JEE ADVANCED PAPER – 2

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Time : 3 Hours Maximum Marks : 180

ANSWER KEY

Solutions with Explanation

PART – 1 : MATHEMATICS

SECTION 1 (Maximum Marks: 18)

• This section contains SIX (06) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH
INCLUSIVE.
• For each question, enter the correct numerical value of the answer using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer. .

Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +𝟑 If ONLY the correct numerical value is entered.
Zero Marks : 0 If the question is unanswered.
Negative Marks : −𝟏 In all other cases.

2t sin⁡ x
1. If the two lines AB: (∫0 ( + 1) dx) x + y = 3t and AC: 2tx + y = 0 intersect at a point A,
x

p
then x-coordinate of point A as t → 0, is equal to q ( p and q are in their lowest form). Find

(p + q).

cos−1 (x 2 − 4x + 5) + x 2
√f(x)dx
2. If I = ∫ π
√f(
sin−1 (x 2 − 4x + 5) − 2x 2 −x)+√f(x)

then find [I] (where [·] denotes greatest integer function)

2
x2
3. If the minimum value of (x1 − x2 )2 + (201 − √(17 − x2 )(x2 − 13)) ,

where x1 ∈ R+ , x2 ∈ (13,17) is (a√b − b)2 where a and b are coprime number then a + b =

4. Find number of integral values of ' λ ' for which equation x 2 + λxy + y 2 = 1 represents an ellipse.
x 2tdt 1
5. limx→0 ∫0 2a t
= 19, then a =
(ex −1−x)√ − +104
3 2

a3r+1 +a3r+2
6. If (1 + x + x 2 )3n+1 = a0 + a1 x + a2 x 2 + ⋯ … . . +a6n+2 x 6n+2 then find ∑2n
r=0 (a 3r − ( ))
2

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SECTION 2 (Maximum Marks: 24)

• This section contains SIX (06) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If only (all) the correct option(s) is(are) chosen.
Partial Marks : +𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +𝟐 If three or more options are correct but ONLY two options are chosen, both
of which are correct.
Partial Marks : +𝟏 If two or more options are correct but ONLY one option is chosen and it is
a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟐 In all other cases.

7. The volume of the parallelopiped whose coterminous edges are represented by the vectors
⃗ × c, 3c × a⃗ and 4a⃗ × b
2b ⃗ = sin⁡ (θ + 2π) î +
⃗ where a⃗ = (1 + sin⁡ θ)î + cos⁡ θĵ + sin⁡ 2θk̂, ⁡b
3
2π 4π 2π 2π 4π
cos⁡ (θ + ) ĵ + sin⁡ (2θ + ) k̂, c = sin⁡ (θ − ) î + cos⁡ (θ − ) ĵ + sin⁡ (2θ − ) k̂ is 18
3 3 3 3 3
π
cubic units, then the values of θ, in the interval (0, 2 ) is/are
π 2π π 4π
(A) 9 (B) (C) 3 (D)
9 9

8. Two sides of a rhombus OABC (lying entirely in first quadrant or third quadrant) of area equal
x
to 2 sq. units are y = , y = √3x. Then possible co-ordinates of B is/are (O being origin)
√3

(A) (1 + √3, 1 + √3) (B) (−1 − √3, −1 − √3)

(C) (√3 − 1, √3 − 1) (D) None of these

9. Let R be the region containing the point (x, y) on the X − Y plane, satisfying
2 ≤ |x + 3y| + |x − y| ≤ 4, then
(A) R is enclosed between two rectangles
(B) R is enclosed between two parallelograms
(C) the area of R is 6 sq. units
(D) the area of R is 8 sq. units

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10. A and B are two events. Suppose
A : It rains today with P(A) = 40%
B : It rains tomorrow with P(B) = 50%Also P (It rains today and tomorrorw) = 30%
Also ⁡E1 : P((A ∩ B)/(A ∪ B)) and E2 : P({(A ∩ B‾) or (B ∩ A‾)}/(A ∪ B)) then which of the
following true?
(A) A and B are independent (B) P(A/B) < P(B/A)
(C) E1 and E2 are equiprobable (D) P(A ∣ A ∪ B) = P(B/A ∪ B)

P P a a
11. Let (q1 , q2 ) and (b1 , b2 ) be any two rational points on the circle x 2 + y 2 = 1 where
1 2 1 2

P1 , P2 , q1 , q 2 , a1 , a2 , b1 and b2 are integers and HCF of (P1 , q1 ), (P2 , q 2 ), (a1 , b1 ) and (a2 , b2 ) is 1 .
Then the statements which are always correct are
(A) q1 = q 2
(B) p1 = ±1 or 0
(C) b1 = b2
(D) a1 = ±1 or 0

12. If f(x − y), f(x)f(y) and f(x + y) are in A.P. for all x, y ∈ R and f(0) ≠ 0 then
(A) f ′ (x) is an even function
(B) f ′ (1) + f ′ (−1) = 0
(C) f ′ (2) − nf ′ (−2) = 0
(D) f ′ (3) + f ′ (−3) = 0

SECTION 3 (Maximum Marks: 24)

• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value
has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

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4 1 5 1 6 1 7 1 m
13. Let S = 1.2.3 . 3 + 2.3.4 . 32 + 3.4.5 . 33 + 4.5.6 . 34 …up to ∞ terms, then S = (m, n are coprime natural
n

numbers). Then m + n = _________ .

14. Number of integral values of p for which the equation √p cos x − 2⁡sin x = √2+√2 − p
possesses a solution, is_______ .
15. Two fair dice, each with faces numbered 1,2,3,4,5 and 6, are rolled together and the sum of the
numbers on the faces is observed. This process is repeated till the sum is either a prime
number or a perfect square. Suppose the sum turns out to be a perfect square before it turns
out to be a prime number. If is the probability that this perfect square is an odd number, then
the value of 14p is________ .

