Chapter 2 Sheretivre % Aton
Ey Ate» An ottern isthe Amatleat: Of mrmocttet LS,
phous Obh I -properetiet Amel takes past inthe Chemical
Acachons and ishoae inde pendarct exlelence ts cloubt ful.
Mtence ,-Hre atoms > dome elaments enctete in native Ldtule
Ae Atoms 4 mocb Sh Hee Clownemts ola wot exiet in mattre-
A) The three bavie ponies fae el Preeemt: in Qn aban
art electron, Proton amet mexrtron,
® lave +treorey —
@A ie dined a4 Q -pereiodia Deturbamee. in space ort
a mediurs “Haat involves Lic placement 4 anodtouial pacticles
® @-periodlie change in korne -physical qpamhties Atle
-presaure Ole, demmperatizre ett:
Thus wave mmoston Aapreaatt ~peepagastion oa -peciodc
disturbance Casouy ened
@ he wiawe ronal fughe angles oi the viby -mohen
Har Ofek
@wren On ofect mNOves up arn dousn Avibvates Continuously,
inta oem of Wawes ts transmitted by a Vvileraxtoey
object +o a dictent place
© buive chances 7
@lovelen, ~~
@St is damoted by > (Lambda)
@sris dafined aacthe dictance hotseen two meareat cert
a tivo meaeedk ctcouga-
Bgere measured hermes of A’Cargetror) , PMC picometer),
sen(namemeter) , rear (miumeter) 1 On contrmeter) , Lum
(arnivcometes) ete.
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rath oS
tHerte = Ls
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@ Stis damoteo bay
@ Seis the Hire takem
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ve jc the Asciphocal een:
TH
a wave to pam Hecougn ene
Wave +9 Completi- clistance 4
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uhere ‘c’is a proportioned ty Comueunt Utuch te called ar
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st is dafined asthe mumber “+ Waves pe Wont Jangth
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Oi denotes! by ‘a
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a Ware.
® Stic bait He Vvecticnl cLstemen purr the Hap of the
ware to “tee lester 84 the Wave .
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Laglt wane. vend “ % 6
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®) Tames Manwell Aug tho Uthen elecbet
Charged -posebicle moves Unclat aacelanaHon , eee
dlecteical and somgnene pl Are -prodiscaof and tran
venitted by tt:
&) These elt ane bramsenitleol in-Hre 3 of Waves
called as electav~iners Wavet 0 eldetromap netic
Andsabons
Oman araumphons of Maxwellte Blectro magnetic
jwave Theoty
» oscillaHry ete sbete Ano weagnatis yes pucoducae|
os cLLOH ~poeticles ane ~perperdiertar +0
cach othea amo} loath are —perpenclicular cpotte direcHen
aon Wave.
sn aoe im mete eld Cornponentr Qn
fester ware have the dame Wavelength,
Satan lips and aomplitade , bck they VibAcie. hy-t20
rraballes sporpera —planes,
Electret
x
Bireotion “f propagation 4 Wave
v ooqrete ‘fret!
Ele chromnsgretic Waves
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Zz@Unvke A
ee teeadndle mec.
lane hee medium and Cammove in Vacuum
but Agee Chavmepet to dupterent rmnediwms ,
@)Treee aves travel witb tha vretocsty oy gibt ie. 3 xi
~™s in VOCLUUm.
Eo Poucticle Native Blechomagnétic Aadsations, —»
( Plamek's Plamekis quaritim + theory AodeaHons) —>
colli a a hoe given y
ent as Q Conhinioud
ergy bathe foe
Beals mie deat erst Cartan phenomena.
qt. but ode the Aame He, it failed
+o eet mi ies nore pronoment LUch a2 24
a The a electrons yearn Ho untae oe
DS een ys AacloHons er aanlie Aurface Ts
a a4 BT ade ef fent”
> pie apecheal Times emntitd by enated atone Cen
| Que Kinasn as Lve Kpectrumn dnd Aral inte | i easton
tre Clamrents-
Ben olan to explo?
