbed by the surrounding is
equal to work done on the surrounding
ii)Refractive index is an example for intensive property
iii) If the enthalpy change of a process is positive then the process is spontaneous
iv) The entropy of an isolated system increases during spontaneous process
a) (i), (ii), (iii) b) (i), (iv) c) (ii), (iv) d) (ii) only
-5 -4
8.If kb and kf for a reversible reaction are 0.8 x 10 and 1.6x 10 respectively
,the value of equilibrium constant is _______
a) 20 b) 0.2 x10-1 c) 0.05 d) 0.2

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 8

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11TH CHEMISTRY PUBLIC QUESTIONS

9.Assertion : Mixture of carbon tetrachloride and chloroform show positive


deviation from raoult‟s law
Reason : In the mixture the inter molecular force of attraction between
chloroform and carbon tetrachloride is weaker than those between
molecules of carbon tetrachloride and chloroform molecules.

n
a) Both assertion and reason are correct and reason is the correct explanation of

l.i
assertion
b) Both assertion and reason are correct and reason is not the correct

da
explanation for assertion
c) Both assertion and reason are false

ka
d) Assertion is true , but reason is false
10.Shape and hybridation of IF5 are :
a) Trigonal bipyramidal sp3d2 b) Trigonal bipyramidal sp3d
vi
c) Square pyramidal sp3d2 d) Octahedral, sp3d2
11.Which of the following is optically active ?
al
a) 3-chlolro pentane b) 2-chloro propane
.k

c) meso-tartaric acid d) glucose


12.Which of the following species is not electrophile in nature ?
w

a) Cl+ b) BH3 c) H3O+ d) +NO2


13.______group is ortho para directing and deactivating group
w

a) amino b) methyl c) halogen d) aldehyde


w

14.The raw material for Rasching process is _______


a) chloro benzene b) phenol c) benzene d) anisole
15.________ cause kidney damage
a) Cadmium , mercury b) Lead, Cadmium
c) Freon, Fluoride d) copper, Cadmium
PART-II
Answer any six from the following questions.Q.no.24 is compulsory 6 X 2 = 12
16.What is syn gas ? How it is prepared ?
17.Write any two similarities between beryllium and aluminium .
18.What is inversion temperature ?
19.What is the effect of added inert gas on the rection at equilibrium ?
20.Linear form carbon dioxide molecules has two polar bonds .yet the molecule has zero
dipole moment. Why ?
21.How do you detect the presence of nitrogen and sulphur together in anorganic compound?
22.What happens when acetylene undergoes ozonolysis ?
23.What is green chemistry ?
24.Calculate the orbital angular momentum for d and f orbital.

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 9

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11TH CHEMISTRY PUBLIC QUESTIONS

PART-III
Answer any six from the following questions. Q.No.33 is compulsory 6 X 3 = 18
25.What do you understand by the term mole ?
26.Ionisation potential of nitrogen is greater than that of oxygen . explain by giving
appropriate reason.

n
27.Among the alkali metal halides, which is covalent ? explain with reason.

l.i
28.Derive ideal gas equation.
29.Define molar heat capacity. Give its unit.

da
30.What is vapour pressure of a liquid ? what is relative lowering of vapour pressure ?
31.explain a suitable method for purifying and separating liquids present in a mixture having

ka
very close boiling point.
32.What is polymerisation ? explain the two types of polymerisation rection of acetylene .
33.The bond length between all the four carbon atoms is same in 1,3-butadiene. Explain
vi
al
PART-IV
Answer all the following questions. 4 X 5 = 20
.k

34.a) i) What are auto redox rections ? give an example .


ii) Define orbital.What are the n and l values for 3px and 4dx2-y2 electron ?
w

(OR)
b) i) Why hydrogen peroxide is stored in plastic containers, not in glass container ?
w

ii) Give the general electronic configuration of lanthanides and actinides.


w

35.a) i) why blue colour appears during the dissolution of alkali metals in liquid ammonia ?
ii) what is boyle‟s temperature ? what happens to real gases above and below the
boyle‟s temperature ?
(OR)
b) i) Derive the relation between kp and kc for a general homogeneous gaseous reaction.
ii) How do you measure heat changes at constant pressure ?
36.a) i) Draw the M.O diagram for oxygen molecule . calculate its bond order
and magnetic character.
ii) Draw and explain the graph obtained by plotting solubility versus
temperature for calcium chloride .
(OR)
b) i) Write the IUPAC names for the following compounds :

(x) (Y) (Z)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 10

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11TH CHEMISTRY PUBLIC QUESTIONS

ii) Calculate the formal charge on carbon and oxygen for the following

structure
37.a) i) explain about inductive effect .
ii) What do you mean by conformation ? Explain about staggered conformation in

n
ethane .

l.i
(OR)
b) i) Among the following compounds ,o-dichloro benzene and p-dichloro benzene ,

da
which has higher melting point ? explain with reason .
ii) Write notes on the adverse effect caused by ozone depletion.

ka
38.a) i) calculate the uncertainty in the position of an electron, if the uncertainty in it velocity
is 5.7 x 105 ms-1 vi
ii) What is the mass of glucose (C6H12O6) in it one litre solution which is isotonic with
6gl-1 of urea (NH2CONH2) ?
al
(OR)
.k

b) i) An organic compound (A) of molecular formula C2H6O, on heating with conc.H2SO4


gives compound (B) . (B) on treating with cold dilute alkaline KMnO4 gives compound
w

(C) . Identify (A), (B) and (C) and explain the reactions.
ii) A simple aromatic hydrocarbon (A) reacts with chlorine to give compound (B) .
w

compound (B) reacts with ammonia to give compound (C) which undergoes
carbylamines reaction. Identify (A), (B) and (C) and explain the reactions.
w

*******

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 11

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11TH CHEMISTRY PUBLIC QUESTIONS

Time allowed : 3.00hours Maximum marks : 70


Sep-2020
PART-I
Note : i) Answer all the questions.
ii) choose the most appropriate answer from the given four alternatives and

n
write the option code and the corresponding answer . 15 X 1 = 15

l.i
1.The maximum number of electrons that can be accommodated in L orbit is
a) 8 b) 2 c) 4 d) 6

da
2.The relative molecular mass of ethanol is ___
a) 0.46g b) 4.6 g c) 460g d) 46g

ka
3.Intra molecular hydrogen bonding is present in___
a) Ortho-nitro phenol b) Ice c) Water d) Hydrogen fluoride
4.Ozone deplection will cause vi
a) Global warning b) Forest fire c) Eutrophication d) Bio-magnification
5.Among the following which is the path function ?
al
a) G b) U c) H d) q
.k

6. match the following


1)Iodoform i) Fire extinguisher
w

2)Carbon tetrachloride ii)Insecticide


3)CFC iii) Antiseptic
w

4)DDT iv)Refrigerants
w

a) (1)- (iii), (2)-(i) , (3)-(iv), (4)-(ii) b) (1)- (ii), (2)-(iv) , (3)-(i), (4)-(iii)
c) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) d) (1)- (i), (2)-(ii) , (3)-(iii), (4)-(iv)
7.Cold dilute alkaline KMnO4 is known as
a) Schiff”s reagent b) Fenton”s reagent
c) Tollen‟s reagent d) Baeyer‟s reagent
8.osmotic pressure (π) of a solution is given by the relation
a) π RT=n b) π= n RT
c) π V=nRT d) None of these
9.n-propyl bromide on rection with alcoholic KOH gives
a) Butyl alcohol b) Propene
c) Butene d) Propyl alcohol
10.Which of the following is incorrect statement ?
a) Equilibrium constant varies with temperature
b) For a system at equilibrium ,Q is always less than the equilibrium constant
c) Equilibrium can be attained from either side of the reaction
d) Presence of catalyst affects both the forward reaction and reverse reaction
to the same extent.

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 12

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11TH CHEMISTRY PUBLIC QUESTIONS

11.Assertion : Helium has the highest value of ionisation energy among all the
elements known.
Reason : Helium has the highest value of electron affinity among all the
elements known.
a) Both assertion and reason are false

n
b) Both assertion and reason are true and the reason is correct explanation for

l.i
the assertion
c) Both assertion and reason are true but the reason is not the correct

da
explanation for the assertion
d) Assertion is true and reason is false .

ka
12.Write the IUPAC name of vi
a) 1-formyl propanol b) 1-hydroxy butanal
c) 2-hydroxy butanal d) 3- hydroxy butanal
al
13.Formula of Gypsum is
a) CaSO4 b)CaSO4.2H2O
.k

1
c) CaSO4. H20 d) CaSO4. H20
2
w

14.Gases tent to behave ideally only at


a) Low temperature and low pressure b) High temperature and High pressure
w

c) High temperature and low pressure d) Low temperature and High pressure
w

15.Which of the following is electron deficient ?


a) NH3 b) PH3 c) (CH3)2 d) BH3

PART-II
Answer any six from the following questions.Q.no.24 is compulsory. 6 X2 = 12
16.Define basicity.Find the basicity of ortho-phosphoric Acid.
17.Write the exchange reactions of Deuterium.
18.state zeroth Law of Thermodynamics.
19.Explain homogeneous and heterogeneous equilibria.
20.Write the shape and molecular geomentry for BF3
21.Which element exhibits maximum catenation and why ?
22.Write the no bond resonance structure shown by propene ?
23.Give the structure and uses of DDT .
24.In degenerate orbitals, why do the completely filled and half filled configurations are
more stable than the partially filled configurations ?

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 13

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11TH CHEMISTRY PUBLIC QUESTIONS

Part-III
Note : Answer any six questions. Question NO.33 is compulsory. 6 X 3 =18
25.State Heisenber‟s Uncertainty Principle .
26.Derive ionic radius using pauling‟s method .
27.How do you convert para hydrogen into ortho hydrogen.

n
28.Distinguish between extensive and intensive property.

l.i
29.Calculate the mole fraction of methanol and water when
0.5 mole of methanol is mixed with 1.5 moles of water.

da
30.What is hybridisation ? mention the type of hybridization found in CH4
31.Explain the different types of polymerisation in ethyne.

ka
32.What is green house effect ? Name the gases that cause green house effect .
33.Explain geometrical isomerism in 2-butene.
vi PART-IV
al
Note : Answer all the questions . 5 X 5 = 25
34. a) Calculate the empirical formula and molecular of a compound containing
.k

76.6% carbon,6.38% of hydrogen and rest oxygen. Its vapour density is 47.
(OR)
w

b) i) Calculate the total number of angular nodes and radial nodes present in
3d and 4f orbitals.
w

ii) Explain why the electron affinity of Be and N is almost zero


w

35.a) i) Write the laboratory method of preparation of hydrogen .


ii) Name the different methods of liquefaction of gases.
(OR)
b) i) How is bleaching powder prepared ?
ii)Write the uses of magnesium.
iii)Write the mathematical formula for compressibility factor „Z‟

36.a) i)Derive the relation between enthalpy ΔH and internal energy ΔU for an ideal gas.
ii) Define reaction quotient.
(OR)
b) i) Calculate the entropy change during the melting of one mole of ice into water at 0 0C
and 1 atm pressure. Enthalpy of fusion of ice is 6008J mol-1
ii) Write any four postulates of molecular orbital theory.

