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Solution - WK-3

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23 views1 page

Solution - WK-3

solotion

Uploaded by

Gamer Devildevesh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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SAPPHIRE INTERNATIONAL SCHOOL, NOIDA

CHEMISTRY WORKSHEET(2024-2025)

Name: _______________ Roll No.: __________ Date: April,2024


Class & Sec: XII A Worksheet No: 3
Theoretical Questions
1. Differentiate between molarity and molality of a solution.
2.What is meant by ‘reverse osmosis’?
3.What are isotonic solutions?
4.Some liquids on mixing form ‘azeotropes’. What are ‘azeotropes’?
5.What type of intermolecular attractive interaction exists in the pair of methanol and acetone?
6.Non-ideal solutions exhibit either positive or negative deviations from Raoult’s law. What are these
deviations and why are they caused? Explain with one example for each type.
7.Define the terms, ‘osmosis’ and ‘osmotic pressure’.
8.What is the advantage of using osmotic pressure as compared to other colligative properties for the
determination of molar masses of solutes in solutions?
9.Explain why aquatic species are more comfortable in cold water rather than in warm water.
10.Why do gases nearly always tend to be less soluble in liquids as the temperature is raised?
11.What is the similarity between Raoult’s law and Henry’s law?
12.How is the vapour pressure of a solvent affected when a non-volatile solute is dissolved in it?
13.(i) On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation
from Raoult’s law is shown by the resulting solution? What change in temperature would you observe after
mixing liquids X and Y?
(ii) What happens when we place the blood cell in water (hypotonic solution)? Give reason.
14.(i) Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases
will have the higher value of KH (Henry’s constant) and why?
(ii) In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes?

Numericals
1. Calculate the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 g of benzene to
lower its freezing point by 0.48 K (Kf = 5.12 K kg mol-1)
2. 100 mg of a protein is dissolved in just enough water to make 10.0 mL of solution. If this solution
has an osmotic pressure of 13.3 mm Hg at 25°C, what is the molar mass of the protein?
(R = 0.0821 L atm mol-1 K-1 and 760 mm Hg = 1 atm.)
3. Calculate the freezing point depression expected for 0.0711 m aqueous solution of Na2S04. If this
solution actually freezes at – 0.320°C, what would be the value of Van’t Hoff factor? (Kf for water is
1.86°C mol-1)
4. A solution prepared by dissolving 1.25 g of oil of winter green (methyl salicylate) in 99.0 g of
benzene has a boiling point of 80.31°C. Determine the molar mass of this compound. (B.P. of pure
benzene = 80.10°C and Kb for benzene = 2.53°C kg mol-1)
5. A solution of glycerol (C3H8O3; molar mass = 92 g mol-1) in water was prepared by dissolving some
glycerol in 500 g of water. This solution has a boiling point of 100.42 °C. What mass of glycerol was
dissolved to make this solution? Kb for water = 0.512 K kg mol-1.
6. What mass of NaCl (molar mass = 58.5 g mol-1) must be dissolved in 65 g of water to lower the
freezing point by 7.5°C? The freezing point depression constant, Kf, for water is 1.86 K kg mol-1.
Assume van’t Hoff factor for NaCl is 1.87.
7. What mass of ethylene glycol (molar mass = 62.0 g mol-1) must be added to 5.50 kg of water to
lower the freezing point of water from 0° C to -10.0° C? (K, for water = 1.86 K kg mol-1)?
8. 15 g of an unknown molecular substance was dissolved in 450 g of water. The resulting solution
freezes at -0.34° C. What is the molar mass of the substance?
(Kf for water = 1.86 K kg mol-1).

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