mn “fhe Above phenomena, Max Plarads
| hn SOL “put founandedl atheoty kunsum ab Plamelel 6 Qluauntwrrn
| oor Blectrowmageetic Aadiadions rade up Ythe
| areHeles:
@) Te vas further extendas! by Sinesteln in 1905:
| The rood pba phe Ha are Qk 14 —
| © yee >
®
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rndlewdtes dis continuo iy Hue. 40m Aarne. pocketr
Oe anh eal % emer ty ideas Coad at
‘s ‘
bn cana Jagtet tho a emerty pascers or energy bumdles
ave Catlad at photon
8) (he energy 4 each -phston ic cLivectly prepectional +o
soe feasponcy Og Hare. AadiaHon. j-e-
Env
“ER OD
Here his a ~prepetetionality tnutant Called as Plametle
Constant uStroae Value le 662 x10 Fa
DThe total Gevaunt Of en emittrol Or Obssebarcl b |
& ody tc a Aome nawnbaars MU ple 4 qpaauetin. |
ie. [e=nhv)
nN =1,2,3,4---
— ot Where -
br nee N= @ poartive mnteger,
5) Ihe energy arrocricittd with vegas Number (Va)
% Qpourta ts as Bmesten of Energy (@). Its value
is a = Na be
(here Na = AVO Numbers 602% 10%
@) Murs, Plamckeorctre Lire Hine haa Given @ Aelationsip
betusean aL a opie Aocdoten,
- : ®
| And He energy anno cory -HN
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7 8 eneng “4 “aogle se AadiaHon intro
photons, which ee witty the a 4 Light.
2) Brevgy of Aingle photon [e= sho che '
S AU Ho photons wviacuum pyanrel | ml Hh. Ape
Baxi me beet theby 4peca he changed Pal if tenent gai ae
Arowever, fe spony Awana auc: ski secal SEBEA
4 PEE saves bub tre abastbecd or
emifed as particles
8) Exergy Absorbed) Inthe. of protons ig equal to
the ementy Acloaaoel me pent platens.
Fae. So)
(dg, hy, ths, +hy3
ow
Y= VP) +9 495
nr
= ada
Dobe 1 AL Dy
_UShere, hy, , hv, and by ave the emensy Of Alaaaast
otens 4,2 anda Avapectively.
Prondy, Ovethe feaquenty of Mulenaze phetin,
4, oe Asepectiv
— Dy, pA Dy are the Wavelength of Asteased Hictent
1,2 ands Aeapectvely. a
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Soe! ce = mhe
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Lamx 6-62x18t xaxte
a <5
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fie fora L
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ms LAOREET
G42) axa 19
ne V5) +1 4 plato
Q2 A ababetbs a- Lon © wavelomat 3007: ard tt
Acemits hoo proton Hf eine ne ie 4 for photon fs
4oorrn tam hat vill be dre &
_
gt Aetanel phaten-
So" \ ce tadb
Dobe ~»y oe
ae
7 = a. A
cad Ro A60
Ae A ee
Ne (200
pees
A 1209
X%, = \200N™m
02 Warelern so platen are A4000A and gro 4°
Apspect in vito Coll) Le Hae AnH Of thelr
pan: Ext | aa eee
Gat? x» ||
tnetioty or ° Roe Ae Lk
senee[ SE BEY
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Bison Let ee Deodert proton
torts Cevain rnintmum a =
preqperey?9 Abuice the prover
A ce. Ghonetab sthenthe
electrand be fected {yum Metol oy
Hae Aurpace 4 tne metal: electric epfeck 7
OWE ts Caled a4 plhoto—
| electric efhect Cunal the eqested electrons are Callsol ax
rato electron.
&)Ina Lose Clravtt, a Cunrent it ica ole -bo-Hhe
vO} ehewtn tamaemb electrons Uhrich Is Collad 24
electric Current ° .
jesbosuert (War $7
Bile mmisimum orergy Of & plsten Aequiced to efeck
am electron (oo 2. he Collaaf
Qo he Werk fier cHon aw
Ose iste Sek a aaa aes | Of Hae metal.
