Rankers Academy JEE

FIITJEE – RBT-4 for (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

QP Code: 100661 Paper-1

Time Allotted: 3 Hours Maximum Marks: 180

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪
BATCHES – Two Yr CRP224(All)

You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) PART – A (01 – 04): This section contains Four(04) questions. Each question has FOUR options. ONLY ONE of
these four options is the correct answer. Each question carries +3 marks for correct answer and -1 marks
for wrong answer.
PART – A (05 –10): This section contains Six (06) questions. Each question has FOUR options. ONE OR MORE
THAN ONE of these four option(s) is(are) correct answer(s).
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result
in −2 marks, as a wrong option is also darkened.
(ii) PART – B (1 – 3): This section contains Three (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER. Each question carries +4 marks for correct answer and there will be no negative marking.
(iii) PART – B (4 – 9): This section contains Six (06) question stems. There are TWO (02) questions corresponding to
each question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round -off the value to TWO decimal places. Each question carries +2 marks
for correct answer and there will be no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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 Rankers Academy JEE
IT−2024 (RBT-4)-Paper-1-(PCM) 2

S
SEEC
CTTIIO
ONN –– II :: P
PHHY
YSSIIC
CSS
PART – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.
 r2 
1. A circular disc of radius R caries surface charge density (r) = 0  1 − 2  , where 0 is a constant
 R 
 
and r is the distance from the centre of the disc. Assume that disc is in xz-plane and its axis is y-
 3 
axis. We have an imaginary hollow sphere of radius R and centre at  0, R, 0  . What is the flux of
 5 
electric field through this imaginary sphere?

408  0 R 2  272  0 R 2 
(A)   (B)  
625  0 
 625  0 


544  0 R 2  136  0 R 2 
(C)   (D)  
625  0 
 625  0 


2. Two particles A and B are projected in the vertical plane with velocity 50 m/s at an angle of 37 with
horizontal and with velocity 60 m/s at an angle of 60 with vertical respectively as shown in the
figure. Find the minimum distance between the particles A and B during the motion? (Take g = 10
3
m/s2 and tan37 = )
4
y
50
A m/s
(0, 10m) 37

(0, 0)
x

60
m/s 60
(20m, −10m)
B
(A) 10 m (B) 15 m

(C) 20 m (D) 8 m

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 3

3. A long container has air enclosed inside at room 37

temperature and atmospheric pressure 105 N/m2 k
between two movable pistons. It has a volume
20,000 cc. The area of cross section is 100 cm2 Push
k
and force constant of springs is k = 781.25 N/m2.
Now push the right piston isothermally and slowly 37 1 2
till it reaches the original position of the left
piston-1 which is movable. What is the final
length of air column. Assume that spring is
initially relaxed and length of spring is very large
as compare to separation between two piston.

(A) 100 cm
(B) 75 cm
(C) 50 cm
(D) 200 cm

axis y

4. A uniform rigid, square loop of mass ‘m’ and side ‘’ is free I R
S
to rotate about an axis in xy plane passing through two
corner as shown in figure. A constant current I is flowing in
 x
the loop. In space magnetic field B(x) = B0 1 +  (iˆ + k)
ˆ is I
 
I
present. Initially loop is held at rest in xy-plane. On
releasing its instantaneous angular acceleration will be
(space is gravity free space) (0, 0)
P I Q x
axis
9IB
(A)
2m
5IB
(B)
2 2m
9IB
(C)
2 2m

5 2IB
(D)
2m

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 4

PART – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MOER THAN ONE of these four option(s) is (are) correct answer(s).

5. A gaseous mixture at 300 K and 2  105 N/m2 pressure contains 6g of H2 and 8g of He. The mixture
is expanded four times its initial volume, through an isobaric heating process. Then it is
isochoricaly cooled unit its temperature again becomes 300 K. After that the gas mixture is
isothermally compressed to its original volume. Choose the correct option(s). (take n2 = 0.695)

31
(A) Ratio of molar specific heat () of the mixture is
21
(B) Ratio of heat absorb in isobaric expansion to that of heat rejected in isochoric cooling is
31
21
(C) Heat rejected in isothermal compression is more than the heat rejected in isochoric
cooling.
161
(D) Efficiency of the complete cycle is .
930

6. An electron, initially at rest, is released far away from a proton (fixed in space). The de-broglie
wavelength of the electron when it is at distance r from proton is . The ratio of its Kinetic energy at
this distance with the kinetic energy of the electron in ground state of hydrogen atom (Bohr model)
with the radius of its orbit being r, is . Pick the correct option(s).

1
(A)   r (B) 
r
1
(C) = (D) =2
2
P

7. A rectangular cavity ABCD is carved inside an equilateral 37 B

8
prism PQR of refractive index   as shown in figure. If min A
5
is the deviation in a ray entering at face PQ and emerging at
face PR, without passing through AB or CD, then which of the C
following is/are correct.
Q D R

(A) There is no effect of cavity of the value of min.

