(2 Structure of Atom

Topic-1 : Different Atomic Models

that Leads to Bohr Model
MCOs with One Correct Answer (a) D, (T), ((V) (b) (), (T), (I)
1. Ifthe Thompson model of the atom was correct, then the (c) ). (D), (TV) (a) (D,(), (1V)
6 The radius of the second Bohr orbit, in terms of the Bohr
result of Rutherford's gold foil experiment would have
been : [Main, July 27, 2021 ()) radius, a,, in Li? is: [Main Jan. 08, 2020 (I1)|
(a) Allof the a-particles pass through the gold foil (a) 2a0 (b) (c) (d)
without decrease in speed. 3 3
(b) a-Particles are deflected over a wide range of angles. 7. Among the following, the energy of 2sorbital is lowest in:
(c) All a-particles get bounced back by 180°. IMain April 12, 2019 (M))
(d) a-Particles pass through the gold foil deflected by (a) K (b) H (c) Li (d) Na
small angles and with reduced speed. 8. The ratio of the shortest wavelength of two spectral series
2. The difference between the radii of 3rd and 4h orbits of
Li is AR,. The difference between the radii of 3dand 4th ofhydrogen spectrum is found to be about 9. The spectral
orbits of He* is AR. Ratio AR, : AR, is: series are: [Main April 10, 2019 ())
|Main Sep. 05, 2020 (1)| (a) Lynan and Paschen (b) Balmer and Brackett
(a) 8:3 (b) 3:8 (c) 2:3 (d) 3:2 (c) Brackett and Pfund (d) Paschen and Pfund
3. The region in the electromagnetic spectrum where the 9. For any given series of spectral lines of atomic hydrogen,
Balmer series lines appear is: |Main Sep. 04, 2020(1)| let Av = Vmay -Vnin be the difference in maximum and
(a) Visible (b) Microwave
(c) Infrared (d) Ultraviolet minimum frequencies in cm. The ratio Av AF Bameris:
4. The shortest wavelength ofH atom in the Lyman series is |Main April 9, 2019 ())
,The longést wavelength in the Balmer series is He* is: (a) 4:1 (b) 9:4 (c) 5:4 (d) 27:5
|Main Sep. 04, 2020 (I1)| 10. What is the work function of the metal if the light of
94 (d) 27,
wavelength 4000¢ generates photoelectrons of velocity
(a) 36 (b)
5
(c)
5 5 6x10 ms from it ? |Main Jan. 12, 2019 (DI
S. For the Balmer series in the spectrum of H atom, (Mass of electron=9x1031 kg
Velocity oflight = 3x 10°ms-!
1 1 Planck's constant=6.626x 1034 Js
V= RH the correct statements among (1) to Charge of electron =1.6x 10-19 JeV)
n (a) 0.9 eV (b) 3.1 eV (c) 2.1ev (d) 4.0 eV
(IV) are: [Main Jan. 08, 2020 (1)|
) As wavelength decreases, the lines in the series 11. Heat treatment of muscular pain involves radiation of
converge wavelength of about 900 nm. Which spectral line of H
() The integer n, is equal to 2 atom is suitable for this purpose ? |Main Jan. 11, 2019 (T)]
(II) The lines of longest wavelength corresponds to n, =3 [R=1x 10 cm.h=6.6 x 10-34 Js, c =3 x 10 ms1
(V) The ionization energy ofhydrogen can be calculated (a) Paschen, oo ’ 3 (b) Paschen, 5’3
from wave number of these lines (c) Balmer, oo ’2 (d) Lyman, oo ’ 1
Structure of Atom

12. The ground state energy of hydrogen atom is -13.6 eV. 21. Energy of an electron is given by E = - 2.178 x
The energy of second excited state of He* ion in eV is:
|Main Jan. 10, 2019 (D)
(a) - 54.4 (b) -3.4 (c) -6.04 (d) -27.2 Wavelength of light required to excite an electron in an
13. Which of the following statements is false? hydrogen atom from level n= 1to n=2 will be: (Main 2013]
