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Chemical Kinetics Jee Advanced Practice Questions.

The document contains 9 multiple choice questions related to kinetics and reaction rates. The questions cover topics like reaction orders, rate constants, half lives, activation energies and their relationship to temperature. Graphs are also included as answer options for some questions.

Uploaded by

Raunak Rahangdale
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© © All Rights Reserved
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Download as PDF, TXT or read online on Scribd
432 views11 pages

Chemical Kinetics Jee Advanced Practice Questions.

The document contains 9 multiple choice questions related to kinetics and reaction rates. The questions cover topics like reaction orders, rate constants, half lives, activation energies and their relationship to temperature. Graphs are also included as answer options for some questions.

Uploaded by

Raunak Rahangdale
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Single Correct Question

Q-1: What is the value of rate constant and the time (minutes) required for the solution to become
optically inactive from the following data.
t/min 0.0 7.2 36.8 46.0 68.0 ∞
Rotation of polarized
light/degree 24.1 21.4 12.4 10.0 5.5 -10.7
Options
(a) k= 0.01119 min-1 and t= 105.4 min
(b) k= 3.2659 min-1 and t= 25.3 min
(c) k= 2.0659 min-1 and t= 10.2 min
(d) k= 1.01119 min-1 and t= 205.4 min

Single Correct Question


Q-2: The gaseous reaction
v1A(g) → v2B(g)
is first order with respect to A. It is studied at a constant pressure with a0 as the initial amount of A.
Which of the following expressions is correct about the volume of the system and the concentration
of A at time t . Where V0 is the volume of the system at t = 0.
Options

(a)

(b)

(c)
(d) None of these
Single Correct Question
Q-3: A compound A dissociated by two parallel first order paths at certain temperature

The reaction is started with 1 mole of pure ‘A’ in 1 litre closed container with initial pressure 2 atm.
What is the pressure (in atm) developed in container after 50 minutes from start of experiment?
Options
(a) 1.25
(b) 0.75
(c) 1.50
(d) 2.50

Single Correct Question


Q-4: A reaction can take place by two paths. k1 and k2 are rate constants for the two paths & E1 and
E2 are their respective activation energies.
At temperature Ta: k1 > k2, E1 < E2
If temperature is raised to Tb, the rate constants change to k1’ & k2’. Which relation is correct between
k1, k2, k1’ & k2’ (considering activation energy does not change with temperature)
Options

(a)

(b)

(c)

(d)
Single Correct Question
Q-5: A(aq) → B(aq) + C(aq) is a first order reaction.
Time t ∞
Moles of reagent n1 n2
Reaction progress is measured with the help of titration of reagent ‘R’. If all
A, B and C react with reagent and have ‘n’ factors

[n factor ; ] in the ratio of 1 : 2 : 3 with the reagent, then k in term of t, n1


and n2 is:
Options

(a)

(b)

(c)

(d)
Single Correct Question
Q-6: Some graph are sketched for the reaction A → B (assuming different orders). Where ‘α’
represent the degree of dissociation.

The order of reaction are respectively.


Options
(a) 0, 1, 2
(b) 1, 0, 2
(c) 2, 0, 1
(d) 1, 2, 0
Single Correct Question
Q-7: Which of the following plots is (are) correct for the given reaction?
([P]0 is the initial concentration of P)

P Q
Options

(a)

(b)

(c)

(d)
Single Correct Question
Q-8: For the following parallel chain reaction what will be that value of overall half-life of A in

minutes?

Options
(a) 3.3
(b) 6.3
(c) 3.6
(d) None of these

Single Correct Question


Q-9: For a 1st order reaction (gaseous) (constant V, T):
a A → (b - 1) B + 1 C (with b > a) the pressure of the system rose by % in time of 10
min. The half life of the reaction is therefore.
Options:
(a) 10 min
(b) 20 min
(c) 30 min
(d) 40 min
Multiple Correct Question
Q-10: Which is correct graph:
Options:

(a)

(b)

(c)

(d)
Multiple Correct Question
Q-11: In the following gaseous phase first order reaction
A(g) → 2B(g) + C(g)
Initial pressure was found to be 400 mm of Hg and it changed to 1000 mm of Hg after 20 min. Then
Options:
(a) Half life for A is 10 min
(b) Rate constant is 0.0693 min-1
(c) Partial pressure of C at 30 min is 350 mm of Hg
(d) Total pressure after 30 min is 1150 mm of Hg

Multiple Correct Question

Q-12: For the reaction 2A + B → C with the rate law and started
with A and B in stoichiometric proportion. Which is/are true?
Options:
(a) Unit of k is Ms-1
(b) [A], [B] and [C] all will be linear functions of time
(c) [C] = 2kt
(d) [C] = kt

Multiple Correct Question

Q-13: For the following reaction the rate of reaction is


Two moles of X are mixed with one mole of Y to make 1.0 L of solution. At 50 s, 0.5 mole of Y is
left in the reaction mixture. The correct statement(s) about the reaction is(are) (Use: ln 2 = 0.693)
Options:
(a) The rate constant, k, of the reaction is 13.86 × 10-4 s-1
(b) Half-life of X is 50s

(c)

(d)
Multiple Correct Question
Q-14: For a first order reaction A(g) → 2B(g) + C(g) at constant volume and 300 K, the total
pressure at the beginning (t = 0) and at time t are P0 and Pt , respectively. Initially, only A is present
with concentration [A]0, and t1/3 is the time required for the partial pressure of A to reach 1/3rd of its
initial value. The correct
option(s) is (are) (Assume that all these gases behave as ideal gases)
Options:

(a)

(b)

(c)

(d)
Integer type question

Q-15: For any acid catalysed reaction,


Half-life period is independent of concentration of A at given pH. At same concentration of A
half-life time is 10 min at pH = 2 and half-life time is 100 min at pH = 3. If the rate law expression
of reaction is r = k[A]x[H+]y then calculate the value of (x + y).

Integer type question


Q-16:

The rate of the reaction for [A] = 0.15 mol dm-3, [B] = 0.25 mol dm-3 and [C] = 0.15 mol dm-3 is
found to be Y × 10-5 mol dm-3 s-1. The value of Y is…….

Integer type question


Q-17: In the decomposition of H2O2 at 300 K, the energy of activation was found to be 18 kcal/mol
while it decreases to 6 kcal/mol when the decomposition was carried out in the presence of a catalyst
at 300 K. How many times is the catalysed reaction faster than uncatalysed one?
(Given your answer by multiplying 107)
Integer type question
Q-18: Consider the following reversible reaction,
A(g)+ B(g) ⇌ AB(g)
The activation energy of the backward reaction exceeds that of the forward reaction by 2RT (in J
mol-1). If the pre-exponential factor of the forward reaction is 4 times that of the reverse reaction, the
absolute value of ΔGƟ (in J mol-1) for the reaction at 300 K is ____.
(Given; ln(2) = 0.7, RT = 2500 J mol-1 at 300 K and G is the Gibbs energy)

Integer type question


Q-19: A reaction take place at 300K. When catalyst is added rate of reaction increases. Calculate
the change in temp (in °C) which would have same effect effect on rate of reaction as that of
catalyst. (Assume catalyst change the activation energy by 20%).

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