Safety Data Sheet

According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

SECTION 1: Identification
1.1. Identification
Product form : Substance
Trade name : Toluene
Chemical name : Toluene
CAS-No. : 108-88-3
Product code : P409 / P409C / P409Q
Formula : C7H8
Synonyms : Benzene, methyl- / Methylbenzene / Phenylmethane / TOLUENE / Methylphenylene
1.2. Recommended use and restrictions on use
Recommended use : Manufacture of paints, varnishes and similar coatings, printing ink and mastics, Production of
foam-based objects, Use in Agrochemicals
1.3. Supplier
US office:
Braskem S.A.
5100 Westheimer Rd - Suite 495
Houston, 77056 - USA

Manufacturer:
Braskem S.A.
Rua Eteno, 1561, Polo Petroquímico de Camaçari
Camaçari, BA, CEP: 42810-000, Brasil

Braskem S.A.
BR 386 – Rodovia Tabaí-Canoas, km 419, Via do Contorno, 850
Triunfo, RS, CEP: 95853-000, Brasil

Braskem S.A.
Av. Presidente Costa e Silva, 1178 – Capuava
Santo André, SP, CEP: 09270-001, Brasil

Contact Email : [email protected]

Emergency Telephone Number (CHEMTREC) : 1-800-424-9300

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids H225 Highly flammable liquid and vapor
Category 2
Skin corrosion/irritation H315 Causes skin irritation
Category 2
Reproductive toxicity H361 Suspected of damaging fertility or the unborn child
Category 2
Specific target organ H336 May cause drowsiness or dizziness
toxicity (single exposure)
Category 3
Specific target organ H373 May cause damage to organs (central nervous system) through prolonged or repeated
toxicity (repeated exposure) exposure
Category 2
Aspiration hazard Category H304 May be fatal if swallowed and enters airways
1

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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

2.2. GHS Label elements, including precautionary statements

GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02 GHS07 GHS08

Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor
H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H336 - May cause drowsiness or dizziness
H361 - Suspected of damaging fertility or the unborn child
H373 - May cause damage to organs (central nervous system) through prolonged or repeated
exposure
Precautionary statements (GHS-US) : P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, sparks, open flames, hot surfaces, No smoking. - No smoking
P233 - Keep container tightly closed
P240 - Ground/Bond container and receiving equipment
P241 - Use explosion-proof electrical, lighting, ventilating equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P260 - Do not breathe mist, spray, vapors
P264 - Wash hands thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear eye protection, protective gloves
P301+P310 - If swallowed: Immediately call a POISON CENTER
P302+P352 - If on skin: Wash with plenty of water
P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing
P308+P313 - If exposed or concerned: Get medical advice/attention
P312 - Call a doctor, a POISON CENTER if you feel unwell
P314 - Get medical advice/attention if you feel unwell
P331 - Do NOT induce vomiting
P332+P313 - If skin irritation occurs: Get medical advice/attention
P362+P364 - Take off contaminated clothing and wash it before reuse
P370+P378 - In case of fire: Use dry extinguishing powder, carbon dioxide (CO2), sand to
extinguish
P403+P233 - Store in a well-ventilated place. Keep container tightly closed
P403+P235 - Store in a well-ventilated place. Keep cool
P405 - Store locked up
P501 - Dispose of contents/container to comply with applicable local, national and international
regulation.
2.3. Other hazards which do not result in classification
Other hazards not contributing to the : Handling this product may result in electrostatic accumulation. Use proper grounding
classification procedures.
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Name Product identifier %
Toluene (CAS-No.) 108-88-3 > 99
(Main constituent)

Full text of hazard classes and H-statements: see section 16

3.2. Mixtures
Not applicable

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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures general : Consult a doctor/medical service if you feel unwell.
First-aid measures after inhalation : Move the affected person away from the contaminated area and into the fresh air. If not
breathing, give artificial respiration. Give oxygen or artificial respiration as needed. Immediately
call a poison center or doctor/physician.
First-aid measures after skin contact : Remove contaminated clothing and shoes. Rinse immediately with plenty of water (for at least
15 minutes). Get medical advice/attention. Wash clothing before re-using.
First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Continue to rinse eye with clean water for 20-30 minutes, retracting eyelids
often. Get medical advice/attention.
First-aid measures after ingestion : Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Never give anything by mouth to an unconscious person. If swallowed, rinse
mouth with water (only if the person is conscious). Seek immediate medical advice.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : Symptoms may include dizziness, headache, nausea and loss of coordination. Suspected of
damaging the unborn child.
Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Inhalation may cause irritation, cough, shortness of
breath. Depression of the central nervous system, headaches, dizziness, drowsiness, loss of
coordination.
Symptoms/effects after skin contact : Causes skin irritation. Repeated or prolonged skin contact may cause dermatitis and defatting.
Symptoms/effects after eye contact : Causes eye irritation. Redness of the eye tissue.
Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. May result in aspiration into the lungs, causing
chemical pneumonia. Depression of the central nervous system, headaches, dizziness,
drowsiness, loss of coordination.
Chronic symptoms : Visual disturbances. Loss of coordination. Auditory disturbances. Damage to kidneys and liver.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : carbon dioxide (CO2), dry chemical powder, foam. Water fog.
Unsuitable extinguishing media : Do not use a solid water stream as it may scatter and spread fire.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapor. Incomplete combustion releases dangerous carbon
monoxide, carbon dioxide and other toxic gases. vapors may cause fire/explosion if source of
ignition is present. Heavier than air, vapors may travel long distances along ground, ignite and
flash back to source. Material can accumulate some static charge during transfer. Agitation can
cause buildup of electrostatic charge.
Explosion hazard : Prolonged exposure to fire may cause containers to rupture/explode.
Reactivity : Forms explosive complexes with silver perchlorate. Forms highly explosive mixture with
tetranitromethane.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Cool closed containers exposed to fire with water spray.
Protection during firefighting : Extra personal protection: complete protective clothing including self-contained breathing
apparatus. For further information refer to section 8: "Exposure controls/personal protection".