(h=6.62 x 10 Js and c= 3.0 x 10 ms )
[Main Online April 16, 2018] (a) 1.214x 10 m (b) 2.816x 10.m
(a) Splitting of spectral lines in electrical field is called (c) 6.500 x 10 m (d) 8.500 x 10 m
Stark eftect 22. The wave number of the first emission line in the Balmer
(b) Frequency of emittedradiation from ablack body goes series of H-Spectrum is: [Main Online April22, 2013|
from a lower wavelength to higher wavelength as the (R= Rydberg constant):
temperature increases
(c) Photon has momentum as well as wavelength (a)R () R 6 4
36 400
(d) Rydberg constant has unit of energy 23. The kinetic energy of an electron in the second Bohr orbit
14. Ejection of the photoelectron from metal in the of ahydrogen atom is [a, is Bohr radius]: [2012]
photoelectric effect experiment can be stopped by applying
0.5V when the radiation of 250 nm is used. The work (b)
(a)
function of the metal is :|Main Online April 15, 2018 (D) 4n° ma 16n-ma;
(a) 4eV (b) 5.5eV (c) 4.5 eV (d) SeV
15. The radius ofthe second Bohr orbit for hydrogen atom is: (C) (d) 64nma,
(Plank's const. h =6.6262 x 104 Js ; mass of 32nma, $7
24. Given that the abundances of isotopes Fe, SOFe and
electron =9.1091 x 10-31kg; charge of electron
e=1.60210 x 10-19 C; permittivity of vaccum Feare 5%, 90% and 5%, respectively, the atomic mass of
E,=8.854185 x 10-2 kg-'m-A) [Main 2017] Fe is [2009S]
(a) 55.85 (b) 55.95 (c) 55.75 (d) 56.06
(a) 1.65Å () 4.76¢ (c) 0.529 (Þ) 2.12A 25. The radius ofwhich of the following orbit is sarme as that
16. If the shortest wavelength in Lyman series of hydrogen of the first Bohr's orbit of hydrogen atom? (2004S)
atom is A, then the longest wavelength in Paschen series (a) He* (n=2) (b) Li (n=2)
of He* is: [Main Online April 8, 2017] (c) Li* (n=3) (d) Be (n=2)
5A 9A 36A 36A 26. Rurtherford's experiment, which established the nuclear
(a) (b (C) (d) model of the atom, used a beam of (2002S]
7
(a) B-particles, which impinged on a metal foil and got
17. Astream of electrons from a heated filaments was passed absorbed
two charged plates kept at a potential difference V esu. If (b) Y-rays, which impinged on a metal foil and ejected
'e' and mare charge and mass of an electron, respectively, electrons
then the value of h/A (where is wavelength associated (c) helium atoms, which impinged on a metal foil and got
with electron wave) is given by: [Main 2016] scattered
(a) helium nuclei, which ipinged on a metal foil and got
(a) ymev (b) V2meV () meV (d) 2meV scattered
18. Which of the following is the energy of apossible excited 27. Which of the following does not characterise X-rays?
(a) The radiation can ionise gases |1992 -1 Mark]
state of hydrogen ? |Main 2015] (b) It causes ZnS to fluorescence
(a) -3.4eV (b) +6.8 eV (c) +13.6 eV (d) -6.8eV (c) Detlected by electric and magnetic fields
19. Ifmand e are the mass and charge ofthe revolving electron (d) Have wavelengths shorter than ultraviolet rays
in the orbit of radius r for hydrogen atom, the total energy 28. The wavelength ofa spectral line for an electronic transition
of therevolving electron will be: is inversely related to: |1988- 1 Mark)
|Main Online April 12, 2014]
(a) the number of electrons undergoing the transition
me' (d)le (b) the nuclear charge of the atom
a) 2 r
b) r
(c)