(B) The minimum deviation min = 46

(C) If the cavity is filled with water (W = 4/3), the min = 46

(D) If the cavity is filled with a liquid of refractive index  = 2, then min = 23

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 5

A B
8. ABCD is square as shown in figure, resistance of side AB,
BC, CD and DA are 8, 2, 14 and 22 respectively. A
point E lies on the CD such that a uniform wire of resistance
32 is connected across AE and constant potential difference
is applied across A and C then B and E are equipotential.
Choose the correct option(s).
D E C
(A) Resistance of DE is 10

(B) Resistance of EC is 10

20
(C) Equivalent resistance across AC is 
3

(D) Equivalent resistance across AC is 10

− +
V3
9. Three alternating voltage sources V1 = 3sint, V2 = XC = 1
5sin(t + 30) and V3 = 5 sin(t − 127) volt +
connected across a resistor, inductor and capacitor V2 2
R= 
as shown in the figure, then choose the correct − 3
option(s) V1 −
+ XL = 2
(A) The maximum current in the resistors is 3 ampere.

(B) The maximum current in the resistor is 2 ampere.

7
(C) Effective impedance of the circuit is 
3

(D) Maximum potential of the three AC source is 21 volts.

10. Two vernier calipers A and B both have M.S.D. of 1 mm. 10 vernier scale division have same length
as 7 main scale division of vernier A and 8 vernier scale division have same length as 3 main scale
division for vernier B.
(A) The least count of vernier A is more than the vernier B.

(B) The least count of vernier A is less than the vernier B.

(C) The least count of vernier B is 0.125 mm.

(D) The magnitude of difference in least count of vernier A and vernier B is 0.025 mm.

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 6

PART – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.

20
1. In the given circuit, the value of R so
that thermal power generated in R will 40 V
R
60 V
be maximum is 4.2m. Find the value 20 V 60 40 30 V
of m. 8 22 40
10

2. Velocity of an object in rectilinear motion is given as function of time by v = 4t − 3t2, where v is in

m/s and t is in seconds. Its average speed over the time interval from t = 0 second to t = 2 seconds,
8K
is m/s. Find the value of K.
27

3. An open pipe 68.48 cm long and a closed pipe 58.4 cm long, both having same diameter, are
producing their second overtone, and these are in unison. Determine the end correction in
centimeter of these pipes.

PART – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to
each question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has
more than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 4 and 5

Question Stem

Three conducting bodies A(solid sphere), B (spherical shell)

and C(hollow sphere with thickness R) are arranged as shown
in the figure. A charge q is given to the inner sphere. When S 1,
S2 both are open capacity of the system is C1 and when S1 is +q
X0R
closed but S2 is open capacity is C2, then (C2 − C1 ) = . C B A R
55 S2
When S2 is closed but S1 is opened capacity is C3 and When 4R S1
both S1 and S2 are closed capacity is C4 then 2R
Y0R 3R
(C4 − C3 ) = .
3

4. The value of X is ………..

5. The value of Y is ………..

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 7

Question Stem for Question Nos. 6 and 7

Question Stem

A uniform rod of mass ‘m=10kg’ and length ‘=20m’ is held

A B
horizontally by two vertical strings of negligible mass and
another rod of mass ‘m’ is also held by two strings with the
rod as shown in the figure. The tension in the string ‘A’
(m, )
immediately after the string B and D is cut is X newton and
the tension in the string ‘A’ immediately after the string B and /6
C is cut is Y newton. (Take g = 10 m/s2) C D
m

/6
6. The value of X is ………..

7. The value of Y is ………..

Question Stem for Question Nos. 8 and 9

Question Stem
P
A monochromatic light source is kept at S having O2
wavelength  in a modified YDSE setup. The minimum value
X
D d
of d so that there is a dark fringe at O is dmin = . For the
M S O1
O
value of dmin, the distance of the 2nd nearest bright fringe
from O is X(as shown) = Kdmin. D D

8. The value of M is………………

9. The value of K is……………….

Space For Rough Work

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 Rankers Academy JEE
IT−2024 (RBT-4)-Paper-1-(PCM) 8

S
SEEC
CTTIIO
ONN –– IIII :: C
CHHE
EMMIIS
STTR
RYY
PART – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

1. Optically active is

(A) Cl H
C C C C
Br H
(B) CH3

(C) Cl

Cl
(D) Cl

Cl
C C C C
Br H

2. O

Et 1. CH MgBr ( excess )
⎯⎯⎯⎯⎯⎯⎯⎯
3
2. H O
→ P (Major )
2

Cl

(A) CH3
Et
OH

CH3
(B) OH
Et
CH3

CH3

(C) CH3
Et
OH

CH3

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IT−2024 (RBT-4)-Paper-1-(PCM) 9

(D) OH
Et
CH3

OH

3. 4 mole of a mixture O2 and O3 is reacted with excess of acidified solution of KI. The liberated iodine
require 1 L of 2 M hypo solution for complete reaction. The mole percent of O3 in the initial sample
is

(A) 25 (B) 30

(C) 75 (D) 50

4. Square pyramidal shape is

(A) XeF2 (B) ICl−4

(C) XeF5+ (D) XeF5−

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 10

PART – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MOER THAN ONE of these four option(s) is (are) correct answer(s).