2π π
1
16. If Equation⁡2(cos−1x) − (a + 2) 2(cos−1 x) − a2 = 0 has only one real root where
|m|
a ∈ (−∞, −m] ∪ [n⁡, ∞)⁡then⁡ =⁡?
n

17. Let : R → R be a differentiable function such that its derivative f ′ is continuous and f(π) = −6.
x π
If F: [0, π] → R is defined by F(x) = ∫0 f(t)dt, and if ∫0 (f ′ (x) + F(x))cosx⁡dx = 2 then the value
of f(0) is______ .

1 1
18. If f(x) = max {x 4 , x 2 , 81} ∀⁡x ∈ [0, ∞) then⁡⁡10 { sum of square of reciprocal values of x } where

f(x) is Non differentiable, is equal to ______________ .

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PART – 2 : PHYSICS

SECTION 1 (Maximum Marks: 18)

• This section contains SIX (06) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH
INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse
and the on-screen virtual numeric keypad in the place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟑 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 In all other cases.

19. A rod of length l forming an angle θ with the horizontal strikes a frictionless floor at A with its
centre of mass velocity v0 and no angular velocity. Assuming that the impact at A is perfectly
elastic, the angular velocity of the rod immediately after the impact is found to be ω =
kv0 cos⁡ θ
. Find k.
l(1+3cos2 ⁡ θ)

20. The diagram shows the PV diagram of a process carried out with a certain quantity of oxygen
7 2 5
(γ = 5). If VA = 3 V0 and VB = 12 V0 , find the volume till the gas absorbs heat. If this volume is
N
V0 , the find N.
12

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21. An object is moving with a velocity of 5 cm/s at an angle of 60∘ with respect to the optic axis of
a fixed concave mirror of focal length 100 cm. The object is at a distance of 50 cm from the
mirror. The velocity of image at the given instant is found to be −10î + K√3ĵ cm/sec. Find K.

d
22. In the YDSE the monochromatic source of wavelength λ is placed at a distance from the
2

central axis (as shown in figure), where d is the separation between the two slits S1 and S2 . The
minimum thickness of the film of refractive index μ = 1.5 to be placed infront of S2 , so that
3
intensity at O becomes th of the maximum intensity is K times 29 × 10−7 metres. Then the
4

value of K is (d <<)

(Take λ = 6000Å; d = 3mm.)

23. A wire is stretched between two fixed points separated by a distance of 2 m such that tension in
it is equal to 30.25kgwt. The wire vibrates in its first overtone. A closed organ pipe of length
5/3 m is brought near the wire. The temperature of the gas in the pipe is 27∘ C. When the organ
pipe is made to vibrate in second overtone, five beats are heard every second. If the tension in
the string is reduced slightly then the number of beats heard per second is reduced to three.
Find the linear (mass) density of the wire in gram/metre. Given Cp /Cv of gas in the organ pipe
= 1.44 and its mean molar mass is 27.7gm.

24. A gas containing hydrogen like ions with atomic no Z, emits photons in transition n + 2 → n,
where n = Z. These photons fall on a metallic plate and eject electrons having minimum de-
Broglie wavelength λ of 5Å. Find the value of ' Z ' if the work function of metal is 4.2eV.

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SECTION 2 (Maximum Marks: 24)

• This section contains SIX (06) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +𝟐 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +𝟏 If two or more options are correct but ONLY one option is chosen and it is
a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟐 In all other cases.

25. A room air conditioner is modelled as a heat engine run in reverse. An amount of heat Qin is
absorbed from the room at a temperature TL by the cooling coils which contains a working gas;
this gas is compressed adiabatically to a temperature TH ; then the gas is compressed
isothermally in a coil outside of the house, giving off an amount of heat Qout ; the gas expands
adiabatically back to a temperature TL and finally expanded isothermally to original state and
the cycle is repeated. An amount of energy W is input into the system in every cycle through an
electric pump. This model describes the air conditioner with the best possible efficiency.

The outside air temperature is TH and the inside air temperature is TL . The air conditioner unit
consumes electric power P. Assume that the air is dry sufficiently so that no condensation of
water occurs in the cooling coils of the air conditioner. Which of the following may be the rate
at which heat is removed from the room?

P TL 3P TL TL 3P TL
(A) 2 (T ) (B) (T ) (C) P (T ) (D) (T )
H −TL 4 H −TL H −TL 2 H −TL

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26. A conducting medium is shaped in a form of a quarter of an annulus of radii ' b '
and a(b>a) and thickness ' t '. Specific resistance of the medium is 'ρ'. The
CORRECT option(s) is/are

2ρ b
(A) Resistance between faces LMNO and PQRS is πt ln⁡ a
πρ
(B) Resistance between faces LMRS and ONQP is b
2tln⁡( )
a

4tρ
(C) Resistance between faces MRQN and LSPO is
b2 −a2

(D) Between faces LMNO & PQRS and LMRS & ONQP, resistance is same.

27. Two resistors, one inductor and a capacitor are connected in a circuit with a battery and switch
as shown in figure. The charge on capacitor and current in inductor is zero at t = 0. Now switch
is closed at t = 0, then choose the CORRECT option(s).

(A) The ratio of maximum current in the branch of inductor to the branch of capacitor is 200.
ln⁡ 2
(B) At t = , the current in the branch of capacitor is 200 times the current in the branch of
8

inductor.

