SEC: INC.

JR_*CO-SC(MODEL-A) Date: 28-08-22

Time: 3 Hrs Max. Marks: 180
28-08-22_INC.JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_WAT-9_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Power , Vertical Circular Motion
PREVIOUS WEEK (20%): Elastic Potential energy of Spring, Spring
Block Problems, Stable and unstable equilibrium
CHEMISTRY: PRESENT WEEK (80%): Ionic Equilibrium-I: Theories of acid &
bases – Arhenius, Bronsted-Lowry and Lewis theory
` (Exclude: Comparision of Acidic & Basic strength), Ionic product of
water and pH scalepH calculation involving strong acid, Strong base
and their mixtures, pH of weak acids and bases, Mixture of weak
acids, Levelling effect, Common ion effect, Dissociation of polyprotic
acids, Salts and their Hydrolysis
PREVIOUS WEEK (20%): Chemical Equilibrium: Equilibrium
involving physical processes: solid - liquid; liquid - gas and solid - gas.
General charecterstics of equilibrium involving physical process,
Equilibrium involving chemical processes, characteristics of
equilibrium state, Law of mass action, equilibrium constant,
characteristics of equilibrium constant, Law of mass action, Kp, Kc &
relation, Degree of disassociation, reaction quotient, Lechatlier’s
principle - factors effecting equilibrium concentration, pressure,
temperature and effect of catalyst, principle applied for synthesis of
ammonia and sulphur trioxide and other typical reactions,
Thermodynamics of equilibrium constant. Significance of ∆G and ∆G˚
in chemical equilibrium

MATHEMATICS: PRESENT WEEK (80%): DETERMINANTS : Introduction of

Determinants & its Properties, Properties of Determinants
PREVIOUS WEEK (20%): TRIGINOMETRIC EQUATIONS: General
Solution, Solution of Trigonometric equation using graph or otherwise,
Equations based on extreme values using graph or otherwise,
Trigonometric inequalities using graph or otherwise
Narayana IIT Academy 28-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-9_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30
Total 20 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 31 – 40) Questions with Integer Answer Type 3 0 10 30
Total 20 60

MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 51 – 60) Questions with Integer Answer Type 3 0 10 30
Total 20 60

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PHYSICS Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of which
ONE or MORE are correct.
1. Consider two blocks made of an exotic material. The friction force between the blocks
  
opposes the relative motion of the blocks and has a magnitude f  k u1  u2 , where u1

and u2 are velocities of the blocks. If k  2 N  s / m

A) Power delivered by friction ‘f’ to the upper blocks is 50W

B) Power delivered by friction ‘f’ to the lower blocks is 50W

C) Total power delivered by friction ‘f’ to the system of blocks is 50W

D) In a frame attached to lower block, power delivered by f to the lower block is zero

2. A body of mass 1 kg starts moving from rest at t=0, in a circular path of radius 8m. Its
Kinetic energy varies with time as k = 2t2 J, where t is in second. Then which of the
following statement(s) are incorrect

A) tangential acceleration 4 m/s2 B) power of all forces at t =2 s is 8W

C) first round is completed in 2s D) tangential force at t = 2s is 4N

3. A block of mass m = 5kg is pulled by external agent by means of string and multiple
pulleys as shown in the figure. At a certain instant the velocity and acceleration of
point P are 5 ms 1 and 5 ms 2 respectively. Surface is smooth, string and pulleys are ideal.

m
P

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A) Kinetic energy of the block at that instant is 2.5J

B) Kinetic energy of the block at that instant is 5J

C) the rate of doing work at the instant by external agent is 2.5w

D) the rate of doing work at the instant on the block is 5w

4. A particle of mass m is released from a height H on a smooth curved surface which

ends into a vertical loop of radius R, as shown

If  is instantaneous angle which the joining the particle and the centre of the loop
makes with the vertical as shown. Then identify the correct statement(s) related to the
normal reaction N between the block and the surface

A) The maximum value N occurs at  =0

B) The minimum value of N occurs at  =  for H>5R/2

C) The value of N becomes zero at    for all H

D) Minimum value of H to complete vertical circular motion is 5R/2

5. A body of mass 1kg is suspended from an inextensible string of length 1 m. When the
string makes an angle 60o with lower vertical, speed of the bob is 4 m/s. (g=10m/s2)

A) Net acceleration of the bob at the instant is 10m / s 2

B) Net acceleration of the bob at the instant is 18.2m / s 2

C)The bob will rise to a maximum height  1.3m with respect to bottom most point

D) The bob will rise to a maximum height greater than 1.3m with respect to bottom
most point

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6. A boat is installed with two identical engines commutes between two towns P and Q
connected by a river. The boat takes t1=50.00 min on its way from P to Q with only one
ENGINE ‘on’ and t2 = 25.00min with both the ENGINES ‘on’. Force of water
resistance is proportional to velocity of the boat relative to water. Assume water flow
velocity to be uniform and the boat always moves with respect to water with its
maximum possible velocity.

