(Batches: e-SANKALP-2325 M1)

IIT – JEE, 2325 Paper Code

101185
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.

B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.

Enrolment No. :

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eSANKALP2325M1-PCM-Paper-(101185)-2

PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. Three charges q, q and –2q are fixed on the vertices of an equilateral triangular plate of edge
length a. This plate is in equilibrium between two very large plates having surface charge density
1 and 2 respectively. Find the period of small angular oscillation about an axis passing through
its centroid and perpendicular to plane. Moment of inertia of the system about this axis I.
0I 0I
(A) 2 (B) 2
qa | 1  2 | 2qa | 1  2 |
20I 2 0I
(C) 2 (D) 2
3qa | 1  2 | qa | 1  2 |

2. The switch Sw is shifted from position 1 to position 2 as shown in Sw 1

the figure. Heat generated in the circuit is
(A) independent of V1 C 2
(B) independent of V2
(C) dependent on V1
(D) dependent on V2
V1 V2

3. The distance between two parallel plates of a capacitor is a. A

conductor of thickness b(b < a) is inserted between the plates
x
as shown in the figure. The variation of effective capacitance b
a
between the surfaces of conductor and plate as a function of
the distance (x) is best represented by

(A) (B)
C C

x x
(a- b) (a - b)
(C) (D)
C C

x x
(a – b) (a – b)

Space for Rough work

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 eSANKALP2325M1-PCM-Paper-(101185)-3

4. A uniform electric field exist m space as shown m figure. A dipole a

placed horizontally. There may be point in the space P, where electric
field is zero. Then value of Q is
r
(A) tan1 2 (B) tan1 3
(C) tan 21
(D) 45 
– +

5. Four metallic plates each of surface area S are placed at

2d
some distance from each other as shown in the figure. P
Then capacitance of the system between P and Q is
0 S 0 S 2d
(A) (B)
3d 2d d
3 0 S 3 0 S Q
(C) (D)
2d d

6. What is the equivalent capacitance across the battery?

79 59 E
(A) C (B) C
30 30 C
41 21
(C) C (D) C C
30 30 2C C
C
C
C
C C

Space for Rough work

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eSANKALP2325M1-PCM-Paper-(101185)-4

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. There is a system of four large parallel plates A, B, C, and D.

Plates A and C are connected to each other with the help of
d d d
metallic wire and plates B and D are connected to the ground
with the help of open switches S1 and S2. Distance between  Q0
 2Q0
 Q0
consecutive plates is d. Initially plates A and B are having a
charge of Q0 each and plate D is having charge +2Q0 (See
figure). At t = 0 switches S1 and S2 are closed simultaneously.
Then the magnitude of charge flown through switch A B C D
(A) S1 is 5Q0 / 3 S1
S2
(B) S1 is Q 0
(C) S2 is 7Q0 / 3
(D) S2 is 2Q 0

8. Three capacitor C1 = 2F, C2 = 3F and C3 = 4Fare separately charged  +

with battery of potential difference 40V, 30V and 10V respectively and C1
then disconnected. After then they are connected to each other as
shown in figure. C3 + +
C2
 
800
(A) Final charge on capacitor C1 = C
13
800
(B) Final charge on capacitor C2 = C
13
380
(C) Final charge on capacitor C3 = C
13
(D) Amount of charge flow in circuit = Zero

9. A parallel plate capacitor with plate area A and separation d has charge Q. A slab of dielectric
constant k is inserted in space between the plates almost completely fills the space. If E0, U0 and
C0 be the electric field, potential energy and capacitance before inserting the slab, then
E
(A) the electric field after inserting the slab is 0
k
(B) the capacitance after inserting the slab is k C0
 1
(C) the induced charge on the slab is Q  1  
 k
U
(D) the energy stored in the capacitor becomes 0 , U0 being the energy of the capacitor before
k
inserting the slab

Space for Rough work

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 eSANKALP2325M1-PCM-Paper-(101185)-5

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the
second decimal place; e.g. xxxxx.xx).