1 5
(C) At t = 8 ln⁡ (4), the potential drop across inductor is 4 times the potential drop across

capacitor.
(D) The potential drop across inductor is maximum at t = 0.
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28. A small disc of mass ' m ' is released on a parabolic curve in a vertical plane such that gravity
2a
acts along negative y-axis. The equation of parabolic curve is x 2 = y, where ' a ' is a positive
√3

constant. Frictional force between disc and curve are sufficient for pure rolling. When disc is
reached at x = a then choose the CORRECT option(s).
(A) Acceleration of disc along the trajectory is √3g
g
(B) Acceleration of disc along the trajectory is
√3
mg
(C) Frictional force between disc and curve is 2
√3
mg
(D) Frictional force between disc and curve is
√3

29. An object ' O ' is kept infront of a converging lens of focal length 30 cm behind which there is a
plane mirror at 15 cm from the lens.
(A) The final image is formed at 60 cm from the lens towards right of it
(B) The final image is at 60 cm from lens towards left of it.
(C) The final image is real.
(D) The final image is virtual.

30. A light string is wrapped on a cylindrical shell and a fraction of length of string is unwrapped. A
particle of mass 2 M is attached on another end of string as shown. The system is kept in a
vertical plane and cylinder can freely rotate about the axis of cylinder Particle is released as
shown in figure. Assuming there is no slipping between cylinder and string. Choose the
CORRECT option(s).

8 g
(A) The angular velocity of cylinder just after string taut is 3 √R

16 g
(B) The angular velocity of cylinder just after string taut is √R
3

8
(C) Velocity of particle just after string taut is 3 √gR
16
(D) Velocity of particle just after string taut is √gR
3

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SECTION 3 (Maximum Marks: 24)

• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value
has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

31. In a screw gauge, there are 100 divisions in circular scale and each main scale division is of
1 mm, length. When there is no gap between the jaws, 97th division coincides with the main
scale zero and zero of main scale is not visible. While measuring the diameter of a ball, the
circular scale is between 3 cm mark and 4 cm mark such that the 76th division of circular scale-
coincides with the reference line, then diameter of the ball is (in cm)

32. Find the magnetic field at the centre ' C ' due to a spinning spherical shell of radius R,
charge/area σ rotating about its diameter with an angular velocity ω = 3rad/sec, R = 2 m,
1.5
σ= C/m2 . Magnetic induction at centre is B × 10−6 (in tesla). Find ' B '
π

33. A string is stretched between a pulley and a wave generator consisting of a plate vibrating up
and with small amplitude and frequency 120 Hz. The standing wave pattern has 4 nodes as
shown. What should be the load (in gm) we want a standing wave with 5 nodes.

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34. Three monochromatic sources having wavelengths 12.42 nm, 6.21 nm and 24.84 nm are placed
close to each other in front of a converging lens such that equal powers from the three equal to
1 mW each fall on a converging lens and then on a small spherical conductor of radius r =
1 mm and work function 62.1 eV (Assume 50% efficiency of emission and no change in
effective value of work function due to photoelectric emission and potential rise) (Use hc =
1242eV − nm) (All electrons emitted by the sphere are immediately removed by some non-
electrical mechanism). At t = 8sec switch S is closed so that the sphere gets connected to the
earth via a resistor of value 6.75 m. Find the current flowing just after the switch is closed. is
10 K Find K = ?

35. In the arrangement shown, a gas is filled inside a balloon, which is placed in a vertical magnetic
field of intensity B. The initial volume of balloon is V0 and the gas is filled inside it at the rate of
a m3 /s. If there is no leakage, find the emf induced (in mV) at t = 8π⁡sec, in a conducting ring,
which is elastic and placed horizontally along the largest circumference of balloon.
[Take : B = 1.5 T, V0 = (20π)m3 , a = 2]

36. Figure shows a container having adiabatic walls and a freely movable separator which is highly
conducting. The separator divides the cylinder in two equal parts A and B each containing 2
moles of ideal diatomic gas at temperature 300 K. Now a heater is switched on in part A, find
25
the heat supplied (in kJ) by heater till pressure in part A is doubled. [Take R = SI units]
3

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PART – 3 : CHEMISTRY

SECTION 1 (Maximum Marks: 18)

• This section contains SIX (06) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH
INCLUSIVE.
• For each question, enter the correct numerical value of the answer using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer. .

Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +𝟑 If ONLY the correct numerical value is entered.
Zero Marks : 0 If the question is unanswered.
Negative Marks : −𝟏 In all other cases.

37. When a lead storage battery is discharged, select number of correct statement is/are:-
(i) SO2 is evolved (ii) Lead sulphate is produced at both electrodes
(iii) Sulphuric acid is consumed (iv) Water is formed
(v) Weight of anode decreases.
Δ
38. BCl3 + Hg ⟶ white ppt. +X
In gas phase what is the maximum number of coplanar atoms in X.
39. If the given reaction sequence is carried out with Benzene, total number of double bond
equivalent (DBE) in compound (Q) is (m) and total number of sp2 carbon atom in compound
(R) is (n), then find the value of (m + n) is______.

40. Following two equilibria are established on mixing two gases A2 and C
(i) 3 A2 ( g) ⇌ A6 ( g)⁡K P = 1.6 atm−2 (ii) A2 (g) + C(g) ⇌ A2 C(g)
If initially A2 and C are mixed in 2: 1 ratio (molar), The total pressure is 1.4 atm and partial
pressure of A6 is 0.2 atm at equilibrium. Number of correct statement is/are:
(I) Partial pressure of ' A2 ' at equilibrium is 0.5 atm.
(II) K P for second reaction is 1.5 atm−1 .
(III) Partial pressure of ' C ' at equilibrium is 0.4 atm.
(IV) Partial pressure of ' A2 C ' at equilibrium is 0.4 atm.

