CLASS : XII MARKS : 31 TIME : 30 MIN DPP. NO.

-17
Single correct
1
Q.1 Graph of lnS° vs is plotted for two gases A and B [S° represents solubility in molarity & T is
T
in Kelvin]. Compare Henry's constant KH for the two gases at same temperature [3]
(B)

(A)
lnS° 

1/T
(A*) KH,A > KH,B (B) KH,A < KH,B
(C) KH,A = KH,B (D) KH,A may be greater or less than KH,B

Q.2 The Henry's law constant for H2S if its solubility in water at STP is 0.195 m is equal to? [3]
(A) 1.95 × 105 Pa (B) 4 × 104 Pa (C) 3.2 × 105 Pa (D*) 2.9 × 107 Pa

Q.3 The value of Henry's constant for three different gases A, B & C at 298 K are 40.3 K bar, 1.67 K bar
& 1.83 × 10–5 K bar. Which of the following order is correct increasing order of solubility of the gases
in water? [3]
(A) B, A, C (B*) A, B, C (C) C, B, A (D) C, A, B

Q.4 Which of the following statements regarding solubility of gas in water is correct ? [3]
(A)As temperature increases, solubility of gas also increases.
(B)Amore polar gas will have lesser solubility as compared to non-polar gas.
(C*) Gases will be more soluble when dissolved at higher pressures.
(D) The dissolution process is always endothermic.

Q.5 The variation of solubility(S) with temperature for Glauber's salt is given as : [3]

S
(gm/100g
of H2O)

32.28°C
T°C
Which of the following options correctly explain the above behaviour?
(A) Dissolution of Glauber salt is exothermic
(B) Dissolution of Glauber salt is endothermic
(C*) At 32.28°C Glauber salt looses water of crystallization due to which dissolution above 32.28°C
becomes exothermic and below 32.28°C it is endothermic
(D)Above 32.28° dissolution of Glauber salt is endothermic and below 32.28°C it is exothermic.
Q.6 Which of the following options correctly represent solubilityof N2 in water (in terms of millimoles/litre)
if N2 is bubbled through water at 293 K at a pressure of 0.768 bar and Henry's contant is 76.8 K bar at
293 K. [3]
(A) 10–5 (B*) 5.56 × 10–1 (C) 10–2 (D) 4.3 × 10–4
Comprehension
Paragraph for question nos. 7 to 9
Consider two identical cylinder piston assembly as shown in figure (a) and in figure (b) are kept in
vacuum.Assume both pistons are massless. Let two masses m1 and m2 are kept on the piston as shown
in figure. Values of m1 and m2 are in the range in which both liquid and vapour phase coexist and are in
equilibrium.

m1 m2

A = 10 mole A = 8 mole
B = 10 mole B = 12 mole

Solution - I Solution - II
Figure (a) Figure (b)
Solution I contains 10 moles of liquid 'A' and 10 moles of liquid 'B' while solution II contains 8 moles of
liquid 'A' and 12 moles of liquid 'B'. Let liquids 'A' and 'B' are completely miscible and form an ideal
binary solution.
Given : PA = 100 torr, PB = 60 torr,,
Let XA = mole faction of 'A' in liquid phase in solution I
X'A = mole faction of 'A' in liquid phase in solution II
YA = mole faction of 'A' in vapour phase in solution I
Y'A = mole faction of 'A' in vapour phase in solution II
Q.7 If m1 = m2 then [3]
(A*) XA = X'A (B) XA > X'A
(C) XA < X'A (D) XA and X'A can't be co-related

Q.8 If m1 = m2 then [3]

(A*) YA = Y'A (B) YA > Y'A
(C) YA < Y'A (D) YA and Y'A can't be co-related

Q.9 Mole fraction of 'A' in liquid phase when 10 moles of solution is vapourised in solution II is :
(A) 0.45 (B*) 0.34 (C) 0.25 (D) 0.28 [3]

More than one may be correct

Q.10 Two volatile liquids A& B are mixed to form an ideal solution. If PAo = 100 mm of Hg & PBo = 150 mm
of Hg then identify the correct option(s) if 10 moles ofAare mixed with 40 moles of B such that moles
vaporised are very small. [4]
(A*) Total pressure when equilibrium gets established will be 140 mm of Hg.
(B*) Mole fraction of Ain vapour state will be less than 0.5.
6
(C*) Mole fraction of B in vapour state is equal to
7
(D*) Moles of B in vapour state should be greater than 80%.
CLASS : XII MARKS : 35 TIME : 30 MIN DPP. NO.-18
Single correct
Q.1 The vapour pressure of pure perflourocyclohexane (C6F12) are given by the following equations:
1890
Solid C6F12 : log10 p(mm Hg) = 8.68 – [3]
T
1530
Liquid C6F12 : log10 p(mm Hg) = 7.60 –
T
The molar enthalpy of fusion of solid C6F12 is approximately
(A*) 1658 cal (B) 360 cal (C) 3420 cal (D) 720 cal