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 14

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11TH CHEMISTRY PUBLIC QUESTIONS

37.a) i)What is van‟t hoff factor „i‟ ?


ii) complete

A) H2C=CH2 + H-Br

n
B) CH3CHO

l.i
da
C)

ka
vi
al
D)
(OR)
.k

b) Explain the purification of a solid organic compound by crystallization method


w

38.a) i) write Brich reduction .


ii) Write any three strategies to control environment pollution.
w

(OR)
w

b) explain the mechanism involved in the elimination reaction of tertiary butyl chloride
with alcoholic KOH.

***********

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 15

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11TH CHEMISTRY PUBLIC QUESTIONS

Time allowed : 3.00hours Maximum marks : 70


Sep-2021
PART-I
Note : i) Answer all the questions.
ii) choose the most appropriate answer from the given four alternatives and

n
write the option code and the corresponding answer . 15 X 1 = 15

l.i
1. Which one of the following of presents 180g of water ?
6.022 X 10 24

da
a) moles of water b) 5 moles of water
180
c) 6.022 X 1024 moles of water d) 90 moles of water
2.Which of the following compound(s) has/have percentage of carbon same as that in

ka
ethylene (C2H4) ?
a) benzene b) propene c) ethane
vi d) ethyne
3.Assertion ; permanent hardness of water is removed by treatment with washing soda
Reasons : Washing soda reacts with soluble calcium and magnesium chloride and sulphate
al
in hard water to from insoluble carbonates.
a) Assertion is true but reason is false
.k

b) Both assertion and reason are true and reason is the correct explanation of assertion
w

c) Both assertion ans reason are false


d)Both assertion and reason are true but reason is the correct explanation of assertion.
w

4.Flame colour of potassium salts in bunsens burner


a) Lilac (violet ) b) crimson red c) Apple green d) yellow
w

5. Formula of plaster of paris


1
a) 3CaSO4.H2O b) CaSO4.2H2O c) 2CaSO4.2H2O d) CaSO4. H2O
2
6. Rate of diffusion of a gas is :
a) directly proportional to the square root of its molecular weight
b) directly proportional to its density
c) inversely proportional to the square root of its molecular weight
d) directly proportional to its molecular weight
7. Heat of combustion is always :
a) zero b) positive
c) either positive or negative d) negative
8. For the following reversible rections at equilibrium A + B C. If the concentration of
the reactants A and B are doubled, then the equilibrium constant will :
a) be halved b) be doubled
c) remain the same d) become one fourth
9.The molality of a solution containing 1.8g of glucose dissolved in 250g of water is
a) 0.02M b) 0.2M c) 0.04M d) 0.01M

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 16

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11TH CHEMISTRY PUBLIC QUESTIONS

10.Match the following


1) N2 molecule i) chemical bond
2) BF3 molecule ii) Trible covalent bond
3) HF molecule iii) Electron deficient molecule
4) NaCl iv) polar covalent bond

n
a) 1)- iii) , 2)- i) , 3)-iv) , 4)- ii) b) 1)-ii) , 2)- iv) , 3)-i) , 4)- iii)

l.i
c) 1)- i) , 2)- iv) , 3)- ii) , 4)- iii) d) 1)- ii) , 2)-iii) , 3)- iv) , 4)- i)
11.The structure of isobutyl group in organic compound

da
a) b)

ka
vi
c) d)
al
12.Which of the following is optically active ?
a) meso-tartaric acid b) 3-chloropentane
.k

c) glucose d) 2-chloropropane
13.The geometrical shape of carbocation is
w

a) planar b) linear c) pyramidal d) tetrahedral


w

14.An alkene is obtained by decarboxylation of sodium propionate.same alkene can be


prepared by :
w

a) reduction of 1-chloro propane b) catalytic hydrogenation of propene


c) reduction of bromo methane d) action of sodium metal on iodomethane
15.Of the following compounds , which has the highest boiling point?
a) t-butyl chloride b) n-butyl chloride
c) n-propyl chloride d) Isobutyl chloride
PART-II
Answer any six from the following questions.Q.no.24 is compulsory. 6 X 2 = 12
16.What is the empirical formula of the following ?
a) Fructose (C6H12O6) ii) Caffeine ( C8H10N4O2)
17.State Aufbau principle
18.How do you convert para hydrogen into ortho hydrogen ?
19.Give any two characteristics of gibbs free energy ?
20.Define Hess‟s law of constant heat summation.
21.What is the relation between KP and KC ? Give one example for which KP is equal
to KC.

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 17

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11TH CHEMISTRY PUBLIC QUESTIONS

22.What is molal depression constant ?


23.Write short notes on Swarts reaction ?
24.Complete the following :

n
a) CH3-CH=CH2 + H2

l.i
b) CH3MgCl + H2O
Part-III

da
Note : Answer any six questions. Question NO.33 is compulsory. 6 X 3 = 18
25. Distinguish between oxidation and reduction .

ka
26.Define electronegativity. State the trends in the variation of electronegativity in
group and period vi
27.What are homogeneous and heterogeneous equilibria? Give example
al
28.What are ideal solutions ? Give example
29.Give the shapes of molecules predicted by VSEPR theory
.k

a) BeCl2 b) NH3 c) H2O


w

30.Give the general formula for the following class of organic compounds
w

a) Alkanes b) Alkenes c) Alkynes


w

31.What is resonance ?
32.Suggest a simple chemical test to distinguish propane and propene
33.Inside a certain automobile engine , the volume of air in a cylinder is 0.375 dm3 ,
when the pressure is 1.05atm . When the gas is compressed to a volume of 0.125 dm3
at the same temperature , What is the pressure of the compressed air ?
PART-IV
Note : Answer all the questions . 5 X 5 = 25
34. a) i) What is exchange energy ?
ii) Write a note on principal quantum number
(OR)
b) i) Define atomic radius.
ii) Explain diagonal relationship

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 18

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11TH CHEMISTRY PUBLIC QUESTIONS

35. a) Discuss the similarities between beryllium and aluminium


(OR)
b) i) State the first law of thermodynamics
ii) What are the conditions for the spontaneity of a process?

n
36. a) How will you determine the molar mass of a solute from osmotic pressure ?

l.i
(OR)

da
b) i) Define Bond Order.
ii) What are the salient features of VB theory ?

ka
37. a) i) What is meant by homologous series ?
ii) Give the structure for the following compounds .
vi
1) 3-methylpentane
2) 2-methylpropan-2-ol
al
3) Propanone
.k

(OR)
b) Explain the formation of H2 molecule using MO-theory
w

38. a) i) How does Huckel rule help to decide the aromatic character of a compound ?
w

ii) Write the rection for conversion of acetylene to benzene.


w

(OR)
b) Simplest alkene (A) rects with HBr to form compound (B). Compound (B) reacts
with ammonia to from compound (C) of molecular formula C2H7N. Compound
(C) undergoes carbylamines test. Identify (A), (B) and (C).

****************

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 19

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11TH CHEMISTRY PUBLIC QUESTIONS

Time allowed : 3.00hours Maximum marks : 70


MAY-2022
Part-I
Note : i) Answer all the questions. 15 X 1 = 15
ii) choose the most appropriate answer from the given four alternatives and

n
write the option code and the corresponding answer

l.i
1.Which of the following is aliphatic saturated hydrocarbon ?

da
a) C9H18 b) C8H14 c) C8H18 d) All of the above

ka
2.Equimolal aqueous solutions of NaCl and KCl are prepared . If the freezing
point of NaCl is -20c , the freezing point of KCl solution is expected to be
a) -10C b) -20C c) 00C vi d) -40

3.The correct relative order of +I effect of alkyl groups is :


al
a) -C(CH3)3 > -CH(CH3)2 > -CH2CH3 > -CH3
b) –CH3
.k

> -CH2CH3 > -CH(CH3)2 > -C(CH3)3


c) -CH2CH3 > -CH3 > -C(CH3)3 > -CH(CH3)2
w

d) –CH(CH3)2 > -C(CH3)3 > -CH2CH3 > -CH3


4.7.5 g of a gas occupies a volume of 5.6 L at 00C and 1 atm pressure.The gas is
w

a) CO b) NO c) CO2 d) N2
w

5.Assertion : In monohaloarenes, electrophilic substitution occurs at ortho and para


positions
Reason : Halogen atom is a ring deactivator
a) Assertion is true but reason is false
b) Both assertion and reason are true and reason is the correct explation of
assertion
c) Both assertion and reason are false
d) Both assertion and reason are true but reason is not the correct explanation
of assertion
6.The intensive property among the quantities below is :
𝑚𝑎𝑠 𝑠
a) Enthalpy b) mass c) d) volume
𝑣𝑜𝑙𝑢𝑚𝑒
7. Which one of the following is incorrect statement ?
a) Presence of catalyst affects both the forward reaction and reverse reaction
to the same extent.
b) for a system at equilibrium Q is always less than the equilibrium constant
c) equilibrium constant varies with temperature
d) equilibrium can be attained from either side of the reaction

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 20

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11TH CHEMISTRY PUBLIC QUESTIONS

8.Match of following
1) –NO2 i) propyl
2) -OCH3 ii) Amino
3) -CH2-CH2-CH3 iii)Methoxy

n
4) –NH2 iv) Nitro

l.i
a) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) b) (1)- (iii), (2)-(iv) , (3)-(i), (4)-(ii)
c) (1)- (iv), (2)-(iii) , (3)-(i), (4)-(ii) d) (1)- (ii), (2)-(i) , (3)-(iv), (4)-(iii)

da
9.Spodumene is the mineral source for which of the following alkali metal ?
a) Lithium b) Sodium c) Rubidium d) Potassium

ka
10.Which of the following has highest hydration energy ?
a) BaCl2 b) MgCl2 c) SrCl2 d) CaCl2
11.Tritium nucleus contains : vi
a) 1p+2n b) 1p+on c) 1p+1n d) 2p+1n
12.Which one of the following is diamagnetic ?
al
a) O22- b) O2+ c) O2 d) None of these
.k

