Sec: OSR.

IIT_*CO-SC Date: 28-04-24

Time: 3HRS Max. Marks: 180

Name of the Student: ___________________ H.T. NO:

28-04-24_OSR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-9(P1)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 5 – 10) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 11 – 16) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 20 – 23) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 24 – 29) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 30 – 35) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 36 – 38) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 39 – 42) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 43 – 48) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 49 – 54) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 55 – 57) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
MATHEMATICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. There are two dice A and B both having six faces. Die A has three faces marked with 1,
two faces with 2 and one faces marked with 3. Die B has one face marked with 1, two
faces marked with 2 and the three faces marked with 3. Both dies are thrown randomly
once. Let E be the event of getting sum of the numbers appearing on top faces equal to x,
P(E) is maximum if x is …

A) 3 B) 4 C) 5 D) 6

2. If A  z1  2  2i  , B  z2  , C  z3  are three points on the argand plane satisfying zk  2i  2

(k = 1, 2, 3). If ABC encloses the maximum area then the sum of imaginary part of z2
and z3 is

A) 2 B) 3/2 C) 4 D) 3

3. Let L1 : x  y  z and the line L2 : 2 x  y  z  1  0  3x  y  2 z  2 and if the shortest

1
distance between the lines L1 and L2 is then value of
p

 
1  p 2  p 3  p 4 1  1  p 2  p 3 is equal to ..

A) 3  2 B) 3  2 2 C) 3  2 D) 2  2

sin x  sin 3x  sin 5x  sin 7x

4. f x  the fundamental period of f(x) is
cos x  cos3x  cos5x  cos 7x

  
A) B) C) D) 
4 3 2

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 5 and 6:
Let A be a square matrix of order 3 satisfies the matrix equation A 3  6A 2  7A  8I  0
and B  A  2I. Also det .A  8

5. The value of det .  adj.  I  2A 1   is equal to

  B  1   p 
6. If adj.        B , where p,q, N, then least value of  p  q  is equal to
 2    q 
 

Question Stem for Question Nos. 7 and 8:

kak 1
Suppose a1, a2 , a3 ,...., a100 are positive real numbers such that ak  for
ak 1  (k  1)

k  2,3, ,100 . Given that a20  a23 . Then

7. a100 is equal to

8. a23 is equal to

Question Stem for Question Nos. 9 and 10:

A certain function f has the properties that f (3 x )  3 f ( x ) for all positive real values of x,

and that f ( x)  1  x  2 for 1  x  3 , N be the smallest positive number that satisfies

f ( N )  f (2001) , then

9. Sum of digits of N is equal to ….

10. Number of positive integral divisors of N is equal to …..

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.

Third term in the expansion of  x  x log 

5
11. 10 x
is 106 then possible value of ‘x’ are –

A) 1 B) 10 C) 105/ 2 D) 106

12. If direct common tangents of circle S1  x 2  y 2  2 x  4 y  4  0 and

S 2  x 2  y 2  8 x  12 y  36  0 touches circle S1  0 at A and B and S3  0 is equation

of circle whose diametrically opposite and points A and B then

A) Equation of S3 is 25 x 2  25 y 2  32 x  76 y  148  0

B) Equation of S3 is x 2  y 2  7 x  8 y  28  0

24
C) Length of common chord of S1  0 and S2  0 is
5

18
D) Length of common chord of S1  0 and S2  0 is
5

5  25  9
13. In ABC if  B  sec1    cos ec 1 5 ,  C  cos ec 1    cot 1   and
4  7   13 

AB = 3.

Which of the following is / are correct?

A) tan A, tan B , tan C are in A.P. B)In radius of ABC is irrational

C)Area of ABC is rational D) Semi – perimeter of ABC is rational

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
14. Which of the following is true about the equation: x 3  3 x 2  3 x  9  2  3 x 2  6 x  1

A) Sum of roots is –2

B) Sum of product of roots taken two at a time is – 3

C) Sum of magnitude of roots is 3

D)Sum of magnitude of roots is 4

15. f  x  is a differentiable function satisfying the functional equaton

f 2  x   f 2  y   2  xy  1  f 2  x  y  x, y  R. Also f  x   0 x  R and

f  2   2.Then which of the following staements is/are correct about f  x ?

