AYJR 2024 (Advanced) - Paper 2 - Provisional Answer Keys
AYJR 2024 (Advanced) - Paper 2 - Provisional Answer Keys
Q1
PT2 nR
2 moles of a diatomic gas undergoes a thermodynamic process V
= constant. The molar heat capacity of the gas is 2
. Find n.
Q2
S is a stationary source of sound emitting waves of frequency 440 Hz. These waves are reflected by a stationary wall and
heard by observer O moving away with v = 10 m/s. Find beat frequency (in Hz ) heard by observer in the position
shown (due to superposition between reflected & direct waves) (Vsound = 330 m/s)
Q3
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Q4
Radiation from hydrogen gas excited to first excited state is used for illuminating certain photoelectric plate. When the
radiation from some unknown hydrogen like gas excited to the same level is used to expose the same plate, it is found
that the de-Broglie wavelength of the fastest photoelectron has decreased 2.3 times. It is given that the energy
corresponding to the longest wavelength of the Lyman series of the unknown gas is 3 times the ionization energy of
hydrogen gas (13.6eV). Find the work function of photoelectric plate in eV. (Take (2.3)2 = 5.25).
Q5
242
Two containers A and B are connected by a conducting solid cylindrical rod of length 7
cm and radius √8.3 cm.
Thermal conductivity of the rod is 693 watt/mole-K. The container A contains two mole of oxygen gas and the container
B contains four mole of helium gas. At time t = 0 temperature difference of the containers is 50∘ C, after what time (in
seconds) temperature difference between them will be 25∘ C. Transfer of heat takes place through the rod only. Neglect
22
radiation loss. Take R = 8.3 J/ mole −K, ln2 = 0.693 and π = 7
.
Q6
As shown in the figure below, consider a large parallel plate capacitor with uniform surface charges 2σ and −2σ on the
upper and the lower plates, respectively. These charges are moving with a constant speed V. The area of each plate is
given as S. Find the value of K such that magnetic field between the plates is B = K(μσV).
Q7
In free space on a circle with radius R0 , four point masses m are located at the vertices of the inscribed square, two of
them carry charge +q, and the other two charge −q. At the initial moment all these particles have same speed in
clockwise direction as shown. It is known that during the motion the minimum distance from any of the point masses to
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the centre O of the initial circle is R1 (R1 < R0 ). Consider that at any time, the charges are at the vertices of square
centered at point O. The action of gravitational forces can be neglected. Determine the speed (in m/s) of any particle at a
position having a distance R1 from the centre of the circle. Take m = 2√2 − 1gm, q = 1μC, R0 = 2R1 = 1 m.
Q8
Inside a uniform sphere of mass M and radius R, a cavity of radius R/3 is made in the sphere as shown.
(4) Escape velocity is defined for earth and particle system only.
Q9
A thin uniform rod AB of mass m = 1 kg and length ℓ = 1 m is hinged at end ' A '. The rod makes an angle θ = 53∘
with the vertical axis and it is rotating with a constant angular velocity ' ω ' about the vertical axis passing through end '
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(3) The net hinge reaction on the rod at end ' A ' is 10√2 N.
(4) The net hinge reaction on the rod at end ' A ' is 10 N.
Q10
Which of the following statements with regards to the Single Slit Fraunhoffer Diffraction and Polarisation of Light
is(are) true?
(1) All the Diffraction Maximas are equidistant from each other.
(2) With regards to Polarisation, the Difference between the transmitted light Intensity and original light intensity is
proportional to the square of the polarisation angle, for very small values of the Polarization angle. (Assume that
Transmission has occurred only once)
(3) The Graph of the Intensity vs angle of diffraction is not Monotonically Decreasing for Positive values of the angle of
Diffraction.
(4) For very small Brewster's angle, the Relative refractive index between two media is proportional to the Brewster's
angle.
Q11
Consider the system of a rough cylinder and a block on an inclined plane with an external force P along the incline in an
impending motion up the incline. Static coefficient between cylinder and plane as well as the block and the plane is μ.
