FINAL JEE–MAIN EXAMINATION – JANUARY, 2024

(Held On Wednesday 31st January, 2024) TIME : 3 : 00 PM to 6 : 00 PM

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 1
Where tan  
1. The number of ways in which 21 identical apples 2
can be distributed among three children such that r  2cos   3sin    17
each child gets at least 2 apples, is
(1) 406 17 5 17 5
r 
(2) 130 7 7
(3) 142 3. Let z1 and z2 be two complex number such that z1
(4) 136 + z2 = 5 and z13  z 32  20  15i . Then z14  z 24
Ans. (4)
equals-
Sol. After giving 2 apples to each child 15 apples left
now 15 apples can be distributed in 1531 C2  17C2 (1) 30 3
ways (2) 75
17  16 (3) 15 15
  136
2
(4) 25 3
2. Let A (a, b), B(3, 4) and (–6, –8) respectively Ans. (2)
denote the centroid, circumcentre and orthocentre Sol.- z1  z 2  5
of a triangle. Then, the distance of the point
z13  z32  20  15i
P(2a + 3, 7b + 5) from the line 2x + 3y – 4 = 0
measured parallel to the line x – 2y – 1 = 0 is z13  z32   z1  z2   3z1z2  z1  z2 
3

(1)
15 5 z13  z32  125  3z1. z 2  5 
7
 20  15i  125  15z1z2
17 5
(2)  3z1z2  25  4  3i
6
 3z1z2  21  3i
17 5
(3)  z1.z2  7  i
7
  z1  z2   25
2
5
(4)
17  z12  z 22  25  2  7  i 
Ans. (3)
 11  2i
Sol. A(a,b), B(3,4), C(-6, -8)
 z12  z22 
2
2:1  121  4  44i
B
 z14  z24  2  7  i   117  44i
C A 2
(-6, -8) (a, b) (3, 4)
 z14  z 24  117  44i  2  49  1  14i 
 a  0, b = 0  P 3,5
Distance from P measured along x – 2y – 1 = 0  z14  z24  75
 x  3  r cos , y = 5+rsin
4. Let a variable line passing through the centre of the Sol.-
circle x2 + y2 – 16x – 4y = 0, meet the positive x
f x    t  t e
2  t2
dt
co-ordinate axes at the point A and B. Then the x

 f   x   2.  x  x 2  e  x ............ 1
minimum value of OA + OB, where O is the 2

origin, is equal to
x2 1
(1) 12
g  x    t 2 e  t dt
(2) 18 0
(3) 20 g  x   xe x  2x   0
2

(4) 24
f   x   g  x   2xe  x  2x 2e  x  2x 2e  x
2 2 2

Ans. (2)
Integrating both sides w.r.t.x
Sol.-  y  2  m  x  8 
f  x   g  x    2xe  x dx
2

 x-intercept
0
 2 
   8 x t
2
m 


 y-intercept
e dt   e  t 
t

  8m  2 
0
0

2  e
 log 9 1
e
1

 OA  OB   8  8m  2
m  1
 9  f (x)  g(x)   1   9  8
f ' m 
2
8  0  9
Let  , ,   be mirror image of the point (2, 3, 5)
m2
6.
1
 m2  x 1 y  2 z  3
4 in the line   .
2 3 4
1
m Then 2  3  4 is equal to
2
(1) 32
 1  (2) 33
 f    18
 2 (3) 31
 Minimum = 18 (4) 34
Ans. (2)
Sol.
5. Let f ,g : (0, )  R be two functions defined by P(2,3,5)

 t  t e
2
x
dt and g(x)   t 2 e t dt .
x
f (x)  
1
2  t2
x 0

Then the value of f   

loge 9  g loge 9 is
equal to R  , ,  
(1) 6
PR   2,3, 4 
(2) 9
(3) 8  PR.  2,3, 4   0
(4) 10    2,   3,   5  .  2,3, 4   0
Ans. (3)  2  3  4  4  9  20  33
7. Let P be a parabola with vertex (2, 3) and directrix  a 2  2b2
x 2 y2
2x + y = 6. Let an ellipse E : 2  2  1, a  b of Put in (1)  b 
2 328
a b 25
1
eccentricity pass through the focus of the  2b 2 
2
4b 2 1 328 656
2    2
 b2  4   
parabola P. Then the square of the length of the  a  a 2 25 25
latus rectum of E, is
385 8. The temperature T(t) of a body at time t = 0 is 160o
(1)
8 F and it decreases continuously as per the
347 dT
(2)   K(T  80) , where K
8 differential equation
dt
512
(3) is positive constant. If T(15) = 120oF, then T(45) is
25
equal to
656
(4) (1) 85o F
25
(2) 95o F
Ans. (4)
Sol.- (3) 90o F
(4) 80o F
(1.6, 2.8)
Ans. (3)
( , )
axis Sol.-
(2, 3) Focur
dT
  k  T  80 
dt
T t
dT
Slope of axis 
1
 T  80  0 Kdt
160 

2
T
1
y  3   x  2
ln T  80 160   kt
2
ln T  80  ln 80   kt
 2y  6  x  2
T  80
 2y  x  4  0 ln   kt
80
2x  y  6  0
T  80  80e  kt
4x  2y 12  0
120  80  80e  k.15
  1.6  4    2.4
40 1
  2.8  6   3.2  e  k15 
80 2
Ellipse passes through (2.4, 3.2)
 T  45   80  80e  k.45
2 2
 24   32 
 80  80  e  k.15 
3
   
      1
10 10
……….(1)
a2 b2 1
 80  80 
b2 1 b2 1 8
Also 1    
a2 2 a 2 2  90
9. Let 2nd, 8th and 44th, terms of a non-constant A.P. 11. The area of the region enclosed by the parabola
be respectively the 1st, 2nd and 3rd terms of G.P. If y = 4x – x2 and 3y = (x – 4)2 is equal to
the first term of A.P. is 1 then the sum of first 32
(1)
20 terms is equal to- 9
(1) 980 (2) 960 (2) 4
(3) 990 (4) 970 (3) 6
Ans. (4) 14
Sol.- 1 + d, 1 + 7d, 1 + 43d are in GP (4)
3
(1 + 7d)2 = (1 + d) (1 + 43d) Ans. (3)
1 + 49d2 + 14d = 1 + 44 d + 43d2 Sol.-
6d2 – 30d = 0
d=5
20
S20   2 1   20  1  5
2 
=10  2  95
=970
10. Let f : R  (0, ) be strictly increasing 4
 x  4 
2
Area    4x  x 2    dx
1 
f (7x) 
3
function such that lim  1. Then, the value
x  f (x)
3 4
4x 2 x 3  x  4 
 f (5x)  Area   
of lim   1 is equal to 2 3 9
x 
 f (x)  1