A)  f  3   3 ( [.] denotes greatest integer function)

B) f  7 3
C) f  x  is even

D) f '  0   0

16. The curve C1 : y  e  x and C 2 : y  e  x sin x  x  0  touch each other at infinitely many
points. Let 0  x1  x 2  ......  x n  ........ be the abscissa of these points of contact. If An
denotes the area bounded by two curves between ordinates x  xn and x  xn1 , then

1  e 2   1 1  e 2   1
A) A1  B) A 2 
2 e5  2 2 e9  2

C) A1, A2, A3 are in A.P. D) A1, A2, A3 are in G.P.

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
17. Suppose that x, y and z are complex numbers of equal magnitude that satisfy
3
xyz  i 5 and xyz  3  i 5 if x  x1  ix2 , y  y1  iy2 and
2

a
z  z1  iz2 for real x1, x2, y1, y2, z1 and z2, then  x1x 2  y1y 2  z1z 2  can be written as
2

b
4a  b 
for relatively prime positive integers a and b. Compute  .
 10 

18. Katrina receives e-mail messages. The table below shows, for a random sample of 40
weekdays, the number of e-mail messages recived by katrina.

Number of e-mail messages 0 1 2 3 4 5 6 7 8

Number of weekdays 2 3 5 6 11 7 3 2 1

The mean of the number of e-mail messages recived per weekday by Katrina is
1
  ;    1 . If A  {x : x is a positive integral divisor of } & B = { x : x is a positive

integral divisor of  2 } , then the sum of digits of n  A  B  

19. Let An represents the area formed by the elements of set A, defined below.


An   x, y   R  R : y   x   x , y  0, 0  x  n, n  N 
If [.] denotes the greatest integer function and {.} denotes the fractional part function,
 A  A6 
then find the value of  3 .
 5 

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
PHYSICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
20. The heat transfer between any solid surface having temperature (T0) and surrounding
having temperature (TS) is defined as rate of heat flow Q  hA  T0  TS  where A is
exposed surface area of solid and h is any positive constant. Suppose hot water is
flowing inside a pipe of outer radius ‘a’ as shown in figure. An insulation having thermal
conductivity (K) is wrapped over the pipe. What should be the thickness (in cm) of the
insulation for maximum heat loss from the pipe to surroundings (a = 3 cm and K = 1, h =
20 in S.I. unit)

A) 1 B) 2 C) 5 D) 3

21. Figure shows three small positively charge particles having charges Q1, Q2 and Q3 and
mass m1, m2 and m3 respectively are placed at the vertex of a triangle having sides I1, I2,
I3. When the charges are released and allowed to move freely under mutual electrostatic
forces, it was observed that they all move along different straight lines. If
Q1 Q 2 Q 3 1 1 1
: :  : : , find I1 : I2 : I3.
m1 m 2 m 3 27 8 64

A) 27 : 8 : 64 B) 3 : 2 : 4 C) 4 : 3 : 2 D) 2 : 6 : 9

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
22. Two mirrors M1 and M2 make an angle  with line AB. A point source S is kept at a
distance r from the point of intersection of mirrors. A small hemispherical annular mask
is kept close to S so that no ray emanating from S directly reaches the screen kept at a
distance b from the source. Interference pattern of rays reflected from M1 and M2 is
observed on the screen. Find the fringe width of this interference patter.  = wavelength
of light being emitted by source

  b  2r sin 2     b  2r cos 2    b  r cos 2    b  2r cos 2 

A) B) C) D)
2r sin 2 2r sin 2 2r sin 2 r sin 2

23. A stunt rider on a unicycle is riding around the arena of a circus in a circle of radius R.
The radius of the wheel of the unicycle is r and the angular velocity with which the
wheel rotates about its horizontal axis is . What is the angular acceleration of the wheel
1
in rad/s2 (Take R = 10 m, r = m and  = 20 rad/s)
2

(Ignore the fact that the wheel axis is inclined).

A) 10 B) 20 C) 30 D) 40

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 24 and 25:
A transparent slab and a thin lens are made using the same material, whose refractive
1000 Å
index () is dependent on the wavelength () of light as   1  . Here,  is in Å.