Wee hvo
here W = Would chron of rmetol
hy =. Planciets Constant
Voz Threahotd :
© eae ae a
The mmininuw a -phsten Acquired
ale om eben peat Nie unfue i a
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© Aceorating +0 bPnectein, hem Lao -euthable
“yepency Alla OW a rnetal Lurface, he Lught
plston gives ies enero torte electrons of rretal
CEM annol the elecinonte ¢ Pedte of yYtomn “Hho rnetal
Aumaoce by Ahabtbing +lw%e enony andthe Aemalyly
Part ©. the ener (hy- WI) © photon te Wace +o mal
the kune-tHe emengy of “Hye efect=t electron.
@Caswl when emergy of Incident plhoter(hy) te
leas tham He work humctron af metal (i)
Jho
hy = hve +b] 3)
©
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[Remo =ht> |—©
Cqposton 4 12, 2amd4 Ore Called a4 phsito elect ric
Latton.
+‘ om eqyastion @, bys hve teh mv*
Lg be
drew = hy h
w= QA(Y-P)
yrs Bh (9%)
a
ond Pen
ZR Ao
2)
on Qand (6) cheno ae Pe clades
Ot tettre Lu}
Maximus Wowelor, Hy (As) i
cnegeenice ter ve
ae a ometal Aurfa
ae 4 tye pha electae effect ae OCHy:
| psast
Go, A gAg
Odoouk Photo ele te eek
&) Two lonpordamt Pot : electron yer
0) Ore phsten a Aurface
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2 Were + hi m0 -Hme Me between the meadclent 4
Oo
Auttoble - yeeqpomeg en metal Aurface ard
Hee veteade o ele nse orn medal Aur ace
Me ot cha. re 5 indewarly § Incielont Aigist—
G&) Shen Hho ibenarh 4 [wetdowt poten 0. sight fe
Invteaaod “Han we mmternbor of electrons efettid
Hae metal turlace Invecaact buck Hye amare term
i akexde of photoelecs pons Adatnd Constant
8
se
= b |
il x |
x > 5
ee Irbemarty 4 bnctdlont Lat
es of chamge of roomy: imerctont Light >
dank Uy
Qaren e pespertylonegy tae K pate ot jl
deacleceend muegzaes but +Hhe mo- 2
oto efectrons tha Dmetot aun hace, irmains the
Cee
290 Che. 4 we now that
ee aba ight fe
Csrrparing Hts eapacion cory | ne eqpation
4 = oe oar ne Shoae alope
1c equal +o A and inter copt poet vail] be equal
+o |W"
4D)
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ae Luwelte Ener, ae cae of -fengpeny
WSpecrat Note:— brhen a ee at article
ae 04,’ OL Awad is ange pant by a Vootchtiol
ay and abo.
‘J youes thea its Kinehe eee will be hemes
Ke = wv] -O
KE = bor —O
From 24>@Q ard)
res™ = 4, Vo
vrs 24
be
am electron, at Aut, it acodlacteof by a potential
i i as —
ae ols Hren itt Kimette enecy vaill be gen
we sev [
r We givenas —
ete ier!
ny
i esf = | 602% \0~ Goule
4 irdercanver sion a eV into 4
Poule And vice verea,
@®
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Pe Spee :
(Dy senx 40
ee
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= maa “4 armetal fe 4.2 ey gy rradiaton
Of 2vo0A°
alls Ont metal hen re |
ete ener tf
of the faatoal> proto electron ty Boule fe 1c
ose Ki bienid caaxd? a) 64x10
Awa c>
= ier Ite Geax ont and) = 993% 10 Fouke.
Dr” “Dow xa
Wedt.2eVe 4.2 x1.602xigto GF2% 18 fouls
KE max = Eime -W = 993 x0'% 672x109!
Ke Erman. = roe (9-43- 692) 2 2-21K 0 Poule-
Q2. Who tt the Wolk fumatron Ofte aenectal ify the Lag
©} wiowelim Hy 40008" 4 erates a ~photvelectrons 4
Vebuty Exioome it?
