Revision date: 26/11/2019 Revision: 5

SAFETY DATA SHEET

MEC 4610

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name MEC 4610

Product number MEC4610

Synonyms; trade names Chlorine Bleach, Soda Bleach

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Biocides

1.3. Details of the supplier of the safety data sheet

Supplier Malaysian Energy Chemical & Services Sdn Bhd
No 2, Jalan PJU 8/8A,
Damansara Perdana,
47820 Petaling Jaya, Selangor
Tel No. +603 7611 4000
Fax No. +603 7611 4105

1.4. Emergency telephone number

Emergency telephone +609 862 3200 (During Office Hours Only)
+1 (703) 527-3887 (CHEMTREC International)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Met. Corr. 1 - H290

Health hazards Skin Corr. 1B - H314 Eye Dam. 1 - H318

Environmental hazards Aquatic Acute 1 - H400

Classification (67/548/EEC or C;R34. N;R50. R31.

1999/45/EC)

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.

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Precautionary statements P260 Do not breathe vapour/ spray.

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P390 Absorb spillage to prevent material damage.
P501 Dispose of contents/ container in accordance with national regulations.

Contains SODIUM HYPOCHLORITE SOLUTION, ... % Cl ACTIVE

Supplementary
precautionary P234 Keep only in original container.
statements P264 Wash contaminated skin thoroughly after handling.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.

2.3. Other hazards

Other hazards None known.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SODIUM HYPOCHLORITE SOLUTION, ... % Cl ACTIVE 10-30%

CAS number: 7681-52-9 EC number: 231-668-3
M factor (Acute) = 10

Classification Classification (67/548/EEC or 1999/45/EC)

Met. Corr. 1 - H290 C;R34 R31 N;R50
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400

SODIUM HYDROXIDE <1%

CAS number: 1310-73-2 EC number: 215-185-5

Classification Classification (67/548/EEC or 1999/45/EC)

Met. Corr. 1 - H290 C;R35
Skin Corr. 1A - H314
Eye Dam. 1 - H318

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

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Inhalation Remove affected person from source of contamination. Get medical attention if any discomfort
continues. When breathing is difficult, properly trained personnel may assist affected person
by administering oxygen.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinse
mouth thoroughly with water. Give plenty of water to drink. DO NOT induce vomiting. Get
medical attention immediately. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs.

Skin contact Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes. Remove
contaminated clothing and rinse skin thoroughly with water. Get medical attention
immediately. Chemical burns must be treated by a physician.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes and get medical attention. Get medical
attention.

4.2. Most important symptoms and effects, both acute and delayed
General information See Section 11 for additional information on health hazards.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media
suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Sodium hypochlorite becomes oxidising as it dries and can cause spontaneous fires under the
correct conditions. Beware of small spillages and thoroughly rinse cloths/rags/mops used to
clean spillages.

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Chlorine. Oxygen.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Keep up-wind to avoid fumes. Cool containers exposed
firefighting to flames with water until well after the fire is out. Control run-off water by containing and
keeping it out of sewers and watercourses.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate
ventilation. Use suitable respiratory protection if ventilation is inadequate. Avoid inhalation of
vapours and contact with skin and eyes. In case of spills, beware of slippery floors and
surfaces.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

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Methods for cleaning up Absorb spillage with inert, damp, non-combustible material. Flush contaminated area with
plenty of water. Do not allow spillages to dry out, flush thoroughly with water. Collect and
place in suitable waste disposal containers and seal securely. Label the containers
containing waste and contaminated materials and remove from the area as soon as possible.
If involved in a fire, shut off flow if it can be done without risk. Containers with collected
spillage must be properly labelled with correct contents and hazard symbol.

6.4. Reference to other sections

Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. Collect and
dispose of spillage as indicated in Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid inhalation
of vapours. Use approved respirator if air contamination is above an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store away from the following materials: Acids. Store at moderate temperatures in dry, well
ventilated area. Use containers made of the following materials: Glass. Polyethylene-lined
mild steel. Suitable plastic material.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
SODIUM HYDROXIDE
Long-term exposure limit (8-hour TWA): WEL
Short-term exposure limit (15-minute): WEL 2 mg/m³
WEL = Workplace Exposure Limit

WATER (CAS: 7732-18-5)

Ingredient comments No exposure limits known for ingredient(s).