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41. Predict the number of unpaired electrons for each of the following:
(i) A tetrahedral d6 ion
(ii) [Co(H2 O)6 ]2+
(iii) [Cr(H2 O)6 ]3+
(iv) A square planar d7 ion
(v) A coordination compound with magnetic moment of 5.92 B.M.
Find the sum of unpaired electrons in (i) + (ii) +(iii) + (iv) + (v)

42. Find the total number of reactions in which the resolvable product is obtained.

(i) (ii)

(iii) (iv)

(v) (vi)

(vii) (viii)

(ix)

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SECTION 2 (Maximum Marks: 24)

• This section contains SIX (06) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +𝟐 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +𝟏 If two or more options are correct but ONLY one option is chosen and it is
a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟐 In all other cases.

43. Select the correct option(s) for a substance not undergoing any chemical and phase change
(A) q = nCv dT is applicable to all substances during heating/cooling at constant ‘v’.
(B) q = nCv dT is applicable for ideal gas during heating/cooling at constant ‘v’ only.
(C) dU = nCv dT is applicable for real gas at constant ‘v’ only
(D) dU = nCv dT is applicable for ideal gas undergoing any process

44. Between ClO2 and Cl2 O :

(A) The Cl − O bond length would be larger in Cl2 O
(B) The bond angle would be larger in Cl2 O
(C) ClO2 is likely to be a coloured compound
(D) Cl2 O is likely to be soluble in water

45. Choose the correct option(s) about reaction sequence:

(A) Both (P) and (Q) are soluble in hot aq. NaOH
(B) (Q) can be obtained by reaction of butanone with m – CPBA
(C) Formation of (R) involves 6 member cyclic transition state
(D) Formation of (Q) involves first order kinetics

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46. In an alloy, atom A form fcc structure atom B is present in alternate tetrahedral voids and atom
C is present in all octahedral voids if radius of A and C are same and equals to 1Å. Both C & B
are in contact with A. Atomic mass of A, B and C are 30 amu, 10 amu and 20 amu respectively
then,
select the correct statements-
3 3 − 4 
(A) Packing efficiency of lattice will be  
 6 
15
(B) Density of lattice will be amu / Å3
4
rB
(C) For lattice = 0.225 (Here rA & rB is radius of A & B respectively)
rA

(D) Radius of B is 0.732 Å

47. Select the correct statement(s):

(A) When HgCl2 reacts with carbonate ion, then basic mercury (II) carbonate is formed
(B) When HgCl2 reacts with carbonate ion, then pH of solution highly increases
(C) The excess of carbonate acts as buffer reacting with the hydrogen ions formed in the
reaction CO2− +
3 + 2H ⟶ CO2 ↑ +H2 O

(D) White ppt. of MgCO3 soluble in dil. H2 SO4

48. If the given reaction sequence is carried out with 2-Chloro-butane,

Then Choose the incorrect statement

(A) (P) reacts with O3 /H2 O2 gives ethanoic acid
(B) (R) is a racemic mixture
(C) (S) reacts with KmnO4 /Δ gives CO2 gas
(D) IUPAC name of (T) is (Z)-1,2-dibromobut-1-ene

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SECTION 3 (Maximum Marks: 24)

• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value
has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

49. Hg 5 (IO6 )2 oxidizes KI to I2 in acid medium and the other product containing iodine is K 2 HgI4 .
If the I2 liberated in the reaction requires 4 mole of Na2 S2 O3 , what are the number of
milimoles of Hg 5 (IO6 )2 that have reacted is

50. White crystalline solid (A) reacts with H2 to form a highly associated liquid (B) and
monoatomic colourless gas (C). The liquid (B) is used for etching glass. Compound (A)
undergoes hydrolysis slowly to form (C), (B) and a diatomic gas (D) whereas IE is almost
similar to that of (C). (B) forms an addition compound with KF to form (E) which is
electrolysed in the molten state to form a most reactive gas (F) which combines with (C) in 2 :
1 ratio to produce (A). Total no. of bond present in compound E.
(Hint: Ionic , covalent, metallic, H-bonds)

51. Find the number of reagents which can oxidise

(i) I2 /NaOH (ii) H2 O2 (iii) (iv) H2 /Pd

(v) NOCl (vi) NH2 − NH2 /pH(4.5 − 6.0) (vii) LiAlH4

(viii) NaBH4

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52. Given is the graph between (a – x)–1 and time.

Hence, rate at the start of the reaction is (in mol L–1 min–1 )

53. In how many of the following reactions one of the products is obtained as a black precipitate?
(i) Bi(OH)3 ↓ +[Sn(OH)4 ]2− (aq) ⟶ Products
(ii) Bi3+ (aq) + I − (aq) (not in excess) ⟶ Products
H+
(iii) Ag + (aq) + H2 S( g) ⟶ Products
Dilution
(iv) [BiI4 ]− (aq) + H2 O (l) ⟶ Products

54. Total number of correct statements are:

(i) Benzaldehyde cannot be obtained by Friedel craft acylation
(ii) Nitrobenzene is used as a solvent during Friedel craft reaction
(iii) Friedel craft acylation requires higher concentration of catalyst than Friedel craft alkylation.
(iv) Benzaldehyde never reduces Fehling solution.
(v) (NH4 )2 S is used for selective reduction of only one −NO2 group into −NH2
⊕
(vi) In coupling reaction attacking electrophile is R − C ≡ O⊕ not⁡ Ph − ≡N
N
(vii) Polyalkylation is a disadvantage during monoalkylation of aromatic compound by Friedel
craft reaction.

(viii) Direct nitration of aniline gives good yield of para-nitro aniline.