13.Splitting of spectral lines in an electric field is called :


a) Compton effect b) Zeeman effect
w

c) Stark effect d) Shielding effect


14.A bottle of ammonia and a bottle of HCl connected through a long tube are opened
w

simultaneously at both ends. The white ammonium chloride ring will be first formed :
w

a) near the ammonia bottle b) at the centre of the tube


c) throughout the length of the tube d) near the hydrogen chloride bottle

15.
a) optical isomers b) resonating structures c) conformers d) tautomers

Part-II
Note : answer any six questions. Question No.24 is compulsory 6 X 2 = 12
16.Define Gram equivalent mass
17.Calculate the maximum number of electrons that can be accommodated in L shell
18.Mention the three types of covalent hydrides .
19.What are the condition for the spontaneity of a process
20.Explain sign convention of heat
21.Give a balanced chemical equation for the equilibrium reaction for which the
[𝑁𝐻3 ]4 [𝑂2 ]5
equilibrium constant is given by expression Kc =
[𝑁𝑂]4 [𝐻2 𝑂]6

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 21

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11TH CHEMISTRY PUBLIC QUESTIONS

22.Define the term “isotonic” solution


23.How will you convert ethyl chloride to ethane ?
24.Complete the following reactions

n
l.i
PART-III

da
Note : Answer any six questions. Question No.33 is compulsory 6X3=18
25.Calculate the oxidation number of underlined elements .

ka
i) CO2 ii) H2SO4
26.Define electron affinity
27.State Dalton Law of partial pressures. vi
28.Write the formula to calculate the molar mass of a solute from realative lowering of
al
vapour pressure values.
29.Describe the formation of HF molecule by orbital overlap
.k

30.What is meant by optical isomerism ?


31.Give any three differences between nucleophiles and electrophiles
w

32.what happens when ethylene is passed through cold dilute alkaline potassium
permanganate ?
w

33.The equilibnrium concentrations of NH3 and N2 and H2 are 1.8 x10-2M , 1.2x10-2M and
w

3x 10-2 M respectively. Calculate the equilibrium constant for the formation of NH3 from
N2 and H2
PART-IV
Note : Answer all the questions. 5 X 5 = 25
34.a)i) How many orbitals are possible for n=4 ?
ii) Write the electronic configuration and orbital diagram for nitrogen ?
(OR)
b) Describe the pauling method for the determination of ionic radius .
35.a) i) What are the reasons for the anomalous properties of Berylium ?
ii) Give any three properties of beryllium that are different from other
elements of the group
(OR)
b) Explain the characteristics of internal energy .
36.a) How will you determine the molar mass of solute from elevation of boiling point ?
(OR)

b) Define i) Bond length ii)Bond angle iii)Bond enthalpy

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 22

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11TH CHEMISTRY PUBLIC QUESTIONS

37.a) How will you determine the ionic character in covalent bond using electronegativity
values ?
(OR)
b) Give the IUPAC names of the following compounds .

n
l.i
da
V ) CH2 = CH – CH = CH2
ka
vi
al
38.a) How will you prepare the following compounds from benzene ?
i) nitrobenzene ii) benzene sulphonic acid iii) BHC
.k

(OR)
b) Simplest alkene (A) reacts with HCl to form compounds (B) .compounds (B) reacts with
w

ammonia to form compound (C) of molecular formula C2H7N. compounds (C) undergoes
w

carbylamines test. Identify (A),(B) and (C)


w

*********

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 23

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11TH CHEMISTRY PUBLIC QUESTIONS

Time allowed : 3.00hours Maximum marks : 70


July-2022
Part-I
Note : i) Answer all the questions.
ii) choose the most appropriate answer from the given four alternatives and

n
write the option code and the corresponding answer

l.i
CHOOSE THE BEST ANSWER 15 X 1 = 15

da
1. Total number of electrons present in 1.7 g of ammonia is :
6.022𝑋 10 22 6.022𝑋 10 24 6.022𝑋 10 23
a) 6.022 X 1023 b) c) d)
1.7 1.7 1.7

ka
2. The total number of orbitals associated with the principle quantum number n=3

a) 9 b) 8 c) 5
vi d) 7
3.Tritium is a ______ emitter
al
a) α b) β c) γ d) none of these
4._________ is used in devising photoelectric cells.
.k

a) Lithium b) Sodium c) Potassium d) Caesium


w

5. Aming the following the least thermally stable is :


a) K2CO3 b) Na2CO3 c) BaCO3 d) Li2CO3
w

6.If temperature and volume of an ideal gas is increased to twice its values, the initial
pressure P becomes :
w

a) 4P b) 2P c) P d) 3P
7.The amount of heat exchanged with the surrounding at constant pressure is
given by the quantity :
a) ΔE b) ΔH c) ΔS d) ΔG
8.If X is the fraction of PCl5 dissociated at equilibrium in the reaction
PCl5 PCl3 + Cl2
Then atarting with 0.5 mole of PCl5 , the total number of moles of reactants and products at
equilibrium is ;
a) 0.5-X b) X+ 0.5 c) 2X+0.5 d) X+1
9.Which one of the following binary liquid mixtures exhibit positive deviation
from Raoult‟s law ?
a) Acetone + Chloroform b) Water + Nitric acid
c) HCl + Water d) Ethanol +Water
10.The ratio of number of sigma ( ) and pi ( π) bonds in 2-butynal is :

8 5 8 9
a) b) c) d)
3 3 2 2

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 24

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11TH CHEMISTRY PUBLIC QUESTIONS

11.The IUPAC name of the com,pound

n
Is
a) 2-ethylbut-2-enoic acid b) 3-ethylbut-3-enoic acid

l.i
c) 3-ethylbut-2-enoic acid d) 2-ethylbut-3-enoic acid

da
12.Match the following
1) -NH2 i) Sulpho-
2) -CN ii) Formyl -

ka
3) -SO3H iii) Amino -
4) -CHO iv) Cyano -vi
a) 1)- i) , 2)- ii) , 3)- iii), 4)- iv) b) 1)- iv), 2)- iii) , 3)- ii) , 4)- i)
c) 1)- iii) , 2)- iv), 3)- i) , 4)- ii) d) 1)- iii), 2)- i) , 3)- iv), 4)- ii)
al
13.-I effect is not shown by
a) -CH2CH3 b) -F c) -Cl d) -NO2
.k

14. Identify the compound (A) in the following reaction :


w
w
w

15. Assertion : Increasing order of boiling points of halo alkanes are


CH3Cl < CH2Cl2 < CHCl3 < CCl4
Reason : The boiling points of halo alkanes increase with increase in the
number of halogen atoms
a) Assertion is true but reason is false
b) both assertion and reason are true and reason is the correct xplanation of
assertion
c) Both Assertion and reason are false
d) both assertion and reason are true and reason is not the correct explanation
of assertion

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 25

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11TH CHEMISTRY PUBLIC QUESTIONS

PART-II
Answer the following any six questions 6 X 2 = 12
16.What is meant by limiting reagents ?
17.State Heisenberg”s uncertainty principle

n
18.Give an example for ionic hydride and covalent hydride.

l.i
19.What is path function ? Give two examples .
20.Define reaction quotient

da
21.50g of tab water contains 20 mg of dissolved solids. What is the TDS val;ue in ppm?
22.How will you prepare ethane by Kolbe”s electrolytic method ?

ka
23.Mention any two methods of preparation of haloalkanes from alcohols.
24.If an automobile engine burns petrol at a temperature of 1089 K and if the surrounding
temperature is 294 K , calculate its maximum possible efficiency .
vi
PART-III
al
Answer the following any six questions 6 X 3 = 18
25.calculate the empirical formula of a compound containing 76.6% carbon, 6.38%,
.k

hydrogen and rest of oxygen.


26.compare the ionisation energy of beryllium and boron
w

27.Distinguish between diffusion and effusion.


28.At particular temperature Kc = 4X 10-2 for the reaction
w

1
H2S(g) H2(g) + S2(g)
2
w

Calculate Kc for each of the following reactions.


i) 2H2S(g) 2H2(g) + S2(g)
3
ii) 3H2S(g) 3H2(g) + S2(g)
2
29.What are the conditions when a solution tends to behavelike an ideal solution?
30.Describe fajan‟s Rule
31.Write short notes on hyper conjugation
32.Explain Brich reduction
33.Give an example for each of the following type of organic compounds
i) Non-benzonoid aromatic compound
ii) Aromatic heterocyclic compound
iii) carbocyclic compound

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 26

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11TH CHEMISTRY PUBLIC QUESTIONS

PART-IV
ANSWER ALL THE QUESTIONS 5 X 5 = 25
34. a) i) Describe about magnetic quantum number ?
ii) Give the electronic configuration of Mn2+ and Cr3+

n
(OR)

l.i
b) i) What are f-block elements ?
ii) State the trends in the variation of electronegativity in group and periods

da
35. a) Discuss the similarities between lithium and magnesium
(OR)

ka
b) i) Define entropy .Give its unit.
ii) List any three characteristics of gibbs free energy.

36. a) Derive KC and KP for synthesis of ammonia


vi
(OR)
al
b) Discuss the formation of C2 molecule using MO theory
.k
w

37. a) mention the shape of the following molecules based on VSPER theory
i) BF3 ii) BrF3 iii) PCl5 iv) SF6 v) IF7
w

(OR)
w

b) Describe any two types of constitutional isomers.