5. High spin complex is/are

2+
(A) Fe (H2 O ) 
 6
(B) FeF6 3−
3− 3+
(C) Fe ( CN)  (D) Co (H2 O ) 
 6  6

6. O

⎯⎯⎯⎯⎯⎯
1. NAH
2. CH −Br
→ P (Major )
3
3. LiAlH4 ( 2 eq )
4. H2O
O
Choose correct option is/are

(A) OH

CH3
P is

OH
(B) Number stereo isomers in P is 4
(C) Number of stereo isomer in P is 3
(D) OH
H3C
P is

OH

7. The correct statement for 2p z orbital is/are

3/2
Z  Zr  −2r /2a
(A) n, ,m     a e cos ( )
a  
3/2
Z  Zr  −2r /2a
(B) n, ,m    2 − a e
a  
(C) xy plane is nodal plane
(D) 2p z ungerade orbital

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 11

8. Which of the following complexes is/are shows the co-ordination isomerism?

(A) Pt (NH3 )  PtCl4  (B) CO ( en )  Cr ( CN) 

 4  3 6

(C)  Ag (NH3 )   AgCl2  (D) CO (NH3 )  CO (NO2 ) 

 2  6 6

9. Choose homopolymer:

(A) Butadiene-styrene (Buna-S)

(B) Polythene
(C) Polypropene
(D) Nylon 6, 6

10. Which statement are correct about following

CH2OH
CH2OH O H
O
H H
OH
H H
OH H CH2OH
OH O
OH H
H OH

(A) Due to presence of Hemiacetal linkage it is non reducing sugar

(B) It is sucrose
(C) Due to absence of Hemiacetal group it can’t give Tollen’s test
(D) Left side is a  − D − Glucose and right side unit is  − D − fructose

PART – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.

1. Number of monohalogen derivative (excluding stereo isomers) for the following is

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IT−2024 (RBT-4)-Paper-1-(PCM) 12

2. Total number of correct statement among the following is

(A)
is aromatic
N
H
(B) NO2

is more reactive than for EAS reaction

N
(C) O O
In H3C C CH2 the presence of C group stabilise the radical
(D) Adiabatic irreversible expansion for ideal gas,  Ssystem = 0
(E) •
In F − C− F the state of hybridization of radical is sp3
|
F

Cl
x
3. Total number of diastereomeric pair for is x then value of is
6
I Br

PART – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to
each question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has
more than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 4 and 5

Question Stem

For the following reaction scheme, percentage yields are given along the arrow
1. NaNH2 (1 eq )
Mg2 C3 ⎯⎯⎯
2
→
H O
( C3 H4 ) ⎯⎯⎯⎯⎯⎯⎯ 3 2. CH −I
Percent yield =70%
→Q
P
(10 gram )

1. Hg ( OAc )2 / H2 O
mCPBA 2. NaBH4
S
Percent yield = 80% R
( x g) Percent yield = 80%

1. LiAlH4 (1 eq )
2. H2 O
T ( gives Tollen ' s test )
Percent yield = 70%
( y g)
If mass of R and T are x and y g respectively then

4. The value of x is_______

5. The value of y is_______

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IT−2024 (RBT-4)-Paper-1-(PCM) 13

Question Stem for Question Nos. 6 and 7

Question Stem

When 2 mole of P(g) is introduced in a closed rigid 1 litre vessel maintained at constant temperature.
Following equilibrium are established
P ( g) Q ( g) + R ( g) , KC1 = W mole / litre
R ( g) S ( g) + Q ( g ) , KC2 = Z mole / litre
Req 1
If pressure at equilibrium is twice the initial pressure and =
Qeq 5

6. The value of W is_________mol/L

7. The value of Z is_________mol/L

Question Stem for Question Nos. 8 and 9

Question Stem

k1
2B k1 = 0.1 min−1

k2 k 2 = k 3 = 0.2 min−1
A 3C
t = 0, 1M
k3
D
If Ct ,Dt at t = 4.606 min−1 are W and Z mol/L

8. The value of W is __________

9. The value of Z is __________

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IT−2024 (RBT-4)-Paper-1-(PCM) 14

S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.

