Vidyamandir

VMC Classes '"'" ""

HT JEE I MEDICAL I FOUNDATION

Date Planned : _ / _ /
Daily Tutorial Sheet - 1 Expected Duration : 90 Min
Actual Date of Attempt : I I JEE Advanced (Archive) Exact Duration :
1. Naturally occurring boron consists of two isotopes whose atomic weights are 10.01 and 11.01.
The atomic weight of natural boron is 10.81. Calculate the percentage of each isotope in
natural boron.
(1978)
2. 2 .76 g of silver carbonate on being strongly heated yields a residue weighing: .._., (1979)
(;)
(A) 2.l6g (B) 2.48g (C) 2.32g (D) 2.64g
3. th
When e same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium
hydroxide, the ratio of volume of hydrogen evolved is: (1979) 0
(A) 1:1 (B) 1:2 (C) 2 :1 (D) 9 :4
4. The largest number of molecules is in :
0 (1979)
(A) 36 g of water (B) 28g of CO
(C) 46 g of ethyl alcohol (D) 54g of nitrogen pentaoxide (N 2 O 5 )
5. The total number of electrons in one molecule of carbon dioxide is : 0 (1979)
(A) 22 (B) 44 (C) 66 (D) 88
6. Accounts for the following. Limit your answer to two sentences, "Atomic weights of most of the elements
are fractional". (1979)
7. The vapour density (hydrogen = 1) of a mixture consisting of NO 2 ruid N2 O4 is 38.3 at 26.7°C. Calculate
- the number of moles of NO 2 in 100 g of the mixture. 0 (1979)
8. The number of electrons present in 18mL of water is _ _ __ _ (1980)
9. The modem atomic mass unit is based on the mass of _ _ _ __ (1980)
10. (a) 1.0 L of a mixture of CO and GO 2 is ~ken. This mixture is passed through a tube containing red hot

charcoal. The volume now becomes 1.6 L. The volumes are measured under the same conditions.
Find the composition of mixture by volume. (1980) 0
(b) A compound contains 28 per cent of nitrogen and 72 per cent of metal by weight. 3 atoms of metal
combine with 2 atoms of nitrogen. Find the atomic weight of metal.
11. 3.0 g of a salt of molecular weight 30 is dissolved in 250 g water. The molarity of the solute on is
(1981)
12. If0.50 mole of BaCI2 is mixed with 0.20 mole of Na 3 PO 4 , the maximum number of moles of Ba (Po
3 )
4 2
that can be formed is : 0 (1981)
(A) O. 70 (B) 0.50 (C) 0.20 (D) 0.10
13. The density of a 3M sodium thiosulphate solution ( Na 2 S 2 O3 ) is 1.25 g / ml . Calculate (i) the percentage
by weight of sodium thiosulphate (ii) the mole fraction of so~lium thiosulphate and (iii) the molalities of
Na+ and s2 o;- ions. 0 (1983)

14. A molal solution is one that contains one mole of solute in : 0 (1986)

(A) 1000 g of solvent (B) 1.0 L of solution

(C) 1.0 L of solution (D) 22 .4 L of solution
15. In which of the expression, the concentration of a solution remains independent of temperature?
(A) Molarity (B) Normality (C) Formality (D) Molality (1988)

DTS-1 25 JEE Advanced (Archive) I Stoichiometry-I

 VMC Vidyamandir
____ Classes '"'""
HT JEE I MEDICAL I FOUNDATION

Date Planned : _/_/_ Daily Tutorial Sheet - 2 Expected Duration : 90 Min

Actual Date of Attempt : I I JEE Advanced (Archive) I Exact Duration : I

16. A sugar syrup of weight 214.2g contains 34.2g of sugar (c 12 H22 o11 ). Calculate (i) molal concentration
(1988J
and (ii) mole fraction ~f sugar in syrup.
17. Calculate the molality of l.0L solution of 93% H2 so 4 , (weight/volume). The density of the solution is
(1990J
1.84g /mL.