38. a) An organic compound (A) C2H4 decolourises bromine water. (A) on reaction with
chloride gives (B) . (A) reacts with HBr to give (C) . identify (A), (B) and (C) explain
the reactions.
(OR)
b) Starting from CH3MgI , how will you prepare the following ?
i) Acetaldehyde ii) Acetone iii) Methane

****************

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 27

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11TH CHEMISTRY PUBLIC QUESTIONS

n
l.i
da
ka
vi
al
.k

UNITWISE PUBLIC QUESTIONS


w
w
w

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 28

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11TH CHEMISTRY PUBLIC QUESTIONS

1.Basic Concepts Of Chemistry And Chemical Calculations

ONE MARKS ;-

n
1.which of the following compound has same percentage of carbon as that of ethylene
(C2H4) ? (mar 19)

l.i
a) benzene b) ethane

da
c) propene d) ethyne
2.The oxidation number of carbon in CH2F2 is ______ (jun19)
a) +4 b) -4

ka
c) 0 d)+2
3.The relative molecular mass of ethanol is ___ (sep20)
vi
a) 0.46g b) 4.6 g
al
c) 460g d) 46g
4. Which one of the following of presents 180g of water ? (sep21)
.k

6.022 X 10 24
a) moles of water b) 5 moles of water
180
c) 6.022 X 1024 moles of water
w

d) 90 moles of water
5.Which of the following compound(s) has/have percentage of carbon same as that in
w

ethylene (C2H4) ? (sep21)


a) benzene b) propene c) ethane d) ethyne
w

6. Total number of electrons present in 1.7 g of ammonia is : (jul22)


6.022𝑋 10 22 6.022𝑋 10 24 6.022𝑋 10 23
a) 6.022 X 1023 b) c) d)
1.7 1.7 1.7

2&3&5 MARKS :-
1.Calculate the equivalent mass of H2SO4 (mar 19).(ipn : 9)
2. calculate oxidation number of oxygen in H2O2 (mar 19). (ipn : 21)
3.A compound having the empirical formula C6H6O has the vapour density 47. Find its
molecular formula. (mar 19).(b/b-42) (ipn : 247)
4.What do you understand by the term mole ? (jun19)(b/b-27) (ipn : 6)
5.What are auto redox rections ? give an example .(jun19) (ipn : 23)
6.Define basicity.Find the basicity of ortho-phosphoric Acid.(sep20)
Basicity is no. of moles of ionisable H+ ions present in 1 mole of the acid
ortho-phosphoric Acid H3PO4 H3PO4 basicity = 3 eq mol-1

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 29

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11TH CHEMISTRY PUBLIC QUESTIONS

7.Calculate the empirical formula and molecular of a compound containing 76.6%


carbon,6.38% of hydrogen and rest oxygen. Its vapour density is 47. (sep20) (b/b-42)
(ipn : 247)
8.What is the empirical formula of the following ? (sep21)(b/b-38)

n
a) Fructose (C6H12O6) ii) Caffeine ( C8H10N4O2)

l.i
9. Distinguish between oxidation and reduction . (sep21) (b/b-30)

da
10..Define Gram equivalent mass (May22) (b/b-28) (ipn :8)
11.Calculate the oxidation number of underlined elements . (May22)

ka
i) CO2 ii) H2SO4
i) CO2 vi
x+2(o) = 0
al
x + 2(-2) = 0
.k

x-4 = 0
w

x = +4
w

oxidation number of carbon is +4


ii) H2SO4
w

2(H)+x +4(o) = 0
2(+1)+x +4(-2) = 0
2+x -8 = 0
x-6 = 0
x =+6
oxidation number of sulfur is +6
12.What is meant by limiting reagents ? (jul22) (ipn : 17)
13.calculate the empirical formula of a compound containing 76.6% carbon, 6.38%,
hydrogen and rest of oxygen. (jul22) (b/b-42) (ipn : 247)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 30

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11TH CHEMISTRY PUBLIC QUESTIONS

2.Quantum Mechanical Model Of Atom

ONE MARKS ;-
1.Splitting of spectral lines in an electric field is called _____ (mar 19)

n
a) Compton effect b) stark effect
c) Zeeman effect d) shielding effect

l.i
2.The energy of an electron in the third orbit of hydrogen atom is –E . The energy of an

da
electron in the first orbit will be _____ (jun19)
𝐸 𝐸
a) -3E b) - c) - d) -9E
3 9

ka
3.The maximum number of electrons that can be accommodated in L orbit is _____(sep20)
a) 8 b) 2 c) 4 vi d) 6
4.Splitting of spectral lines in an electric field is called : (May22)
a) Compton effect b) Zeeman effect
al
c) Stark effect d) Shielding effect
5. The total number of orbitals associated with the principle quantum number n=3 (jul22)
.k

a) 9 b) 8 c) 5 d) 7
2&3&5 MARKS :-
w

1.state and explaine pauli‟s exclusion principle. (mar 19).(b/b-31) (ipn :52 )
w

2. Write the de-broglie equation. (mar 19). (ipn : 40 )


3. Define orbital.What are the n and l values for 3px and 4dx2-y2 electron ? (jun19)
w

(b/b-32) (ipn : 44,257 )


4. calculate the uncertainty in the position of an electron, if the uncertainty in its velocity is
5.7 x 105 ms-1 (jun19) (ipn : 43,252 )EY :2
5.Calculate the orbital angular momentum for d and f orbital. ( jun19) (compulsory 2 mark)

Angular momentum = 𝑙(𝑙 + 1)
2𝜋
orbital angular momentum for d
l=2

= 2(2 + 1)
2𝜋

= 6
2𝜋
orbital angular momentum for f l=3

= 3(3 + 1)
2𝜋

= 12
2𝜋

=2 3
2𝜋

= 3
2𝜋

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 31

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11TH CHEMISTRY PUBLIC QUESTIONS

6.In degenerate orbitals, why do the completely filled and half filled configurations are more
stable than the partially filled configurations ? (sep20) (compulsory 2 mark)

The stability of exactly half-filled orbitals in degenerate orbitals is stronger than that of other
partially filled configurations. This can be explained using symmetry and the concept of

n
exchange energy . half and completely-filled subshells become more stable because of the

l.i
symmetrical distriburion of electron.
Reason :-

da
i) Symmetrical distribution of electron in orbital
ii) Exchange energy

ka
7.State Heisenber‟s Uncertainty Principle . (sep20) (ipn : 42 )
8.Calculate the total number of angular nodes and radial nodes present in 3d and 4f orbitals.
vi
(sep20) (b/b-28) (ipn : 257 )
9.What is exchange energy ? (sep21) (ipn :56 )
al
10.State Aufbau principle (sep21) (ipn : 52 )
.k

11.Write a note on principal quantum number (sep21) (ipn : 44 )


12.Calculate the maximum number of electrons that can be accommodated in L
w

shell(May22)
The maximum number of electrons that can be accommodated in a given
w

shell is 2n2.
w

L shell is n = 2
= 2 (2)2
=8
maximum number of electrons that can be accommodated in L shell = 8
13.How many orbitals are possible for n=4 ? (May22) (b/b-27)(ipn : 256 )
14. Write the electronic configuration and orbital diagram for nitrogen ? (May22) (ipn :54 )
15.State Heisenberg”s uncertainty principle (jul22) (ipn : 42 )
16. Describe about magnetic quantum number ? (jul22) (ipn : 45 )
17.Give the electronic configuration of Mn2+ and Cr3+ (jul22) (b/b : 39 )

Mn2+ 1s2 2s2 2p6 3s2 3p6 4s0 3d5


Cr3+ 1s2 2s2 2p6 3s2 3p6 4s0 3d3

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 32

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11TH CHEMISTRY PUBLIC QUESTIONS

3.Periodic Classification Of Elements

ONE MARKS ;-
1.The element with positive electron gain enthalpy is _____ (mar 19)

n
a) Argon b) Fluorine
c) Hydrogen d) sodium

l.i
2.The effective nuclear charge experienced by the d1 electron in the given electronic
configuration, (1s)2 (2s,2p)8 (3s,3p)8 (3d)1 (4s)2 is : (jun19)

da
a) 4 b) 3 c) 2.1 d) 6.9
3.Assertion : Helium has the highest value of ionisation energy among all the elements

ka
known.
Reason : Helium has the highest value of electron affinity among all the elements known.
vi
(sep20)
a) Both assertion and reason are false
al
b) Both assertion and reason are true and the reason is correct explanation for the
assertion
.k

c) Both assertion and reason are true but the reason is not the correct explanation for
w

the assertion
d) Assertion is true and reason is false .
w

2&3&5 MARKS :-
w

1.Explain diagonal relationship (mar 19) (b/b-41) (ipn : 90)


2.State and explain Dobereiner”s “triad” (mar 19) (ipn :69 )
3.Ionisation potential of nitrogen is greater than that of oxygen . explain by giving
appropriate reason. ( jun19)(b/b-44i) (ipn : 85 )
4.Give the general electronic configuration of lanthanides and actinides. ( jun19) (b/b-36)
(ipn :78 )
5.Derive ionic radius using pauling‟s method . (sep20) (b/b-39) (ipn : 83)
6. Explain why the electron affinity of Be and N is almost zero(sep20) (ipn : 86)
7.Define electronegativity. State the trends in the variation of electronegativity in
group and period (sep21) (b/b-47) (ipn :87,88 )
8.Define atomic radius. (sep21) (ipn : 79 )
9.Explain diagonal relationship (sep21) (ipn : 90 )
10.Define electron affinity (May22) (ipn : 86 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 33

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11TH CHEMISTRY PUBLIC QUESTIONS

11.Describe the pauling method for determination of ionic radius . (May22) (ipn : 83 )
12.What are f-block elements ? (jul22) (ipn : 78 )
13. State the trends in the variation of electronegativity in group and periods (jul22)
(b/b-47) (ipn :87,88 )

n
14. define valency (mar 19) (ipn :88 )

l.i
15.How will you determine the ionic character in covalent bond using electronegativity

da
values ? (May22)
Pauling estimated the percentage of ionic character in various Aδ- – Bδ+ polar covalent

ka
bonds from known (XA–XB) values and has derived the following
conclusions : vi
(i) When (XA–XB) = 1.7, the amount of ionic character in Aδ- – Bδ+ bond is 50%
al
and that of covalent character is also 50%. Thus A-B bond is 50% ionic and
50% covalent.
.k

(ii) When (XA–XB) < 1.7, the amount of ionic character in Aδ- – Bδ+ bond is less
w

than 50% and that of covalent character is more than 50%. Thus Aδ- – Bδ+
w

bond is predominantly covalent and hence is represented as A–B.