2 r
(c) the diflerence in the energy of the energy levels
involved in the transition
20. If and à be threshold wavelength and wavelength of (d) the velocity ofthe electron undergoing the transition.
incident light, the velocity of photoelectron ejected from 29. The triad of nucleithat is isotonic is |1988 - 1Mark]
the metal surface is: |Main Online April11,2014]
2hc
(b) c.N, F
(a) ) (b) V m (A0-2) () c.'N."F
30. The ratio of the energy of aphoton of 2000Å wavelength
2hc 0 - radiation to that of4000Åradiation is: |1986- 1 Mark]
(©) Vm . () (a) 4 (b) 4 (c) ½ (d) 2
c-10
Chemistry
31. Rutherford's alpha particle scattering experiment 42. Wavelength of high energy transition of H-atoms is
eventually led to the conclusion that : 1986- 1Mark] 91.2nm. Calculate the corresponding wavelength of He
(a) mass and energy are related atoms. (2003- 2 Marks)
(b) electrons occupy space around the nucleus 43. Calculate the wave number for the shortest wavelength
(c) neutrons are buried deep in the nucleus
(d) the point of impact with matter can be precisely transition in the Balmer series of atomic hydrogen.
determined. |1996 - 1Mark]
32. Electromagnetic radiation with maximum wavelenghis: Metal Li Na K Mg Cu Ag FeI W
(eV) 2.4 2.3 2.2 3.7 4.3 4.3 4.7 6.3 4.75
|1985-1 Mark
(a) ultraviolet (b) radiowave 44. According to Bohr's theory, the electronic energy of
(c) X-ray (d) infrared hydrogen atom in the nth Bohr's orbit is given by
33. The radius of an atomic nucleus is of the order
of:
-21.76x 10-19
(a) 10-1 cm (b) 10-1 cm (c) 10-15 cm|1985-1 Mark]
(d) 10-8 cm
E,= -J. Calculate the longest wavelength
34. Bohr model carn explain :
|1985- 1 Mark] oflight that will be needed to remove an electron from the
(a) the spectrum of hydrogen atom only
(b) spectrum of an atom or ion containing one third Bohr orbit of the He* ion. |1990-3 Marks
electron only 45. Calculate the wavelength in
(c) the spectrum of hydrogen molecule Angstrom of the photon that
(d) the solar spectrum is emitted when an electron in the Bohr orbit, n =2 returns
35. Which electronic level would allow the to the orbit, n = 1in the hydrogen atom. The
hydrogen atom to ionization
absorb a photon but not to emit a photon? potential of the ground state hydrogen atom is 2.17 x 10-l1
erg per atom. |1982- 4Marksl
(a) 3s
|1984- 1Mark] 46. The energy of the electron in the second and the
(b) 2p (c) 2s (d) Ls third
36. The increasing order (lowest first) for the
values of elm Bohr's orbits of the hydrogen atom is -5.42 x 102 erg
(charge mass) for electron (e), proton (p), neutron (n) and and -2.41 x 10-12 erg respectively.
alpba particle (a) is : |1984 -1Mark] wavelength of the emitted radiation when theCalculate the
electron drops
a) e,p, n, a (b) n,p, e, from the third to the second orbit.
|1981 -3 Marks)
(c) n, p, , e (d) n, a,P, e
37. Rutherford's scattering experiment is Fill in the Blanks
the related to the size of
(a) nucleus [1983-1 Mark] 47. The light radiations with discrete quantities of energy are
(b) atom called s...........oo*
(c) electron (d) neutron 48. |1993- 1Mark]
38. Rutherford's experiment on scattering of Elements of the same mass number but of different
numbers are known as atomic
showed for the first time that theatom has |1981a-particles
-1 Mark] 49. Isotopes of an [1983 - 1Mark]
(a) electrons (b) protons element differ in the number of ...n
(c) nucleus their nuclei.
(d) neutrons |1982 - 1Mark]
39. The number of 50. The mass of a
number 70 is
neutrons in dipositive zinc ion with mass hydrogen atom is ...... kg.
(a) 34 |1979] |1982- 1 Mark]
(b) 36 (c) 38 (d) 40 True/ False
?
