Advanced Level Problem Solving-9| JEE 2023

Date : Maximum Marks: 72

General Instructions
Paper Scheme:
1. The question paper consists of three sections (Section 1, Section 2 (Type A & B), Section 3 & Section 4).
2. Section 1 contains 7 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice may be Correct
3. Section 2 contains Two Paragraphs containing 3 Questions on each paragraph. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE CHOICE is correct.
4. Section 3 contains 5 single Integer Value Correct type Questions. Each question has an integer answer between
0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
5. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group properly in the space given in the ANSWER SHEET.

Marking Scheme:
1. Section-1 : 4 marks for all correct answers, +1 for partially correct answer and –1 (Negative Marking) for
incorrect answer. Zero marks if none of the bubbles are darkened.
2. Section-2 : 4 marks for correct answer and –1 (Negative Marking) for incorrect answer. Zero marks if none
of the bubbles are darkened.
3. Section-3 : 4 marks for correct answer. There is NO negative marking for incorrect response. Zero marks if
none of the bubbles are darkened.
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SUBJECT : CHEMISTRY 72 MARKS

SECTION 1
MULTIPLE CORRECT ANSWERS TYPE
This section contains 7 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONE or
MORE Choices may be Correct :

1. 100 ml 0.5 N H2SO4 (strong acid) is neutralized with 200 ml 0.2 M NH4OH in a constant pressure
calorimeter which results in temperature rise of 1.4oC. If heat capacity of calorimeter content is
1.5 kJ/oC, then which statement is/are correct ?
Given: HCl  NaOH 
 NaCl  H 2O  57kJ

CH3COOH  NH 4 OH 
 CH 3COONH 4  H 2 O  48.1 kJ
(A) Enthalpy of neutralization of HCl v/s NH4OH is –52.5 kJ/mol
(B) Enthalpy of dissociation (ionization) of NH4OH is 4.5 kJ/mol
(C) Enthalpy of dissociation of CH3COOH is 4.6 kJ/mol
(D) ∆H for 2H 2 O    
 2H   aq.  2OH –  aq. is 114 kJ

2. 2 moles of an ideal diatomic gas is subjected to the following process, mark the correct options :
(R = 2 Cal/mole.K)

(A) W=0 (B) q = 4480 cal

(C) ∆H = 4480 cal (D) ∆U = 1600 cal

3. The Schrödinger wave equation for hydrogen atom for 4s-orbitals is given by
3/ 2
 1  
 r 
1
16 4  a 0 
2

     1   8  12  e 
 / 2
where a0 = 1st Bohr radius and  
2r
a0
. The distance

from the nucleus where there will be radial node :

a
(A) r 0 (B) r  3a 0 (C) r  a0 (D) r  2a 0
2

4. Some hydrogen like atoms in ground state absorbs ‘n’ photons having same energy & on de-excitation it
emits exactly ‘n’ photons. Then the energy of absorbed photon may be :
(A) 91.8 eV (B) 40.8 eV (C) 48.4 eV (D) 54.4 eV

1
5. A solution contains Na2CO3 and NaHCO3. 10 ml of this solution requires 2.5 ml of   M  HCl
5
solution for the end point using phenolphthalein as indicator. In another experiment, 10 ml of the same
1
original solution requires 7.5 ml of   M  HCl solution for the end point using methyl orange, as
5
indicator. Which of the following statement(s) is/are correct regarding the original solution ?

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(A) 10 ml of original solution contains 0.053 g Na2CO3

(B) 10 ml of original solution contains 0.042 g NaHCO3
(C) Concentration of Na2CO3 in original solution is 0.05 M
(D) Concentration of NaHCO3 in original solution is 0.05 M

6. A2Ox is oxidized to AO3 by MnO 4 in acidic medium. If 1.5 × 10-3 mole of A2Ox requires 40 ml of 0.03
M-KMnO4 solution in acidic medium, then which of the following statement(s) is/are correct ?
(A) The value of “x” = 1 (B) The value of “x” = 3
(C) Empirical formula of oxide is AO3. (D) Empirical formula of oxide is A2O3.