Assume impending slip at A and C. What is the limiting value of the static coefficient μs at B such that the impending
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2μ
(1) μs = 6μ2 +7μ+3
Q12
A bowl of water is placed on one of the plates of a beam scale, which is balanced. One of our fingers is immersed into
the water, such that the bowl is not touched. Will the scale remain balanced or not, if (i) not a drop of water flows out of
the bowl; (ii) the bowl was full to the brim, and the water flows off the plate of the scale?
Q13
Two conducting spheres A and B of radius R and 2R are connected by a thin conducting wire. The conducting sphere '
B ' is surrounded by a grounded thin concentric conducting shell ' C ' with radius (
101
50
R). The connecting wire between
the spheres A and B is not touching the thin shell ' C '. If conducting sphere ' B ' is given a charge ' Q ' and the
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separation between the spheres A and B is much larger than their radii. Then choose the correct option(s).
Q
(1) The charge appearing on the conducting sphere ' A ' is 201
.
Q
(2) The charge appearing on the conducting sphere ' A ' is 101
.
100Q
(3) The charge appearing on the conducting sphere ' B ' is 101
.
200Q
(4) The charge appearing on the conducting sphere ' B ' is 201
.
Q14
A light stick of length ℓ rests with its one end against the smooth wall and other end against the smooth horizontal floor
as shown in the figure. The bug starts at rest from point B and moves such that the stick always remains at rest, ap is the
magnitude of acceleration of bug of mass m, which depends upon its distance of x from the top end of the stick. Choose
the CORRECT option(s) :
(1 − )
g x
(1) ap = sin θ ℓ
(1 − )
g x
(2) aP = cos θ ℓ
(3) The time taken by the bug to reach the bottom of the stick having started at the top end from rest is π
2
√ ℓ sin
3g
θ
.
(4) The time taken by the bug to reach the bottom of the stick having started at the top end from rest is π
2
√ ℓ sin
g .
θ
Q15
Question Stem
If a point P moves in plane along a given curve y = f(x), the angular velocity of point P about a fixed point O in the
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plane is the rate of change of the angle that OP line makes with a fixed direction [OX− line ] in the plane
Let OP = r at t = t sec
P M = rdθ = P Q sin ϕ, But if dθ is very small then. P Q ≅P R = ds (arc length)
⇒ rdθ = ds sin ϕ
dθ 1 ds v sin ϕ Magnitude of component of velocity of point perpendicular to radius vector
⇒ = sin ϕ = =
dt r dt r Magnitude of radius vector
dθ vp
⇒ =
dt r2
Question
If two particles A and B are having speed 10√3 m/s and 20 m/s at a particular instant as shown in the figure, then the
angular velocity of A with respect to B at the same instant is mark absolute value in rad/s.
Q16
Question Stem
If a point P moves in plane along a given curve y = f(x), the angular velocity of point P about a fixed point O in the
plane is the rate of change of the angle that OP line makes with a fixed direction [OX− line ] in the plane
Let OP = r at t = t sec
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⇒ rdθ = ds sin ϕ
dθ 1 ds v sin ϕ Magnitude of component of velocity of point perpendicular to radius vector
⇒ = sin ϕ = =
dt r dt r Magnitude of radius vector
dθ vp
⇒ =
dt r2
Question
If point P moves on parabolic path y 2 = 4(x + 1), where x and y are in meter with constant speed 2 m/s. Its angular
velocity (in rad/sec) about focus at an instant when it makes angle 60∘ at focus with x-axis is [all angles are measured in
Q17
Question Stem
If two deuterium nuclei get close enough together, the attraction of the strong nuclear force will fuse them to make as
isotope of helium. The process will release a vast amount of energy. The range of nuclear force is 10−15 m. This is the
principle behind the nuclear fusion reactor. The deuterium nuclei moves so fast hence it is not possible to contain them
Question
The strength of magnetic field (in mT) required to make deuterium nuclei moving with this speed, to be confined in a
Q18
Question Stem
If two deuterium nuclei get close enough together, the attraction of the strong nuclear force will fuse them to make as
isotope of helium. The process will release a vast amount of energy. The range of nuclear force is 10−15 m. This is the
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principle behind the nuclear fusion reactor. The deuterium nuclei moves so fast hence it is not possible to contain them
Question
The following is the process of formation of the Helium nuclei from the nuclear fusion of deuterium nuclei (Given
1 amu = 931.5Mev/c2 )
2
1H + 21 H → 31 H + 11 H + ΔE1
3
1
H + 21 H → 42 He + 10 n + ΔE2
[m (21 H) = 2.014102 a.m.u, m (31 H) = 3.016049 a.m.u, m (42 He) = 4.002603 a.m.u,
m (10 n) = 1.008665 a.m.u, m (11 H) = 1.007825 a.m.u] then ΔE1 + ΔE2 is - (in MeV round off to nearest integer).