The optical system of the slab and the lens is arranged as shown:

The slab has thickness t = 10 cm, while the radius of curvature of the curved surface of
the lens is R = 5 cm. The light rays being used in the experiment is bichromatic with
wavelengths 1 = 4000 Å and
2 = 5000 Å. If a parallel beam is incident from above the system, let the focal length of
the system be denoted by fA (i.e. f A and f A would be focal lengths for 1 and 2), while
1 2

if the rays are incident from below, let the focal length of the system be denoted by fB
(i.e. f B and f B would be the focal lengths for 1 and 2).In each case, focal length is
1 2

measured as the distance of interface of the slab and lens from the point of focus.
24. The value of f A is ……… (in cm)
1

25. The value of f B is …….. (in cm)

2

Question Stem for Question Nos. 26 and 27:

In space, there exists a uniform magnetic field in an infinitely long cylindrical region of
radius R. The field is given by B  B0 t directed downward, where B0> 0. An insulating
charged rigid loop in the shape of an equilateral triangle carries a uniform linear charge
density 0 and is initially at rest (t = 0). The triangle inscribes the boundary of cylindrical
region as shown

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P

This whole arrangement is in a gravity-free space and consider the mass of the triangular
loop to be M0. Then (initially), regarding the triangular loop, the angular acceleration
n 3  B0 R
and acceleration of COM is aCOM.
2 0

26. Find n?
27. Find aCOM
Question Stem for Question Nos. 28 and 29:
A conducting spherical shell mounted on an insulated stand is exposed to a radiation of
wavelength . The threshold wavelength of the conducting shell is, 0(>). Since energy
of incident photon is greater than threshold energy, the emission of photo electrons will
occur and due to it sphere gets charged and its potential becomes V0 and at this moment
emission of photoelectrons stops. A parallel plate capacitor of capacitance C0 is
connected to shell through a switch.
hc
(Given: = 12 × 10-7 V-m,  = 4000 Å, 0 = 6000 Å, C0 = 2F, R = 18 cm)
e

By closing the switch the capacitor is connected to sphere as shown in figure. The
charge on the capacitor after long time is q0C and
V0
When potential of the conducting shell is , the maximum kinetic energy of the
2
emitted photoelectrons when they are far from the conducting shell, is K in eV.
28. Find value of q0
29. Find value of 2K

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
30. A particle of mass m is rigidly attached to the circumference of a uniform circular ring
of same mass m and radius R which is placed on a rough horizontal surface as shown in
figure. When the ring is released from rest from the initial position shown in the figure,
it starts rolling without slipping on the rough horizontal surface. At the moment when
the ring has rotated by an angle   30 , choose the correct option(s).

g
A) The angular velocity of the ring is
3R

2g
B) The angular acceleration of the ring is
3 3R

mg
C) The frictional force acting on the ring is
3

mg
D) The frictional force acting on the ring is
2 3

31. Charge Q is uniformly distributed over the curved surface of a non-conducting long
hollow cylinder of mass m, length  and radius R which is placed on a rough inclined
plane of inclination  as shown in the figure. The cylinder starts rolling without slipping
 0Q2 
down the rough inclined plane. Then choose the correct option(s).  Take  m
  

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P

4g sin 
A) The acceleration of the cylinder is
9

2g sin 
B) The acceleration of the cylinder is
9

2mg sin 
C) The frictional force acting on the cylinder is
9

5mg sin 
D) The frictional force acting on the cylinder is
9

32. For the given circuit as shown in figure R1   6.0  0.3   101 , R2   3.0  0.6   101 ,

C  1.0  0.1 F , E   4.0  0.4   101 V . At t = 0, the circuit is formed and the

capacitor is initially uncharged.

A) Maximum error in calculation of maximum current in branch of capacitor can be 0.4

A

B) Maximum error in calculation of maximum current in branch of capacitor can be 0.04

A

C) Maximum fractional error in calculation of time constant of circuit during charging

can be 0.45

D) Maximum fractional error in calculation of time constant of circuit during charging

can be 0.25

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
33. A square loop containing an inductor of inductance 4 H and a capacitor of 2F, kept in the
plane of wires (infinite) carrying current I1 = 4t amp and I2 = 2t amp as shown. At t=0,
there is no current in the inductor and no charge on capacitor. Choose correct statements.