(iii) When (XA–XB) > 1.7, the amount of ionic character in Aδ- – Bδ+ bond is
w

more than 50% and that of covalent character is less than 50%. Hence Aδ- –
Bδ+ bond is predominantly ionic and hence is represented as A– B+

16.compare the ionisation energy of beryllium and boron (jul22) (ipn : 85 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 34

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11TH CHEMISTRY PUBLIC QUESTIONS

4.Hydrogen
ONE MARKS ;-
1.What percentage of solution of H2O2 is called as “100-volume‟ H2O2 ? (mar 19)
a) 15% b) 50%
c) 20% d) 30%

n
2.The type of H-bonding present in orthonitro phenol and p-nitro phenol are ______

l.i
Respectively. (jun19)
a) Inter molecular H-bonding and intra molecular H-bonding

da
b) Intra molecular H-bonding and inter molecular H-bonding
c) Intra molecular H-bonding and no H-bonding
d) Intra molecular H-bonding and intra molecular H-bonding

ka
3.Intra molecular hydrogen bonding is present in________ (sep20)
a) Ortho-nitro phenol b) Ice
c) Water vi d) Hydrogen fluoride
4.Assertion ; permanent hardness of water is removed by treatment with washing soda
al
Reasons : Washing soda reacts with soluble calcium and magnesium chloride and sulphate
in hard water to form insoluble carbonates. (sep21)
.k

a) Assertion is true but reason is false


b) Both assertion and reason are true and reason is the correct explanation of assertion
w

c) Both assertion ans reason are false


d)Both assertion and reason are true but reason is the correct explanation of assertion
w

5.Tritium nucleus contains : (May22)


w

a) 1p+2n b) 1p+on
c) 1p+1n d) 2p+1n
6.Tritium is a ______ emitter(jul22)
a) α b) β c) γ d) none of these
2&3&5 MARKS :-
1.How is Tritium prepared ? (mar 19)(ipn : 104 )
2. complete the following equation (ipn : 111 )
Na2O2 + ?  Na2SO4+ H2O2 (mar 19)
3.What is syn gas ? How it is prepared ? ( jun19) (ipn :103 )
4.Why hydrogen peroxide is stored in plastic bottle containers not in glass container ?
(jun 19) (ipn : 112 )
5.Write the exchange reactions of Deuterium. (sep20) (ipn : 105 )
6.How do you convert para hydrogen into ortho hydrogen. (sep20) (ipn : 102 )
7.Write the laboratory method of preparation of hydrogen . (sep20) (ipn : 103 )
8.How do you convert para hydrogen into ortho hydrogen ? (sep21) (ipn : 102 )
9.Mention the three types of covalent hydrides . (May22) (ipn : 113 )
10.Give an example for ionic hydride and covalent hydride. (jul22) (ipn : 113 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 35

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11TH CHEMISTRY PUBLIC QUESTIONS

5.Alkali And Alkaline Earth Metals


ONE MARKS ;-
1.Find A in the following reaction CaO + 3C A + CO (mar 19)
a) CaC2 b) CO2 c) Ca d) Ca2O

n
2. which compound is named as “blue john” among the following compounds ? (mar 19)
a) Ca3(PO4)2 b) CaO c) CaH2 d) CaF2

l.i
3.When CaC2 is heated in atmospheric nitrogen in an electric furnace, the compound formed
is __________ (jun19)

da
a) Ca(CN)2 b) CaNCN c) CaC2N2 d) CaNC2
4.Formula of Gypsum is ________ (sep20)

ka
1
a) CaSO4 b) CaSO4.2H2O c) CaSO4. H20 d) CaSO4. H20
2
5.Flame colour of potassium salts in bunsens burner (sep21)
vi
a) Lilac (violet ) b) crimson red c) Apple green d) yellow
6. Formula of plaster of paris (sep21)
al
𝟏
a) 3CaSO4.H2O b) CaSO4.2H2O c) 2CaSO4.2H2O d) CaSO4. H2O
𝟐
.k

7.Spodumene is the mineral source for which of the following alkali metal ? (May22)
a) Lithium b) Sodium c) Rubidium d) Potassium
w

8.Which of the following has highest hydration energy ? (May22)


a) BaCl2 b) MgCl2 c) SrCl2 d) CaCl2
w

9._________ is used in devising photoelectric cells. (jul22)


a) Lithium b) Sodium c) Potassium d) Caesium
w

10. Among the following the least thermally stable is : (jul22)


a) K2CO3 b) Na2CO3 c) BaCO3 d) Li2CO3
2&3&5 MARKS :-
1.Explain why Ca(OH)2 is used in white washing . (mar 19) (ipn : 145 )
2.Among the alkaline earth metals BeO is insoluble in
water but other oxides are soluble .why ? (mar 19) (ipn : 142 )
3.Write any two similarities between beryllium and aluminium ( jun19). (ipn : 140 )
4.Among the alkali metal halides, which is covalent ? explain with reason. ( jun19)(ipn:130)
5.why blue colour appears during the dissolution of alkali metals in liquid ammonia
(jun19) (ipn : 130 )
6.How is bleaching powder prepared ? (sep20) (ipn :145 )
7.Write the uses of magnesium. (sep20) (ipn : 141)
8. Discuss the similarities between beryllium and aluminium (sep21) (ipn : 140 )
9. What are the reasons for the anomalous properties of Berylium ? (May22) (ipn : 139)
10. Give any three properties of beryllium that are different from other elements of the
group (May22) (ipn : 139 )
11. Discuss the similarities between lithium and magnesium (jul22) (ipn :129 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 36

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11TH CHEMISTRY PUBLIC QUESTIONS

6.Gaseous State
ONE MARKS ;-
1.use of hot air ballone in meteorological observatory is an (mar 19)
application of________
a) Kelvin‟s Law b) Brown‟s Law

n
c) Boyle’s Law d) Newton‟s Law

l.i
2.When an ideal gas undergoes unrestrained expansion, no cooling occurs because the
molecules ________ (jun19)

da
a) are above the inversion temperature b) exert no attraction force on each other
c) do work equal to the loss in kinetic energy d) collide without loss of energy
3.Gases tent to behave ideally only at _____ (sep20)

ka
a) Low temperature and low pressure b) High temperature and High pressure
c) High temperature and low pressure d) Low temperature and High pressure
4. Rate of diffusion of a gas is : (sep21)
vi
a) directly proportional to the square root of its molecular weight
al
b) directly proportional to its density
c) inversely proportional to the square root of its molecular weight
.k

d) directly proportional to its molecular weight


5.7.5 g of a gas occupies a volume of 5.6 L at 00C and 1 atm pressure .The gas is (May22)
w

a) CO b) NO c) CO2 d) N2O
6.A bottle ao ammonia and a bottle of HCl connected through a long tube are opened
w

simultaneously at both ends. The white ammonium chloride ring will be first formed :
(May22)
w

a) near the ammonia bottle b) at the centre of the tube


c) throughout the length of the tube d) near the hydrogen chloride bottle
7.If temperature and volume of an ideal gas is increased to twice its values, the initial
pressure P becomes : (jul22)
a) 4P b) 2P c) P d) 3P
2&3&5 MARKS :-
1.what are ideal gas ? (mar 19) (ipn : 169 )
2. State Diffusion law. (mar 19) (ipn : 168 )
3.What is inversion temperature ? ( jun19) (ipn : 175)
4.Derive ideal gas equation. ( jun19) (ipn : 165 )
5.what is boyle‟s temperature ? .what happens to real gases above and below the boyle‟s
temperature ? ( jun19) (ipn : 171 )
6.Write the mathematical formula for compressibility factor „Z‟ (sep20) (ipn : 169 )
7. Name the different methods of liquefaction of gases. (sep20) (ipn : 175 )
8.Inside a certain automobile engine , the volume of air in a cylinder is 0.375 dm3 ,
when the pressure is 1.05atm . When the gas is compressed to a volume of 0.125 dm3
at the same temperature , What is the pressure of the compressed air ? (sep21)
(ipn :162-268) (compulsory 3 mark)
9.State Dalton Law of partial pressures. (May22) (ipn : 166 )
10.Distinguish between diffusion and effusion. (jul22) (ipn : 168 )
S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 37

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11TH CHEMISTRY PUBLIC QUESTIONS

7.Thermodynamics

ONE MARKS ;-
1.The SI unit of molar heat capacity is : ______ (mar 19)

n
a) JK-1 mol-1 b) KJ mol-1 c) Kj mol-1 d) cm
2.Among the following statements, which one is /are correct ? (jun19)

l.i
i) During cyclic process the amount of heat absorbed by the surrounding is equal to
work done on the surrounding

da
ii)Refractive index is an example for intensive property
iii) If the enthalpy change of a process is positive then the process is spontaneous
iv) The entropy of an isolated system increases during spontaneous process

ka
a) (i), (ii), (iii) b) (i), (iv) c) (ii), (iv) d) (ii) only
3.Among the following which is the path function ? (sep20)
vi
a) G b) U c) H d) q
4. Heat of combustion is always : (sep21)
al
a) zero b) positive
c) either positive or negative d) negative
.k

5.The intensive property among the quantities below is : (May22)


𝒎𝒂𝒔𝒔
a) Enthalpy b) mass c) d) volume
w

𝒗𝒐𝒍𝒖𝒎𝒆
6.The amount of heat exchanged with the surrounding at constant pressure is given by the
w

quantity : (jul22)
a) ΔE b) ΔH c) ΔS d) ΔG
w

2&3&5 MARKS :-
1.state the third law of thermodynamics (mar 19) b/b-42 (ipn : 218 )
2.calculate the entropy change during the melting of one mole of ice into water at 00c.
enthalpy of fusion of ice is 6008 J mol-1. (mar 19) (ipn : 213 )
3.C(s) + O2(g)  CO2(g) Calculate the standard entropy change for the above reaction, given
the standard entropies of CO2(g), C(s), O2(g) are 213.6,5.740 and 205 jk-1 respectively.
(mar19) (ipn : 212 )
4.Define molar heat capacity. Give its unit. ( jun19) b/b-34(ipn : 201 )
5. How do you measure heat changes at constant pressure ? ( jun19) (ipn : 204 )
6.state zeroth Law of Thermodynamics. (sep20) (ipn :195 )
7.Distinguish between extensive and intensive property. (sep20) (ipn : 189 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 38

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11TH CHEMISTRY PUBLIC QUESTIONS

8.Derive the relation between enthalpy ΔH and internal energy ΔU for an


ideal gas. (sep20) (ipn : 197 )
9. Calculate the entropy change during the melting of one mole of ice into water at 0 0c and

n
1 atm pressure. Enthalpy of fusion of ice is 6008J mol-1 (sep20) (ipn : 213 )

l.i
10.Define Hess‟s law of constant heat summation. (sep21) (ipn : 207 )

da
11.Give any two characteristics of gibbs free energy ? (sep21) (b/b-52)
12. State the first law of thermodynamics (sep21) (ipn : 195 )

ka
13. What are the conditions for the spontaneity of a process? (sep21) (ipn : 215 )
14.What are the condition for the spontaneity of a process (May22) (ipn : 215 )
vi
15.Explain sign convention of heat (May22) (ipn : 192 )
al
16. Explain the characteristics of internal energy . (May22) (ipn : 191 )
17.What is path function ? Give two examples . (jul22) (ipn : 191 )
.k