So. photoelectric eqyactton hy = WL vo
We ho -Lovev™
We he pe
> >
ox g
We 6.62x10"tx 3x VO" 1 1x ie
Set
4-000 x (0'° ~ (xi e
26
We G62xXBx10 _ 4.55x10'! x sexid°
af
4X10
= -Y
we AGES XIV 168-810"
As
Lye 4965 XH 1638 X19
14
We BrB27#x10 Joule
ye 2229x188 ey 2 20F EV.
|. 602 «10
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“The man poatilates 4 Hats Model Qe as poo
QT postulate —s
-tn aterm is ele ee ee! and Aphericat In shope
vortl) the pout eof Muclens Hanley protons avd
mecttrans ft nro contre Stile ~ are
ch electrons Aowokve arourd the mucteus Loith &
depnite velocity tn a cemtan-bied closed circenfar
P Callad ar ts ar -Shells oe AttatHon hater:
_These aebala otbital are mumbercht aa 4, 1 Bob and
stemmed as KL, MN thre Muclews-
— bach vbr 94 & “pied and parched Vora yerendy
istuch means Hot on ads Om electron tevewvif
jramorbit tt meithe mor Looms en ,
— Bleotrens Aenoined i ef orbl ts onan tinue
suasdortie +0 force? urbseh are
rea» Kez —O (fur hohe T poatilalz)
my smh a
an e) ce « ios >
vez oh
Qn
On page in equation (), we ge
om (eh— = Kxe™
QT
mbm . xe®
Ananth yf
a a Khe
Fate
he Plounctets umstamt 2 6.62% eye
R=Ble
fae ee &-s)
ee he xivreu Cas unit of change Of electren)
me 4 11a’,
me Boelws whe
qe actaamie wo. 04 the element
xe rods
ong tei hn 2, in eguocion B, Ve
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Fe ee Oe
0
nS
Zz
®Oishen both m and -z are mat umstant,
yr on
za
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fev = ze! a) (4yeem Sent pectuelate)
oreut = a —® (C « v i )
26
rp = toh
2nmv
On p othe ualve + in equation 1,
Ve kz" x anyif
ie ae
©
On pubtlng the voles Ke, Tandy in equation ©,
Eten z Ve Contam =>
y
7
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Vol
n
SE)
MMetermincelton of emery ofan oleetven by Bobws
pottulates—y
We pote emer a eee in ay orbit is eqpal to
the Aw of Hae KE Qrnd PE Of the electron Inte eit
Go [TE = KE FPE | —O
z
KE * am alectyon = 1 mv
Ce rove ke!)
= otk
CE + kaze Pon an
+
PAB. Of aan electron ew o-FXY
— Kegnr
a
Pé = -Kee* LO
‘he olure Of PE. and KE in equation, we get
Op "g 7 = ee =. —Kze") = kee Kas"
25
Th = Ks" 4-1)
@2)
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ae mh
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whe Kee ve Artes!
On pre Has Volt 04 Tren 10, aud h in £4, "One
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mt
Lerye (0 Soule, 20
Tes - 2143 wie xe Gouke per adorn |-0
*
leve \ 602 X10" Soule
Ee
TEE = B26 KZ vead mmavoT! (6
7 =
Ten IBD KE KT maT!
Te: = —13\2 FE KS —@
n>
6 Gand \o dunotes Hae chygerent
4 ehectvon Mm &
en a
Tybee SLbit™
Giron is comstee | Exp BG) “ eet |
ins on
4 deoren®
son 6,48,
1 Ts es, a
Hence the ener fy
es niiththe Fe in 20S
ober GUbit
a
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ee
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Go, With the invwense Inthe Adowic No
ener | af paroutat de etren in agp
cleoregaes
(6) Len both 2 and n arre mot Conelen™
Ea 25
he
aa S Ve
Ao, ' L (21 SARs)
@ For Hatem , eh
ere eT]
aS
on ao
Rabric sebit
€)- 38H ey |
€ - ~8#ev
Ge -\Shev
Ey = 208h eV
= -OS4ev
® E,-E)= 10-2EV = Agar
&) by -&y = D€agn =
& C4" & * Degas? O66 eV
bn & = Abe? & aLeVv
Aiene, withthe Increase inthe ele ~, energy
eleatren 120 but the erorty » bse:
aI
\-e9ev
24
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(&) P.6. QY am elechron—> pé. = —Kee
=
(>) TE. Pi meron Té. = —kee™
ar
KE’ nea
Ope Bron * t\
fe [ke --Té
at Del Abit hove min.