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection Wear protective gloves. Rubber (natural, latex). Neoprene. Polyvinyl chloride (PVC). The most
suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can
provide information about the breakthrough time of the glove material. It should be noted that
liquid may penetrate the gloves. Frequent changes are recommended.

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Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact. Wear apron or protective clothing in case of contact.

Hygiene measures Provide eyewash station and safety shower. Wash hands at the end of each work shift and
before eating, smoking and using the toilet. Promptly remove any clothing that becomes
contaminated. When using do not eat, drink or smoke. Wash promptly with soap and water if
skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. Wash
contaminated clothing before reuse.

Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended
occupational exposure limit. If ventilation is inadequate, suitable respiratory protection must
be worn. Chemical respirator with organic vapour cartridge.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Colourless to pale yellow.

Odour Chlorine.

Relative density 1.235 - 1.27 @ 25°C

Solubility(ies) Completely soluble in water.

Viscosity < 20 cP @ 20°C

9.2. Other information

Other information Not available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid contact with strong reducing agents. Avoid exposure to high temperatures or direct
sunlight.

10.5. Incompatible materials

Materials to avoid Strong reducing agents. Ammonia. Amines. Chemically-active metals. Strong acids.

10.6. Hazardous decomposition products

Hazardous decomposition Thermal decomposition or combustion products may include the following substances :
products Chlorine. Oxygen.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation May cause respiratory irritation.

Ingestion Corrosive. Small amounts may cause serious damage. Swallowing concentrated chemical
may cause severe internal injury. May cause chemical burns in mouth, oesophagus and
stomach.

Skin contact Causes severe burns. May cause serious chemical burns to the skin.

Eye contact Causes serious eye damage.

Acute and chronic health This product is corrosive. This product may cause skin and eye irritation. Prolonged contact
hazards may cause burns.

Route of entry Inhalation Ingestion.

Target organs Eyes Skin Respiratory system, lungs Gastro-intestinal tract

SECTION 12: Ecological Information

Ecotoxicity The product contains a substance which is very toxic to aquatic organisms.

12.1. Toxicity
Toxicity Poisonous to fish and plankton in water bodies

Ecological information on ingredients.

SODIUM HYPOCHLORITE SOLUTION, ... % Cl ACTIVE

Acute aquatic toxicity

LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Acute toxicity - fish LC₅₀, 96 hours: 0.1-2.48 mg/l, Fish

SODIUM HYDROXIDE

Acute toxicity - fish LC₅₀, 96 hours: 179 mg/l, Fish

12.2. Persistence and degradability

Persistence and degradability The product is expected to be slowly biodegradable.

Ecological information on ingredients.

SODIUM HYDROXIDE

Persistence and The product contains only inorganic substances which are not biodegradable.
degradability

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

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12.4. Mobility in soil
Mobility The product is soluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB No data available.
assessment

12.6. Other adverse effects

Other adverse effects Not known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Empty containers should be taken for local recycling, recovery or waste disposal

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Reuse or recycle products wherever possible.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1791

UN No. (IMDG) 1791

UN No. (ICAO) 1791

14.2. UN proper shipping name

Proper shipping name HYPOCHLORITE SOLUTION
(ADR/RID)

Proper shipping name (IMDG) HYPOCHLORITE SOLUTION

Proper shipping name (ICAO) HYPOCHLORITE SOLUTION

14.3. Transport hazard class(es)

ADR/RID class 8

IMDG class 8

ICAO class/division 8

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

14.5. Environmental hazards

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Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-B

14.7. Transport in bulk according to Annex II of MARPOL and the IBC
Code
Transport in bulk according
to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of
Hazardous Chemicals) Regulation 2013
Occupational Safety and Health Act 1994
Environmental Quality Act 1974

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Revision comments Review overall SDS.

Issued by FY

Revision date 26/11/2019

Revision 5

Risk phrases in full R31 Contact with acids liberates toxic gas.
R34 Causes burns.
R35 Causes severe burns.
R50 Very toxic to aquatic organisms.

Hazard statements in full H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.

The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process unless specified in the text.

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