PART-B (CHEMISTRY)

SECTION – 1 : (Maximum Marks : 80)

 This section contains TWENTY (20) questions.
 Each question has FOUR options (1), (2), (3) and (4) ONLY ONE of these four option is correct
 Marking scheme :
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases

31. The major product [B] in the following reactions is

(1) CH3 – CH2 – CH = CH – CH3

(4) CH2 = CH2

32. The major product obtained in the following reaction is

(1) (2)

(3) (4)


33.
 1

For emission line of atomic hydrogen from ni = 8 to nf = n, the plot of wave number  against  2  will be
n 
(The Rydberg constant, RH is in wave number unit)
(1) Linear with slope RH (2) Linear with intercept – RH
(3) Non-linear (4) Linear with slope – RH
34. Which of the following is not an essential amino acid?
(1) Tyrosine (2) Valine (3) Lysine (4) Leucine
35. Number of amphoteric compound among the following is __________
(1) BeO (2) BaO (3) Be(OH)2 (4) Sr(OH)2
36. The type of pollution that gets increased during the day time and in the presence of O3 is :
(1) Reducing smog (2) Oxidising smog (3) Global warming (4) Acid rain

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37. Among the following, the aromatic compounds are :

(A) (B) (C) (D)

Choose the correct answer from the following options :

(1) (A) and (B) only (2) (B) and (C) only (3) (B), (C) and (D) only (4) (A), (B) and (C) only

38. What is the major product formed by HI on reaction with

(1) (2)

(3) (4)

39. The IUPAC name for the following compound is

(1) 6-formyl-2-methyl-hex-3-enoic acid (2) 2, 5-dimethyl-6-carboxy-hex-3-enal

(3) 2, 5-dimethyl-5-carboxy-hex-3-enal (4) 2, 5-dimethyl-6-oxo-hex-3-enoic acid
40. Elevation in the boiling point for 1 molal solution of glucose is 2 K. The depression in the freezing point for
2 molal solution of glucose in the same solvent is 2 K. The relation between Kb and Kf is :
(1) Kb = 0.5 Kf (2) Kb = 2 Kf (3) Kb = 1.5 Kf (4) Kb = Kf
41. The process that involves the removal of sulphur from the ores is :
(1) Smelting (2) Roasting (3) Leaching (4) Refining
42. A solution of sodium sulphate contains 92 g of Na+ ions per kilogram of water. The molality of Na+ ions in
that solution in mol kg–1 is:
(1) 16 (2) 4 (3) 8 (4) 12
43. A group 15 element, which is a metal and forms a hydride with strongest reducing power among group 15
hydrides. The element is :
(1) Sb (2) P (3) As (4) Bi
44. The major product of following reaction is

(1) RCH2NH2 (2) RCHO (3) RCONH2 (4) RCOOH

45. The major component/ingredient of Portland Cement is :
(1) tricalcium aluminate (2) tricalcium silicate
(3) dicalcium aluminate (4) dicalcium silicate

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46. Consider the elements Mg. Al, S, P and Si, the correct increasing order of their first ionization enthalpy is :
(1) Mg < Al < Si < S < P (2) Al < Mg < Si < S < P
(3) Mg < Al < Si < P < S (4) Al < Mg < S < Si < P
47. In polymer Buna-S: 'S' stands for :-
(1) Sulphonation (2) Strength (3) Sulphur (4) Styrene
48. The correct order of the following compounds showing increasing tendency towards nucleophilic
substitution reaction is :-

(1) (iv) < (iii) < (ii) < (i) (2) (iv) < (i) < (ii) < (iii) (3) (iv) < (i) < (iii) < (ii) (4) (i) < (ii) < (iii) < (iv)
49. Given below are two statements :
Statement I : H2O2 can act as both oxidising and reducing agent in basic medium.
Statement II : In the hydrogen economy, the energy is transmitted in the form of dihydrogen.
In the light of the above statements, choose the correct answer from the options given below :
(1) Both statement I and statement II are false (2) Both statement I and statement II are true
(3) Statement I is true but statement II is false (4) Statement I is false but statement II is true
50. At 100°C, copper (Cu) has FCC unit cell structure with cell edge length of x Å. What is the approximate
–3
density of Cu (in g cm ) at this temperature?
[Atomic Mass of Cu = 63.55 u]
422 205 105 211
(1) (2) (3) (4)
x3 x3 x3 x3
SECTION – 2 : (Maximum Marks : 20)
 This section contains TEN (10) questions. You have to attempt any five (05) of them.
 The answer to each question is NUMERICAL VALUE with two digit integer and decimal upto one digit.
 If the numerical value has more than two decimal places truncate/round-off the value to ONE decimal
placed.
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : No negative marking.

51. The number of chiral carbons in chloramphenicol is ___________.

52. 

Consider the reaction N2 O4 (g) 
 2NO2 (g) . The temperature at which KC = 20.4 and KP = 600.1, is
______ K. (Round off to the Nearest Integer)
–1 –1
[Assume all gases are ideal and R = 0.0831 L bar K mol ]
53. The rate constant of a reaction increases by five times on increase in temperature from 27°C to 52°C. The
value of activation energy in kJ mol–1 is _______ (Rounded-off to the nearest integer)
–1 –1
[R = 8.314 J K mol ]

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54. On complete reaction of FeCl3 with oxalic acid in aqueous solution containing KOH, resulted in the
formation of product A. The secondary valency of Fe in the product A is ____.
(Round off to the Nearest Integer).
–1
55. The ratio of number of water molecules in Mohr's salt and potash alum is ________ × 10 .
(Integer answer)
56. The molar conductivities at infinite dilution of barium chloride, sulphuric arid and hydrochloric acid are 280,
2 –1
860 and 426 Scm mol respectively. The molar conductivity at infinite dilution of barium sulphate is
2 –1
_______S cm mol (Round off to the Nearest Integer).
57. The volume, in mL, of 0.02 M K2Cr2O7 solution required to react with 0.288 g of ferrous oxalate in acidic
medium is _______.
(Molar mass of Fe = 56 g mol–1)
58. Complete combustion of 3 g of ethane gives x  1022 molecules of water. The value of x is ______. (Round
off to the Nearest Integer).
23
[Use : NA = 6.023 × 10 ; Atomic masses in u : C : 12.0 ; O : 16.0 ; H : 1.0]
59. A xenon compound 'A' upon partial hydrolysis gives XeO2F2. The number of lone pair of electrons present
in compound A is _______(Round off to the Nearest integer)
60. Two solutions, A and B, each of 100 L was made by dissolving 4 g of NaOH and 9.8 g of H2SO4 in water,
respectively. The pH of the resultant solution obtained from mixing 40 L of solution A and 10 L of solution B
is________.

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