woud Stade usbvle +he
callact at Cxcited Stedes
the Wavst excited tala
2) ta the hypreak on A
tr Ans
other Bone Orbits ovr
The aecond Doober's eke
Vile He ingintte Bobs obs Gr=
Snakes —» St isthe
nergy isthe
Awmove oy move on Blethen “from ume aide maces
| excted ease) in ad atbm. or Alyy ae “rn £peces.
Ve ond fe pees
aes (12Ez2) - (Bee
ey iL)
Ae = OFISS27
ae = 18627 eV
Dp tyeagensiaw 24 00 [ae STEER]
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Arimore oto excite an electron excitcof Atate
ho infinity Chisghiedt ected Ltede) ing en Ube
atiarn .
OE = &- Em
De = F196 x27) _ (3.62%
A ne
DE = +1962?
ne
AE = 13627 eV her mn ts al
ne amore tham 1 les
-Hhoun co
©) fax typlaagen etm 22h D-for SExy mira
GEy) =e = 13-6 xt)”
@
GE, = 136. 9-4eV
a
re a ea illest +9 oF cited
AE 2 Sm, - Ens
Dé = pues (eee
mae
Efe 5 eV.
ne
ia tephogpen dim e- 9 ft Seu) mea.
EO: CA) +e s6cn* = 138 + 136 ees
[eer aaee TORT fray tte
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Aceon UhKen vocation’, OF a paseticrlay Wavelam pts ane
anol zed -f Oa priem
Ogee ave w'beleay claaeit red Into duvo iypes-
© a Kes a Emeion ‘ apectyurn.
leu
2) Noapeption ny Apect yw, —y EShen Lote ptt sear CUmy
Rare ig fvtt paseo! Feaveth ‘the Seat dy vapours
a chemical substance and dee voural sec{ bry thro apedtxoscope
hen Much type 4 eapecir ine fe cattecl as baorphon
Apectrum.
Bests aloo 4s Lig ceapPinccous Apectrusn * clarfe Lines.
@Emission 4 pect —7 When the Aadtection emiitteof
Ame Aswree -& q hore AWM or by poo pasting el eabete
cUxch: Sl a gaa eck Lod prvaurs Ov by Aeath
Agere Atubstamee “bo fs demperature etc, Rg rolls dnd
aay “The prtem ane then Lecelved onthe protograptc
plate the apectrarn oblaned Le CaALtedl at Bmission
Qpectywm.
&) Te Apectun Q AadliaHon emilee by Q Auubstamce
wr tte excited & is the enctacion Apectwm.
@Emurcion Spectrum ie Of two
a> Continuous apectrum >) ge ectrud
2 ea aN le
lmurce Auchas Aun 0 bulb &
ownates by pacing emoudl. artim, i ne Cala
BLE ap te anon dient enous ron il towed SI,
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omens intothe neat Hence, Hae spectrum fe cA Mad ad
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&9t may ba moled Hrot on para Toca “the pric , red
Colows NTH the Lengeat Wavelem ath ic den tata east
Lule violet: colow wath Fhe Qiscontnnius -epectrum—y Wihen gases ov vapound 9 O-
chemical aubtance are droatad nan lectete ave OF Oma.
Runoon flame ‘i. ie emitted Of Tots Upbtyay he pamad
ahraoudl. @ prion t om cLicComtinnows Apectrum re Jrodiucads
Hat te vtwoo type -
bb Lin - Spectrum of atowic Apectrurn
it) Bam Apectwwr a, Molecntak cpectru.