Intrger Value Arswer 51. Inagiven electricfield,
B-particles are
40. The work function (0)of
some metals is listed below. The a-particles in spite of a-particles havingdeflected
larger
more than
charge.
number of metals which will show |1993-1 Markl
when light of300 nm wavelength fallsphotoelectric effect
on the metal is
52. Gamma rays are
electromagnetic radiations of
of 10 cm to 10 cm. wavelengths
(2011] |1983 -1Mark]
Numerie /New StemBamei Questio 6 MC
with One or More thn Oue (orret Answer
41, Electromagnetic radiation of wavelength 663 nm is 53. The energy of an electron in the first
just Bohr orbit of Hatom
sufficient to ionise the atom of metal A. The ionization is -13.6 eV. The possible energy
state(s) for electrons in Bohr orbitsvalue(s)
energy ofmetal Ain kJ mol- is . (Rounded-off to the of the excited
nearest integer) of hydrogen is (are)
Ih=6.63 x 10- Js, c= 3.00 x 10 ms-1, NA =6.02 x (a)
|1998 - 2 Marks]
-3,4 eV (b) -4.2 eV
10 mol] [Main,Feb. 25, 2021 (I)) (c) -6.8 eV (d) -1.5 eV
Structure of Atom -11
54. The sum of the number of neutrons and proton in the
Which of the following options has the correct combination
isotope of hydrogen is: |1986 - 1 Mark] considering List-I and List-II?
(a) 6 (b) 2 (c) 4 (d) 3
55. When alpha particles are sent through a thin metal foil, (a) (III), (S) (b) (I).(Q
most of them go straight through the foil because: (c) (III),(P) (d) (I),(U)
|1984-1 Mark] E10 Subjeetive Problems
(a) alpha particles are much heavier than electrons
(b) alpha particles are positively charged 60. Calculate the energy required to excite one litre of
(c) most part of the atom is empty space
(d) alpha particle move with high velocity hydrogen gas at 1atm and 298 K to the first excited state
56. Many elements have non -integral atomic masses because: of atomic hydrogen. The energy for the dissociation ofH
(a) they have isotopes |1984- 1 Mark] H bond is 436 kJ mol-!, |2000 -4 Marks]
(b) their isotopes have non-integral masses 61. Consider the hydrogen atom to be a proton embedded in a
(c) their isotopes have different masses
(d) the constitutents, neutrons, protons and electrons, cavity of radius a, (Bohr radius) whose charge is
combine to give fractional masses neutralised by the addition of an electron to the cavity in
57. An isotone of 32 Ge is : vacuum, infinitely slowly. Estimate the average total
[1984- 1 Mark] energy of an electron in its ground state in a hydrogen
77
(a Ge (b) 3 As (c) 4 Se (d) Se atom as the work done in the above neutralisation process.
Match the Following Also, if the magnitude of the average kinetic energy is
58. Consider the Bohr's model of aone - electron atom where
half the magnitude of the average potential energy, find
the electron moves around the nucleus. In the following
the average potential energy. |1996 - 2 Marks]
List-I contains some quantities for the nh orbit of the 62. Iodine molecule dissociates into atoms after absorbing
atom and List-II contains options showing how they
light of 4500Å. If one quantum of radiation is absorbed
depend on n [Adv. 2019] by each molecule, calculate the kinetic energy of iodine
List-I List-II atoms.
Radius of the nh orbit (P) <n2
Angular momentum ofthe (Bond energy of I,=240 kJ mol-) |1995-2 Marks]
electron in the nth orbit ()cnl 63. Find out the number of waves made by a Bohr electron in
(1) Kinetic energy of the electron one complete revolution in its 3rd orbit. | 1994 -3 Marks]
in the nth orbit
IV) Potential energy of the 64. What transition in the hydrogen spectrum would have the
electron in the nh orbit (S)«n' same wavelength as the Balmer transition n = 4ton=2of
(T) « n² He* spectrum? |1993-3 Marks)
(U) c nl2
Which of the following options has the correct 65. Estimate the difference in energy between Ist and 2nd Bohr
ombination considering List-I and List-11? orbit for a hydrogen atom. At what minimum atomic
(a) (II), (R) (b) (I),(O) number, a transition from n=2ton = 1energy level would
(c) (),(P) (d) ),(T) result in the emission of.-rays with à - 3.0x 10 m? Which
59. Consider the Bohr's model of aone-electron atom where hydrogen atom-like species does this atomic number
the electron moves around the nucleus. In the following correspond to ? |1993-5 Marks)
List-I contains some quantities for the nh orbit of the
atom and List-Il contains options showing how they 66. The electron energy in hydrogen atom is given by
depend on n. JAdv. 2019) E-(-21.7x 10 1)/n ergs. Calculate the energy required
List-4 List-II to remove an electron completely trom the n = 2orbit.