Q19
A solution prepared by mixing 10 mL of a 0.10M solution of the R enantiomer of a compound and 30 mL of a 0.10M
solution of the S enantiomer was found to have an observed specific rotation of +4.8. What is the absolute value of
Q20
A solution is created by mixing equal volumes of 0.1M Na2 SO4 and 0.1M BaCl2 . The resultant solution volume is 1
litre, its temperature rises to ' T ' = 50∘ C and it also contains a precipitate mass. Through highly accurate measurements,
total ionic concentration is found to be 0.20005 M (excluding H+ and OH− ions). Then report the number of correct
(A) Final solution contains equal moles of all ions (excluding H+ and OH− ions)
−
(B) Final solution contains equal moles of Na+ and Cl ions.
2−
(C) Final solution contains equal moles of Ba+2 and SO4 ions.
Q21
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A quantity of 25 mL of solution containing both Fe2+ and Fe3+ ions is titrated with 25 mL of 0.0200 M KMnO4 and
dilute H2 SO4 . As a result all the Fe2+ ions are oxidised to Fe3+ ions. Next 25 mL of the original solution is treated with
Zn metal. Finally, the solution requires 40 mL of the same KMnO4 solution for oxidation to Fe3+ .
MnO−
4 + 5Fe
2+
+ 8H+ ⟶ Mn2+ + 5Fe3+ + 4H2 O
Molar concentration of Fe3+ in original solution is
Q22
How many of the following polymers contain atoms of halogen family in their structures?
Q23
Degree of Unsaturation of C ?
Q24
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Let, the number of amino acids which exists as cation at pH = 7 be ' x ' and the number of amino acids which exists as
x
anion at pH = 7 be ' y ', then find the value of y
.
Q25
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Q26
Radionucleide ' P ' decays into ' Q ' and ' Q ' decays into ' R ' as :
t1/2 =1000hrs t1/2 =10 min
P −−−−−−−→ Q −−−−−−−→ R
K1 K2
[NA = 6 × 1023 ]
(1) NQ = 6 × 1023
(2) NQ = 1020
(3) NR = 6 × 1023
(4) NR = 1023
Q27
The radial distribution functions [P(r)] is used to determine the most probable radius, which is used to find the electron
dP (r)
in a given orbital dr
for 1 s-orbital of hydrogen like atom having atomic number Z, is
(2r − ) e−2Zr/a0
dP(r) 16πZ 3
2Zr2
dr
= a30 a0
Q28
Compound (X), molecular formula C8 H8 O, is water insoluble and gives yellow ppt. with I2 /NaOH. It reacts with
H2 N − OH in the presence of NH4 Cl/NH4 OH to give two geometrical isomers, which can go for rearrangement with
acids. Compound (X) can be,
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(1)
(2)
(3)
(4)
Q29
(1)
(2)
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(3)
(4)
Q30
(1) 0.34 V
(2) 0.76 V
(3) 0.26 V
(4) 0.14 V
Q31
A crystalline cubic solid is made up of atoms A, B, C and D such that atoms ' A ' are present at each of the corner, ' B '
atoms at each of face centre, ' C ' atoms in each of octahedral void and ' D ' atoms in each of the tetrahedral voids of the
unit cell. Now choose the correct statement(s) regarding the above solid.