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Keep away from open flames, hot surfaces and sources of ignition.

6.1.1. For non-emergency personnel

Protective equipment : Wear suitable protective clothing, gloves and eye/face protection. For further information refer
to section 8: "Exposure controls/personal protection".
Emergency procedures : Evacuate unnecessary personnel.

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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

6.1.2. For emergency responders

Protective equipment : Wear suitable protective clothing, gloves and eye/face protection. For further information refer
to section 8: "Exposure controls/personal protection".
Emergency procedures : Eliminate every possible source of ignition. Stop leaks if it can be done without personal risk.
6.2. Environmental precautions
Do not allow uncontrolled discharge of product into the environment. Absorb remaining liquid with sand or inert absorbent and remove to safe place.
Prevent spillage from spreading by using sand or earth. Use water spray to disperse the vapors. Do not flush down sewers. Notify authorities if product
enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams.
Methods for cleaning up : Absorb remaining liquid with sand or inert absorbent and remove to safe place. Keep the
recovered product for subsequent recycling. Place in an appropriate container and dispose of
the contaminated material at a licensed site.
6.4. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection". For disposal of residues refer to section 13: "Disposal considerations".

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : Container remains hazardous when empty. Continue to observe all precautions.
Precautions for safe handling : Ground/bond container and receiving equipment. Use grounded electrical/mechanical
equipment. Take precautionary measures against static discharge. Electrostatic charges may
be generated during handling.
Hygiene measures : Wash hands before breaks and after work. Do not eat, drink or smoke when using this product.
Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Provide adequate ventilation. Use only non-sparking tools. Use only explosion-proof
equipment. Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure. Ground/bond container and receiving equipment.
Storage conditions : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Store in dry, cool, well-ventilated area. Keep in original containers closed. Store only
in a limited quantity.
Incompatible materials : Nitric acid. Sulfuric acid. Strong oxidizing agents. tetranitromethane. Silver perchlorate. uranium
hexafluoride.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Toluene (108-88-3)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH Remark (ACGIH) Visual impair; female repro;
OSHA Remark (OSHA) (2) See Table Z-2.
8.2. Appropriate engineering controls
Appropriate engineering controls : Provide local exhaust or general room ventilation to minimize vapor concentrations. Emergency
eye wash fountains and safety showers should be available in the immediate vicinity of any
potential exposure.

8.3. Individual protection measures/Personal protective equipment

Hand protection:
VITON gloves. protective gloves: neoprene gloves, PVA
Eye protection:
Chemical goggles or safety glasses. Contact lenses should not be worn
Respiratory protection:

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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

An approved organic vapor respirator/supplied air or self-contained breathing apparatus must be used when vapor concentration exceeds
applicable exposure limits

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Colorless
Odor : Aromatic
Odor threshold : No data available
pH : No data available
Melting point : -95 to -94.5 °C
Freezing point : No data available
Boiling point : 110.6 °C
Flash point : 4.4 °C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 22 mm Hg (20°C)
Relative vapor density at 20 °C : 3.1
Relative density : 0.866 g/cm³ @ 20°C
Solubility : Water: Insoluble
Acetone: 100 (mg/mL) @ 18°C
Log Pow : 2.11 - 2.8
Auto-ignition temperature : 480 °C
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : 1,2 – 7,1%
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Forms explosive complexes with silver perchlorate. Forms highly explosive mixture with tetranitromethane.
10.2. Chemical stability
Stable at ambient temperature and under normal conditions of use.
10.3. Possibility of hazardous reactions
Reacts violently with. Incompatible materials.
10.4. Conditions to avoid
Keep away from open flames, hot surfaces and sources of ignition. Avoid static electricity discharges.
10.5. Incompatible materials
Nitric acid. Sulfuric acid. Strong oxidizing agents. tetranitromethane. silver perchlorate. uranium hexafluoride.
10.6. Hazardous decomposition products
No hazardous decomposition products known at room temperature. Incomplete combustion releases dangerous carbon monoxide, carbon dioxide and
other toxic gases.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Likely routes of exposure : Inhalation; Ingestion; Skin and eye contact
Acute toxicity : Not classified
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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