( 1 + x3 + 3 x 2 + 2x ) is equal to
2
1.
0
(A) 4
(B) 5
(C) 6
(D) 7

2. Assume that P = {(x, y) : x2 + 2y2 = 10} and Q = {(x, y) : y = mx + c}. If P  Q =  for all m  [–1, 1],
then minimum positive integral value of c is
(A) 3
(B) 4
(C) 5
(D) 10

3. The locus of the centre of the circle which touches the circle (x – 1)2 + y2 = 9 and the line x = 6 is a
curve whose directrix is
(A) x=1
(B) y=9
(C) y = –4
(D) x=9

x
4. If f(x) is a 4 degree polynomial satisfying f ( x ) = for x = 0, 1, 2, 3, 4, then f(6) is
x +1
12
(A)
7
(B) 0
(C) 1
(D) –6

Space For Rough Work

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PART – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MOER THAN ONE of these four option(s) is (are) correct answer(s).

k
( sin−1 ex + sec −1 e− x )
5. The value of definite integral  ( −1 k −1 x )( x
e + e− x )
dx (where k  R) is
− tan e + tan e


(A) ln2 ( 2tan−1 ek )
2

(B) independent of k

(C) dependent on k


(D) ln2
2

6. Let g(x) be a cubic polynomial with leading coefficient unity such that the roots of g(x) = 0 are the
squares of the roots of x3 + x + 1 = 0, then

(A) g(3) is a prime number

(B) last two digits of (g(1))50 are 49

(C) when (g(2))2022 is divided by 5, remainder is 2

(D) g(x) = 0 has all 3 roots real

7. Let P and Q be two square matrix of order 3, then which of the following statement is/are always
CORRECT?

(A) PQPT is symmetric matrix

(B) PQ – QP is skew symmetric matrix

(C) If Q = |P|P–1, |P|  0, then adj(PT) – Q is skew symmetric matrix

(D) If Q + PT = 0 and P is skew symmetric matrix then Q15 is also skew symmetric matrix

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8. A tangent L1 is drawn to the curve x2 – 4y2 = 16 at point A in first quadrant whose abscissa is 5.
Another tangent L2 parallel to L1 meets the curve at B. L3 and L4 are normal to the curve at A and B
lines L1, L2, L3, L4 forms a rectangle, then

(A) equation of normal at B is 12x + 10y + 75 = 0

2400
(B) area of rectangle L1 L2 L3 L4 is
61

32
(C) radius of largest circle inscribed in the rectangle is
61

109
(D) radius of the circle circumscribing the rectangle is
2

9. The integral point satisfying |z – 1| + |z + 1|  6 in the argand plane for which ||z + 2| – |z + || is
minimum (where  is complex cube root of unity) is/are

(A) (2, 0)

(B) (1, 2)

(C) (–3, 0)

(D) (0, 2)

x
 x2 + 1  2x 
10. Let for x  [1, ),  f ( x ) dx =   f (x) − x + 2
2x  
 = ln2 , then for x  [1, ) which of the
x + 1
1
following is/are TRUE?

(A) f(1) = ln 2

xf  ( x ) − f ( x )
(B) Range of g ( x ) = is [0, 2]
x

 f (x) 
(C) lim 
x →3  x 
=2

f ( x)
(D) h( x) = is an odd function
x
(where [.] denotes greatest integer function)

Space For Rough Work

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IT−2024 (RBT-4)-Paper-1-(PCM) 17

PART – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.

1. If P is the number of ways in which a person can walk up a stairway which has 11 steps if he can
P
take 1 or 2 steps up the stairs at a time, then is equal to
16

9
2. In a triangle ABC, side AC = 4 units and sin A sin B + sin B sin C + sin C sin A = . If A is the area
4
A
of the triangle ABC, then is equal to
3

3. If p is the least positive integer which satisfies the equation |x – 2| + |x2 – 9x + 20| = |x2 – 8x + 18|
and q is the minimum value of sin2 x + sin x + 1 and  is the only positive root of
( )
(( 2021)2022 − 1) x2 + p − ( 2021)2022 x = 1, then the value of ( 2022 − 1) p2 + (p − 1− 2017 ) pq + 8q is

PART – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to
each question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has
more than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 4 and 5

Question Stem
k ; i= j

Let An = [Aij] be a n  n matrix such that A ij = 1 ; i − j = 1 . Let Bn denote the determinant of
0 ; otherwise

matrix An

4. If k = 2, then B2022 is equal to

2022
5. If k = 1, then  Bp is equal to (where |.| denotes absolute value function)
p =1

Space For Rough Work

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Question Stem for Question Nos. 6 and 7

Question Stem

Let A1, A2, A3, ….. A12 be a regular polygon of 12 sides whose centre is origin. Let the complex numbers
representing vertices A1, A2, A3, ….. An be z1, z2, z3, ….. z12 respectively. Let OA1 = OA2 = OA3 = ….. OA12 =
1 (where O is origin)

6. The value of |A1 A2|  |A1 A3|  |A1 A4|  ….. |A1 A12| is equal to

7. The value of |A1 A2|2 + |A1 A3|2 + ….. |A1 An|2 is

Question Stem for Question Nos. 8 and 9

Question Stem

Suppose 12 students of a class are asked a question successively in a random order and exactly 4 of them
know the answer. Assume that none of them are aware of the answers given by other students, answer the
following

8. If the probability that 6th student to be asked the question is the first one to know the answer is k,
then 99k is equal to