(1) 4  64 64 4 1 27 
     
(2) 0  2 3 2 3 9 
(3) 7/5   27  21  6
(4) 1
12. Let the mean and the variance of 6 observation a,
Ans. (2)
b, 68, 44, 48, 60 be 55 and 194, respectively if
Sol.- f : R  (0, )
a > b, then a + 3b is
f  7x  (1) 200
lim 1
x  f  x 
(2) 190
f is increasing (3) 180
f  x   f 5x   f  7x  (4) 210
Ans. (3)
f  x  f  5x  f  7x  Sol.- a, b, 68, 44, 48, 60
 
f x f x f x Mean = 55 a>b
f  5x  Variance = 194 a + 3b
1  lim 1
x  f  x  a  b  68  44  48  60
 55
 f  5x   6
  1  220  a  b  330
 f  x    a  b  110......(1)
 1 1  0
 Also, 14. Consider the function f : (0, )  R defined by
 xi  x 
2
 log e x
 n
 194 f (x)  e . If m and n be respectively the
number of points at which f is not continuous and f
  a  55    b  55    68  55    44  55 
2 2 2 2

is not differentiable, then m + n is

  48  55    60  55   194  6
2 2
(1) 0
  a  55    b  55   169  121  49  25  1164
2 2
(2) 3
  a  55    b  55   1164  364  800
2 2 (3) 1
(4) 2
a 2  3025  110a  b 2  3025  110b  800
Ans. (3)
 a 2  b 2  800  6050  12100
Sol.-
a 2  b 2  6850.......(2)
f :  0,    R
Solve (1) & (2);
f x  e
 log e x
a=75,b=35
 a  3b  75  3  35   75  105  180
 1
13. If the function f : (, 1]  (a, b] defined by  ;0  x  1
1  e ln x
f  x   ln x  
f (x)  ex 3x 1 is one-one and onto, then the
3
e  1 ;x 1
distance of the point P(2b + 4, a + 2) from the line 
 eln x
x + e–3y = 4 is :
1
(1) 2 1  e6 (2) 4 1  e6  1  x; 0  x  1

(3) 3 1  e6 (4) 1  e6 x
1
Ans. (1)  ,x 1
Sol.- f  x   e x3 3x 1 x
f '  x   e x3 3x 1 .  3x 2  3
 ex3 3x 1 . 3  x  1 x  1 1

For f '  x   0
 f  x  is increasing function 0 1
a  e  0  f   
b  e131  e3  f  1
P(2b + 4, a + 2) m = 0 (No point at which function is not continuous)
 P  2 e3  4,2  n = 1 (Not differentiable)
m+n=1
P
15. The number of solutions, of the equation

d esin x  2esin x  2 is
(1) 2
(2) more than 2
x + e -3 y = 4
(3) 1
d
 2e3  4  2e3  4  2 1  e6 (4) 0
1  e6 Ans. (4)
Sol.- Take esin x  t  t  0  Sol.- 6C
m  2  6 Cm1  6 Cm 2 8 C3

m1  Cm2 8 C3
2 7C 7
t 2
t
8C
m 2 8 C3
t2  2
 2
t m  2
 t 2  2t  2  0 And n 1 P : n P  1:8
3 4
 t2  2t  1  3
 n  1 n  2  n  3  1
  t  1  3
2
n  n  1 n  2  n  3 8
 t 1 3  n 8
 t  1  1.73
 n Pm1 n 1 Cm 8 P3 9 C2
 t  2.73 or -0.73 (rejected as t > 0)
98
 esin x  2.73  8 7  6 
2
 loge esin x  loge 2.73
= 372
 sin x  loge 2.73  1
So no solution.
18. A coin is based so that a head is twice as likely to
16. If a  sin 1
sin 5 and b  cos 1
cos 5 , occur as a tail. If the coin is tossed 3 times, then
then a  b is equal to the probability of getting two tails and one head is-
2 2

(1) 4  25
2
2
(1)
(2) 8  40  50
2 9

(3) 4  20  50
2 1
(2)
(4) 25 9
Ans. (2) 2
(3)
Sol. a  sin 1  sin 5  5  2 27

and b  cos 1  cos5   2  5 (4)

1
27
a 2  b2   5  2   2  5
2 2
Ans. (1)
 8 2  40  50 1
Sol. Let probability of tail is
3
17. If for some m, n; 6 Cm  2  6
Cm1  6 Cm2 8 C3
 Probability of getting head =
2
n 1 3
and P3 :n P4  1: 8, then n Pm 1  n 1 Cm is equal
 Probability of getting 2 tails and 1 head
to
(1) 380 1 2 1
    3
(2) 376  3 3 3
(3) 384 2
 3
(4) 372 27
Ans. (4) 2

9
19. Let A be a 3 3 real matrix such that 0  0 
   
1  1   1  1  0   0 Given A 1    2 
               
A  0   2  0  , A  0   4  0  , A 1   2 1  .
 0   0 
1  1  1  1   0   0
           
 y1  0 
 x  1     
      y2    2
Then, the system  A  3I  y  2 has    
   
z  3  y3  0 
   
(1) unique solution  y1  0, y2  2, y3  0
(2) exactly two solutions  from (2), (3), (4), (5), (6) and (7)
(3) no solution x1  3x, x 2  0, x3  1
(4) infinitely many solutions y1  0, y2  2, y3  0
Ans. (1)
z1  1, z2  0, z3  3
 x1 y1 z1 
Sol.- Let A   x 2 y2 z2   3 0 1
 x 3 y3 z3  A   0 2 0 
 1 0 3 
1   2 
     x   1
Given A  0    0  …. (1)    
     Now  A  3l   y    2 
1   2     
 z  3 
 x1  z1   2 
     0 0 1  x   1
  x 2  z 2   0    0 1 0   y    2 
     1 0 0   z   3 
 x 3  z3   2 
 z  1 
 x1  z1  2 …. (2)   y    2
  x  3 
x 2  z2  0 …. (3)
x 3  z3  0 …. (4)
 z  1,  y  2,  x  3
20. The shortest distance between lines L1 and L2,
 1  4 
    x 1 y 1 z  4
Given A  0    0  where L1 :   and L2 is the line
   