18.If an automobile engine burns petrol at a temperature of 1089 K and if the surrounding
w

temperature is 294 K , calculate its maximum possible efficiency . (jul22)


w

(ipn : 211 ) (compulsory 2 mark)


w

19.Define entropy .Give its unit. (jul22) (ipn : 210,211 )


20. List any three characteristics of gibbs free energy. (jul22) (b/b-52)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 39

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11TH CHEMISTRY PUBLIC QUESTIONS

8.Physical And Chemical Equilibrium


ONE MARKS ;-
1.When Δng is negative in chemical equilibrium reaction then (mar 19)
a) Kp<Kc b) Kp=1/Kc c) Kp=Kc(RT)-ve d) Kp > Kc
-5 -4

n
2.If kb and kf for a reversible reaction are 0.8 x 10 and 1.6x 10 respectively ,the value of
equilibrium constant is _______ (jun19)

l.i
a) 20 b) 0.2 x10-1 c) 0.05 d) 0.2
3.Which of the following is incorrect statement ? (sep20)

da
a) Equilibrium constant varies with temperature
b) For a system at equilibrium ,Q is always less than the equilibrium constant
c) Equilibrium can be attained from either side of the reaction

ka
d) Presence of catalyst affects both the forward reaction and reverse reaction to the same
extent.
vi
4. For the following reversible rections at equilibrium A + B C. If the
concentration of the reactants A and B are doubled, then the equilibrium constant will :
al
(sep21)
a) be halved b) be doubled
.k

c) remain the same d) become one fourth


5. Which one of the following is incorrect statement ?(may22)
w

a) Presence of catalyst affects both the forward reaction and reverse reaction
to the same extent.
w

b) for a system at equilibrium Q is always less than the equilibrium constant


c) equilibrium constant varies with temperature
w

d) equilibrium can be attained from either side of the reaction


6.If X is the fraction of PCl5 dissociated at equilibrium in the reaction
PCl5 PCl3 + Cl2
Then Starting with 0.5 mole of PCl5 , the total number of moles of reactants and products
at equilibrium is ; (jul22)
a) 0.5-X b) X+ 0.5 c) 2X+0.5 d) X+1

2&3&5 MARKS :-
1.Define –Le-Chatelier principle. (mar 19) b/b-32(ipn : 16 )
[𝐶𝑎𝑂 (𝑆) ][𝐶𝑂2(𝑔) ]
2.Write the balanced chemical equation for the Kc= (mar 19) (ipn : 8 )
[𝐶𝑎𝐶𝑂 3(𝑔) ]

CaCO3 CaO + CO2


3.What is the effect of added inert gas on the rection at equilibrium ? (jun19)b/b-38(ipn :19 )
4.Derive the relation between kp and kc for a general homogeneous gaseous reaction.
(jun19)b/b-39 (ipn :6 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 40

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11TH CHEMISTRY PUBLIC QUESTIONS

5.Explain homogeneous and heterogeneous equilibria. (sep20) (ipn : 5 )


6. Define reaction quotient. (sep20) (ipn : 11 )
7.What is the relation between KP and KC ? Give one example for which KP is equal
to KC. (sep21) b/b- 28(ipn : 7 )

n
8.What are homogeneous and heterogeneous equilibria? Give example (sep21) (ipn :5 )

l.i
9.Give a balanced chemical equation for the equilibrium reaction for which the equilibrium

da
[𝑁𝐻3 ]4 [𝑂2 ]5
constant is given by expression Kc = (May22) b/b-37 (ipn : 295)
[𝑁𝑂]4 [𝐻2 𝑂]6

ka
4NO + 6H2O 4NH3 + 5O2
vi
10.The equilibnrium concentrations of NH3 and N2 and H2 are 1.8 x10-2M , 1.2x10-2M and
al
3x 10-2 M respectively. Calculate the equilibrium constant for the formation of NH3 from
.k

N2 and H2 (May22) (ipn :15 ) (compulsory 3 mark)


w

11.Define reaction quotient (jul22) (ipn : 11)


12.At particular temperature Kc = 4X 10-2 for the reaction (jul22) (b/b-44 ) (ipn : 295)
w

1
H2S(g) H2(g) + S2(g)
w

Calculate Kc for each of the following reactions.


i) 2H2S(g) 2H2(g) + S2(g)
3
ii) 3H2S(g) 3H2(g) + S2(g)
2

13. Derive KC and KP for synthesis of ammonia (jul22) (ipn : 14 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 41

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11TH CHEMISTRY PUBLIC QUESTIONS

9.Solutions
ONE MARKS ;-
1.osmotic pressure ( π) of a solution is given by the relation __ (mar 19)
a) π rt=n b) V= π nRT
c) π= n RT d) π V=nRT

n
2.Assertion : Mixture of carbon tetrachloride and chloroform show positive deviation from

l.i
raoult‟s law
Reason : In the mixture the inter molecular force of attraction between chloroform and

da
carbon tetrachloride is weaker than those between molecules of carbon
tetrachloride and chloroform molecules. (jun19)
a) Both assertion and reason are correct and reason is the correct explanation of

ka
assertion
b) Both assertion and reason are correct and reason is not the correct explaination for
assertion vi
c) Both assertion and reason are false
d) Assertion is true , but reason is false
al
3.osmotic pressure (π) of a solution is given by the relation (sep20)
.k

a) π RT=n b) π= n RT
c) π V=nRT d) None of these
w

4.The molality of a solution containing 1.8g of glucose dissolved in 250g of water is (sep21)
a) 0.02M b) 0.2M c) 0.04M d) 0.01M
w

5.Equimolal aqueous solutions of NaCl and KCl are prepared . If the freezing point of NaCl
is -20c , the freezing point of KCl solution is expected to be (May22)
w

a) -10C b) -20C
c) 00C d) -40C
6.Which one of the following binary liquid mixtures exhibit positive deviation from Raoult‟s
law ? (jul22)
a) Acetone + Chloroform b) Water + Nitric acid
c) HCl + Water d) Ethanol +Water

2&3&5 MARKS :-
1.State the term “isotonic solution” (mar 19)(b/b-37) (ipn : 56)
2. NH3 and HCl do not obey Hentry‟s law. Why ? (mar 19) (ipn : 40)
3.What is vapour pressure of a liquid ? what is relative lowering of vapour
pressure ?(jun19) (b/b-32 )
4.What is the mass of glucose (C6H12O6) in it one litre solution which is isotonic with 6gl-
1 of urea (NH2CONH2) ? ( jun19) (ipn : 57,299)ey-13

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 42

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11TH CHEMISTRY PUBLIC QUESTIONS

5. Draw and explain the graph obtained by plotting solubility versus temperature for calcium
chloride . ( jun19) (ipn : 37)
6.Calculate the mole fraction of methanol and water when 0.5 mole of methanol is mixed

n
with 1.5 moles of water. (ipn : 33) (SEP20)

l.i
7.What is van‟t hoff factor „i‟ ? (sep20) (ipn : 58)

da
8.What is molal depression constant ? (sep21) (ipn : 54)
9.What are ideal solutions ? Give example (sep21) (ipn :46 )

ka
10.How will you determine the molar mass of a solute from osmotic pressure ?
(sep21)(ipn:56 ) vi
11.Define the term “isotonic” solution . (May22) b/b-37(ipn :56 )
al
12.Write the formula to calculate the molar mass of a solute from realative lowering of
vapour pressure values. (May22) (ipn : 50 )
.k

13. How will you determine the molar mass of solute from elevation of boiling point ?
w

(May22) (ipn :53 )


w

14.50g of tab water contains 20 mg of dissolved solids. What is the TDS val;ue in ppm?
w

(jul22) (ipn :34 )


15.What are the conditions when a solution tends to be have like an ideal solution?
(jul22) (ipn : 46 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 43

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11TH CHEMISTRY PUBLIC QUESTIONS

10.Chemical Bonding
ONE MARKS ;-
1.which of the following molecule does not contain π bond ? (mar 19)
a) CO2 b) H2O
c) SO2 d) NO2

n
2.Shape and hybridation of IF5 are : (jun19)

l.i
a) Trigonal bipyramidal sp3d2 b) Trigonal bipyramidal sp3d
c) Square pyramidal sp3d2 d) Octahedral, sp3d2

da
3.Match the following (sep21)
1) N2 molecule i) chemical bond
2) BF3 molecule ii) Trible covalent bond

ka
3) HF molecule iii) Electron deficient molecule
4) NaCl iv) polar covalent bond
vi
a) 1)- iii) , 2)- i) , 3)-iv) , 4)- ii) b) 1)-ii) , 2)- iv) , 3)-i) , 4)- iii)
c) 1)- i) , 2)- iv) , 3)- ii) , 4)- iii) d) 1)- ii) , 2)-iii) , 3)- iv) , 4)- i)
al
4.Which one of the following is diamagnetic ? (May22)
.k

a) O22- b) O2+
c) O2 d) None of these
w

5.The ratio of number of sigma ( ) and pi ( π) bonds in 2-butynal is : (jul22)


𝟖
w

5 8 9
a) b) c) d)
𝟑 3 2 2
w

2&3&5 MARKS :-
1.what is called bond length ? name the techniques through which the length of a bond can
be determined . (mar 19) ( ipn ; 76)
2. Write the structure of the following compounds. (mar 19) ( ipn ; 82,83 )
A) NH3 B) BF3
3.Both C2H2 and CO2 have the same structure. Explain why. (MAR19)
 C2H2 and CO2 has sp hybridisation linear structure
 The linear structure of ethyne and that of carbon dioxide is explained on the basis of
hybridisation.
 Ethyne molecule is formed when both the carbon atoms undergo sp hybrisation and
have two unhybridised orbitals (2py and 2px)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 44

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11TH CHEMISTRY PUBLIC QUESTIONS