0 a
A) Maximum charge on capacitor is 4 n2


0 a
B) Maximum charge on capacitor is 8 n2


0a
C) Maximum current in inductor is n2
2

2 0 a
D) Maximum current in inductor is n2


dQ
34. The relation between change in entropy S and temperature T is defined as dS  ,
T
where dQ is heat transfer at temperature T. If internal energy U of an ideal gas and
entropy are related as S  lnU , for n mole of gas and internal energy at absolute is
zero, then choose the correct option(s)

A) The heat transfer only depends on the temperature

B) The molar heat capacity of n mole of gas is directly proportional to n

C) The molar heat capacity of n mole of gas is inversely proportional to n

D) Heat absorbed is behaving as state function

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
35. A long taut rope aligned long x-axis has two transverse waves 1  A1 sin  kx  wt  1  and
 2  A 2 sin  kx  wt   2  on it simultaneously. 1 tries to oscillate the particles of the rope
in the plane a1y  b1z  0 , whereas  2 tries to oscillate them in the plane a 2 y  b 2 z  0 .
Given A1 , A 2 , k, w, 1 , 2 , a1 , a 2 , b1 , b2 are constants, then which of the following is/are
correct.

A) If 1   2  0 , the rope will be confined to oscillate in fixed single plane.


B) If 1  2  , A1  A 2 and a1a2 + b1b2 = 0, then perpendicular distance of all point on
2
the rope from x-axis will be same.


C) If 1  2  , A1  A 2 and a1a2 + b1b2 = 0, the rope will not be confined to a single
2
fixed plane

3
D) If 1  2  , A1  A 2 and a1a2 + b1b2 = 0, then perpendicular distance of all point
2
on the rope from x-axis will be same

SECTION - 4 (Maximum Marks : 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
36. Nuclei of a radioactive element A are being produced at the rate of t2 at time instant t.
The element A has a decay constant . If N is the number of active nuclei of element A
dN
at any time t, then is found to be minimum at
dt
 
t = 4s. Value of N at t = 4s is  1  22  . Find the value of .


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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
37. A vertical steel rod has radius r1 and has coating of liquid film on it. The liquid slides
under gravity and speed of layer of liquid at radius r from the axis is
gr22  r  g 2 2
v ln   r  r1  where r2 is outer radius of liquid film,  is coefficient of
2  r1  4

viscosity and  is density of liquid. The force on the unit length of rod due to viscosity

of liquids is N gr12 for r2  3 . Find the value of N.

r1

38. A smooth hemispherical bowl (mass M and radius R) is in a gravity-free space. The co-
ordinate is so chosen that the base of the bowl is in the xy plane with the centre of the
base at the origin.

A ball (mass m) is moving with a constant velocity of v0  ˆi  . The ball collides with the

bowl at the location  , ,

R R R 
 . The collision is elastic and the bowl starts rotating
2 2 2

about the axis parallel to the vector  aiˆ  b ˆj  ckˆ , where a, b and c are the smallest
positive integers possible. Find the value of a + b + c.

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
CHEMISTRY MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
39. A volume of 100 ml of 0.5 N – H2SO4 solution is neutralized with 200 ml of 0.2 M –
NH4OH in a constant pressure calorimeter which resulted 1.4oC rise in temperature. The
heat capacity of the calorimeter system is 1.5 kJ/oC. Some useful thermochemical
equations are as follows:

HCl  NaOH 
 NaCl  H 2 O  57 kJ

CH3COOH  NH 4OH 
 CH3COONH 4  H 2O  48.1 kJ

Which of the following statement is incorrect?

A) Enthalpy of neutralization of HCl vs NH4OH is -52.5 kJ/mol

B) Enthalpy of dissociation (ionization) of NH4OH is 4.5 kJ/mol

C) Enthalpy of dissociation (ionization) of CH3COOH is 4.6 kJ/mol

+ –
D) H for 2H2O(l) 
 2H (aq) + 2OH (aq) is 114 kJ

40.

The entire system is at equilibrium at 300 K. The volume of each chamber is 82.1 l. The
total pressure in left chamber is 4 atm and in right chamber is 2 atm. NH3(g) and H2S(g)
are obtained only from the dissociation of NH4HS(s). The value of KP (in atm2) for the
 NH 3  g   H 2S  g  is
reaction: NH 4 HS  s  

A) 2 B) 3 C) 1 D) 4

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
41. Which of the following ion has 6 electrons in its 4f orbital

A) Sm2+ B) Eu3+ C) Gd3+ D) Tb3+

42. The major product formed in the following reaction is:

A) B) C) D)

SECTION - 2 (Maximum Marks : 12)

This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 43 and 44:
The lowering of vapour pressure on adding a non-volatile solute may be measured by
Ostwald-Walker method. In this method, dry air is first passed through a series of
vessels having the solution, then through a series of vessels having pure solvent and
finally through a vessel (normally U-tube) having the absorbent of the solvent. The
masses of solution and pure solvent decreases due to removal of vapours of solvent in
the flow of air and the mass of absorbent increases due to absorption of the vapour of
solvent in order to make the air dry. By measuring the changes in mass, we may
determine the lowering of vapour pressure and hence, the composition of solution, from
Raoult’s law.