2 3 2
1   4  passing through the points A  4, 4,3 .B  1,6,3
  x1  z1   4  x  3 y z 1
    and perpendicular to the line   , is
   x 2  z 2   0  2 3 1
    121 24
  x 3  z3   4  (1) (2)
221 117
 x1  z1  4 …. (5)
141 42
(3) (4)
x 2  x 2  0 …. (6) 221 117
x3  z3  4 Ans. (3)
Sol.- 

x  4 y 4 z 3  2
2 sin x cos x
L2    
2  sin 4 x  cos 4 x dx
3 2 0 0

x 2  x1 y 2  y1 z 2  z1 

2 3 2  2
2 sin x cos xdx
3 2 0

2  1  2sin 2 x  cos2 x
0
 S.D 
n1  n 2 

2 2
sin 2x
5 5 7   2  sin 2 2x dx
2
2 3 2 0

3 2 0 
  2
2 sin 2x
n1  n 2 
2  1  cos2 2x dx
0
141
 Let cos 2x  t
4iˆ  6ˆj  13kˆ
141

16  36  169 22. Let a, b, c be the length of three sides of a triangle
141 satisfying the condition (a2 + b2)x2 – 2b(a + c).

221 x + (b2 + c2) = 0. If the set of all possible values of

SECTION-B 
x is the interval  ,  , then 12 2  2 is equal 

120 x 2 sin x cos x to ______.
3 0 sin 4 x  cos4 x
21. dx is equal to _________.
Ans. (36)
Ans. (15)

Sol.- a 2
 b2  x 2  2b  a  c  x  b2  c2  0
x 2 sin x . cos x
Sol.-  sin 4 x  cos4 x dx  a 2 x 2  2abx  b 2  b 2 x 2  2bcx  c 2  0
0
  ax  b    bx  c   0
2 2


 
2

sin x . cos x
x 2     x  dx
2  ax  b  0, bx  c  0
0
sin x  cos x
4 4
abc b + c > a c+a>b

2 sin x . cos x  2x  2 

0
sin 4 x  cos 4 x
 

1 5 1 5
2 2
x sin x cos x sin x cos x
 2  dx  2  dx x
0
sin x  cos x
4 4
0
sin 4 x  cos 4 x 2 2
 
1  5 1  5
 2 sin x cos x
 2 . 
2
sin x cos x x , or x 
4 0 sin 4 x  cos 4 x
dx  2  sin 4 x  cos4 x dx 2 2
0
 5 1 5 1 24. Let the coefficient of xr in the expansion of
 x
 x  3   x  3  x  2  
2 2 n 1 n 2

5 1 5 1
 ,   x  3  x  2  .......   x  2
n 3 2 n 1
2 2

   5  1  
n


2 2
5 1  be  r . If  n   n , ,   N, then the value
12       12 
2 2 r

 =36
r 0
 4 
  of    equals __________.
2 2

23. Let A(–2, –1), B(1, 0), C  ,  and D  ,   be Ans. (25)

the vertices of a parallelogram ABCD. If the point Sol.-

 x  3   x  3  x  2    x  3 
n 1 n 2 n 3
C lies on 2x – y = 5 and the point D lies on

 x  2   ........   x  2 
2 n 1
3x – 2y = 6, then the value of       is

equal to ________.  r  4n 1  4n  2  3  4n 3  32.......  3n 1

Ans. (32) n 1
 3  3 2 3 
n 1

4 1     .....    
Sol.-  4  4   4  
n
D  ,   3
1  
 4n 1   
C  ,   4
6
2y =
3x – P 3
1
4
A(-2,-1)  4  3    n
n n n

B(1,0) 2x – y = 5
  4,   3
   2  1    1   2   2  16  9  25
P ,  , 
 2 2   2 2
25. Let A be a 3  3 matrix and det (A) = 2. If
  2  1  1 
 and 
2 2 2 2
     3.....(1),     1......(2)
 
n  det adj adj ......  adjA   
2024-times
Also,  ,   lies on 3x – 2y = 6
Then the remainder when n is divided by 9 is equal
3  2  6 ......(3) to ___________.
and  ,  lies on 2x – y = 5 Ans. (7)

 2   5.........(4) Sol.- A  2

Solving (1), (2), (3), (4)


adj adj  adj.....  a    A   n 12024

  3, =  11, =  6,  12 2024 times

        32 22024
A

 222024
 22024   22  22022  4 8
674
 4  9  1
674  x 2 x3   x 2 x3 
ax 2 1  x    .....   b  x    ....... 
 2! 3!   2 3 
 22024  4  mod 9   x 2
x 3

Sol.- cx 1  x    ....... 
 x! 3! 
 22024  9m  4, m  even lim
x 0 3 sin x
x.
x
29m4  16 .  23   16  mod 9
3m
 c  b  x    c  a  x 2   a    x 3  ......
b b c
 lim  2   3 2
1
7 x  x3

26. Let a  3iˆ  2ˆj  k,

ˆ b  2iˆ  ˆj  3kˆ and c be a
c  b  0,
b
ca  0
2
  
vector such that a  b  c  2 a  b  24ˆj  6kˆ  b c
a    1 a=
3
bc
3
3 2 4 2
 
and a  b  ˆi .c  3. Then c is equal to _____.
2
9 9 9
a 2  b2  c2   
16 4 4
16  a  b  c 2   81
Ans. (38) 2 2

Sol.-  a  b   c  2  a  b   24ˆj  6kˆ 28. A line passes through A(4, –6, –2) and B(16, –2,4).