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ANSWER KEY

SECTION – 1
Q. 1 2 3 4 5 6
A. 5 3 7 2 2010 0
SECTION – 2
Q. 7 8 9 10 11 12
MATHS
A. ABD AB BC BC AC BD
SECTION – 3
Q. 13 14 15 16 17 18
A. 5 1 8 1.5 4 8.2

SECTION – 1
Q. 19 20 21 22 23 24
A. 6 7 5 2 1 2
SECTION – 2
Q. 25 26 27 28 29 30
PHYSICS
A. ABC AB ACD BD BC AC
SECTION – 3
Q. 31 32 33 34 35 36
A. 3.79 2.4 144 89 500 25

SECTION – 1
Q. 1 2 3 4 5 6
A. 3 4 11 3 16 6
SECTION – 2
Q. 7 8 9 10 11 12
CHEMISTRY
A. ABCD ACD ABC ABD ACD AD
SECTION – 3
Q. 13 14 15 16 17 18
A. 250.00 3 3 0.125 3 6

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Solutions

PART – 2 : MATHEMATICS
3t
1. lim 2t sin⁡ x
t→0 ∫0 ( x +1)dx−2t

3 3
Use⁡L. Hospital⁡Rule⁡lim ⇒
sin⁡ 2t
2 ( 2t + 1) − 2 2
t→0

4 √f(x)dx 4 π π
2. Only possible value of x is 2 ⇒ I = ∫π−4 π
. So 2I = ∫π−4 1 ⋅ dx = 8 − 2 ⇒ I = 4 − 4
2 √f( −x)+√f(x) 2
2

x2
3. (x1 − x2 )2 + (y1 − y2 )2 where y1 = 1 and y2 = √(17 − x2 )(x2 − 13)
20

Point (x1 , y1 ) lie on x 2 = 20y and (x2 , y2 ) lie on (x − 15)2 + y 2 = 4

For shortest distance along common normal x1 = 10, y1 = 5, x2 = 15 − √2

4. For equation to represent ellipse h2 < ab and Δ ≠ 0.

2x
[ ]
2a x
√ − +104 1 x 1 1
3 2
5. ⇒ lim (ex −1)
= 19 ⇒ 2lim ex −1 ⋅ lim = 19
x→0 x→0 x→0 √2a−x+104
3 2

1 1 2a
⇒ 2(1) = 19 ⇒ + 104 = 1444 ⇒ a = 2010
2a 3
√ +104
3

6. Put x = 1, ω,⁡ω2
7. ⃗ × c‾, 3c × a⃗, 4a⃗ × ⃗b]| = 18
volume = |[2b
√3
24[a⃗⃗bc]2 = 18⁡ ⇒ ⁡[∣ a⃗⃗bc ∣] =
2
(1 + sin⁡ θ) cos⁡ θ sin⁡ 2θ
2π 2π 4π
⃗ |sin⁡ (θ + ) cos⁡ (θ + ) sin⁡ (2θ + )|
Now, [a⃗bc] = 3 3 3 |
|
2π 2π 4π
sin⁡ (θ − ) cos⁡ (θ − ) sin⁡ (2θ − )
3 3 3
Applying R1 → R1 + R 2 + R 3 we get after simplification,
√3 1
⃗ c]| = √3|cos 3θ| =
|[a⃗b ⇒ cos 3θ = ±
2 2
π 2π 4π π 2π 4π
⇒ 3θ = , , ⇒θ= , ,
3 3 3 9 9 9

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8. ∠COA = 30∘
1
Area of rhombus = 2 ⋅ (2 OA ⋅ OCsin30∘ )

OA = OC = 2, ∠OAB = 150∘
OA2 + AB 2 − OB2
cos⁡ 150∘ =
2OA ⋅ AB
√3
OB2 = 4 + 4 + 2 ⋅ 2 ⋅ 2 = 8 + 4√3
2
OB = √2(√3 + 1)
Coordinates of B(±√2(√3 + 1)cos45∘ , ±√2(√3 + 1)sin⁡ 45∘ )

9. The region is enclosed between two parallelograms of areas 4 × 2 and 2 × 1. The area
= 8 − 2 = 6.
P(A∩B) 0.3 1
10. P(E1 ) = P(A∪B) = 0.6 = 2
0.3 1
P(E2 ) = 0.6 = 2
P(A∩B) 0.3 3 0.3 3
(B) = 0.5 = 5 = 0.60; P(B/A) = 0.4 = 4 = 0.75
P(B)

p √q2 −p2 p′
11. Let x = q be a rational number ⇒ y = ± ⇒y=
q q
P P
⇒ If (x, y) = (q1 , q2 ) is a rational point on the circle then q1 = q 2 and b1 = b2 .
1 2

12. 2f(x)f(y) = f(x − y) + f(x + y)

at x = y = 0⁡ ⇒ ⁡f(0) = 1⁡(∵ f(0) ≠ 0)
at y = 0
⇒ ⁡2f(x) = f(−x) + f(x)
⇒ ⁡f(x) = f(−x)⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡f(x) is an even function
⇒ ⁡f ′ (x) = −f ′ (−x)⁡⁡⁡⁡⁡⁡⁡f ′ (x) is an odd function

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n+3 1 3 2 1 1
13. Tn = n(n+1)(n+2) × 3n = {2n − n+1 + 2(n+2)} × 3n