Q.2 Two liquids Aand B form an ideal solution. The solution has a vapour pressure of 700 torr at 90° C. It
is distilled till 2/3rd of the solution is collected as condensate. The composition of the condensate is
X 'A =0.75 and that of the residue is X"A = 0.3. If the vapour pressure of the residue at 90° is 600 torr,,
which of the following option is incorrect. [3]
(A) The composition of the original liquid was XA = 0.6.
(B*) The composition of the original liquid was XA = 0.4.
0 2500
(C) PA  torr
3
(D) PB0 = 500 torr
(E) The composition of the original liquid was XB = 0.4

Q.3 Two liquid Aand B form an ideal s olution. The ratio of vapour pressures of pure liquids Aand B are 3
: 5. if the mole- fraction of A in the liquid solution at equilibrium with vapours, is 0.4, then the mole-
fraction of B in the vapour is [3]
3 5 2 2
(A) (B*) (C) (D)
5 7 7 5

Q.4 A liquid system consists of two immiscible liquids water and n-butyl chloride distills at one atmosphere
pressure. If vapour pressure of water at that temperature is 570 mm of Hg, then the ratio of masses of
water and n-butyl chloride distilled is : [3]
(A) 3 : 1 (B*) 0.58 : 1 (C) 1 : 1 (D) 1 : 3

Q.5 The ratio of vapour pressures over solution phase on mixing two immiscible liquids is : [3]
(A) always greater than the molar ratio in which they are mixed in the solution phase
(B) equal to ratio of their weight in solution phase
(C) equal to ratio of the moles in the solution phase.
(D*) equal to ratio of moles in vapour phase.

Q.6 For an ideal binary liquid solution of A and B where A is more volatile, which relationship between
XA , YA , XB and YB is correct? [3]
[X  represents mole fraction in liquid phase, Y  represents mole fraction in vapour phase]
YA YB
(A) YA > YB (B) XA < XB (C*) X  X (D) None of these
A B
Q.7 A non volatile solute is added to H2O(S) H2O(l) equilibrium mixture at its melting point 273K.
Select the option which correctly represent the true/ false nature of statements. [3]
Statement - 1 : Reaction will move in forward direction.
Statement - 2 : Equilibrium will remain unaffected.
Statement - 3 : All the ice will melt.
(A) All the statements are correct (B*) Only statement - 2 is incorrect
(C) Only statement - 1 is correct (D) Only statement - 3 is incorrect

More than one may be correct

Q.8 Two liquids A and B form a non-ideal solution with large positive deviation. The pressure vs liquid
composition graph is [4]

P PBo

PAo

0.0 X 1.0

XB
Which of the following statement(s) is /are correct regarding the solution?
(A*)At any composition XB < X, the vapour at equilibrium will have greater mole-fraction of 'B' than its
mole-fraction in liquid.
(B*)At any composition XB > X, the vapour at equilibrium will have greater mole-fraction of 'A' than its
mole fraction in liquid.
(C*)At any composition XB < X, traces of pure liquid 'A' may be obtained by distillation but not pure
'B'.
(D*)At any composition XB > X, traces of pure liquid 'B' may be obtained by distillation but not pure
'A'.

Q.9 Two liquids 'X' and 'Y' when mixed form a solution which shows significant positive deviation from
Rault's law. Also, it is known that normal boiling point of 'X' is more than that of 'Y'. Identify the
incorrect option(s). [4]
(A) Boiling point of the mixture will always be less than that of 'X'.
(B)Azeotropic composition obtained will have lower boiling point as compared to 'Y'.
(C*) If a small amount of 'Y' is added into the solution, boiling point will decrease.
(D*) When distilled, the solution will give pure 'Y' as distillate and pure 'X' as residue.

Subjective
Q.10 Calculate the number of binary liquid solutions which are expected to follow Raoult's law. [5]
(1) Solution of benzene & toluene
(2) Solution of hexane & heptane
(3) Solution of chloroform & methanol
(4) Solution of methanol & acetone
(5) Solution of chloroform & acetone
(6) Solution of HNO3 & water
(7) Solution ofAniline & phenol
(8) Solution of two volatile liquids which can give maximum boiling azeotrope.
(9) Very dilute aqueous solution of glucose
(10) Solution of two volatile liquids which on mixing do not show contraction / expansion of volume.
[Ans. 4]