5iˆ  ˆj  4kˆ   c  2  7iˆ  7ˆj  7kˆ   24ˆj  6kˆ The point P(a, b, c) where a, b, c are non-negative
integers, on the line AB lies at a distance of 21
ˆi ˆj kˆ
units, from the point A. The distance between the
5 1 4  14iˆ  10ˆj  20kˆ
points P(a, b, c) and Q(4, –12, 3) is equal to ____.
x y z
Ans. (22)
 ˆi  z  4y   ˆj  5z  4x   kˆ  5y  x   14iˆ  10ˆj  20kˆ
Sol.-
z  4y  14, 4x  5z  10,5y  x  20
x4 x6 z2
 a  b  i  .c  3  
12 4 6
 2iˆ  3jˆ  2kˆ  .c  3 x4 y6 z2
   21
2x  3y  2z  3 6 2 3
7 7 7
 x  5, y  3, z  2
 6 2 3 
c  25  9  4  38  21  4,  21  6,  21  2 
2
 7 7 7 
  22, 0, 7    a, b, c 

ax 2e x  b log e 1  x   cxe  x  324  144  16  22

27. If lim  1,
x 0 x 2 sin x 29. Let y = y(x) be the solution of the differential
equation
then 16(a2 + b2 + c2) is equal to ______.
sec 2 xdx   e 2y tan 2 x  tan x  dy  0,
Ans. (81)
  
0x , y    0. If y    ,
2 4 6
8
Then e is equal to ______.
Ans. (9)
Sol.- 30. Let A = {1, 2, 3, ………100}. Let R be a relation
dx 2y
sec 2 x  e tan 2 x  tan x  0 on A defined by (x, y)  R if and only if 2x = 3y.
dy
 dx dt  Let R1 be a symmetric relation on A such that
 Put tan x  t  sec x  
2

 dy dy  R  R 1 and the number of elements in R1 is n.

dt
 e 2y  t 2  t  0 Then, the minimum value of n is ___________.
dy
dt Ans. (66)
 t   t 2 .e 2y
dy
Sol.-
1 dt 1
  e 2y
t 2 dy t R   3, 2  ,  6, 4  ,  9, 6  , 12,8  ,......... 99, 66 
 1 1 dt du  n(R)  33
 Put  u 2  
 t t dy dy   66
du
 u  e 2y
dy
du
 u  e 2y
dy

I.F.  e   e  y
 dy

ue y   e  y  e 2y dy
1
 e y  e y  c
tan x

x  , y  0, c  0
4

x , y=
6
3e  e  0


e2  3
e8   9
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A Sol.
31. A light string passing over a smooth light fixed
pulley connects two blocks of masses m1 and m2 .
If the acceleration of the system is g/8, then the
ratio of masses is

M  iA
= 5   0.2    0.1 iˆ 
= 0.1 iˆ  
(1)
9
(2)
8   
  M  B  0.1 iˆ  2  10 3   ˆj
7 1
4 5
 
= 2  104 kˆ N  m
(3) (4)
3 3 33. The measured value of the length of a simple
Ans. (1) pendulum is 20 cm with 2 mm accuracy. The time
for 50 oscillations was measured to be 40 seconds
Sol. a
 m1  m2  g  g
with 1 second resolution. From these
 m1  m2  8
measurements, the accuracy in the measurement of
8m1  8m 2  m1  m 2 acceleration due to gravity is N%. The value of N
7m1  9m 2 is:
(1) 4 (2) 8
m1 9
 (3) 6 (4) 5
m2 7
Ans. (3)
32. A uniform magnetic field of 2  103 T acts along
Sol. T  2
positive Y-direction. A rectangular loop of sides 20 g
cm and 10 cm with current of 5 A is Y-Z plane.
42
The current is in anticlockwise sense with g
T2
reference to negative X axis. Magnitude and g  2T
 
direction of the torque is : g T
(1) 2  104 N  m along positive Z –direction 0.2  1 
  2 
(2) 2  104 N  m along negative Z-direction 20  40 
(3) 2  104 N  m along positive X-direction 0.3
=
(4) 2  104 N  m along positive Y-direction 20
0.3
Ans. (2) Percentage change =  100 = 6%
20
34. Force between two point charges q1 and q 2 37. The speed of sound in oxygen at S.T.P. will be
placed in vacuum at ‘r’ cm apart is F. Force approximately:
between them when placed in a medium having (Given, R  8.3 JK1 ,   1.4)
dielectric K = 5 at ‘r/5’ cm apart will be:
(1) 310 m / s
(1) F/25 (2) 5F
(3) F/5 (4) 25F (2) 333 m/s
Ans. (2) (3) 341 m/s
1 q1q 2 (4) 325 m/s
Sol. In air F 
40 r2 Ans. (1)
In medium RT 1.4  8.3  273
Sol. v 
1 q1q 2 25 q1q 2 M 32 103
F'    5F
4  K 0   r ' 2
4  5 0   r 2  314.8541 315 m / s
35. An AC voltage V  20sin200t is applied to a 38. A gas mixture consists of 8 moles of argon and 6
series LCR circuit which drives a current moles of oxygen at temperature T. Neglecting all
  vibrational modes, the total internal energy of the
I  10 sin  200t   . The average power
 3 system is
dissipated is: (1) 29 RT
(1) 21.6 W (2) 200 W (2) 20 RT
(3) 173.2 W (4) 50 W
(3) 27 RT
Ans. (4)
(4) 21 RT
Sol.  P  IV cos 
Ans. (3)
20 10
   cos60
o
Sol. U  nC V T
2 2
 50 W  U  n1CV1 T  n 2CV2 T
36. When unpolarized light is incident at an angle of 3R 5R
 8 T  6 T
60° on a transparent medium from air. The 2 2
reflected ray is completely polarized. The angle of = 27RT
refraction in the medium is
39. The resistance per centimeter of a meter bridge
(1) 30 0 (2) 60 0
wire is r, with X  resistance in left gap. Balancing
0 0
(3) 90 (4) 45 length from left end is at 40 cm with 25 
Ans. (1)
resistance in right gap. Now the wire is replaced by
Sol. By Brewster’s law
another wire of 2r resistance per centimeter. The
new balancing length for same settings will be at
(1) 20 cm
(2) 10 cm
(3) 80 cm
(4) 40 cm
At complete reflection refracted ray and reflected
Ans. (4)
ray are perpendicular.
 X 25 42. A block of mass 5 kg is placed on a rough inclined
surface as shown in the figure.