10. A parallel plate capacitor is connected to a battery of emf V volts as shown. k=2
Now a slab of dielectric constant k = 2 is inserted between the plates of
capacitor without disconnecting battery. The electric field between the plates of
d
PV
capacitor after inserting the slab is E = . The value of P is
2d
V

11. A cavity is taken out from a uniform conducting sphere. P

Inside the cavity a dipole is placed as shown in the figure. d
Find the potential at point P (in Volt). +q

 R
(q = 108 C,  = 0.1 mm,  = 30, d = 10 cm, R = 12 cm) q

12. One end of a spring of negligible unstretched length

and spring constant k is fixed at the origin (0,0). A point
particle of mass m carrying a positive charge q is
attached at its other end. The entire system is kept on

a smooth horizontal surface. When a point dipole p
pointing towards the charge q is fixed at the origin, the
spring gets stretched to a length l and attains a new
equilibrium position (see figure below). If the point
mass is now displaced slightly by  l << l from its
equilibrium position and released, it is found to oscillate

1 k
at frequency . The value of is ______.
 m

Space for Rough work

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eSANKALP2325M1-PCM-Paper-(101185)-6

PART II : CHEMISTRY
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. The molecule which is isomeric with pentan-3-one and also showing positive iodoform test is
(A) pentanal (B) 3-methybutan-2-one
(C) 2,2-dimethylpropanal (D) pent-1-ene-3-ol

2. O
 i HCN

ii LiAlH
 4
iii NaNO /H
2
 A  . Product A will be
Major

(A) O (B) O

(C) (D)

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 eSANKALP2325M1-PCM-Paper-(101185)-7

3. Identify the starting reagent needed to make the following cyclic ketone by an intramolecular aldol
condensation reaction.

NaOH
?  
Heat

O
O
O O H
(A) (B)
O
O
O O

(C) (D)
O H

4.
O
H3O+
CH3– C – CCl3 + CH3MgBr(excess) A B

B is

(A) (B)
O
OH
CH3 – C – CH3
CH3 – C – CCl3
CH3

(C) (D) None of these

OCH3
CH3 – C – CCl3
CH3

Space for Rough work

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eSANKALP2325M1-PCM-Paper-(101185)-8

5. In the following sequence of reaction

O O

H dil. NaOH NaBH4

   A  B
NO2
The product (B) is:

(A) (B) OH

NO2
NO2
(C) O (D) None of these

NH2

H3C
6. i ) HSH 2C CH2  CH 2SH
  B. B is
O ii) Ph  Li
iii) CH3  CH 2X

H3C
S S
(A) O (B)
H3C
H3C
H3C
OH
H3C

(C) (D) S S
H
CH3 H3C Ph

Space for Rough work

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 eSANKALP2325M1-PCM-Paper-(101185)-9

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. Which of the following reaction products give haloform test?

(A) (B) Cl

H O/
HNO 
2
Q
OH 2
 P Cl
NH2
(C) O (D) H3 O
HCHO  CH3MBr  S



H3 O
H3C C OC2H5  R

8. Which compounds react with PCl5?

(A) CH3CHO (B) CH3COCH3
(C) C2H6 (D) C2H5OH

9. Which statements are correct in the case of acetaldehyde and acetone?

(A) both react with HCN
(B) both give iodoform test
(C) only acetaldehyde give aldol condensation product
(D) both can be reduced into alcohols

Space for Rough work

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eSANKALP2325M1-PCM-Paper-(101185)-10

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the
second decimal place; e.g. xxxxx.xx).

10. What is the maximum number of moles of CH3MgCl that can be consumed by one mole of
phosgene?

11. Among the following the total number of compound which give positive iodoform test is:
O O
H3C CH CH3 , H3C CH2 CH2 OH , H3C CH2 OH , H3C C CH3 , C CH3
OH
OH O O O
CH CH3 , H3C C OH , H3C C NH2 and H3C CH2 C CH2 CH3

12. How many equivalents of base are consumed in the following reaction?
Br /OH / 
CH3 CHO 
2
 HCBr3  HCOO
1 equivalent 

Space for Rough work

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 eSANKALP2325M1-PCM-Paper-(101185)-11

PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.