(Atoms from the lattice sites of the unit cell have to removed completely and not partially)
(1) If all atoms lying along or inside one of the octant are removed, then the formula of resulting solid would be
be AB2 C3 D8 .
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(3) If all atoms lying along one of the C3 - axis of symmetry are removed, then the formula of resulting solid would be
AB4 C4 D8 .
(4) If all the atoms lying along one of the C2 - axis of symmetry are removed, then the formula of resulting solid would
be A2 B6 C5 D16 .
Q32
[X] + H2 O2 + H+ ⟶ [Y] + H2 O
(Blue colour)
Q33
Question Stem
Question
Q34
Question Stem
Question
Molecular mass of B is m.
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Q35
Question Stem
Addition of non-volatile solute always lowers the vapour pressure of solvent, therefore, it will be in equilibrium with
solid phase at a lower pressure and hence at a lower temperature, the difference between the freezing points of the pure
solvent and its solution is called depression of freezing point. The depression in freezing point when 1 mol of solute is
dissolved in 1000gm of solvent is called molal freezing point depression constant (Kf ). The value of Kf for H2 O is
1.86 K mol−1 kg. To understand this, a solution of 25%(w/w)MgCl2 containing impurity of the chloride of a trivalent
metal M having atomic mass 43.5gm (24% by weight of MgCl2 ) has been prepared. In this solution MgCl2 is
completely dissociated. On the other hand only 50% dissociation of MCl3 takes place and molality is approximately
equal to molarity.
Question
Depression in freezing point of the solution is (mark answer to two decimal places)
Q36
Question Stem
Addition of non-volatile solute always lowers the vapour pressure of solvent, therefore, it will be in equilibrium with
solid phase at a lower pressure and hence at a lower temperature, the difference between the freezing points of the pure
solvent and its solution is called depression of freezing point. The depression in freezing point when 1 mol of solute is
dissolved in 1000gm of solvent is called molal freezing point depression constant (Kf ). The value of Kf for H2 O is
1.86 K mol−1 kg. To understand this, a solution of 25%(w/w)MgCl2 containing impurity of the chloride of a trivalent
metal M having atomic mass 43.5gm (24% by weight of MgCl2 ) has been prepared. In this solution MgCl2 is
completely dissociated. On the other hand only 50% dissociation of MCl3 takes place and molality is approximately
equal to molarity.
Question
Q37
20 40 γ−α
Let (1 + x + x2 ) = ∑k=0 ak xk . If αa11 = βa10 + γa9 , where α, β, γ ∈ N , then the value of β
is
Q38
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Q39
|x−4|
Consider, f(x) = |x|+1
. If sum of all distinct possible values of sin−1 (sin[f(x)]) is aπ + b, then find the absolute value
of (a + b).
[Note: [z] denotes greatest integer function less than or equal to z.]
Q40
1 1 1 x(ln x)2
Let Sn = 1n
+ 3n
+ 5n
+ … . ∞ and ∫01 1−x4
dx = mS3 , then value of m is
Q41
Let A be a 2 × 2 matrix, and suppose that A2 = 0. Then for each scalar c, det(cI − A) = cx . Find x.
Q42
Let A1 , A2 , A3 , A4 be the areas of the triangular faces of a tetrahedron, and h1 , h2 , h3 , h4 be the corresponding altitude
of the tetrahedron. If volume of tetrahedron is 1/6 cubic units, then find the minimum value of
Q43
6 6
Six points (xi , yi ) , i = 1, 2, … . .6 are taken on the circle x2 + y 2 = 4 such that ∑i=1 xi = 8 and ∑i=1 yi = 4. The line
segment joining orthocenter of a triangle made by any three points and the centroid of the triangle made by other three
points passes through a fixed point (h, k). Find the value of h + k.