lone Soectun | Band Qnectrum
Dstica cUecontinuons emriecoy $) ot te @ cLiscunfinucus exstssten
dpechrum Cdhich has Aharp, “emresion £ pectnum atti x
Astinet and well dapinednes a Aertet edd
worth dau wre Lines: * “ad “ent *
3) The Line £pectrwn tethe — 2)The hand specteum te the
chanacterittes “ atoms Ardit choracteristies andletules ae
fealeo called as atewe
eeetoyptien Eunbston
oT — a
Continuous Aitcosrti woud
C rs - L
Lane ov Apbomie Apectrwm Promd ur Molecular Spectrum
H)Enaseion Spectre 4 H Sy
Ashen Kane na at Low tetoleen im the
duschage the Lt ernitleof on pea electtte
ccchy te examined ma pectrogiaph, the apechrunn
oblaued fr called a4 the emarition apecttwm st ;
QS conta loge murber o| Lret uShich are qouped
Into BL eseres UNI are Ad jolt
WD hymen Aerses
2) Palret Aerred
S Faschen Aenried
4) Bracket dented
5) Pspurd Avred:
@ Te woe murmlant Of AU dre Lines in ol the Aeriet 6
Combo caloattd bythe Pydlorg eqpatton.
(Shere myarnd mare hale numb Ond YP)
Zz - Abomie no- the Alngls dlechond ENOL
Re Qiks Conttamsls 1096 EO, &
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Seen ee “ee
Name of om,
\ Lpectral A2glan.
the dertet i q'
Dayan Seid 1 | 2,3,4,5,6,9----| Utyaviolet ac
2)Babrret Losses 2 345, Gt -----| YilbleAegion
\ |
9) Prosten ek \"* 6 A------- Neal Tne ved Aagion
ae | 4 Bb %----- = + Sneaared Acgton
SDP frre Aorteh 5 |gt------- Pteperes egies
© Beewasion Rydberg’ eq pox Pokus Poatnlocted
when a recstcl +0 Mediate ‘recharge 91 heatial
© athe Sako tee hound sie fe
wes ‘alum en i.
emery levels: Ax Hy ee
Jevels, Ao they emit energy and Actin to Ground
atole or Other Lowel ener: y Ate he the
ew are brghet en 4 i hethe energy Y
ernitted Aod adton rae fom Boke
Kinna thet TEE shu |)
Oe Ne ee energy Atadtes are,
and my asepectt
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3— “4 Auboaholl —> cemplex shape.
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“odes”
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of orb; = Dfe)4h = 7 .
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Afar paubsholl tea => Cyc de, dni fe
So, mo-€} orbitals S2X(DtLa6t) = FAbiala
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2(2k+L) OL 4842
1D Hone Aubshell, £=0 =
ny
Qo,mo of electrons = +f0)+2 = 042 =2 Eke
2) ot § * aubshell, Le L = —
Qo, mo Of electrons = 40/42 =4-4+2 = 6Elo
3) Wiaawbahell =2 =
jo,mo-Of electrons = 4C2)-+2 = Q42 = 10eu.
4) pr awbsholl, h=2 =>
So, no.e4 elechrond = 4(3) +2 =12-+2 =14 Ele.
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OAM. = < b Lafond = fh [a05 = 0
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(©) The value A pamges eo Yto'm-1"
(4) The Value ae Can mevet be ~megative mOL pactonal.
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Wt Laat hodueed by Lamcte’ +o explain Zeeman eppect:
© Ot repens to dt tee dlde;taHons of electron could
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orbitals
® Mm elechvon ducto it Oebital emotion around the nucleus
generates an eClectric ele’ USbuch intiuin -produced a
ett Yield Wich can itera wits the extemal
metiopetd. Tus, under Hee Inflromec athe external
nett. Yell the electrons O a AubahelL Can oerent
+herselvet ty cevteun preferred egies 4 pace around
hemucleur Called at orbitals.
| OHlence the metic, dum numbet daterminestre
| umber OL Geierytations Othe electron precentin
Q Aubshell-
© Since, each eitentotion Carrespenclt fo am OLbital Hentie,
tha magnetic qpaenhum mumbo etermines Hae muse &
epbitals present bn ee
©) Total values Of on =) Deed
Rove Hae yodiae 6} my = Ltott imeluscling cor.
Qo, the values Oe dependent ontine vale ie
© The volues 4" Cam be posite, negative eter
but can nevel cHonal.
&) Like the vole MM. the values af om Qre aleo_lers
than the values of wi
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