9. If the probability that 1st and 12th student knows the answer is k, then 99k is equal to

Space For Rough Work

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Q. P. Code: 100661

ANSWERS
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
1. B 2. C 3. A 4. A
5. A, B, D 6. A, D 7. A, B, C 8. A, C
9. A, C, D 10. B, C, D

PART – B
1. 4 2. 4 3. 2 4. 288.00
5. 32.00 6. 25.00 7. 25.00 8. 02.00
9. 03.00

S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. D 2. A 3. A 4. C
5. A, B 6. A, B 7. A, C, D 8. A, B, D
9. B, C 10. B, C, D

PART – B
1. 4 2. 3 3. 4 4. 10.08
5. 03.44 6. 01.00 7. 04.00 8. 01.08
9. 00.36

S
SEEC
CTTIIO
ONN –– 3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. C 2. B 3. D 4. B
5. B, D 6. A, B 7. C, D 8. A, B, C, D
9. A, C 10. A, B, C

PART – B
1. 9 2. 4 3. 6 4. 2023.00
5. 1348.00 6. 12.00 7. 24.00 8. 04.00
9. 09.00

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Answers & Solutions

S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
1. B
Sol. r= y
(4/5)R

q r

(0,3/5 R,0)
R
(R, 0, 0)
x

Charge on circular part


q = (r)  2r  dr
(4/5)R
 
= 
r3
20  r − 2
 R  dr =
272
625
(
0 R2 )
0  
q 272  0 R2 
= = =  
0 625  0 


2. C
Sol. The path of projectile motion as observed by the other projectile motion is a straight line. The
vertical component 30 m/s will get cancelled. Hence B will travel horizontal with respect to A. Hence
minimum separation = 20 m.

3. A
Sol. P1V1 = P2V2
 (2k cos2 37)x  −4
(105) (20,000  10−6) = 105 + −4  (100  10 )x
 100  10 
x2 + x −2 = 0
x
x = 1 m = 100 cm

4. A

Sol. Torque on the loop due to magnetic field axis

y
y y
=  (I2B dy )
0
0
2 
+ (IB0 dy)
0
2 S
I R
2
3IB0
I = 45
2 2 dy I
1 2 3IB0 2  9IB0  dy
m =  =  I 45
6 2 2  2m  y

P I Q x
axis

5. A, B, D
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n1f1 + n2 f2 3  5 + 2  3 21
Sol. f= = =
n1 + n2 3+2 5
2 31
 = 1+ =
f 21
Let initial volume and pressure are V0 and P0 respectively
Heat absorb in isobaric expansion

Q1 = (3P0 V0 ) = 9.3P0 V0
 −1
Heat rejected in isochoric cooling
1
Q2 = (3P0 V0 ) = 6.3P0 V0
 −1
Heat rejected in isothermal compression Q3 = nRT0n4 = P0V0n4
Q1 − Q2 − Q3  161 
Efficiency = = 
Q1  930 

6. A, D

1 ke2
Sol. mu2 − =0
2 r
2k
 u= e
mr
h 1
=   r
mu u
1 ke2
KE1 = mu2 =
2 r
1 ke2
For Bohr model, mv 2 = = KE2
2 2r
KE1
 = =2
KE2

7. A, B, C

Sol. The deviation produced by ABCD is zero. Hence the cavity will not have any effect on the deviation.
 +A
sin  min 
=  2 =8
A 5
sin  
2
  + A   8   60 
sin  min  =   sin  
 2  5  2 
min = 46

8. A, C

Sol. Equivalent resistance between A and E A B

x + 22
y=
x + 22 + 32
For B and E to be equipotential
R AE REC
=
R AR RRC
(22 + x)  32 8 D E C
 = =4 x
(54 + x)  (14 − x) 2
Solve to get : x = 10 

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9. A, C, D

2 5
 2  7
Sol. z = (2 − 1) +  2
 = 
 3 3 30
V1 = 3sin t, V2 = 5sin(t + 30), V3 = 5sin( t − 127) 3
Vmax = 21 volts
Vmax 21 37
Imax = = = 3 amp
z 7
3 5

10. B, C, D

7S
Sol. For A, 1V = = 0.7 mm
10
Least count of A = 5 − 0.7  7 = 0.1 mm
3S
For B, 1V = = 0.375 mm
8
Least count of B = 2 − 0.375  5 = 0.125
Difference = 0.125 − 0.1 = 0.025 mm

PART – B
1. 4

28  42
Sol. R= = 16.8 
70

2. 4

Sol. v = 4t − 3t2
S = 2t2 − t3 + C
When v = 0,  t = 0 and t = 4/3
 4  32
S(t = 0) = C, S  t =  = + C , S(t = ) = 0
 3  27
32 32 64
Distance traveled = + =
27 27 27
64 32
Average speed = = m/s
27  2 27

3. 2

3v 5v
Sol. =
2 1 4 2
3v 5v
=
2( 1 + 2e) 4( 2 + e)
12 − 10
e= 2 1
= 2 cm 1
8
2

4. 288.00

5. 32.00

Sol. (for Q.4-5):

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When S1, S2 both are open capacity of the system is C1. Then C1.
40 (3R)(R)
(40 4R)
(3R − R)
C1 =
40 (3R)(R)
+ 40 4R
(3R − R)
3
(40R)   (4)
2 (40R)(3.4)
C1 = =
3  11
 2 + 4
 
480R
C1 =
11

When S1 is closed but S2 is open capacity is C2. Find C2.