Toluene (108-88-3)
LD50 oral rat 2600 mg/kg
LD50 dermal rabbit 12000 mg/kg
LC50 inhalation rat (mg/l) 12.5 mg/l/4h
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Toluene (108-88-3)
IARC group 3 - Not classifiable
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
Specific target organ toxicity – single exposure : May cause drowsiness or dizziness.
Specific target organ toxicity – repeated : May cause damage to organs (central nervous system) through prolonged or repeated
exposure exposure.
Aspiration hazard : May be fatal if swallowed and enters airways.
(Based on available data, the classification criteria are not met)

Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Inhalation may cause irritation, cough, shortness of
breath. Depression of the central nervous system, headaches, dizziness, drowsiness, loss of
coordination.
Symptoms/effects after skin contact : Causes skin irritation. Repeated or prolonged skin contact may cause dermatitis and defatting.
Symptoms/effects after eye contact : Causes eye irritation. Redness of the eye tissue.
Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. May result in aspiration into the lungs, causing
chemical pneumonia. Depression of the central nervous system, headaches, dizziness,
drowsiness, loss of coordination.
Chronic symptoms : Visual disturbances. Loss of coordination. Auditory disturbances. Damage to kidneys and liver.

SECTION 12: Ecological information

12.1. Toxicity
Toluene (108-88-3)
LC50 fish 1 15.22 - 19.05 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 5.46 - 9.83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC50 fish 2 12.6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
LC50 other aquatic organisms 2 3.78 (2 days)
EC50 Daphnia 2 11.5 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LOEC (acute) 2.76 mg/l (aquatic vertebrates - 7 days)
LOEC (chronic) 2.77 mg/l (fish - 40 days)
NOEC (acute) 10 mg/l 72 hours- Algae
NOEC (chronic) 1.39 mg/l (fish - 40 days)

12.2. Persistence and degradability

Toluene (108-88-3)
Persistence and degradability Readily biodegradable. not persistent.
BOD (% of ThOD) 69 % ThOD (5 days in non-adapted effluent)

12.3. Bioaccumulative potential

Toluene (108-88-3)
Log Pow 2.11 - 2.8
Bioaccumulative potential not bioaccumulable.

12.4. Mobility in soil

No additional information available

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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

12.5. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods
Regional legislation (waste) : Disposal must be done according to official regulations. Consult an expert on waste disposal or
treatment.
Product/Packaging disposal recommendations : Dispose of this material and its container at hazardous or special waste collection point.
Consult an expert on waste disposal or treatment.
Additional information : Container remains hazardous when empty. Continue to observe all precautions.

SECTION 14: Transport information

Classification for LAND transport: DOT

UN Number : UN1294
Proper Shipping Name : Toluene
Class / Division : 3 - Flammable liquid
Packing group : II
Reportable quantity : Toluene

Classification for SEA transport: IMO - IMDG

UN Number : UN1294
Proper Shipping Name : TOLUENE
Class / Division : 3 - Flammable liquid
Packing group : II
Marine pollutant : Toluene
Transport in bulk according to Annex II of
MARPOL 73/78 and the IBC Code:
Product name : Toluene

Classification for AIR transport: IATA – ICAO

UN Number : UN1294
Proper Shipping Name : Toluene
Class / Division : 3 - Flammable liquid
Packing group : II

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product, therefore it cannot be
considered exhaustive. See guidelines of US DOT, IMDG and IATA regulations before transporting the product. The transportation organization is
responsible for compliance with laws, regulations and rules for the transport of the material.

SECTION 15: Regulatory information

15.1. US Federal regulations
Toluene (108-88-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 313 - Emission Reporting 1%
15.2. International regulations
CANADA
Toluene (108-88-3)
Listed on the Canadian DSL (Domestic Substances List)

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 Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Product: Toluene
Revision date: 10/Oct/2017 Version: 4.2

EU-Regulations
Toluene (108-88-3)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

National regulations
Toluene (108-88-3)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Japanese Pollutant Release and Transfer Register Law (PRTR Law)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Listed on the TCSI (Taiwan Chemical Substance Inventory)

15.3. US State regulations

Toluene (108-88-3)
U.S. - California - Proposition 65 - Carcinogens No
List
U.S. - California - Proposition 65 - Developmental Yes
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male

SECTION 16: Other information

Full text of H-phrases:
--- H225 Highly flammable liquid and vapor
---
--- H304 May be fatal if swallowed and enters airways
---
--- H315 Causes skin irritation
---
--- H336 May cause drowsiness or dizziness
---
--- H361 Suspected of damaging fertility or the unborn child
---
--- H373 May cause damage to organs through prolonged or repeated exposure
---

Braskem - SDS_US_GHS_HazCom_2012 (modified 161213)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product. It warns that the handling of any chemical substance requires the previous knowledge of its hazards for the user. It is up to the user of the product
company providing this SDS to and promote the training of its employees about possible risks come upon of the product. The information contained herein is not absolute, but only general information on
the use of the chemical and indication of safety and security measures.

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