4.Linear form carbon dioxide molecules has two polar bonds .yet the molecule has zero
dipole moment. Why ? ( jun19) b/b-40 ( ipn ; 80 )
5.Draw the M.O diagram for oxygen molecule . calculate its bond order and magnetic
character. ( jun19) ( ipn ; 100 )

n
6.Calculate the formal charge on carbon and oxygen for the following structure

l.i
( jun19) ( ipn : 72)

da
7.Write the shape and molecular geomentry for BF3 (sep20) ( ipn : 91 )
8.What is hybridisation ? mention the type of hybridization found in CH4 (sep20) ( ipn : 92 )

ka
9.Write any four postulates of molecular orbital theory. (sep20) ( ipn : 97)
vi
10.Give the shapes of molecules predicted by VSEPR theory (sep21) ( ipn :82,83,83 )
al
a) BeCl2 b) NH3 c) H2O
.k

11.Define Bond Order. (sep21) ( ipn : 76 )


12.What are the salient features of VB theory ? (sep21) ( ipn : 86 )
w

13.Explain the formation of H2 molecule using MO-theory (sep21) ( ipn : 99 )


w

14.What is resonance ? (sep21) ( ipn :78 )


w

15.Describe the formation of HF molecule by orbital overlap. (May22) ( ipn :88 )


16.Define i) Bond length ii)Bond angle iii)Bond enthalpy . (May22) ( ipn : 76,77)
17.Describe fajan‟s Rule (jul22) ( ipn : 81 )
18. Discuss the formation of C2 molecule using MO theory (jul22) ( ipn : 100 )
19.mention the shape of the following molecules based on VSPER theory (jul22)
i) BF3 ii) BrF3 iii) PCl5 iv) SF6 v) IF7 ( ipn : 82,83,83,84,84 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 45

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11TH CHEMISTRY PUBLIC QUESTIONS

11.Fundamentals Of Organic Chemistry


ONE MARKS ;-
1.many of the organic compounds are inflammable because of Its_______ (mar 19)
a) vander waal‟s force b) co-ordinate nature
c) covalent nature d) ionic nature

n
2.Which of the following is optically active ? (jun19)

l.i
a) 3-chlolro pentane b) 2-chloro propane
c) meso-tartaric acid d) glucose

da
3.Write the IUPAC name of (sep20)

ka
a) 1-formyl propanol b) 1-hydroxy butanal
c) 2-hydroxy butanal d) 3- hydroxyl butanal
vi
4.The structure of isobutyl group in organic compound (sep21)
al
a) b)
.k
w

c) d)
w

5.Which of the following is optically active ? (sep21)


a) meso-tartaric acid b) 3-chloropentane
w

c) glucose d) 2-chloropropane
6.Which of the following is aliphatic saturated hydrocarbon ? (May22)
a) C9H18 b) C8H14 c) C8H18 d) All of the above
7.match of following (May22)
1) –NO2 i) propyl
2)-OCH3 ii) Amino
3)-CH2-CH2-CH3 iii)Methoxy
4) –NH2 iv) Nitro
a) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) b) (1)- (iii), (2)-(iv) , (3)-(i), (4)-(ii)
c) (1)- (iv), (2)-(iii) , (3)-(i), (4)-(ii) d) (1)- (ii), (2)-(i) , (3)-(iv), (4)-(iii)

8. (May22)

a) optical isomers b) resonating structures


c) conformers d)tautomers

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 46

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11TH CHEMISTRY PUBLIC QUESTIONS

9.The IUPAC name of the compound (jul22)

Is
a) 2-ethylbut-2-enoic acid b) 3-ethylbut-3-enoic acid
c) 3-ethylbut-2-enoic acid d) 2-ethylbut-3-enoic acid

n
10.Match the following (jul22)

l.i
1) -NH2 i) Sulpho-
2) -CN ii) Formyl -

da
3) -SO3H iii) Amino -
4) -CHO iv) Cyano -

ka
a) 1)- i) , 2)- ii), 3)- iii , 4)- iv) b) 1)- iv , 2)- iii) , 3)- ii) , 4)- i)
c) 1)- iii), 2)- iv), 3)- i) , 4)- ii) d) 1)- iii), 2)- i) , 3)- iv) , 4)- ii)
2&3&5 MARKS :- vi
1.Describe the reaction involved in the detection of nitrogen in an organic compound by
lassaigne method. (mar 19) (ipn : 138)
al
2.which is the suitable method for detection of nitrogen present in food and fertilizers?
.k

(compulsory 2 mark) (mar 19) (ipn :147 )


This method is carried much more easily than the Dumas method. It is used largely in the
w

analysis of foods and fertilizers. Kjeldahls method is based on the fact that when an organic
compound containing nitrogen is heated with Conc. H2SO4, the nitrogen in it is
w

quantitatively converted to ammonium sulphate.


w

3.Give the structural formula for the following compounds. (mar 19) (compulsory 3 mark)
a)m-dinitrobenzene b)p-dichlorobenzene c)1,3,5,Tri-methyl Benzene

4.Identify the cis and trans isomers for the following compounds (mar 19)
a) b)

TRANS CIS
5.Write the IUPAC names for the following compounds. (mar 19)

(A) (B)
2-methyl butane 2,2-dimethyl propane

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 47

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11TH CHEMISTRY PUBLIC QUESTIONS

6. Write any two different components you get during fractional distillation of coal tar at any
two different temperatures. (mar 19)
S.NO Name of the fraction Temperature range Name of the components
1 Crude tight oil 350-443k Benzene, toluene,xylene
2 Middle oil 443-503k Phenol,naphthalene

n
3 Heavy oil 503-543k Napththalene,cresol

l.i
4 Green oil 543-633k Antharacene
5 Pitch Alone 633k residue

da
7.How do you detect the presence of nitrogen and sulphur together in an organic

ka
compounds ? ( jun19) (ipn : 139)
8.explain a suitable method for purifying and separating liquids present in a mixture having
vi
very close boiling point. ( jun19) (ipn : 150) (fractional distillation )
9. Write the IUPAC names for the following compounds : ( jun19)
al
.k

(x) (Y) (Y)


5-oxohexanoic acid 4-chloro pent-2-yne 2-ethoxy propane
w

10.Explain geometrical isomerism in 2-butene. (sep20) (ipn :135 ) (compulsory 3 mark)


w

11. Explain the purification of a solid organic compound by crystallization


w

method (sep20) (ipn : 149 )


12.Give the general formula for the following class of organic compounds (sep21)
a) Alkanes b) Alkenes c) Alkynes
CnH2n+2 CnH2n CnH2n-2
13.What is meant by homologous series ? (sep21) (ipn : 112)
14.Give the structure for the following compounds . (sep21)
1) 3-methylpentane
2) 2-methylpropan-2-ol
3) Propanone
3-methylpentane 2-methylpropan-2-ol Propanone

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 48

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11TH CHEMISTRY PUBLIC QUESTIONS

15.What is meant by optical isomerism ? (May22) (ipn : 137 )


16.Give the IUPAC names of the following compounds . (May22)

2-bromo-3-methylbutane

n
methoxymethane

l.i
da
2-hydroxybutanal

ka
4-chloropent-2-yne
vi
v) CH2 = CH – CH = CH2 1,3-butadiene
al
17.Which element exhibits maximum catenation and why ? (ipn : 110)
.k

18.Give an example for each of the following type of organic compounds (jul22)
(compulsory 3 mark)
w

i) Non-benzonoid aromatic compound


w
w

azulene
ii) Aromatic heterocyclic compound

iii) carbocyclic compound

cyclopropane

19. Describe any two types of constitutional isomers. (jul22) (ipn : 132)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 49

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11TH CHEMISTRY PUBLIC QUESTIONS

12.Basic Concepts Of Organic Reactions

ONE MARKS ;-
1.Which of the following species does not exert a resonance effect ? (mar 19)

n
a) C6H5NH2 b) C6H5NH3+ c) C6H5OH d) C6H5Cl

l.i
2.Which of the following species is not electrophile in nature ? (jun19)

da
a) Cl+ b) BH3 c) H3O+ d) +NO2
3.Which of the following is electron deficient ? (sep20)

ka
a) NH3 b) PH3 c) (CH3)2 d) BH3
4.The geometrical shape of carbocation is (sep21) vi
a) planar b) linear c) pyramidal d) tetrahedral
al
5.The correct relative order of +I effect of alkyl groups is : (May22)
a) -C(CH3)3>-CH(CH3)2>-CH2CH3>-CH3 b) –CH3>-CH2CH3>-CH(CH3)2>-C(CH3)3
.k

c) -CH2CH3>-CH3>-C(CH3)3>-CH(CH3)2 d) –CH(CH3)2>-C(CH3)3>-CH2CH3>-CH3
w

6.-I effect is not shown by (jul22)


w

a) -CH2CH3 b) -F c) -Cl d) -NO2


w

2&3&5 MARKS :-
1. Explain with example the positive mesometric effect. (mar 19) ( ipn : 169 )
2. What are nucleophiles and electrophiles ? give one example each (mar 19) ( ipn : 164 )

3. (mar 19) ( ipn : 174 )

Amide carboxylic acid


4.The bond length between all the four carbon atoms is same in 1,3-butadiene. Explain
(compulsory 3 mark) ( jun19) ( ipn : 168 )
1,3-butadiene is a conjugated molecule with four overlapping p-orbital on adjacent
atoms,and a electrons are delocalised over four atoms. This shortens the bond length of
central c bond thus, the bond length between all the four-c- atoms are same in 1,3-butadiene

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 50

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11TH CHEMISTRY PUBLIC QUESTIONS

5. explain about inductive effect . ( jun19) ( ipn : 166 )


6.Write the no bond resonance structure shown by propene (sep20) ( ipn : 170 )
7.Give any three differences between nucleophiles and electrophiles. (May22) ( ipn : 164 )
8. complete ( ipn : 173,173,173,173 )

n
l.i
A) (sep20)

da
ka
B) H2C=CH2 + H-Br

C) CH3CHO
vi
al
.k
w

D)
w

9.Write short notes on hyper conjugation (jul22) ( ipn : 170 )


w

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 51

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11TH CHEMISTRY PUBLIC QUESTIONS