40 (3R)(2R)
(40 .4R)
(3R − 2R) (40R)(6)(4) 480R
C2 = = =
40 (3R)(2R) (6 + 4) 5
+ 40 4R
(3R − 2R)
When S2 is closed but S1 is opened capacity is C3. Find C3
40 (2R)(R)
(40 4R)
(2R − R) 40R  2  4 160R
C3 = = =
40 (2R)(R) 6 3
+ 40 4R
(2R − R)
When both S1 and S2 are closed. Capacity is C4 is . Then C4 is equal to
C4 = 4 04R
C4 = 16 0R

6. 25.00

7. 25.00

Sol. (for Q.6-7):

When B and D is cut
mg − T = ma
taking torque about mid point of rod
m 2 a
T = 
2 12 /2
T = mg/4

8. 02.00

9. 03.00

Sol. (for Q.8-9):

There is a dark fringe at O if path difference = /2

x = SO2O − SO1O =
2

2 D + d − 2D =
2 2
2
 d 
2

2D  1 +  − 2D =  
 2 
2
 2D 
D
dmin =
2
The bright fringe is formed at P if the path differnece = 
x = SO1P − SO2P = 

( D + D2 + X2 − ) ( D +d 2 2
+ D2 + (x − d)2 ) = 
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 x2   d2   (x − d)2 
D + D 1 +  − D  1 +  − D  1 +  = 
 2D2 2D2 2D2
     
x 2 d2 (x − d)2
− − =
2D 2D 2D
D
x=2 = 3 dmin
2

S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. D

Sol. Due to absence of plane of symmetry. Option (D) is optically active.

2. A

Sol.

O CH3
O
Et
⎯⎯⎯⎯⎯
→
CH3MgBr Et

Cl
Cl
NGP
CH3 CH3
Et Et

O O
⎯⎯⎯⎯⎯
→
3 CH MgBr

CH3

CH3
Et
OH
⎯⎯⎯
2
→
H O
(P )
CH3

3. A

Sol. KI + O3 ⎯⎯
→KOH + I2 + O2
I2 + Na2 S2 O3 ⎯⎯ →NaI + Na2 S4 O6
Law of chemical equivalence,
(ne )I = (ne )Na S O = (ne )O
2 2 2 3 3

 ( ne )Na S O = ( ne )O
2 2 3 3

 2  1 = 2  moleO
3

mole O3 =1
1
Mole of % O3 =  100 = 25%
4

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4. C

Sol. XeF2 ⎯⎯
→ linear
ICl−4 ⎯⎯
→ square planar
XeF5+ ⎯⎯
→ square pyramidal
XeF5− ⎯⎯
→pentagonal planar

5. A, B

Sol. A and B are high spin complex [NO pairing] C and D are low spin complex.

6. A, B

Sol. O O

+ NAH ⎯⎯→ + CH3 − Br

O O
OH O

CH3 CH3

⎯⎯⎯ ⎯
LiAlH
4

OH O
(P )
Number of stereo isomers in P is 4.

7. A, C, D

3/2
 Z   Zr 
Sol. n, ,m      e−2r /2a cos ( ) and xy plane is nodal plane
a  a 
Number of nodal plane = 1
2p z is ungerade orbital.

8. A, B, D

Sol.  Ag (NH3 )   AgCl2  will not show the co-ordination isomerism.

 2

9. B, C

Sol. Polythene and polypropene are homopolymer.

10. B, C, D

Sol. CH2OH
CH2OH O H
O
H H
OH
H H
OH H CH2OH
OH O
OH H
H OH
Structure is of sucrose which is non reducing sugar due to absence of Hemiacetal group.

PART – B
1. 4

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Sol. H2 C Cl CH3 CH3 CH3

Cl
Cl
, , ,
Cl

2. 3

•
Sol. F − C− F → hybridization sp3 .
|
F
O
||
− C − group stabilize the radical.

Aromatic
N
H
NO2

> For EAS reaction

N
 Ssystem  0 for adiabatic irreversible process.