) Radius of the nh orbit (P) «n 2 What is the longest wavelength (in cm) oflight that can be
(II) Angular momentum ofthe used to cause this transition? 1984-3 Marks]
electron in the nh orbit ()«n!
67. Naturally occurring boron consists of two isotopes whose
() Kinetic energy of the electron
in the nth orbit (R) « atomie weights are 10.0land 11.01. The atomic weight of
((V) Potential energy of the electron natural boron is l0.81. Calculate the percentage of each
in the nth orbit (S)« n' isotope in natural boron. |1978]|
(T) « n²
(U) « n2
C-12
Chemistry
Topic2:Advancement Towards Quantum
Mechanical Model of Atom
MOQs with One Correct Answer 6. At temperature T, the average kinetic energy of any
1. The figure that is not a direct manifestation ofthe
nature of atoms is: quantum particle is kT.
2 The de Broglie wavelength follows the
|Main Sep. 02, 2020 ()) order:
(a) |Main Online April 11, 2015)
Intensity T,> TË (a) Visible photon>Thermal neutron > Thermal electron
of black body (b) Thermal proton > Thermal electron >Visible photon
radiation
(c) Thermal proton >Visible photon > Thermal electron
(d) Visible photon >Thermal electron > Thermal neutron
Wavelength
(b) R K Na
1 The de-Broglie wavelength ofa particleofmass 6.63 gmoving
Kinetic with avelocity of 100 ms is: Main Online April 12, 20 14]
energy of
photoelectrons (a) 10-33m (b) 10-35 m (c) 103 m (d) 1025m
8 The de Broglie wavelength of a car of mass 1000 kg and
Frequency of incident velocity 36 km/hr is: |Main Online April23, 2013})
radiation
(c) > Increasing wavelength (a) 6.626x 10-34 mn (b) 6.626 x 1038m
(c) 6.626 x 1031m (d) 6.626 x 10-30m
9. The wavelength associated with a golfball
weighing 200 g
and moving at a speed of 5 m/h is of the order
(a) 10-0 m (b) 10-20 m (c) 10-30 m 12001S)
Absorption spectrum (d) 10m
(d) 10. Which of the following relates to photons both as
Internal motion and as a stream of particles? wave
energy of [1992 - 1 Mark]
Ar (a) Inference (b) E= mc?
(c) Diffiraction (d) E=hv
300 400 500 600
Temperature (K) Integer Value Answer
2 The de Broglie wavelength of an electron in the 4h Bohr 11. Consider a helium (He) atom
that
orbit is:
|Main Jan. 09, 2020 (1)| wavelength 330 nm. The change in theabsorbs a photon of
velocity (in cms)
(a) 2ra, (b) 4a, of He atom after the
(c) 6ta, (d) 8Ta, photon absorption is
3. Ifpisthe momentum of the fastest electron ejected from (Assume : Momentum is conserved when photon is
a metal surface after the irradiation of absorbed.