1 3 1 3 1
= { − − + }
2 n ⋅ 3n 3n ⋅ (n + 1) 3n (n + 1) 3n (n + 2)
1 1 1 1 1 1
tn = { − } − { − }.
2 (n)3n−1 (n + 1)3n 2 (n + 1)3n−1 (n + 2)3n
1 1 1 1 1 1
∴ tk = { k−1
− k
}− { k−1
− }
2 (k)3 (k + 1)3 2 (k + 1)3 (k + 2)3k
Sn = ∑nk=1 t k
1 1 1 1 1 1 1 1 1 1
[(1 − 2⋅3) + (2⋅3 − 3⋅32 ) + (3⋅32 − 4⋅33 ) + ⋯ . ((n−1)3n−2 − n3n−1) + (n3n−1 − (n+1)3n )]+
2
1 1 1 1 1 1 1 1 1 1 1
[( − ( 1 ) + ( 1 − 2
)+( 2− 3
) + … ( n−2 − ( n−1
)+( n−1
)−( )]
2 2 3.3 3.3 4.3 4.3 5.3 n3 (n + 1)3 (n + 1)3 (n + 2)3n
1 1 1 1
Sn = 2 [1 − (n+1)3n + 2 − ((n+2)3n )]
1 1 1
lim Sn = 2 [1 − 0 + 2 − 0] = 4 ⇒ m = 1, n = 4
n⟶∞

m+n=5
14. The given equation will have a solution if
P ≥ 0, ⁡2 − P ≥ 0⁡ and ⁡|√Pcos⁡ x − 2sin⁡ x| ≤ √P + 4
⇒ P ≥ 0, ⁡2 − P ≥ 0⁡ and ⁡|√2 + √2 − p| ≤ √P + 4

⇒ P ≥ 0, ⁡P ≤ 2⁡ and ⁡(√2 + √2 − P)2 ≤ P + 4 ⇒ P ≥ 0, ⁡P ≤ 2⁡ and ⁡P 2 + 2P − 4 ≥ 0

⇒ P ≥ 0, ⁡P ≤ 2⁡ and ⁡(P + 1)2 ≥ 5 ⇒ P ≥ 0, ⁡P ≤ 2⁡ and ⁡|P + 1| ≥ 5
⇒ P ≥ 0, ⁡P ≤ 2⁡ and P ∈ (−∞, −(√5 + 1)]U[√5 − 1, ∞) ⇒ Pϵ[−1 + √5, 2]
Number of integral values of p = 1(i.e.p=2)
15. Square → 4 or 9 → (1,3), (3,1), (2,2), (6,3)(3,6), (5,4), (4,5)
Prime → 2 or 3 or 5 or 7 or 11
→ (1,1), (1,2), (2,1), (1,4), (4,1), (2,3), (3,2), (1,6), (6,1), (5,2), (2,5), (3,4), (4,3), (6,5), (5,6)
22
P( square or prime ) = 36
4 14 4 14 14 14 4
Perfect squre is odd + ⋅ + ⋅ ⋅ ⋅ + ⋯…
P( ) = 36 36 36 36 36 36 36
perfect square before prime 7 14 7 14 14 7
36 + 36 ⋅ 36 + 36 ⋅ 36 ⋅ 36 + ⋯ …
4
( 36
14 )
1 − 36 4
= = P ⇒ 14P = 8
7 7
( 36
14 )
1 − 36

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16. A ∈ (−∞, −3] ∪ [1, ∞)
|m| |3| 3
⇒ = = = 1.5
n 2 2
π
17. I = ∫0 (f ′ (x) ⋅ cos⁡ x + f(x) ⋅ cos⁡ x)dx = 2
π π
= ∫0 f ′ (x) ⋅ cos x ⋅ dx + ∫0 f(x). cos⁡ x ⋅ dx = 2
π π
= (cos⁡ x ⋅ f(x))π0 − ∫0 (−sin⁡ x) ⋅ f(x)dx + ∫0 f(x) ⋅ cos⁡ x ⋅ dx = 2
π π
⇒ ⁡(cosπ ⋅ f(π) − cos0 ⋅ f(0)) + ∫0 sin⁡ x ⋅ f ′ (x)dx + ∫0 f(x) ⋅ cos⁡ xdx = 2
π π
⇒ ⁡(−1) ⋅ (−6) − f(0)) + +(sin⁡ x ⋅ f(x))π0 − ∫0 cos⁡ x ⋅ f(x)dx + ∫0 f(x) ⋅ cos⁡ x ⋅ dx = 2
⇒ ⁡6 − f(0) + (sin⁡ π − f(π) − sin⁡ 0 ⋅ f(0)) = 2
⇒ ⁡f(0) = 4

1
18. F(x) is Non differentiable at x = , 1
9

Sum⁡of⁡square⁡of⁡reciprocal 92 + 12
= = 8.2
10 10

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PART – 2 : PHYSICS

19. Let, v = linear velocity of rod after impact (upwards), ω = angular velocity of rod

and J = linear impulse at A during impact

Then, J = ΔP = Pf − Pi
J = mv − (−mv0 )
∴ ⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡J = m(v + v0 )
Angular impulse = ΔL
l ml2
∴ ⁡J ( cos θ) = Iω = ω
2 12
Collision is elastic (e = 1)
∴ ⁡ Relative speed of approach = Relative speed of separation at point of impact
1
v0 = v + ωcos⁡ θ
2
solving above equation, we get
6v0 cos⁡ θ
ω=
l(1 + 3cos2 ⁡ θ)

P 7 P
20. =
V0 −Vx 5 Vx

5 Vx = 7 V0 − 7 Vx
7 V0
Vx =
12

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21. The velocity of object can be divided into two
components.
ux = 2.5⁡cm/s and
uy = 2.5√3 cm/s
For image distance, we have,
1 1 1
− =
v 50 −100
∴ v = 100 cm
Since, object between focus and pole image will be virtual and erect. After time dt position of
object and image will be as shown in figure.
1 1 1
Differentiating u + u = f with respect to time we get,
dv du
−v −2 ⋅ ( ) − u−2 ( ) = 0
dt dt
∴ Component of v1 along x-direction,
v2
ux = − ( 2 ) ux = −10 cm/s
u
We can assume m = 2 to be constant in the given time interval.
Hence,
I′ I′′ = m(O′ O′′ ) = (2)(2.5√3)dt = 5√3⁡dt
∴ y − component of velocity of image,
I′ I′′
vy = = 5√3 cm/s
dt
d2
22. Path difference at O is Δ = − (μ − 1)t
2l
λ 3th
But Δ = 6 for of maximum intensity
4