3. 4

Sol. Number of diastereomeric pair 8C2 −4

8
= −4
2 6
78
= −4
2
x = 24
x
 =4
6

4. 10.08

5. 03.44

Sol. (for Q. 4 to 5):

Mg2 C3 ⎯⎯⎯→ CH3 − C  CH
2 H O

NaNH2

CH3 − I
CH3 − C  C − CH3 CH3 − C  C Na+
(Q)

O O
H3C C CH2 CH3 (R ) ⎯⎯⎯⎯
mCPBA
→ H3C C O CH2 CH3 ( S )

O
H3C C H
(T)
MassCH −CC−H
3
= 10, MCH
3 − C  C −H= 40 gram/mole

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10 1
 MoleCH = =
3 −C CH
40 4
1 70 7
 Mole of Q =  =
4 100 40
7 80
Mole of R = 
40 100
7 80
Mass of R =   72
40 100
x = 10.08 g
7 80 80 70
Mass of T =      44
40 100 100 100

6. 01.00

7. 04.00

Sol. (for Q. 6 to 7):

P Q + R
2 0 0
2−x x+y x−y
R S + Q
x 0 0
x−y y y+x
2−x+x+y+x−y+y = 4
x+y=2
x−y 1 2
= ;y = x
x+y 5 3
Hence, x = 1.2
y = 0.8
(x − y) (x + y) 2  0.4
K C1 = W = = =1
2−x 0.8
( x + y )( y ) 2  0.8
K C2 = Z = = =4
x−y 0.4

8. 01.08

9. 00.36

Sol. (for Q. 8 to 9):

k1
2B
2x
k2
A 3C
ao = x − y − z 3y
k3
D
Z
−k1 +k 2 +k3 
A t = ao  e t
−0.5 4.606
= 1 e
1
 A t = 10
−1
= 0.1 M =
10
k1 x 1 x
=  = … (1)
k2 y 2 y

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k2 y
= y=z … (2)
k3 z
At = ao −  x + y + z
0.1 = 1 −  x + y + z
x + y + z = 1 − 0.1 = 0.9 … (3)
A t = 0.1 M, Bt = 2x = 0.36M
Ct = 3y = 1.08 M, Dt = 0.36 M

S
SEEC
CTTIIO
ONN –– 3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. C

1 1 1
Sol. Let ( x 2 + 2x ) 3 = y  x2 + 2x + 1 = y3 + 1  x = −1 + ( y3 + 1) 2  f −1 ( x ) = −1 + ( x3 + 1) 2
2 2

 (f x ) + 1 + f ( x ) ) dx 
−1 ( −1 (
f x ) dx
0 0
2 2
dx
Let f–1(x) = t  x = f(t) 
dt
= f(t) ;  tf  ( t ) dt = tf ( t ) −  f ( t ) = 2f ( 2 ) −  f ( x ) dx
0 0
2 2 2 2

 (f x ) + 1 + f ( x ) ) dx = 2f ( 2 ) −  f ( x ) dx +  1dx +  f ( x ) dx = 2f(2) + 2 = 2  2 + 2 = 6
−1 (

0 0 0 0

2. B

Sol. 10 m2 + 5 – c2 < 0
Thus c2 > 15

3. D

C1C2 = r1 + r2  ( h − 1) + k 2 = r + 3 and h = 6 – r
2
Sol.
 r = 6 – h ; (h – 1)2 + k2 + r2 + 9 + 6r C2 C1
 h2 + 1 – 2h + k2 = (6 – h)2 + 9 + 6(6 – h) (1, 0) (h, k)
 h2 + 1 – 2h + k2 = 36 + h2 – 12h + 9 + 36 – 6h
 k2 = 16h + 80  y2 = –16(x – 5)
Equation of directrix is x – 5 = 4  x = 9 x=6

4. B

Sol. Let g(x) = f(x)(x + 1) – x  g(0) = g(1) = g(2) = g(3) = g(4) = 0

 g(x) = f(x)(x + 1) – x = kx(x – 1)(x – 2)(x – 3)(x – 4)
1
Put x = –1  1 = kx – 1x – 2x – 3x – 4x – 5  k = −
120
x ( x − 1)( x − 2 ) ( x − 3 ) ( x − 4 )
 f ( x )( x + 1) − x = −
120
65432
Put x = 6  f ( 6 )  ( 7 − 6 ) = −  f(6) = 0
120

5. B, D

k
( sin−1 ex + cos−1 ex ) ex
Sol.  ( tan−1 ek + tan−1 ex ) e2x + 1 . Let tan–1 ex = t
−
tan−1 ( ek )
 1
2  ( t + tan−1 ek ) dt
0

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6. A, B

Sol. 2 = x   = x replace x by x in x3 + x + 1 = 0. We get g(x) = x3 + 2x2 + x – 1

 g(3) = 47  g(1) = 3  350 = (10 – 1)25 = 25
C01025 + ..... 25C23102 + 25
C2410 − 1
 g(x ) > 0 x R  g(x) has only 1 real root

7. C, D

Sol. (PQPT)T = PQTPT  PQPT is not symmetric

(PQ – QP)T = QTPT – PTQT
adj P
Q= P  Q = adj P
P
 (adj (PT) – Q)T = (adj (PT) – adj P)T = adj P – adj PT
and Q = –PT  Q = P  Q is also skew symmetric