Then( consider that both engine delivers same power)

A) We can conclude that the river flow is from P towards Q

B) We can conclude that the river flow is from Q towards P

C) On its way from Q to P with one engine on the minimum time the boat take is nearly
13min

D) On its way from Q to P with both engine on the min time the boat take is nearly
10.35 min

7. A plank is moving along a smooth surface with constant speed V. A block of mass ‘M’
is gently placed on it. Initially the block slips and then acquires the constant speed (V),
same as the plank. Throughout the period, a horizontal force is applied on the plank to
keep its speed constant. Then

A) Work performed by external force is MV 2

1
B) Work performed by external force is MV 2
2

1
C) The heat developed due to friction between the block and the plank is MV 2
2

D) power delivered by friction of plank on block is always zero

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8. An ideal spring is inserted in a 2.0m long transparent pipe held vertically on a floor and
then the lower end of the spring and the pipe are glued on the floor. Inner surface of the
pipe is friction less. A ball is dropped in to the pipe. Kinetic energy of the ball is
recorded at various heights above the floor and the data thus obtained are shown in the
following graph.

(note AB is straight line part of the graph) Identify the correct statement(s) from the
following?

A) the relaxed length of the spring is 1.5m

B) the force constant of the spring is 40N/m

C) the mass of the block is 0.5kg

D) the power delivered by the gravity to the block when it is at a height of 1.5m above
the floor is the maximum when compared to any other position in the graph.

9. A small sphere of mass m is connected by a string to a nail at O and moves in a circle

of radius ‘r’ on the smooth plane inclined at an angle  with the horizontal. If the
sphere has a velocity u at the top position marked A, identify the correct option(s)

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3rg
A) minimum velocity at A so that string does not get slack instantaneously is
5

11mg
B) tension at B if sphere has required velocity to just complete circle at A is
5

21mg
C) tension at C if sphere has required velocity to just complete circle is
5

3mg
D) centripetal force at point A is if it just get slack instantaneously
5

10. In the arrangement a special box is used to several identical plates each of mass ‘m’
and thickness ‘t0’ contains an ideal spring connected with light piston loaded in it.
When the box is empty, the piston touches the other end of the container and the spring
is relaxed. The plates can be inserted or pulled out through a opening at the top of the
box as shown in figure. Initially the box contains ‘n’ identical square plates each of
edge l =5cm. Coefficient of friction between all the surfaces in contact is  =0.5. all the
plates are pulled out one by one in two different waves as shown in figure. Let W1 and
W2 the work done by external agent pulling the plates in case-1 and case-2
respectively. It was noted that when n = 20,
|W2 – W1| =10J, then(g = 10m/s2)

A) mass of each plate is 50gm

B) mass of the plate cannot be concluded with out the information of force constant of
spring

C) W1  (kt0 n(n  1)  mgn2 )l , where k is force constant of spring

D) W2  (kt0 n(n  1)  mgn2 )l , where k is force constant of spring

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Narayana IIT Academy 28-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-9_Q’P
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
11. A particle of mass m is moving in a circular path of constant radius r such that its
centripetal acceleration is varying with time t as ac  k 2 rt 2 , where k is a constant. The
power delivered to the particle by the forces acting on it isas a function of time is
mk x r y t . Where x,y are integers. Find (x+y)

12. Consider the arrangement shown in the figure mass of the block A is 40 gm. Pulley

and string is light. Point P is pulled upward with velocity given by v  5tjˆ m / s . The
power in watt of the external force applied at P at t  4 second is………….( g=10m/s2.)