Sol. 1
G
=0.


g
5k
1=40c 2=60cm
25 X
 .....(i) 300
r 1 r 2
25 X If F1 is the force required to just move the block
 ..... (ii)
2r '1 2r '2
up the inclined plane and F2 is the force required
From (i) and (ii)
'2  2  40 cm to just prevent the block from sliding down, then
40. Given below are two statements: the value of F1  F2 is : [Use g  10m / s2 ]
Statement I: Electromagnetic waves carry energy
as they travel through space and this energy is (1) 25 3 N (2) 50 3 N
equally shared by the electric and magnetic fields. 5 3
Statement II: When electromagnetic waves strike (3) N (4) 10 N
2
a surface, a pressure is exerted on the surface.
In the light of the above statements, choose the Ans. ( √ ) BONUS
most appropriate answer from the options given Sol. f K  mg cos 
below:
(1) Statement I is incorrect but Statement II is 50  3
 0.1
correct 2
(2) Both Statement I and Statement II are correct.  2.5 3 N
(3) Both Statement I and Statement II are incorrect.
(4) Statement I is correct but Statement II is
incorrect.
Ans. (2)
1 B2
Sol. 0 E 2 
2 20
1
E  CB and C 
0 0 F1  mg sin   f K
41. In a photoelectric effect experiment a light of
 25  2.5 3
frequency 1.5 times the threshold frequency is
made to fall on the surface of photosensitive
material. Now if the frequency is halved and
intensity is doubled, the number of photo electrons
emitted will be:
(1) Doubled (2) Quadrupled
(3) Zero (4) Halved
Ans. (3)
f
Sol. Since  f 0 F2  mg sin   f K
2 i.e. the incident frequency is less
than threshold frequency. Hence there will be no  25  2.5 3
emission of photoelectrons.
 F1  F2  5 3 N
 current  0
43. By what percentage will the illumination of the R2
Sol. R1 
lamp decrease if the current drops by 20%? 2
(1) 46% (2) 26% R0
R 0  A1   A2 
1/3 1/3

(3) 36% (4) 56% 2
Ans. (3) 1
A1  A2
Sol. P  i2R 8
192
Pint  I2int R A1   24
8
Pfinal   0.8 Iint  R 46. The mass of the moon is 1/144 times the mass of a
2

planet and its diameter 1/16 times the diameter of a

% change in power = planet. If the escape velocity on the planet is v, the
Pfinal  Pint escape velocity on the moon will be:
 100  (0.64  1)  100  36%
Pint v v
(1) (2)
3 4
44. If two vectors A and B having equal magnitude
v v
R are inclined at an angle  , then (3) (4)
12 6
 Ans. (1)
(1) A  B  2 R sin  
2 2GM
Sol. Vescape 
 R
(2) A  B  2 R sin  
2 2GM
Vplanet  V
 R
(3) A  B  2 R cos  
2 2GM  16 1 2GM
VMoon  
144 R 3 R

(4) A  B  2 R cos   VPlanet
2 V
VMoon  =
3 3
Ans. (3)
47. A small spherical ball of radius r, falling through a
Sol. The magnitude of resultant vector viscous medium of negligible density has terminal
R '  a 2  b 2  2ab cos  velocity 'v'. Another ball of the same mass but of
radius 2r, falling through the same viscous medium
Here a  b  R
will have terminal velocity:
Then R '  R 2  R 2  2R 2 cos  v v
(1) (2)
2 4
 R 2 1  cos 
(3) 4v (4) 2v
 Ans. (1)
 2R 2cos 2
2 Sol. Since density is negligible hence Buoyancy force
will be negligible

 2R cos At terminal velocity.
2
Mg  6rv
45. The mass number of nucleus having radius equal to
1
half of the radius of nucleus with mass number 192 V (as mass is constant)
r
is: v r'
(1) 24 (2) 32 Now, 
v' r
(3) 40 (4) 20 r '  2r
Ans. (1) v
So, v ' 
2
48. A body of mass 2 kg begins to move under the Sol.
action of a time dependent force given by

 
F  6t iˆ  6t 2 ˆj N . The power developed by the

force at the time t is given by:


(1) 6t4  9t5 W 
(2) 3t 3
 6t  W5

(3)  9t 5
 6t  W3

If A = 0 ; A  1
(4)  9t 3
 6t  W5

Ans. (4) A=1; A 0

Sol. 
F  6t iˆ  6t 2 ˆj N  B = 0 ; B 1


F  ma  6tiˆ  6t 2 ˆj  B=1; B0

a
F

 3tiˆ  3t2ˆj     
Y = A  B  A  B = 1  1 = 0
m
t 50. Consider two physical quantities A and B related
3t 2 ˆ 3 ˆ
v   adt  it j
2 B  x2
0
to each other as E  where E, x and t have
At

P  F.v  9t3  6t5 W 
dimensions of energy, length and time
49.
respectively. The dimension of AB is

(1) L2 M1T0

(2) L2 M1T1

(3) L2 M1T1

(4) L0 M1T1
The output of the given circuit diagram is Ans. (2)

Sol.  B  L2
(1) (2)
x2 L2 1
A  
2
tE TML T 2 MT 1

A  M1T
 AB   L2 M 1T1 
(3) (4)

Ans. (3)
 SECTION-B 53. The magnetic flux  (in weber) linked with a
51. In the following circuit, the battery has an emf of 2 closed circuit of resistance 8 Ω varies with time (in
2 seconds) as   5t2  36t  1 . The induced current
V and an internal resistance of  . The power
3 in the circuit at t = 2s is _______ A.
consumption in the entire circuit is ______ W. Ans. (2)
 d 
Sol.       10t  36
 dt 
at t  2,   16 V
 16
i  2A
R 8
54. Two blocks of mass 2 kg and 4 kg are connected
by a metal wire going over a smooth pulley as
shown in figure. The radius of wire is 4.0  105
m and Young's modulus of the metal is
Ans. (3) 2.0 1011 N / m2 . The longitudinal strain
4 1
Sol. R eq   developed in the wire is . The value of 
3 
V2 4 is____. [Use g  10 m / s2 )
P   3W
R eq 4 / 3

52. Light from a point source in air falls on a convex

curved surface of radius 20 cm and refractive index
1.5. If the source is located at 100 cm from the
convex surface, the image will be formed at____
cm from the object.
Ans. (12)
Ans. (200)  2m1m2  80
Sol. Sol. T g = N
 m1  m2  3
A  r2  16  1010 m2
 F T
Strain =  
AY AY
80 / 3 1
= 10 11