18. A solid mixture (5.0g) consisting of lead nitrate and sodium nitrate was heated below 600°C until the
weight of the residue was com,tant. If the Joss in weight is 28.0 per cent, find the amount of lead nitrate
and sodium nitrate in the mixture. 0 (1990J

19. The weight of 1 x 1022 molecules of CuSO 4 • 5H2 O i s _ _ _ _ _ (1991J

3
20. 8.0575 x 10-2 kg of Glauber's salt is dissolved in water to obtain 1dm of solution of density
1077.2kg m-3 . Calc;_ulate the molality, molarity and mole fraction of Na 2 SO 4 in solution. 0 (1994J

21. A plant virus is found to consists of uniform cylindrical particles of 150A in diameter and 5000A long.
The specific volume of the virus is 0. 75cm 3 / g. If the virus is considered to be a single particle, find its
molar mass. (1999J
22. The normality of 0.3M phosphorus acid (H3 PO 3 ) is : 0 (1999J
(A) 0.1 (BJ 0.9 (CJ 0.3 (DJ 0.6
23. How many moles of electrons weigh 1kg? 0 (2001J
1
- x l 054
1 6.023 (DJ
(A) 6.023 X 1023 --x10 31
(B) (CJ - - - - - - x10 8
9.108 9.108 9.108 X 6.023
24. An aqueous ~olution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH
required to completely neutralize 10 mL of this solution is: 0 (2001J

(A) 40mL (BJ 20mL (CJ lOmL (D) 4mL

25. Which has maximum number of atoms? 0(2003)

/ Al 24 g ofC (12) (BJ 56 g of Fe (56) (CJ 27 g of Al (27) (DJ 108 g of Ag (108)
26. i Find the molarity of water. Given: p = 1000 kg / m 3 (2003)

27. · Dissolving 120 g of urea (MW= 60) in 1000 g of water gave a solution of density 1.15g mL- 1. The
molarity of solution is: (.,:)
.._, (2011)
(A) 1.78 M (B) 2.00M (C) 2.05M (DJ 2.22M
28 29.2% (w/W) HCI stock solution has density of 1.25g mL- 1• The molecular weight of HCl is 36.5g mol- 1.
The volume (mL) of stock solution required to prepare a 200 mL solution of 0.4 M HCI is _ _ _ . (2012)
A compound H2 X with molar weight of 80g is dissolved in solvent having density of 0.4gmL- 1.
Assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is : (2014)
· the same as ,·ts
The mole fraction of a solute in a solution is 0 ·1 · At 298 K, molan·ty of th"1s solu tion 1s
molality. Density of this solution at 298 K is 2.0 g cm- • The ratio of the molecular weights of the solute
3

and solvent, [ MWsolute is J (i' (2016)

MWsolvent '-'

26 1
JEE Advanced (Archive) I Stolchlometrv-
 Vidyamandir
VMC
---- Classes ., , . •
111' JEE I MEDICAL I FOUNDATION

31. 5.00 mL of 0 .10 M oxalic acid solution taken in a conical flask is titrated against NaOH from a burette
using phenolphthalein indicator. The volume of NaOH required for the appearance of permanent faint
pink color is tabulated below for five experiments. What is the concentration, in molarity, of the NaOH
solution? (.,:'\ (2020)
'-"
Exp. No. Vol. ofNaOH (mL)
1 12.5
2 10.5
3 9.0
4 9.0
5 9 .0

DTS-2 27 JEE Advanced (Archive) I Stoichiometry-I

I/ JEE Advanced (Archive) DTS 1 -2

I
1

20%, 80%
,, '

A A
4

A
s

A
6

Isotopic ::;.;J.~
7
I 8

24
II
9
l
·- 0.473 6.023x10 C-12 isotope
1 II I I
" if; ~'i~~rto,: ' ,'C 1 , 11 ' 12 13 14 15
" '
(a) Vc02 =0.6L, Vea =0.4L (b) 24gm/mol .0.4 D (i) 37.92 (ii) 0 .065 (iii) 7.73m A D

16 , '17 · 18 19 20
"

(i) 0.556 (ii) 0.0099 10.42 Pb{NO 3 )i =3.3g, NaNO3 =l.7g .4.14g (i) 0 .25M (ii) 0.251m (iii) XNa s =0.0045
2 04
.,
"2L, 22 29
" '
30 31
6
70.68 X 10 g D A A 55.56 C 8 8 9 0.11