43. If the mass of absorbent increased by 0.24 gm and the mass of pure solvent (water)
decreased by 0.02 gm, then the mass percent of solute (glucose) in its aqueous solution
is
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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
44. If the experiment is performed with aq. AlCl3 solution ( = 0.8) prepared by dissolving 1
mole AlCl3 in 17 mole water and the decrease in mass of solution is found to be 0.18
gm, then the increase in mass of absorbent should be

Question Stem for Question Nos. 45 and 46:

1 mole of Pb3O4  4 HNO3 
 X  Y  2 H 2O

Y is powerful oxidizing agent

2Y  2 H 2 SO4 

 2 PbSO4  Z  2 H 2O

Z is paramagnetic in nature

45. Find number of atoms in one molecule of Y.

46. Find the number of unpaired electron in one molecule of Z.

Question Stem for Question Nos. 47 and 48:

47. What is the degree of unsaturation in compound D?

48. What is the molecular weight of compound A?

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
49. The correct statements is/are
A) CsCl crystal likely to show Schottky defect
B) CsCl crystal likely to show Frenkel defect
C) Photosensitivity of AgBr is due to the presence of Frenkel defect in it
D) Crystals having F-centers are coloured and paramagnetic
50. The cell potential for the unbalanced chemical reaction
Hg 22  NO3  H  
 Hg 2  HNO2  H 2 O ; E 0cell  0.02 V

is measured under standard state conditions in the electrochemical cell.  2.303 RT  0.06 
 F 

Then which is/are the correct statement(s)

A) Solution in cathodic compartment is acidic
B) Solution in Anodic compartment is acidic
2
C) Cell potential will be zero at pH  , if activity of other components are equal to one
9
D) 0.6 moles of electron pass through the circuit when 0.6 moles of Hg2+ are produced in
the cell

51. Which of the following are correct?

A) All cupric halides are known except the iodide
B) At 1M conc, Fe3+oxidises I  but not Br 
C) At 1M conc H  reduces to H2 thermodynamically by all the metals of first transition
series except Cu
D) Cr2+ reduces H  to H2 and Cr3+oxidises I  to I2

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
52. Which reaction is/are appropriate for the synthesis of pentan-2-one?

A)

B)

C)

D)

53. A disconnection of 1,4-diphenylbut-2-yne is given below followed by possible

corresponding synthetic reactions. Which of (a)-(d) include a suitable first reagent?

Disconnection:

Synthetic steps for the disconnection shown:

A) BuLi, THF B) EtMgBr, Et2O

C) NaOEt, EtOH D) NaNH2, NH3

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P
54. Which of the following equations shows the correct outcome of the main reaction?

A)

B)

C)

D)

SECTION - 4 (Maximum Marks : 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
55. If gold number for a protective colloid is 0.08 then ‘x’ milligrams would be needed to
protect 50 ml of a standard gold sol from being coagulated on addition of 5 ml of 10%
NaCl solutions.

The total number of ions from below set giving white precipitate with appropriate
amount of Na2S2O3(aq) are ‘y’

Hg 2 , Pb2 , Cu 2 , Ag 

Find 5x + y

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Narayana IIT Academy 28-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-9(P1)_Q’P

 Fe  CO 4  ,  V  CO 6  ,
2 
56. K  PtCl3  C 2 H 4   ,  Fe  H 2O 5 NO  SO 4
I II III IV

How many of the following statements are correct for the above set of compounds?

(a) I has lower C – O bond length than II.

(b) II has lower C – O bond length than I.

(c) I follows Sidgwick EAN Rule.

(d) II follows Sidgwick EAN Rule.

(e) III has higher C-C bond length than C2 H 4 .

(f) Synergic bonding is involved in all the given (four) complex compounds.

(g) I, II, III are organo-metallic compounds.

57. Identify A and B in the following reaction sequence, if x is the number of non-
conjugated double bond in A and y is the number of conjugated double bond in B, then
identify the sum of x + y?

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