13. Power of the only force acting on a particle of mass 1kg moving in straight line
depends on its velocity as P  2 where  is in ms1 and P is in Watt. If initial
velocity of the particle is 1ms1 , then the magnitude of displacement of the particle in
'ln 2' seconds will be (in m)

14. A car of mass M is accelerating on a level smooth road under the action of a single
force F acting along the direction of motion. The power delivered to the car is constant
and equal to P . If the velocity of the car at an instant is V , then after travelling a
7 MV 3
distant of the velocity become kV . The k is
3P

15. A mass is attached to one end of a massless string, the other end of which is attached to
a fixed support. The mass swings in a vertical circle as shown in the figure. Assuming
that the mass has the minimum speed necessary at the top of the circle to keep the

string from going slack, at an angle   with upward vertical, the string is suddenly
n
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cut so that the resulting projectile motion of the mass has its maximum height position
located vertically above the centre of the circle. Find n

16. A pump lifts 1000 L water per minute from a 20 m deep well and ejects it at a speed of
20 ms1. Find the horse power of the motor required for the pump. If efficiency of the

motor is 80% if the electric power that it consumes is P hp then find the value of |P-3|
to the nearest integer? (1hp = 746W,g=10m/s2)
 
17. The combined frictional and air resistance on a bicyclist has the force F  aV where

V is his instantaneous velocity and a  4 newton – sec / m. At maximum effort, the
cyclist can generate 400 watt propulsive power. At this power the speed of the bicycle
N m/s. Find N/5.

18. A system of identical blocks A and B of masses 1kg each connected by a ideal spring
of force constant k1 is placed on aideal spring of force constant k2 , which rests on the
ground. Both the springs are vertical and the whole system is in equilibrium. Find
increment in gravitational potential energy of the system(in J) in lifting the block A
upwards until the lower spring becomes relaxed.

Given k1  k2  100 Nm1 ,g=10m/s2.

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19. Two beads of mass meach are initially at rest at the top of a friction less hoop of mass
M and radius R, which stands vertically on the ground. The beads are given tiny kicks,
and they slide down the hoop, on to the right and other to the left as shown in the
figure. The largest value of m/M for which the hoop never rises up off the ground is n.
Find 2n.

20. A particle of mass 5kg is free to slide on a smooth ring of radius r = 20cm fixed in a
vertical plane. The particle is attached to one end of a spring whose other end is fixed
to the top point O of the ring. Initially the particle is at rest at a point A of the ring such
that OCA  60o , C being the centre of the ring. The natural length of the spring is also
equal to r = 20cm. After the particle is released and slides down the ring the contact
force between the particle and the ring becomes zero when it reaches the lowest point
B. the force constant of the spring is (p x 100) N/m. find p

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CHEMISTRY Max Marks: 60
SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
21. SO3  g   CO  g  
 SO2  g   CO2  g  which of the following activity can reduce the

equilibrium concentration of CO to half?

A)Increasing pressure twice
B) Increasing the volume of reaction container to two times of its initial value
C) Adding two moles of CO2 gas
D) Adding two moles of helium gas at constant pressure
22. Degree of hydrolysis of a salt of strong acid and weak base is

A) Independent of dilution B) Increases with dilution

C) Decreases with increase in Kb value D) Increases with increase in Kb value

23. Value of VNaOH is

A) 291 ml B)145.5 ml C) 75 ml D) 582 ml

24. From the following plot, say which is the strongest electrolyte?

A) HA B) HB C) HC D) HD
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25. Pure PCl5  g  was introduced into an evacuated vessel and comes to equilibrium at
247 0 C and 2 atm pressure. At equilibrium the equilibrium mixture contains 40% by

volume of Cl2  g  PCl5  g  

 PCl3  g   Cl2  g 

Which of the following statement(s) regarding the above equilibrium is/are correct?

A) K P for the equilibrium is 1.6 atm

B) KC for the equilibrium is 0.071

C) Addition of inert gas to the equilibrium mixture at constant pressure increase the
number of moles of PCl3

D) Increase in pressure increases the number of moles of Cl2

26. If 0.1 M CH 3COOH  K a  1.8  105  is diluted at 250 C , then which of the following will

be correct?

A)  H   will increase B) pH will increase

C) Number of H  ions will increase D) K a will increase

27. When 0.1 mole solid NaOH is added in 1 L of 0.1 M NH 3  aq   K b  2  105  , then select

the correct statement(s)

A) Degree of dissociation of NH 3 approaches to zero

B) Change in pH by adding NaOH would be 1.85

C) In solution,  Na    0.1M ,  NH 3   0.1M , OH   0.2 M

D) On adding of OH  , K b of NH 3 does not changes

28. Which of the following is an amphiprotic anion?

A) HCO3 B) H 2 PO4 C) HS  D) HPO32

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29. Which of the following solutions at 298 K have pH less than 7.
[Given pKa of CH 3COOH  4.74]
A) 108 M HCl
B) 108 M NaOH
C) 10 mL of 106 M HCl diluted to 100 mL
D) 10 mL of 0.01 M CH 3COOH at the end point by titration using 0.01 M NaOH
30. Which of the following when mixed at 298 K, will give a solution with pH greater than
7?