8. A, B, C, D

Sol. Equation of L1
3  3
5x − 4  y  = 16 A  5, 
2  2
5x – 6y = 16
L3
 Equation of tangent of B
5x – 6y = –16
 Equation of normal at A
75 B
6x + 5y =
2 L4
 Equation of normal at B is L2
L1
75
6x + 5y = −
2
32
Distance between tangents 2r
61 32 / 61

75 75 / 61
Distance between normals
61

9. A, C

Sol. ||z + 2| – |z + || is minimum when z lies


2
on the major axis of the ellipse x2 y2
+ 1
 a 8

10. A, B, C

f (x)  1  x2 + 1
x
Sol.  f ( x ) dx = 2 
x +  −
x 2
+ 1 using Leibnitz Rule
1

f(x)  1  f (x)  1 xf  ( x ) − f ( x ) 2x
f (x) = x +  + 1 − 2  − x  = 2
2  x 2  x  x2 x +1
f (x)
Integrating both sides, we get = ln ( x 2 + 1)
x

PART – B
1. 9

Sol. Let x1 be the number of times he took 1 step up the staircase

Let x2 be the number of times he took 2 step up the staircase
x1 + 2x2 = 11
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Number of ways
6!
x1 = 1 x2 = 6 1, 2, 2, 2, 2, 2 =6
1! 5!
7!
x1 = 3 x2 = 4 1, 1, 1, 2, 2, 2, 2 = 35
3! 4!
8!
x1 = 5 x2 = 3 1, 1, 1, 1, 1, 2, 2, 2 = 56
3! 4!
9!
x1 = 7 x2 = 2 1, 1, 1, 1, 1, 1, 1, 2, 2 = 36
2! 7!
10!
x1 = 9 x2 = 1 = 10
9! 1!
x1 = 11 x2 = 0 1
–––––––––––––
144
–––––––––––––
 P = 144

2. 4

9
Sol. 2 sin A sin B + 2 sin B sin C + 2 sin C sin A =
2
9
cos(A – B) – cos(A + B) + cos(B – C) – cos(B + C) + cos(C – A) – cos(C + A) =
2
9
 cos(A – B) + cos(B – C) + cos(C – A) + cos A + cos B + cos C =
2
9 9 3
 cos(A + B) + cos(B – C) + cos(C – A) = – (cos A + cos B + cos C)  −  3
2 2 2
 cos(A – B) + cos(B – C) + cos(c – A) = 3
3
A=B=C A=  16 = 4 3
4

3. 6

Sol. (x – 2)(x2 – 9x + 20)  0  x  [2, 4]  [5, )

p=2
2
 1 3 3 3
  sin x +  + , least value is  q=
 2 4 4 4
−1
 x = 1 satisfies it   = 1 and other root is
( 2021)2022 − 1
3
  = 1, q = ,p=2
4

4. 2023.00

5. 1348.00

Sol. (for Q.4.-5):

k 1 0 
k 1
 
A1 = k  B1 = k ; A 2 =    B2 = k – 1 ; A 3 =  1 k 1  B3 = KB2 – 1B1
2

1 k  0 1 k 
k 1 0 0 
1 k 1 0
Similarly, A 4 =    B4 = kB3 – B2
 0 1 k 1
 
0 0 1 k 
Thus, Bn = KBn – 1 – Bn – 2. If k = 2, B1 = 2, B2 = 3, B3 = 4, B4 = 5
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Thus, B2022 = 2023

If k = 1, Bn = Bn – 1 – Bn – 2 ; B1 = 1, B2 = 0, B3 = B2 – B1 = –1, B4 = B3 – B2 = –1
B5 = B4 – B3 = 0 ; B6 = 1 and it goes on
B6n + 1 = 1 ; B6n + 2 = 0 ; B6n + 3 = –1  B6n – 4 = –1 ; B6n + 5 = 0 ; B6n = 1
2022
4
Thus,  Bp =  2022 = 1348
k =1 6

6. 12.00

7. 24.00

Sol. (for Q. 6.-7):

z1, z2, z3, ….. z are also the roots of z12 = 1 i.e. 12th roots of unity
z12 – 1 = (z – z1)(z – z2)(z – z3) ….. (z – z12)
z12 − 1
= ( z − z2 ) ( z − z3 ) ( z − z 4 ) ..... ( z − z + 2 )
z −1
1 + z + z2 + …..z11 = (1 – z1)(1 – z3)(1 – z4) ….. (1 – z12)
Put z = 1, 12 = |1– z2| |1 – z3| |1 – z4| ….. |1– z12|

 |z2 – z1|2 = |z1|2 |(ei2/12 – 1)|2 = 22 sin2  |A1 A2|2 + |A1 A3|2 + ….. |A1 A12|2
12
  2 3 11    2 4 2  
= 4 sin2 + sin2 + sin + ..... sin2  = 2 11 −  cos + cos + ..... cos2 
 12 12 12 12    12 12 12 
= 2(11 – (–1)) = 24

8. 04.00

4 8 C5
Sol. 
7 12 C5

9. 09.00

4 3 1
Sol.  =
12 11 11

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