16  10  2  10 12
2 1 2  1   12
 
v u R 55. A body of mass 'm' is projected with a speed ‘u’
1.5 1 1.5  1 making an angle of 45° with the ground. The
 
v 100 20 angular momentum of the body about the point of
v  100 cm projection, at the highest point is expressed as
Distance from object 2 mu3
. The value of 'X' is_______.
= 100+100 Xg
= 200 cm Ans. (8)
Sol. 57. The distance between charges +q and –q is 2l and
0
between +2 q and -2 q is 4l . The electrostatic
ucos45 potential at point P at a distance r from centre O is
u  ql 
0
H   2   109 V , where the value of  is
45 r 
O
1
u 2 sin 2  ______. (Use  9  109 Nm2C 2 )
L  mu cos  40
2g

1
 mu 3  x 8
4 2g

56. Two circular coils P and Q of 100 turns each have

same radius of  cm. The currents in P and R are

1 A and 2 A respectively. P and Q are placed with

Ans. (27)
their planes mutually perpendicular with their Sol.
centers coincide. The resultant magnetic field
P1  2q
induction at the center of the coils is x mT ,
P2  8q
where x =_________.
P
[Use 0  4  107 TmA 1 ]

Ans. (20) r
0
Sol. 120 60 0

Pnet  6q
K p.r 9  10  6q 
9

V
r3

r2

cos 1200 
q 
=   27   2   109 Nm2c 2
r 
0 Ni1 0  1  100    27
BP    2  10 3 T
2r 2 58. Two identical spheres each of mass 2 kg and radius
50 cm are fixed at the ends of a light rod so that the
0 Ni 2 0  2  100 separation between the centers is 150 cm. Then,
BQ    4  10 3 T moment of inertia of the system about an axis
2r 2
perpendicular to the rod and passing through its
x
Bnet  B2P  BQ2 middle point is kg m2 , where the value of x is
20
____.
= 20 mT Ans. (53)
x = 20
Sol. 2k . k 5k
Sol. k eq  k
2 kg 2 kg 3k 3
I
m k eq
Angular frequency of oscillation   
c cm
50 50
m
5k
150 cm   
3m
75 cm
2 3m
2  Period of oscillation      2
I   mR2  md 2   2  5k
5 
12m
2 1 
2
 3   53
2 
I  2  2     2      kg  m2 5k
5 2
  4
    20

60. A nucleus has mass number A1 and volume V1 .
X = 53
Another nucleus has mass number A2 and volume
59. The time period of simple harmonic motion of
V2 . If relation between mass number is A2  4 A1 ,
M
mass M in the given figure is  , where the
5K V2
then  ________.
value of  is _______. V1

Ans. (4)
Sol. For a nucleus
4
Volume: V  R3
3
R  R0  A 
1/3

4
V R30 A
3
V2 A 2
  4
Ans. (12) V1 A1
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 62. A sample of CaCO3 and MgCO3 weighed 2.21 g
is ignited to constant weight of 1.152 g. The
61. Match List I with List II
composition of mixture is :
LIST – I LIST – II (Given molar mass in g mol1
CaCO3 :100, MgCO3 :84 )
(Complex ion) (Electronic
Configuration (1) 1.187 g CaCO3  1.023 g MgCO3

A. Cr  H 2 O 6 
3 I. t 2g 2 eg0 (2) 1.023 g CaCO3  1.023 g MgCO3
 
(3) 1.187 g CaCO3  1.187 g MgCO3

B. 3 II. (4) 1.023 g CaCO3  1.187 g MgCO3

 Fe  H 2 O 6  t 2g3 eg 0
 
Ans. (1)

Sol:- CaCO3 s  

CaO s   CO2  g 
C.  Ni  H 2 O 6 
2 III. t 2g3 eg 2
  MgCO3 s  

MgO s   CO2  g 

Let the weight of CaCO3 be x gm

D. 3 IV.
 V  H 2 O 6  t 2g 6 eg 2
 weight of MgCO3   2.21  x  gm
 

Moles of CaCO3 decomposed = moles of CaO

Choose the correct answer from the options given
below : formed

(1) A-III, B-II, C-IV, D-I x

 moles of CaO formed
100
(2) A-IV, B-I, C-II, D-III
x
 weight of CaO formed   56
(3) A-IV, B-III, C-I, D-II 100
(4) A-II, B-III, C-IV, D-I Moles of MgCO3 decomposed = moles of MgO
formed
Ans. (4)
3
 2.21  x  
Sol:- Cr  H 2 O 6  Contains Cr 3 :  Ar  3d 3 : t 32g eog moles of MgO formed
84

3 2.21  x
 Fe  H 2 O 6  Contains Fe3 :  Ar  3d 5 : t 32g eg2  weight of MgO formed   40
  84
2 2.21  x x
 Ni  H 2 O 6 
  Contains Ni 2 :  Ar  3d8 : t 62g eg2   40   56  1.152
84 100
3  x  1.1886 g  weight of CaCO3
 V  H 2 O 6 
  Contains V 3 :  Ar  3d 2 : t 22g ego
& weight of MgCO3  1.0214 g
63. Identify A and B in the following reaction sequence. Sol:-
Br
S 1 : S 8  12 OH  4S 2   2S 2 O 32  6H 2 O
Conc. HNO 3 (i) NaOH
A B S2 : ClO4 cannot undergo disproportionation
(ii) HCl
reaction as chlorine is present in it’s highest
Br OH
oxidation state.
NO2 NO2 NO2 NO2
(1) A= , B= 65. Identify major product ‘P’ formed in the following
reaction.
NO2 NO2
Br Br O
OH Anhydrous
C ‘P’
(2) A= , B= Cl AlCl3
+ (Major Product)

NO2 NO2
Br Br O
NO2 OH
(1) O C
(3) A= , B=
Cl
NO2 OH
NO2 NO2
(2) COCH 3
(4) A= , B=
OH
Ans. (1)
Br Br OH
NO2 NO2
Sol:- Con. HNO3 (i)NaOH
NO2 NO2 O
NO2 NO2
(3) C
H
(Acid base
NaOH reaction)

OH O Na
+ O
NO2 NO2 NO2 NO2
(ii) HCl
(4) C
NO2 NO2
64. Given below are two statements :
Statement I: S8 solid undergoes
disproportionation reaction under alkaline Ans. (4)
2
conditions to form S2 and S2 O3
Statement II: ClO4 can undergo ..
O
O
O
..
..