13.Hydrocrbons
ONE MARKS ;-
1.______group is ortho para directing and deactivating group (jun19)
a) amino b) methyl

n
c) halogen d) aldehyde

l.i
2.Cold dilute alkaline KMnO4 is known as ______ (sep20)

da
a) Schiff”s reagent b) Fenton”s reagent
c) Tollen‟s reagent d) Baeyer’s reagent

ka
3.n-propyl bromide on rection with alcoholic KOH gives (sep20)

a) Butyl alcohol
vi b) Propene
c) Butene d) Propyl alcohol
al
4.An alkene is obtained by decarboxylation of sodium propionate.same alkene can be
.k

prepared by : (sep21)
w

a) reduction of 1-chloro propane b) catalytic hydrogenation of propene


c) reduction of bromo methane d) action of sodium metal on iodomethane
w

5. Identify the compound (A) in the following reaction : (jul22)


w

2&3&5 MARKS :-
1.How will you get the following products with the given reactants ? (mar 19)
A)Acetylene  Benzene (ipn :204 )
B)Phenol  Benzene (ipn : 210 )
C)Benzene Tolune (ipn : 210 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 52

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11TH CHEMISTRY PUBLIC QUESTIONS

2.The simple aromatic hydrocarbon compound (A) reacts with bromine to give (B).
compound (A) reacts with Raney Ni and gives (C). Identify (A) , (B) and (C).(MAR19)

n
l.i
da
ka
vi
al
S.NO COMPOUNDS FORMULA NAME
.k

1 A C6H6 Benzene
w

2 B C6H5-Br bromobenzene
w

3 C C6H12 cyclohexane
w

3.What happens when acetylene undergoes ozonolysis ? ( jun19) (ipn : 203 )


4.What is polymerisation ? explain the two types of polymerisation rection of acetylene .
( jun19) (ipn : 204 )
5. What do you mean by conformation ? Explain about staggered conformation in ethane .
( jun19) (ipn : 187 )
6. An organic compound (A) of molecular formula C2H6O, on heating with conc.H2SO4
gives compound (B) . (B) on treating with cold dilute alkaline KMnO4 gives compound
. Identify (A), (B) and (C) and explain the reactions.(JUN19)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 53

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11TH CHEMISTRY PUBLIC QUESTIONS

n
l.i
S.NO COMPOUNDS FORMULA NAME

da
1 A C2H5OH Ethanol

ka
2 B CH2 = CH2 Ethene

3 C HO-CH2-CH2-OH
vi Ethane-1,2-diol
al
7.Explain the different types of polymerisation in ethyne. (sep20) (ipn : 204 )
.k

8. write Brich reduction . (sep20) (ipn : 215 )


9.Complete the following : (sep21) (compulsory 2 mark)
w
w

a) CH3-CH=CH2 + H2 CH3-CH2-CH3
w

Propane

b) CH3MgCl + H2O CH4 + Mg(OH)Cl

methane

10.Suggest a simple chemical test to distinguish propane and propene (sep21) (b/b-39 )

11.How does Huckel rule help to decide the aromatic character of a compound?
(sep21)(ipn : 205 )
12.Write the rection for conversion of acetylene to benzene. (sep21) (ipn : 210 )
13.How will you convert ethyl chloride to ethane ? (May22)
Zn/HCl [H]
CH3-CH2-Cl CH3-CH3 + HCl
ethyl chloride ethane

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 54

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11TH CHEMISTRY PUBLIC QUESTIONS

14.what happens when ethylene is passed through cold dilute alkaline potassium
permanganate ? (May22) (ipn : 198 )
15. How will you prepare the following compounds from benzene ? (May22)
(ipn : 211,212,215 )

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i)nitrobenzene ii)benzene sulphuric acid iii)BHC

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16.How will you prepare ethane by Kolbe”s electrolytic method ? (jul22) (ipn :201 )

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17.Explain Brich reduction (jul22) (ipn : 215 )
18. An organic compound (A) C2H4 decolourises bromine water. (A) on reaction with

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chloride gives (B) . (A) reacts with HBr to give (C) . identify (A), (B) and (C) explain
the reactions. (jul22) vi
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S.NO COMPOUNDS FORMULA NAME

1 A CH2 = CH2 Ethene

2 B Cl-CH2-CH2-Cl 1,2-dichloroethane

3 C CH3-CH2-Br bromoethane

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 55

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11TH CHEMISTRY PUBLIC QUESTIONS

14.Haloalkanes And Haloarenes


ONE MARKS ;-
1.match the following (mar 19)
Compound uses
1)Chloro picrin i) detection of primary amine

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2)Methyl isocyanide ii) DDT

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3)Chlolro benzene iii) paint remover
4)Meythylene chlorine iv) soil sterilizer

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a) (1)- (iv), (2)-(iii) , (3)-(ii), (4)-(i) b) (1)- (iii), (2)-(iv) , (3)-(ii), (4)-(i)
c) (1)- (i), (2)-(ii) , (3)-(iv), (4)-(iii) d) (1)- (iv), (2)-(i) , (3)-(ii), (4)-(iii)

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2.The raw material for rasching process is _______ (jun19)
a) chloro benzene b) phenol c) benzene d) anisole
3. match the following (sep20) vi
1)Iodoform i) Fire extinguisher
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2)Carbon tetrachloride ii)Insecticide
3)CFC iii) Antiseptic
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4)DDT iv)Refrigerants
a) (1)- (iii), (2)-(i) , (3)-(iv), (4)-(ii) b) (1)- (ii), (2)-(iv) , (3)-(i), (4)-(iii)
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c) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) d) (1)- (i), (2)-(ii) , (3)-(iii), (4)-(iv)
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4.Of the following compounds , which has the highest boiling point? (sep21)
a) t-butyl chloride b) n-butyl chloride
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c) n-propyl chloride d) Isobutyl chloride


5.Assertion : In monohaloarenes, electrophilic substitution occurs at ortho and para positions
Reason : Halogen atom is a ring deactivator (May22)
a) Assertion is true but reson is false
b) Both assertion and reason are true and reason is the correct explation of assertion
c) Both assertion and reason are false
d) Both assertion and reason are true but reason is not the correct explanation
of assertion
6. Assertion : Increasing order of boiling points of halo alkanes are
CH3Cl < CH2Cl2 < CHCl3 < CCl4
Reason : The boiling points of halo alkanes increase with increase in the number of
halogen atoms (jul22)
a) Assertion is true but reason is false
b) both assertion and reason are true and reason is the correct explanation of assertion
c) Both Assertion and reason are false
d) both assertion and reason are true and reason is not the correct explanation of assertion

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 56

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11TH CHEMISTRY PUBLIC QUESTIONS

2&3&5 MARKS :-
1.how is alkane prepared from Grignard reagent ? (mar 19)(ipn : 241 )
2.Write note on Williamson‟s synthesis. (mar 19) (ipn : 234 )
3. Among the following compounds ,o-dichloro benzene and p-dichloro benzene , which has
higher melting point ? explain with reason . ( jun19) (b/b-41(ii)
4.Give the structure and uses of DDT . (sep20) (ipn : 250 )

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5.explain the mechanism involved in the elimination reaction of tertiary butyl chloride with

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alcoholic KOH. (sep20) (ipn : 237 )
6. Simplest alkene (A) rects with HBr to form compound (B). Compound (B) reacts

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with ammonia to from compound (C) of molecular formula C2H7N. Compound
(C) undergoes carbylamines test. Identify (A), (B) and (C). (sep21) (lesson 13& 14)

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vi B
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S.NO COMPOUNDS FORMULA NAME


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1 A CH2 = CH2 Ethene


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2 B CH3-CH2-Br Bromoethane

3 C CH3-CH2-NH2 Ethylamine

7.Write short notes on Swarts reaction ? (sep21) (ipn : 231 )


8.Complete the following reactions . (May22) (ipn : 243,244 ) (compulsory 2 mark)

9.Simlest alkene (A) reacts with HCl to form compounds (B) .compounds (B) reacts with
ammonia to form compound (C) of molecular formula C2H7N compounds (C) undergoes
carbylamines test. Identify (A),(B) and (C). (May22)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 57

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11TH CHEMISTRY PUBLIC QUESTIONS

S.NO COMPOUNDS FORMULA NAME

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1 A CH2 = CH2 Ethene

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2 B CH3-CH2-Cl chloroethane

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3 C CH3-CH2-NH2 Ethan amine

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10. A simple aromatic hydrocarbon (A) reacts with chlorine to give compound (B) .
compound (B) reacts with ammonia to give compound (C) which undergoes carbylamines
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reaction. Identify (A), (B) and (C) and explain the rteactions. (jun19)
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S.NO COMPOUNDS FORMULA NAME

1 A C6H6 Benzene

2 B C6H5-Cl chlorobenzene

3 C C6H5-NH2 aniline

11.Mention any two methods of preparation of haloalkanes from alcohols. (jul22)


(ipn : 230,231 )
12. Starting from CH3MgI , how will you prepare the following ? (jul22)
i) Acetaldehyde ii) Acetone iii) Methane (ipn : 240,240,241 )

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 58

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11TH CHEMISTRY PUBLIC QUESTIONS

15.Environmental Chemistry
ONE MARKS ;-
1.what is the pH of rain water_____ (mar 19)
a) 5.6 b) 4.6

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c) 6.5 d) 7.5
2.________ cause kidney damage (jun19)

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a) Cadmium , mercury b) Lead, Cadmium
c) Freon, Fluoride d) copper, Cadmium

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3.Ozone deplection will cause (sep20)
a) Global warning b) Forest fire

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c) Eutrophication d) Bio-magnification

2&3&5 MARKS :- vi
1.define- acid rain (mar 19) (ipn :264 )
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2.What is green chemistry ? ( jun19) (ipn : 275 )
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3.Write notes on the adverse effect caused by ozone depletion. ( jun19) (ipn : 269 )
4.What is green house effect ? Name the gases that cause green house effect
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(sep20) (ipn:263 )
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5.Write any three strategies to control environment pollution. (sep20) (ipn : 274 )
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“Life is nothing without chemistry

All are made up of atoms and molecules”


May
be any
comments S.MANIKANDAN.M.Sc.B.Ed.,
PG ASST. IN CHEMISTRY
Mob :7708543401 mail : [email protected]
THAGAMTHEERTHAPURAM(PO)
CHINNASALEM (TK)
KALLAKURICHI(DT)

S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 59

Please send your Materials & Question Papers to [email protected] (or) Whatsapp - 9385336929
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11TH CHEMISTRY PUBLIC QUESTIONS

YOUR HINTS

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l.i
da
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vi
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w
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S.MANIKANDAN.,M.Sc.,B.Ed., PG ASST IN CHEMISTRY 7708543401 Page 60

Please send your Materials & Question Papers to [email protected] (or) Whatsapp - 9385336929

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