A) 25 mL of 0.1M HNO3  25 mL of 0.1M NaOH

B) 100 mL of 0.1M CH 3COOH  100 mL of 0.1M KOH

C) 100 mL of 0.2M H 2 SO4  100 mL of 0.3M NaOH

D) 50 mL of 0.1M HCl  50 of 0.2M NaCl

SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
31. Compound x dissociated according to the reaction 2 X  g    2Y  g   Z  g  , with degree

of dissociation which is small compared to unity, if the expression for  in terms of

1/ n

equilibrium constant K P and total pressure P is given as    P  . The value of n is

2K
 P 

32. A one litre vessel contains 3 moles each of gases A,B,C and D at equilibrium. If one
mole each of A and B are removed, KC for A  g   B  g  
 C  g   D  g  will be

33. The following equilibrium was established at constant T in a rigid container starting
with only AB  g  , AB  g  
 A  g   B  g  .

The degree of dissociation of AB is 20% under these conditions & the relative vapour
density of the equilibrium mixture is ‘y’. Neon gas (inert) is added in the container
such that its mole fraction is 0.4. The vapour density of the gaseous mixture in the
container is ‘z’. Then y  z is

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34. The gaseous reaction: A  g   nB  g  
 mC  g  is represented by following curves

What is the value of n  m

35. The dissociation constant of a substituted benzoic acid at 250 C is 1 10 4 . Find the pH of
a 0.01 (M) solution of its sodium salt

36. CH 3COOH and CF3COOH in their aqueous solution ionizes as:

 CH 3COO   H 3O 
(I) CH 3COOH  H 2O 

K a1 , G10 , S10 are acid dissociation constant, standard free energy change & standard
entropy change respectively, for dissociation of acetic acid.
 CF3COO   H 3O 
(II) CF3COOH  H 2O 

K a2 , G20 , S20 are acid dissociation constant, standard free energy change & standard
entropy change respectively, for dissociation of trifluoroacetic acid. If both solutions
are 1M each then the number of correct statements amongst the following are?
(enthalpy change for both reactions are almost same)
(i) K a  K a
1 2
(ii) G10  G20

(iii) G10  G20 (iv) S10  S 20

(v) S10  S 20 (vi) S10 & S 20 are both positive

(vii) S10 & S 20 are both negative (viii) S 20  S10

(With increase in eletronegativity of surrounding atoms on adjacent carbon to COOH

group, increases strength of acid)

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37. A schematic graph of the first derivative of the pH curve is plotted for the titration of
10ml of unknown HCl solution by using 0.2M Ca  OH 2 , as shown

The concentration of HCl solution will be _______M

(Give your answer as nearest integer)

38. 3.838L water is added in 300 ml of 0.1M HA so that its  H   is decreased by a factor of

x, Ka for HA  1.6  10 4 find the approximate value of x

39. The following equilibrium exists in a closed vessel in 1L capacity

A  g   3B  g  
 4C  g 

Initial concentration of A  g  is equal to that of B  g  . The equilibrium concentration of

A  g  and C  g  are equal. K c for the reaction is

40. 200 ml of 1M CH 3COOH  K a  106  is mixed with 200 ml of 0.1M HCOOH  K a  105  .

The pH of the resulting mixture is

(Give your answer as near by integer)

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MATHEMATICS Max Marks: 60
SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
1  sin 2 x cos 2 x sin 2 x
41. If maximum and minimum values of sin 2 x 1  cos 2 x sin 2 x are  ,  ,
2
sin x 2
cos x 1  sin 2 x
then which of the following is/are true ?
A)    99  4

B)  3   17  26

C)  2 n   2 n is always an even integers for n  N

D) A triangle can be constructed having its sides as  ,  ,  

a2 a 2  (b  c ) 2 bc
42. The determinant b
2
b 2  (c  a ) 2 ca is divisible by
c2 c 2  ( a  b) 2 ab

A) a + b + c B) (a + b) (b + c) (c + a)

C) a2+ b2 + c2 D) (a – b) (b – c) (c – a)