disproportionation reaction under acidic condition. Sol:- C

C
C
In the light of the above statements, choose the Cl
+ AlCl3 + AlCl 4
most appropriate answer from the options given O
Electrophile
below : C O
(1) Statement I is correct but statement II is +
C
incorrect. H

(2) Statement I is incorrect but statement II is

correct AlCl4
(3) Both statement I and statement II are incorrect O
(4) Both statement I and statement II are correct C
Ans. (1)
66. Major product of the following reaction is – Br
1
Sol:- 2
3
4 5
_
D Cl
? Br

CH3 2, 3-dibromo -1-phenylpentane

68. Select the option with correct property -
(1)  Ni  CO 4  and  NiCl4 
2
both diamagnetic
(1) Cl D (2) H D
(2)  Ni  CO 4  and  NiCl4 
2
both paramagnetic

(3)  NiCl4  diamagnetic,  Ni  CO 4 

H CH3 CH3 2
Cl
paramagnetic
(4)  Ni  CO 4  diamagnetic,  NiCl4 
Cl 2
(3) D CH 3 (4) D
paramagnetic
H Cl H CH 3 Ans. (4)
Sol:-  Ni  CO 4   diamagnetic, sp3 hybridisation,
Ans. (3 or 4)
number of unpaired electrons = 0

 NiCl4 2 ,  paramagnetic, sp3 hybridisation,

Sol:- D D Cl D H3C D Cl
+

CH3
H
CH3
H Cl H H 3C number of unpaired electrons = 2
(±) (±) 69. The azo-dye (Y) formed in the following reactions
is Sulphanilic acid  NaNO2  CH3COOH  X
67. Identify structure of 2,3-dibromo-1-phenylpentane.

Br Br X+ Y

1. NH 2
HSO 3 N=N
Br 1.
N=N SO 3H

2. HO3S N=N NH 2
Br
2.
Br HO3S N=N

HSO 3 N=N
3.
Br 3.
NH 2
Br
HSO 3 N=N NH 2
4.
4.
Br

Ans. (3) Ans. (4)

 
O NH 2 NH3 HSO 4 NH2
||
Sol:- NH2 N  N  O  C  CH3 Conc. H 2SO 4 453-473K Lassaigne’s test 2
Fe SCN 
Sol:-
Blood red colour
 NaNO2  CH3COOH SO3H

C
71. A g  B g    g  The correct relationship
SO3 H SO3 H 2
X 
O
between KP ,  and equilibrium pressure P is
||
N  N  O  C  CH3 1 1
 2 P 2
(1) K P 
2  
1
+ 2

3 1
 2 P 2
SO3 H NH2
(2) K P 
 2    2 1   
1

1 3
 2 P 2
(3) K P 
2  
3
HO3S NN NH2 2

1 1
Y   2 P 2
Red azo-dye
(4) K P 
2  
3
2

Ans. (2)
This is known as Griess-Ilosvay test.
C
Sol:- A g  
 B g   g 
2
70. Given below are two statements : 
t = teq 1   
2
Statement I: Aniline reacts with con. H2SO4 
followed by heating at 453-473 K gives p- PB 

. P, PA 
1 
. P , PC  2 .P
     
aminobenzene sulphonic acid, which gives blood 1   1   1  
 2  2  2
red colour in the 'Lassaigne's test'. 1
P .P 2
KP  B C
Statement II: In Friedel - Craft's alkylation and PA
acylation reactions, aniline forms salt with the 3 1

AlCl3 catalyst. Due to this, nitrogen of aniline 

2 P2
1
aquires a positive charge and acts as deactivating 1    2    2
group. 72. Choose the correct statements from the following
A. All group 16 elements form oxides of general
In the light of the above statements, choose the formula EO2 and EO3 where E = S, Se, Te and
correct answer from the options given below : Po. Both the types of oxides are acidic in nature.
B. TeO2 is an oxidising agent while SO2 is
1. Statement I is false but statement II is true reducing in nature.
C. The reducing property decreases from H 2S to
2. Both statement I and statement II are false H2Te down the group.
D. The ozone molecule contains five lone pairs of
3. Statement I is true but statement II is false electrons.
Choose the correct answer from the options given
4. Both statement I and statement II are true below:
1. A and D only 2. B and C only
Ans. (4) 3. C and D only 4. A and B only
Ans. (4)
Sol:- (A) All group 16 elements form oxides of the Sol:- Steam distillation technique is applied to separate
EO2 and EO3 type where E  S, Se, Te or Po . substances which are steam volatile and are
immiscible with water.
(B) SO2 is reducing while TeO2 is an oxidising
76. Given below are two statements :
agent.
(C) The reducing property increases from H 2S to Statement I: Group 13 trivalent halides get easily
hydrolyzed by water due to their covalent nature.
H2Te down the group.
Statement II: AlCl3 upon hydrolysis in acidified
.. 3
O ..
have six lone pairs aqueous solution forms octahedral  Al  H 2 O 6 
O
..

(D) O ..
..

..
ion.
73. Identify the name reaction.
CHO In the light of the above statements, choose the
CO, HCl correct answer from the options given below :
Anhyd. AlCl3/CuCl 1. Statement I is true but statement II is false
(1) Stephen reaction
2. Statement I is false but statement II is true
(2) Etard reaction
(3) Gatterman-koch reaction 3. Both statement I and statement II are false
(4) Rosenmund reduction 4. Both statement I and statement II are true
Ans. (3) Ans. (4)
Sol:-
CHO Sol:- In trivalent state most of the compounds being
CO, HCl covalent are hydrolysed in water. Trichlorides on

Anhyd. AlCl3/CuCl hydrolysis in water form tetrahedral  M  OH 4 
Gatterman-Koch reaction species, the hybridisation state of element M is
74. Which of the following is least ionic ? sp3.
(1) BaCl2 (2) AgCl In case of aluminium, acidified aqueous solution
(3) KCl (4) CoCl2 3
forms octahedral  Al  H 2 O 6  ion.
Ans. (2)
77. The four quantum numbers for the electron in the
Sol:- AgCl  CoCl2  BaCl2  KCl (ionic character)
outer most orbital of potassium (atomic no. 19) are
Reason : Ag  has pseudo inert gas configuration. 1
(1) n  4, l = 2, m  1, s  
75. The fragrance of flowers is due to the presence of 2
some steam volatile organic compounds called 1
(2) n  4, l = 0, m  0 , s  
essential oils. These are generally insoluble in 2
water at room temperature but are miscible with 1
(3) n  3, l = 0, m  1 , s  
water vapour in vapour phase. A suitable method 2
for the extraction of these oils from the flowers is - (4) n  2 , l = 0, m  0 , s  
1
1. crystallisation 2
2. distillation under reduced pressure Ans. (2)
3. distillation Sol:- 19 K 1s2 , 2s2 , 2p6 , 3s2 , 3p6 , 4s1 .
4. steam distillation Outermost orbital of potassium is 4s orbital
Ans. (4) 1
n  4, l  0, ml  0, s   .
2
78. Choose the correct statements from the following Sol:- CH3 shows M and  I .