T v v 1 T
23. v = √ m ; vw = λ = ℓ = ℓ √m

v 3v 5λ
For organ pipe: vop = λ = 2ℓ ; ℓpipe = (2nd overtone)
4

γP γpRT γRT
where, vs = √ =√ =√ = 360 m/s
ρ ρM M
3×360
vop = = 270 Hz
4

vw − vop = 5 ⇒ vw = 275 Hz

1 302.5
275 = ×√ ⇒ m = 10−3 kg/m
2 m

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1 1 Z2 −(Z+2)2 4(Z+1)×13.6
24. E = −(13.6eV)Z 2 ((Z+2)2 − Z2) = −13.6 × ( )= eV
(Z+2)2 (Z+2)2

h2
Now energy of electron is k = 2λ2 m;
h
(Wehave⁡λ = ) or⁡k = 6eV
√2mk
4(Z + 1) × 13.6 (Z + 1) 3
So, = 10.2eV⁡or = ⇒ (Z − 2)(3Z + 2) = 0
(Z + 2)2 (Z + 2)2 16
So, the value of Z = 2 (neglecting the negative / fractional value)
Qout Tout TL
25. = ⁡&⁡Qout = Qin + W ⇒ Qin = W (T )
Qin Tin H −T1

Qin TL
= P (T )
t H −TL

26. Between faces LMNO and PQRS

ρdr
dR = π
t2r
2ρ b
R= ln⁡
tπ a

Between faces LMRS and ONQP for an element at distance r from O.

π
ρ2r
dR =
tdr
b
1 1 tdr 2t b
So, = ∫ =∫ π = ln⁡ ( )
R dR a ρ r ρπ a
2
ρπ
R= b
2tln⁡( )
a

50
27. (i1 )0 = = 2⁡amp
25

50
(i2 )0 = = 0.01amp
5000
τ1 = 0.125sec
τ2 = 0.125sec
i2 = 200i1
−t −t
400 (1 − e0.125 ) = (0.01e0.125 )

q di1
4( ) = L
C dt
t −t
4 × 50 (1 − e0.125 ) = 50e−0.125

1 5
∴ t = ln⁡ ( )
8 4
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2a 2 dy x
28. x2 = y ⇒ 2x = a dx ⇒ tan⁡ θ = √3 a
√3 √3

gsin⁡ θ g mgsin⁡ θ mg
∴ θ = 60∘ ⇒ a = = ⇒f= 2 =
I mR 2√3
1 + cm2 √3 1+ I
mR cm

29. Conceptual.

30. v0 = 4√gR
⃗
J = ΔP
−∫ Tdt = 2M(v − 4√gR) (1)

−∫ Tdt = 2M(Rω − 4√gR) (2)

(∫ Tdt)R = MR2 ω
From (1) and (2)
8 g 8
ω = √ ⁡&⁡v = √gR
3 R 3

Pitch
31. Least count = Number of divisions on circular scale
1 mm
= = 0.01 mm
100
= 0.001 cm
Zero error = −0.03 mm
Measurement = 3.76 − (−0.03)
= 3.79 mm

32. dq = 2πσRdθ × Rsin⁡ θ

dqω
di = = σR2 ωsin⁡ θdθ
2π
μ0 di × R2 ⋅ sin2 ⁡ θ
dB =
2 R3
π
μ0
= σωR ∫ sin⁡ θdθsin⁡ θcos2 ⁡ θdθ
2R 0

μ0 σωR cos3 ⁡ π − cos 3 ⁡ 0

= [−[cos⁡ π − cos⁡ 0] + ]
2 3
= 2 × 4π × 10−7 × 1.5 × 3 × 2 = 24 × 10−7 = 2.4

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3 256g 4 mg
33. 120 = 2×1.5 √ ⇒ 120 = 2×1.5 √
μ μ

m 9
= ⇒ m = 9 × 16 = 144gm
256 16
hc 1242eV−nm
34. 62.1eV = λ = = λ0 = 20 nm
0 λ0

∴ Photoelectric emission takes place only for λ1 and λ2

Now, for any wavelength
In time t → Energy incident = Pt
Pt λPt
∴ In time t → No. of photon incident = hc =
( ) hc
λ

1 λpt
∴ ⁡ Number of photoelectrons emitted = 2 ( hc )
1 (λpt)
∴ ⁡ Charge developed = 2 × (e)
(hc)
kq 1 λpte
∴ ⁡ Potential of sphere = = 4πε
r 0 2hcr
1 λ pte
∴ Potential difference across the resistor = 4πε
0 2hcr

1 λ1 pte
∴ ⁡ V1 = ( )( )
4πε0 hc 2r
1242mn9)
(10−3 )t(e) −9
1 1
∴ ⁡V1 = (9 × 10 ( ) = 9 × 10 × ( ) × ( ) × t = 4.5 × 107 t
1242eV − nm 2 × 10−3 100 2
1 λ2 pte
V2 = ( )( )
4πε0 hc 2r

9)
6.21 nm (10−3 )(t)(e) 1 t 4.5
V2 = (9 × 10 ( ) −3
= 9 × 10−9 × ×( )= × 107 t
1242eV − nm 2 × 10 200 2 2
4 4 dr dr a
35. V0 = 3 πr03 ⇒ V0 + at = 3 πr 3 ⇒ a = 4πr 2 dt ⇒ ⃗ ⋅A
= 4πr2 ⇒ ϕ = B ⃗ = B ⋅ πr 2
dt

dϕ dr 2πB ⋅ r ⋅ a Ba
= πB ⋅ 2r = =
dt dt 4πr 2 2r
1/3
3
From (1), r = [ (V0 + at)]
4π
36. Since walls are adiabatic heat lost to surrounding = 0
Movable separator is highly conducting ⇒
temperature remains same in both chambers at all time
⇒ separator doesn't move or work done by gas = 0
5
∴ nCv dT = dθ ⇒ dθ = (2 × n) ( R) (2T0 − T0 ) ⇒ dθ = 25kJ
2