1/ z 1/ z   x  y / z2
If     y  z  / x
2
43. 1/ x 1/ x then
 y  y  z  / x2 z  x  2 y  z  / xz  y  x  y  / xz 2

A)  is independent of z B)  is independent of x

C)  depends on z D)  is independent of y

2  2  1
44. If  1    a 4  b 3  c 2  d   e , then which of the following is/are true?
  2  1 

A) a  b  c  d  e  4 B) a  b  c  d  e  4

C) e  2 D) a  b  c  d  2

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45. If a1b1c1 , a2b2c2 , a3b3c3 are three digit numbers, each of which is divisible by a non – zero
a1 b1 c1
integer k, then   a2 b2 c2 is always
a3 b3 c3

A) divisible by k B) divisible by k 2

C) divisible by 2k D) not divisible by k

46. If a 2  b 2  c 2  ab  bc  ac  0, a, b, c  R , then the value of the determinant

 a  b  2 a 2  b2
2
1
b  c  2 b2  c2
2
1 is
c2  a2 c  a  2
2
1

A) 65 B) a 2  b 2  c 2  31 C) 4  a 2  b 2  c 2  D) 0

47. Which of the following values of ‘  ’ satisfy the equation

1    1  2  1  3 
2 2 2

 2     2  2   2  3   648 .
2 2 2

 3     3  2   3  3 
2 2 2

A) 0 B) 9 C) –9 D) 4

a c ca ac
c b bc bc
48. If    0 , then
ab bc 0 ac
x y z 1 x  y

A) a,b,c are in A.P B) b,a,c are in A.P

C) a,c,b are in G.P D) a,c,b are in H.P

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49. Which of the following is/are true?


, x    ,   , is 3
x
A) Numbers of solutions of  tan x 
2 4

x
B) Number of solutions of x 4  2 x 2 sin 2  1  0 is 2
2

C) Number of solutions of cos7 x  sin 4 x  1 in x   0,2  is 4

1 7
D) The smallest positive root of the equation sin 1  x   cos x is x  
2 4

1 1
50. A solution  x, y  of the system of equations x  y  and cos 2  x   sin 2  y   is
3 2

5 7
A)  ,  B)  ,  C)  ,  D)  , 
7 5 2 1 13 11

6 6  
3 3   6 6  6 6

SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
 2  3  1   3
t
51. If  1 2   4  p 4  q 3  r  2  s  t is an identity in  , then 
6
 3 4 3

x3  1 x2 y x2 z
52. Number of positive integral solution (x,y,z) of the equation xy 2 y3  1 y 2 z  11
xz 2 yz 2 z3  1
is

53.  
Let f  x   ln x  x 2  1 , then the value of determinant

 
f  sin 2017  f  sin


6
f e 
 2   2017   
determinat f  cos  f  cos  f  tan  is
 3   2   3
 5 

f e  f  cot


6 
f 0

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a1a5 a1 a2 a2 a10 a2 a3
54. If a1 , a2 , a3 ,....., a12 are in A.P.(all are distinct) and 1  a2 a6 a2 a3 ,  2  a3a11 a3 a4 ,
a3a7 a3 a4 a4 a12 a4 a5

then 1 :  2 is equal to_______

55. Let a third order determinant 1  a ij ; i, j  1, 2,3 and the determinant  2 is

constructed by multiplying the element aij of 1 by 2i j ,i.e.  2  2i j a ij ;i, j  1, 2,3 ,

5 2  41
then is equal to ______
5 2  41

56. Consider a matrix ‘A’ of order 3  3 given by

x 2018 x 2019  2018 x 2020  2019

A  x 2020  2018 x 2019 x 2018  2020 , x  R and f  x   det  A  , then the value
x 2019  2019 x 2018  2020 x 2020

2021
 f  r  r  2019  
of r 1 is
2018

cos  x    cos  x    cos  x   

57. If f  x   sin  x    sin  x    sin  x    , then f    2 f    f   is equal to _____
sin      sin      sin    

58. If a,b,c are the roots of the equation x 3  3 x 2  3 x  7  0 , then the value of

2bc  a 2 c2 b2
c2 2ac  b 2 a2 is
b 2
a 2
2ab  c 2

59. The number of solutions of the equation

 sin x  13   cos x  13   sin x 3   2sin x  cos x  2 3 in 0, 2  is

1 1
60. The number of solutions of the equation sin 5 x  cos5 x   ,  sin x  cos x  is
cos x sin x

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