light having Use: Planck constant =6.6 x10-34 Js,
wavelength , then for 1.5p momentum of the Avogadro number
photoelectron, the wavelength of the light should be: =6x 1025 mol-, Molar mass ofHe
=4g mol)
(Assume kinetic energy of ejected photoelectron to be |Adv. 2021|
very high in comparison to work function): 12. The atomicmasses ofHe' and
Ne' are 4 and 20 a.m.u.,
|Main April 8, 2019 (1)) respectively. The value of the de Broglie wavelength of
'He' gas at 73°C is *M" times that of the de
(a) 4 Broglie
3 (a) wavelength of'Ne' at 727°C M'is |Adv. 2013|
4. If the de Broglie wavelength of the
orbit in a hydrogenic atom is equal toelectron
in nh Bohr Nunerie /New Stem Bawd Questios
1.5 Tla, (a, is Bohr
radius),then the value of n/zis: [Main Jan. 12, 2019 (11)) 13. The kineticenergy of an electron in the second Bohr orbit
(a) 0.40 (b) 1.50 (c) 1.0 (d) 0.75
S. The de-Broglie's wavelength of electron present in first of a hydrogen atom is equal to The value of 10x is
Bohr orbit of "H atom is:(Main Online April 15, 2018 xma,
(a) 4x0.529A (b) 2Tx 0.529A
(I1)]. . (a,is radius of Bohr's orbit) (Nearest integer)
[Given : T=3.14]
(c) o.52T29 A (d) 0.529Ã
|Main, Aug, 27, 2021 (1)|
 Structure of Atom -13

14. The work function of sodium metal is 4.41 x10-19 J. If 10 Subjective Problems
photons of wavelength300 nm are incident on the metal,
the kinetic energy of the ejected electrons will be 17. Find the velocity (ms) of electron in first Bohr's orbit of
(h=6.63 x 10-34 Js; c=3 x 10 m/s) x 1021 J. radius a,. Also find the de Broglie's wavelength (in m).
Find the orbital angular momentum of 2p orbital of
[Main Sep. 02, 2020(ID| hydrogen atom in units of h / 2r. [2005-2 Marks)
4 Fill in the Blanks 18. A ball of mass 100 g is moving with 100 ms-. Find its
wavelength. |2004- 1 Mark]
15. Wave functions of electrons in atoms and molecules are
called.
19. The Schrodinger wave equation for hydrogen atom is
[1993- 1 Mark] |2004-2 Marks]
16. The uncertainty principle and the concept of wave nature 3/2
of matter were proposed by and 1
respectively. (Heisenberg, Schrodinger, Maxwell, de
Broglie) |1988- 1Mark] Where a, is Bohr's radius. Ifthe radial node in 2s be at ry
then find r, in terms of ao

Topic-3 : Quantum Mechanical

Model of Atom
7. The electrons are more likely to be found:
1 MOQs with One Correct Answer
[Main April 12, 2019 (DI
1. The orbital having two radial as well as two angular nodes
is: [Main Feb. 26, 2021 ())
y)
(a) 3p (b) 4d (c) 5d (d) 4f
2. In the sixth period, the orbitalsthat are filled are:
[Main Sep. 05, 2020 ()]
(a) 6s,4, Sd, 6p (b) 6s, 5d, 5f, 6p
(c) 6s, 5f, 6d, 6p (d) 6s, 6p, 6d, 6f
3. The correct statement about probability density (except at
infinite distance from nucleus) is: Main Sep. 05, 2020 (1I)| (a) in the region a and c (b) in the region a and b
a) Itcan be zero for ls orbital
(b) It can be negative for 2p orbital (c) only in the region a (a) only in the region c
(c) It can be zero for 3p orbital
8. The graph between y and r (radial distance) is shown
(d) It can never be zero for 2s orbital below. This represents : [Main April 10, 20199 (1)|
4 Consider the hypothetical situation where the azimuthal
quantum number, 1, takes values 0, 1, 2,...n+ 1, where n
is the principal quantum number. Then, the element with
atomic number: |Main Sep. 03, 2020 (1))
(a) 9 is the first alkali metal
(b) 13 has a half-filled valen ce subshell
(c) 8 is the first noble gas
(d) 6has a 2p-valence subshell (a) 3s orbital (b) 2s orbital
5. The number of subshells associated with n =4 and (c) ls orbital (d) 2p orbital
m=-2quantum numbers is: [Main Sep. 02, 2020(1) 9. The isoelectronic set of ions is [Main April 10, 2019 ())
(a) 8 (b) 2 (c) 16 (d) 4 (a) N²-, 0²-, Fand Na*
6. The number of orbitals associated with quantum numbers
(b) N, Li, Mg? and 0:,
1 (c) F,Li, Na* and Mg
[Main Jan. 07, 2020 ()]
n=5, m, =+,is: (d) Lit, Na", 0²- and F-
(a) 11 (b) 25 (c) 50 (d) 15