1.   y
The angle of intersection of curves e x cos y sin x  3 sin y e y  1  0 and e cos x sin y = sin x at
origin is
 
(A) (B)
2 3
 
(C) (D)
4 6

1

2. A continuous function f : [0, 1]  R satisfies  f  x  dx  4
0
1
Statement-I:  f  c  for some c  (0, 1)
1 c
1
Statement-II: f  c   for some c  (0, 1)
2c
1 1
Statement-III:  f c   for some c  (0, 1)
1 c 2c
(A) all statements are correct (B) statement-I is correct, II, III are incorrect
(C) statement-I, II are correct III is incorrect (D) statement-II is correct I, III are incorrect

3. If f(x) = (x – 1) |x2 – 2007x + 2010| + (sin(x – 1)).ln x has

(A) local min at x = 1 (B) local max at = 1
(C) no local extremum at x = 1 (D) none of these

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eSANKALP2325M1-PCM-Paper-(101185)-12

1
4. The minimum value of the function f(x)   {x} occurs at x equals to
2{ x}
(Where {.} represents fractional part function)
1 1
(A) n  , n I (B) n  , n I
2 2
1 1
(C) n  , n I (D) n  , n  I
2 2 2

5. The maximum value of

x 3

 3x  x 3  x 2  2x  2
is equal to
x 2
x2 
(A) 2 (B) –1
(C) 0 (D) 1

6. If f(x) is a twice differentiable function and given that f(1) = 2, f(2) = 5 and f(3) = 10, then
(A) f(x) = 2  x  (1, 3) (B) f(x) = f(x) = 2 for some x  (2, 3)
(C) f(x) = 3  x  (2, 3) (D) f(x) = 2 for some x  (1, 3)

SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

ax 2  bx  c
7. Let f(x) = . If f(x) is not a constant function and both minimum and maximum values
dx 2  ex  f
of f(x) exist then
(A) f(x) must be a continuous function (B) 4ac must be more then b2
2
(C) 4fd must be more then e (D) ae must not be equal to bd

Space for rough work

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 eSANKALP2325M1-PCM-Paper-(101185)-13

8. Let f : R+  R+ such that f(x) is a differentiable function and f(x) < 0 and f(x) f –1(x) + x2 – 16 = 0,
then
(A) equation has atleast one real root (B) equation has no real root
(C) equation has atleast two real roots (D) f(x)f–1(x) is a decreasing function

  
9. Let f(x) = cos2x.etanx, x    ,  then
 2 2

(A) f(x) has a point of local minima at x =
4
  
(B) f(x) has a point of local maxima in the interval   , 0 
 4 
  
(C) f(x) has exactly two points of local maxima/minima in   , 
 2 2
  
(D) f(x) has no root in   , 
 2 2

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. XXXXX.XX).

10. Let f : R  R be a differentiable function satisfying f(x) = f(y)f(x – y)  x, y  R and

4
f (0)   {2x}dx , where {.} denotes the fractional part function and f(–3) = e.Then | + | is
0
equal to

11. Suppose the function f(x) – f(2x) has the derivative 5 at x = 1 and derivative 7 at x = 2. The
derivative of the function f(x) – f(4x) – 10x at x = 1, is equal to

4
12. Let f be a continuous and differentiable function in (x 1, x2). If f(x).f(x)  x 1   f  x   and
2 1 2
lim  f  x    1 and lim   f  x   
. Then minimum value of  x12  x 22  is
x  x1 x x2 2
(where [.] denotes the greatest integer function)

Space for rough work

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eSANKALP2325M1-PCM-Paper-(101185)-14

(Batches: e-SANKALP-2325 M1)

IIT – JEE, 2325 Paper Code

101185
(CLASS XI)

ANSWERS
PHYSICS (PART-I)

1. C 2. D 3. C 4. A

5. B 6. A 7. A,C 8. A, C

9. A, B, C, D 10. 2.00 11. 0.00

12. 3.14 (0.50 to 0.50) or (3.13 to 3.15)

CHEMISTRY (PART-II)

1. B 2. A 3. C 4. D

5. B 6. B 7. A, C, D 8. A, B, D

9. A, B, D 10. 3.00 11. 5.00 12. 4.00

MATHEMATICS (PART-III)