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PART – 3 : CHEMISTRY
Δ
38. 2BCl3 + 2Hg → Hg 2 Cl2 ↓ +⁡B2 Cl4
(white ppt) (x)

So the maximum number of coplanar atoms in X is 4

39.

m = 5 & n = 6 ⇒ m + n = 5 + 6 = 11
PA6
40. 3A2 (g) ⇌ A6 (g); K P = 1.6 = 3
(PA2 )

3 0.2
PA2 = √1.6 = 0.5 atm

Also pressure of 𝐴2 used for the formation of 𝐴6 = 0.6 atm

For A2 (g) + C(g) ⇌ A2 C(g)

At t = 0 2P P 0

At eq. 2P-P'-0.6 P − P′ P′

Also for 3A2 (g) ⇌ A6 (g),

At t = 0 2P 0

At eq. 2P-P'-0.6 0.2

PA2 = 0.5 = 2P − P ′ − 0.6

Also Total pressure = PA2 + PC + PA2C + PA6 = 1.4
(A2 + C + A2 C + A6 = 1.4) ⇒ P = 0.7 ⇒ K p = 1.5
41. (i) A tetrahedral d6 ion → high spin 4
(ii) [Co(H2 O)6 ]2+ → 3
(iii) [Cr(H2 O)6 ]3+ → 3
(iv) A square planar d7 ion → 1
(v) A coordination compound with magnetic moment of 5.92 B.M. → 5

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 U   U 
43. dU =   dT +   dV
 T  v  V T

44. Chlorine dioxide is a yellow to reddish gas or a red-brown liquid

4  4rA3 + 4rB3 + 4rC3  4  4(1)3 + 4(1)3 + 4( 3 − 1)3 

46. P.C. =   =  
3  a3  3  (4)3 

3 3−4 4  30 + 4 10 + 4  20 15
P.E. = ⇒d= 3
= amu / Å3
6 4 4
rA + rC = a/2 = 2 Å ⇒ a = 4 Å ⇒ rA + rB = 1.732a/4
47. A: When HgCl2 reacts with carbonate ion, then basic mercury (II) carbonate is formed
HgCl2 + CaCO3 → HgCO3 + CaCl2
C: The excess of carbonate acts as buffer reacting with the hydrogen ions formed in the
reaction CO2− +
3 + 2H → CO2 ↑ +H2 O

D: White ppt. of MgCO3 soluble in dil. H2 SO4

MgCO3 (White ppt.) + H2 SO4 → MgSO4 (aq) + H2 CO3 (aq)

48.

49. Eq. of Hg 5 (IO6 )2 = Eq. of I2 = Eq. of Na2 S2 O3

moles of Hg 5 (IO6 )2 × 16 = 4 × 1
moles of Hg 5 (IO6 )2 = 0.25 moles = 250 milimoles.
50. Ionic, covalent and H-bonds
52. Since, the graph of t vs (a – x)–1 is a straight line, it must be a second order reaction.
1  1 1
 k=  – 
t  (a – x) a 
1 1
or = Kt +
a–x a
On comparing, slope
k = tan = 0.5 mol–1 L min–1
1
OA = = 2 L mol–1
a
or a = 0.5 mol L–1
Rate = k(a)2 = 0.5  (0.5)2 = 0.125 mol L–1 min–1.
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53. (i) Bi(OH)3 ↓ +[Sn(OH)4 ]2− (aq) → Bi2 SnO3 ↓ (black precipitate) +H2 O
(ii) Bi3+ (aq) + I − (aq)( not in excess ) → BiI3 ↓ (black precipitate)
H+
(iii) 2Ag + (aq) + H2 S( g) ⟶ Ag 2 S ↓ (black precipitate) +H2
Dilution
(iv) [BiI4 ]− (aq) + H2 O(l) ⟶ BiOI4 ↓ (white precipitate) +H2
54. Benzaldehyde cannot be obtained by Friedel craft acylation - Correct. Friedel-Crafts acylation
involves the reaction of an aromatic ring with an acyl chloride, which results in a
ketone. Benzaldehyde is an aldehyde, not a ketone, so it cannot be obtained through this
reaction
Nitrobenzene has group which acts as a strong electron-withdrawing group and deactivates the
benzene ring. The reaction will only occur at the reactant we will use, no side products will be
obtained. So, it is a good solvent to use in Friedel-Crafts reactions.
Friedel craft acylation requires higher concentration of catalyst than Friedel craft alkylation -
Correct. Friedel-Crafts acylation generally requires a higher concentration of catalyst (usually
Lewis acids like AlCl3) compared to Friedel-Crafts alkylation because the acylating agent is less
reactive.
Aldehydes that lack alpha hydrogens, such as benzaldehyde or pivalaldehyde (2,2-
dimethylpropanal) cannot form an enolate and thus do not give a positive Fehling's test
Polyalkylation is a disadvantage during monoalkylation of aromatic compound by Friedel craft
reaction - Correct. Polyalkylation can occur during Friedel-Crafts alkylation, leading to the
formation of multiple alkyl groups on the aromatic ring.
Nitration is carried out in an acidic medium. In a strongly acidic medium, aniline is protonated
to give anilinium ion (which is meta-directing). For this reason, aniline on nitration gives a
substantial amount of m-nitroaniline.

APNI KAKSHA 30