7. Among the plots, which of them represent Charle’s law ?

(A) (B) (C) (D)

SPACE FOR ROUGH WORK

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SECTION-2
Table-1 : Answer Q.8, Q.9 and Q.10 by appropriately matching the information given in the three columns of the
following table.

Considering ideal behavior of gas, match the following.

Column I Column II Column III
Magnetic behavior is same as Standard enthalpy of formation
(I) B2 (g) (A) (P)
that of S2(g) (∆fHo) > O
Can diffuse faster than ethene
Ionisation energy greater than
(II) C2 (g) (B) (Q) under similar conditions of P and
corresponding gaseous atom
T.
will apply force per collision
equal to CO2(g) on wall of
(III) N2 (g) (C) Partial 2s-2p mixing (R)
container during collision at
same T.
number of electrons with will have larger momentum than
(IV) Na2 (g) (D) (S)
ms = +1/2  4 CO (g) at same T.

8. Which of the following is correctly matched ?

(A) (I) (A) (S) (B) (II) (B) (P) (C) (III) (D) (Q) (D) (IV) (C) (R)

9. Total number of correct matching for B2(g) in column (II) & column (III) respectively are :
(A) 4, 3 (B) 3, 3 (C) 3, 4 (D) 3, 2

10. Which of the following is incorrectly matched ?

(A) (II) (C) (S) (B) (III) (A) (R) (C) (IV) (A) (S) (D) All of these
Table-2 : Answer Q.11, Q.12 and Q.13 by appropriately matching the information given in the three columns of
the following table.
Column I Column II Column III
(Ideal gas) (Related equations) (Related properties)
Reversible isothermal expansion cp
(I) (A) p1v1  p2 v 2 ;   (P) Sgas  0
process cv
Reversible adiabatic expansion p1v1  p2 v 2  nRT
(II) (B) (Q) Ssurr  0
process
Irreversible isothermal expansion w   pext  v 2  v1  Sgas  0
(III) (C) (R)
process
(IV) Free adiabatic expansion process (D) H  nc p,m  T2  T1  (S) Ssurr  0

11. Which of the following is correctly matched ?

(A) (I) (C) (R) (B) (I) (D) (Q) (C) (II) (C) (Q) (D) (III) (C) (R)
12. Which of the following is correctly matched ?
(A) (IV) (A) (Q) (B) (IV) (C) (R) (C) (II) (B) (P) (D) (III) (D) (Q)

13. Number of options correctly matched for free adiabatic expansion process in column II & Irreversible
isothermal expansion process in column III respectively are :
(A) 3, 2 (B) 3, 1 (C) 4, 2 (D) None of these

SPACE FOR ROUGH WORK

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SECTION-3
NUMERICAL VALUE TYPE QUESTIONS
This section contains 5 single Integer Value Correct type Questions. Each question has an integer answer between
0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.

14. ‘w’ is the mass of Iron (in gm) which will be converted into Fe 3O4 by the action of 18 gm of steam on it.
What is the value of w/7 ?
Fe  H 2 O 
 Fe3O 4  H 2

15. Find out the difference in number of angular nodes and number of radial nodes in the orbital to which
last electron of chromium is present.

16. Under the identical conditions of temperature, the density of gas ‘X’ is two times to that of gas ‘Y’,
while molecular mass of gas ‘Y’ is three times that of ‘X’. Calculate the ratio of pressure of ‘X’ and ‘Y’.

17. A perfect gas undergoes a reversible adiabatic expansion from (300K, 200 atm) to (90K, 10 atm). Find
the atomicity of gas.

18. Consider the following molecule.

p
Calculate the value of , here p and q are total number of dπ – pπ bonds and total number of sp3
q
hybridised atoms respectively in the given molecule.

SPACE FOR ROUGH WORK

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