1. C 2. A 3. C 4. B

5. D 6. D 7. A, C, D 8. A, D
9. A, B, C 10. 4 11. 9 12. 1

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 eSANKALP2325M1-PCM-Paper-(101185)-15

SOLUTIONS
PHYSICS (PART-I)
1. C
Net dipole moment = 3qa
| 1  2 | 
 =  3qa  I
20
2
3qa | 1  2 |  2  20 I
 I    T  2 .
20  T  3qa | 1  2 |

2. D

3. C
1 1 1
 
C C1 C2
x a b  x
= 
0 A 0 A
0 A
 C=
ab

4. A
At point P. Net electric field must be zero. Electric field due to E
diapole must be vertically upward.
     90 r 
tan 
tan   
2 – +
tan 
tan(90  ) 
2
tan 
cot  
2
tan2   2
  tan1 ( 2)

5. B
C1 and C 2 are in parallel and equivalent of C1 and C3
is series with C3 1 2 2 3 3 4

0 S S S
C1  , C2  0 , C3  0
2d 2d d C1 C2 C3
 S
C1  C2  0
d
S
Required Cequivalent = 0
2d

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eSANKALP2325M1-PCM-Paper-(101185)-16

6. A
Equivalent circuit can be drawn as C C 2/3C C
79 2C
2C
Equivalent capacitance = C. C C 
30 C
C C

C C C C

2C 2C
 8/3C C 
C C 19C/11

7. A,C
d d d
0 Q0 Q0 Q0 Q0 Q0 Q0 0
    
3 3 3 3 3 3

A B C D

S2
S1

8. A, C
–80 – q 40 – q 90  q
–  =0
2 4 3
240
q= C
13

9. A, B, C, D
Use the concept of capacitor.

10. 2.00

11. 0.00
Charge on the outside surface of conducting sphere is zero so field and thus potential at any
point outside the sphere is zero.

12. 3.14 (0.50 to 0.50) or (3.13 to 3.15)

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 eSANKALP2325M1-PCM-Paper-(101185)-17

CHEMISTRY (PART-II)

1. B
For a compound to show positive iodoform test the molecule should either have CH3CO- or
CH3CH(OH)- groups. Out of the options given all of them are isomers of pentan-3-one as they
have the same molecular formula but different structural formula, 3-methybutan-2one satisfies
both the condition of being an isomer of pentan-3-one and also showing positive iodoform test.
O OH
O O
H3C H3C H3C CH3
CH3
H H
CH3 H3C
CH3 CH2

3-methylbutan-2-one 2,2-dimethylpropanal pent-1-en-3-ol

pentanal
2. A
OH OH
CN OH O
CH2 NH2
CH2

3. C
4. D

O

CH3 – C – CCl3 + CH3MgBr

O O OH
1) CH3MgBr
CH3 – C – CCl3 CH3 – C – CH3 CH3 – C – CH3
2) H2O
CH3
CH3
5. B
O O O

H dil. NaOH
  

NO2 NO2

NaBH4

OH

NO2
 Crossed-Aldol condensation
 NaBH4 does not reduce C = C and NO2 gr.

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eSANKALP2325M1-PCM-Paper-(101185)-18

6. B

PhLi CH 3CH 2X

S S S S S S

H3C H CH3 H3C

H3C
7. A, C, D

P=

Q=
O

Oxidation by XO
R= CH3 COOH  C2H5 OH ; C2H5 OH  CH3 CHO

OH

S = H3C C H
H
8. A, B, D
Nucleophilic addition reaction over carbonyls.

9. A, B, D

10. 3

O O O Me
MeMgCl MeMgCl MeMgCl
Cl C Cl 
 Me C  Me
Cl  C Me 
 Me C Me
O

11. 5
The following compounds give positive iodoform test
O O OH
H3C CH CH3 , H3C CH2 OH , H3C C CH3 , C CH3 , CH CH3
OH

12. 4
Three equivalents to remove three hydrogens from CH3 group and one for attack on C of CHO
group.