A. Mn 2O7 is an oil at room temperature Cl shows M and  I but inductive effect
dominates.
B. V2O4 reacts with acid to give VO22 NO2 shows M and  I .

C. CrO is a basic oxide Electrophilic substitution 

1
M and  I
D. V2 O5 does not react with acid
  M and  I
Choose the correct answer from the options given
Hence, order is B  A  C  D .
below :

1. A, B and D only
80. Consider the following elements.
2. A and C only A'B' Period
Group
3. A, B and C only C'D'

4. B and C only Which of the following is/are true about

A', B', C' and D' ?
Ans. (2)
A. Order of atomic radii: B'  A'  D'  C'
Sol:- (A) Mn 2O7 is green oil at room temperature. B. Order of metallic character : B'  A'  D'  C'
C. Size of the element : D'  C'  B'  A'
(B) V2O4 dissolve in acids to give VO2+ salts.
D. Order of ionic radii : B'  A '  D '  C'
(C) CrO is basic oxide
Choose the correct answer from the options given
(D) V2 O5 is amphoteric it reacts with acid as well below :
as base. 1. A only 2. A, B and D only
3. A and B only 4. B, C and D only
79. The correct order of reactivity in electrophilic
substitution reaction of the following compounds Ans. (2)
Sol:- In general along the period from left to right, size
is : decreases and metallic character decrease.
CH3 Cl NO2 In general down the group, size increases and
metallic character increases.
B'  A'  size  C'  A'  size 

A B C D D'  C'  size  D'  B'  size 

1. B  C  A  D B'  A'  metallic character 

2. D  C  B  A D'  C'  metallic character 

3. A  B  C  D B'  A '  size 

4. B  A  C  D D'  C'  size 

Ans. (4)  C statement is incorrect.

 SECTION-B 84. Number of isomeric products formed by mono-
chlorination of 2-methylbutane in presence of
81. A diatomic molecule has a dipole moment of
sunlight is _______.
1.2 D. If the bond distance is 1Å , then fractional
charge on each atom is ______ 101 esu . Ans. (6)

(Given 1 D  1018 esu cm) Sol:- Cl2/h

* +
Ans. (0) Cl   Cl

Sol:-   1.2 D  q  d * + Cl
 1.2 1010 esu Å  q 1Å Cl
 
q  1.2 1010 esu

82. r  k  A  for a reaction, 50% of A is decomposed  Number of isomeric products = 6

in 120 minutes. The time taken for 90%
decomposition of A is ______ minutes. 85. Number of moles of H  ions required by 1 mole

of MnO 4 to oxidise oxalate ion to CO2 is ____.
Ans. (399)
Sol:- r  k  A  Ans. (8)

So, order of reaction = 1 Sol:-

t1/2  120 min 2MnO4  5C2O24  16H 
2Mn 2  10CO2  8H2O
 Number of moles of H  ions required by 1
For 90% completion of reaction 
mole of MnO 4 to oxidise oxalate ion to CO2 is 8
2.303  a 
k log  
t ax 86. In the reaction of potassium dichromate, potassium
chloride and sulfuric acid (conc.), the oxidation
0.693 2.303 100 state of the chromium in the product is
  log
t1/2 t 10 (+)_______.
 t  399 min. Ans. (6)
83. A compound (x) with molar mass 108 g mol1 Sol:- K 2Cr2O7  s   4KCl  s   6H 2SO4  conc.
undergoes acetylation to give product with molar
mass 192 g mol1 . The number of amino groups in  2CrO2Cl2  g   6KHSO4 + 3H2O
the compound (x) is ______.
This reaction is called chromyl chloride test.
Ans. (2)
Here oxidation state of Cr is +6.
O O
Sol:- R  NH2  CH3  C  Cl 
 R  NH  C  CH3 87. The molarity of 1L orthophosphoric acid  H3 PO 4 
having 70% purity by weight (specific gravity
Gain in molecular weight after acylation with one
1.54 g cm3 ) is ______M.
NH2 group is 42.
Total increase in molecular weight = 84 (Molar mass of H3PO4  98 g mol1 )

84 Ans. (11)
 Number of amino group in x  2
42
Sol:- Specific gravity (density) = 1.54 g/cc.
89. From the vitamins A, B1 , B6 , B12 , C, D, E and K,
Volume  1L  1000 ml
the number vitamins that can be stored in our body
Mass of solution  1.54 1000
is ______.
 1540 g
% purity of H2SO4 is 70% Ans. (5)
So weight of H3PO4  0.7 1540  1078 g Sol:- Vitamins A, D, E, K and B12 are stored in liver
1078 and adipose tissue.
Mole of H3PO4  = 11
98 90. If 5 moles of an ideal gas expands from 10 L to a
11 volume of 100 L at 300 K under isothermal and
Molarity   11
1L reversible condition then work, w, is x J. The
88. The values of conductivity of some materials at value of x is ______.
298.15 K in Sm1 are 2.1103 ,
(Given R  8.314 J K1mol1 )
1.0 1016 ,1.2 10, 3.91,1.5 102 ,
1107 ,1.0 103 . The number of conductors Ans. (28721)
among the materials is ______. Sol:- It is isothermal reversible expansion, so work done
Ans. (4) negative
Sol:-
Conductivity  S m -1  V 
W  2.303 nRT log  2 
2.1  103   V1 
1.2  10  conductors at 298.15K
3.91 
1  103   100 
 2.303  5  8.314  300 log  
1  1016 Insulator at 298.15 K  10 

1  107 
1.5  102 Semiconductor at 298.15 K  28720.713 J

Therefore number of conductors is 4.  28721J