JEE (Main + Advanced) 2024

NURTURE COURSE

INORGANIC CHEMISTRY QUIZ # 01 TIME : 30 Min.

SECTION–I (i) : (Maximum Marks : 42)
This section contains 14 questions. Marking scheme : +3 (–1)
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option(s) is correct.
1. Which of the following orbital(s) have n = 3 and l = 1 :-
(A) 3s (B) 3px (C) 3dxy (D) 3d z2
1. Ans. (B)
2. Which of the following statements are CORRECT ?
(I) A large number of orbitals are possible in an atom.
(II) Qualitatively these orbitals can be distinguished by their size, shape and orientation
(III) An orbital of smaller size means there is more probability of finding the electron near the nucleus
(IV) Each orbital is designated by four quantum numbers
(A) Only IV (B) I and II (C) I, III and IV (D) I, II and III
2. Ans. (D)
3. Which of the following statements are INCORRECT ?
(I) Orbit and orbital are synonymous
(II) There are n2 orbitals in shell, all the orbitals of a given value of n constitute a single shell of an atom
(III) Hydrogen and hydrogen like systems (eg. He+, Li+2), principal quantum number alone determines
the energy of the orbitals
(IV) The principal quantum number, n, is a positive integer with values of 1, 2, 3, .... etc.
(A) Only I (B) I and II (C) I and IV (D) I , III and IV
3. Ans. (A)
1 1
4. Given this set of quantum number for a multi electronic atom 2, 0, 0, and 2, 0, 0 – . What is the
2 2
next higher energetic allowed set of n and l quantum numbers
(A) n = 2, l = 0 (B) n = 2, l = 1 (C) n = 3, l = 0 (D) n = 3, l = 1
4. Ans. (B)
5. In the following electronic configuration, some rules have been violated.

4p
4s
3d
(I) Hund's rule (II) Pauli's exclusion principle (III) Aufbau principle
(A) I and II (B) I and III (C) II and III (D) I, II and III
5. Ans. (C)
1
6. An electron has a spin quantum number + and magnetic quantum number –1. It can not be present
2
in :
(A) d-orbital (B) ƒ-orbital (C) p-orbital (D) s-orbital
6. Ans. (D)

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7.
2s 2px 2py 2pz
if one electron is added into given electronic arrangement then upcoming electron will have :
(A) Similar spin with that of electron of 2pz
(B) Similar value of magnetic quantum number with that of 2px
(C) Similar value of (n + ) with that of 2s orbital
(D) Accomodation in either 2py or 2pz orbital
7. Ans. (D)
8. The orbital diagram in which the Aufbau principle violated is ?

(A) (B) (C) (D)

2s 2px 2py 2pz 2s 2px 2py 2pz 2s 2px 2py 2pz 2s 2px 2py 2pz

8. Ans. (B)
9. The maximum number of e¯ in a subshell is given by the expression :
(A) 4 + 2 (B) 4 – 2 (C) 2 + 1 (D) 2 – 1
9. Ans. (A)
10. Consider following set of quantum number for an electron in an atom
1
= 1, m = 0, ms = +
2
Which of the following is CORRECT ?
(A) It belongs to K shell
(B) Maximum probability of this electron is in double dumb bell shape orbital
(C) Least possible principal quantum number = 3
(D) In same atom, this set is possible for some other electron also
10. Ans. (D)
11. An element 'X' with mass number 81 contains 31.7% more neutrons as compared to protons, then what
is the representation of element 'X'.
(A) 81 (B) 81 (C) 81 (D) none
38 X 35 X 34 X
11. Ans. (B)
12. Which of the following statement is CORRECT?
(A) Two different species can be isotopes as well as isobars
(B) Two isobars can be of same element
(C) Two isotopes can NOT be of same element
(D) All are incorrect
12. Ans.(D)
40 40 40
13. 18 X, 19 Y , 20 Z2
(A ) ( B) (C )

Select the correct options

(A) number of protons : A = B = C (B) number of electrons : A < B < C
(C) number of neutrons : A < B < C (D) number of neutrons : A > B > C
13. Ans.(D)

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14. Which of the following statement is true for 14 15 16

6 C 7 N 8 O

(A) they have equal number of protons (B) they have equal number of electrons
(C) they have equal number of neutrons (D) they have equal mass number
14. Ans.(C)
(ii) One or more options correct Type
This section contains FIVE multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE are correct. 4(–1)

15. The given ground state electronic configuration 1s2 does not obey :-
2s 2p

(A) Hund's rule (B) Aufbau principle

(C) Pauli exclusion rule (D) (n + l) rule
15. Ans. (A, C)
16. Which of the following statement is CORRECT for d z2 orbital.
(A) It has value of l = 2 (B) It has four lobes
(C) It has two nodal cone (D) It is axial orbital
16. Ans. (A, C, D)
17. If two subshells have equal value of (n + ) and one of them has n = 4, = 3, while second subshell
has dumbell shape orbitals. Then which of the following statement is / are correct :
(A) Second subshell has value of n = 6 (B) Each orbitals of second subshell has one nodal plane
(C) Second subshell is d-subshell (D) First subshell is f-subshell
17. Ans. (A, B, D)
18. Select the CORRECT statement(s) :
(A) The maximum value of principal quantum number is 7
(B) For n = 2 there may be four subshells and may contain a maximum of 8 electrons
(C) 'M' shell can accomodate a maximum of 18 electrons
(D) The energy of 5p-orbital is more than that of 4d-orbital
18. Ans. (C, D)
19. Which of the following set of quantum number is / are correct for last electron of nitrogen :
n l m ms n l m ms
1 1
(A) 3 2 1 + (B) 2 1 –1 –
2 2

1 1
(C) 2 1 0 + (D) 2 1 +1 –
2 2
19. Ans. (B, C, D)

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(iii) Paragraph Type

This section contains 1 paragraph each describing theory, experiment, data etc. Each question of
a paragraph has only one correct answer among the four choices (A), (B), (C) and (D). 3(0)
Paragraph for Q. No. 20 to 21
The plane and point at which zero electron density exists is known as nodal plane and nodal point
respectively.
Nodal plane also refers as angular node. Number of angular nodes depends on shape of orbital only and
size of orbital has no role in it.
Based on the comprehension answer the following questions-
20. Which of the following pair of orbitals contains at least one common nodal plane:-
(A) px and py (B) dxz and dz2 (C) dxy and pz (D) dxz and px
20. Ans. (D)
21. Select the CORRECT statement -
(A) In dz2 orbital 2 nodal planes are in xz and yz plane
(B) dz2 and d x2 y2
have one common nodal plane

(C) one 4d orbital contains only 2 electrons of opposite spin

(D) one 3d orbital contains a total of 10 electrons
21. Ans. (C)
SECTION-IV : (Integer Value Correct Type)
This section contains 2 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–1)
1. Find the maximum value of (n × l) for the subshells which are filled between '4p' to '6s' subshell :-
1. Ans. (8)
2. Find the number of orbitals, which have atleast one common nodal plane with dzx.
px, py, pz, dxy, dyz, d z2 , s , d x 2 y2
2. Ans. (4)

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