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 eSANKALP2325M1-PCM-Paper-(101185)-19

MATHEMATICS (PART-III)
1. C
Let x = ky and y = m 2x be tangents, then for y, x very close to zero
 x2  y2 yy  x3   y3  y2 
 1  x  .....  1   .....  x    3  y  .....   y  .....   0
 2  2 4!  3!   3!  2 
 2 x3 xy 2   y3 y4 
x  x   .....   3  y 2   .....   0
 2 2   2 3! 
2 2 4
 x   y y 
 k  kx  k .....   3  y   0
 2   2 3! 
x
As x, y  0,  k  k = 0. Similarly m 2 = 1
y
2. A
1 1
1
Let g  x  
1  x2
,  f  x  dx   g  x  dx
0 0
1
   f  x   g  x   dx  0
0
1
 f(c) = g(c) for some c  (0, 1) =
1 c2
1 1 1
Since c  (0, 1),  
1  c 1  c 2 2c

3. C
As f(1) = 0
f(1+) > 0
f(1–) < 0  no local extremum at x = 1

4. B
1 1 1
f(x)   1   x   { x}   1  f(x)  2   1 . (AM  GM)
2  x 2{ x} 2
1 1 1
 fmin  2  1 which occurs when {–x} =  x  n   x n ,nI
2 2 2

5. D
 
x3  3x  x3  x 2  2x  2

x2  x  2
1
x2  x  2 x2  x  2

6. D
2
Let g(x) = f(x) – x – 1
g(1) = g(2) = 0
So; g(C1) = 0 for at least one C1  (1, 2)
Similarly g(C2) = 0 for at least one C2  (2, 3)
Using LMVT on x  (C1, C2)
g  C2   g  C1 
g(C) = 0
C2  C1
f(C3) = 2

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eSANKALP2325M1-PCM-Paper-(101185)-20

7. A, C, D
For f(x) to be bounded, its denominator should never become zero. So, its discriminant must be
ax 2  bx  c a
negative. Also for some finite x, f(x) must be equal to lim f(x) i.e., 
x  dx 2  ex  f d
 bdx + cd = aex + af
 (ae – bd)x = cd – af
So, ae  bd

8. A, D
–1 2
Let g(x) = f(x) f (x) and h(x) = – x + 16
Hence g(x) is a decreasing function as g(x) < 0
For g(x) = h(x) these two graph intersect atleast one point when x  (0, )

9. A, B, C
f(x)  cos2 x  etan x  f '(x)  etan x (1  sin 2x)
 f "(x)  etan x ( 2cos 2x)  etan x sec 2 x  (1  sin2x)
  tan2 x  1  
 f "(x)  etan x 2  2 
  sec 2 x  2 tan x   = f(x)(tan x  1)  tan3 x  tan2 x  3 tan x  1
  1  tan x  
Now, let g(x)  tan3 x  tan2 x  3 tan x  1  g'(x)   3 tan2 x  2 tan x  3  sec 2 x  0
    
So, g(x) is increasing. Also, g    g(0)  0 . So, g(x) has exactly one root in   , 
 4  2 2
   
So, f(x) has exactly two roots in   ,  . At x  , f(x) has a local minima
 2 2 4

10. 4
Given f(x) = f(y)f(x – y)
Replace x by (x + y)
f(x + y) = f(y).f(x)
4
 f(x) = ekx  f(x) = kekx. But f(0) =  {2x}dx  2
0
2x
 f(0) = k = 2  f(x) = 2e
 f(–3) = 2e–6  | + | = 4

11. 9
y = f(x) – 2f(2x)
y(1) = f(1) – 2f(2) = 5 …(1)
and y(2) = f(2) – 2f(4) = 7 …(2)
Now let y = f(x) – f(4x)
y = f(x) – 4f(4x)
y(1) = f(1) – 4f(4) …(3)
Substituting the value of f(2) = 7 + 2 f(4) in (1)
f(1) – 2 [7 + 2 f(4)] = 5
f(1) – 4f(4) = 19

12. 1
2f  x   f   x  d  2

 2x  0  sin1  f  x    x2  0
4 dx
1  f  x 
–1 2 2
Let g(x) = sin ((f(x)) ) – x is a non-decreasing function.

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 eSANKALP2325M1-PCM-Paper-(101185)-21

 lim  g  x   lim  g  x 
x  x1 x x2

 
  x12   x 22
2 6
2 2 
 x1  x 2    x12  x 22   1
3

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