Q44
(3) f ′ (a)(f(1) + f(0)) + f ′′ (b) (f ′ (0) + f ′ (1)) > 0 for some a, b ∈ (0, 1)
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(4) If f is increasing with upward concavity then, ∃α ∈ (0, ∞) for which f(x) > 0
Q45
P (x) is a least degree polynomial such that (P (x) − 1) is divisible by (x − 1)2 & (P (x) − 3) is divisible by (x + 1)2 ,
then
Q46
⎡x 0 0⎤
Let A = ⎢ 0 0 ⎥ ; x, y, z ∈ I with the condition that det(adj(adj A)) = 212 × 38 × 54 , S1 is set of all the matrices
⎣0 z⎦
y
0
A, S2 is set of all such matrices A where trace of A is divisible by 2, and x, y, z ∈ N and S3 is set of all such matrices A
, where ( trace A3 ) − 3 det A = 0, and x, y, z ∈ N . Let the number of elements in set S1 , S2 and S3 be 2α, β and γ
respectively.
α
(1)
β+γ
< 10
α
(2)
β−γ
> 15
α
(3)
β+γ
>9
α
(4)
β−γ
< 14
Q47
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Q48
π/2
If z is a unimodular complex number such that Re(z − 1) + Re(z 2 ) = ∫0 sin x ln | sin x − cos x|dx, then z can
satisfy
(1) z + z̄ = −2
(2) z + z̄ = 1
π
(3) arg(z) = 3
(4) arg z = π
Q49
Let a ray of light through P (10, 25, 35) is incident at point Q on the plane x + y + z = 100 and passes through the point
(1) coordinates of foot of perpendicular from P on the given plane is (20, 45, 35)
x−10 y−25 z−35
(2) equation of incident ray is 2
= 1 = 3
x−40 y−60 z−60
(3) equation of reflected ray is 2 = 3 = 1
Q50
(3) P (0) = 1
(4) P (x) has exactly two local minima at x1 and x2 such that |x1 − x2 | = 2.
8 √2
The line y = 1 touches the curve at a certain point Q and the enclosed area between the line and the curve is 15
. Let
P (x)−g(x)−g(−x)
g(x) = Ax2 + Bx + C(A ≠ 0) such that limx→0 x2
is finite and is equal to the slope of the tangent of g(x)
1
(1) the value of A is − 2
1
(2) the value of B + C is − 2
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Q51
Question Stem
∞
It is given Is = ∫0 e−t ⋅ ts−1 dt, (s > 0) and Ip ⋅ Iq = π
sin(pπ)
(where 0 < p ≤ q < 1 & p + q = 1).
Question
10 )
i
Q52
Question Stem
∞
It is given Is = ∫0 e−t ⋅ ts−1 dt, (s > 0) and Ip ⋅ Iq = π
sin(pπ)
(where 0 < p ≤ q < 1 & p + q = 1).
Question
∞ ∞
A = ∫0 x2 e−x dx and B = ∫0 e−x dx. If the value of AB is k1 , then [k] is
4 4
Q53
Question Stem
Using three basic colours (Red, Blue, Green) different colour are made by mixing these two or more colours in equal
proportion. The n vertical stripes are painted by all colours available, such that no two consecutive stripes have same
colour.
Question
For n = 13, the number of ways of painting these stripes such that only alternate stripes are painted by a basic colour is
Q54
Question Stem
Using three basic colours (Red, Blue, Green) different colour are made by mixing these two or more colours in equal
proportion. The n vertical stripes are painted by all colours available, such that no two consecutive stripes have same
colour.
Question
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The number of ways of painting these stripes so that no two consecutive stripes have any basic color common is denoted
by tn . If t2025 − K. t2024 = M. t2023 , where K and M are integers. Find the value of K + M .
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Answer Key
Q9 (1) (3) Q10 (2) (3) (4) Q11 (1) (4) Q12 (2) (4)
Q13 (1) (4) Q14 (1) (4) Q15 (1) Q16 (0.25)
Q25 (1.25) Q26 (2) (3) Q27 (1) (2) (3) (4) Q28 (1) (4)
Q29 (1) (2) (3) (4) Q30 (3) Q31 (2) (3) (4) Q32 (1) (3) (4)
Q45 (2) (4) Q46 (3) (4) Q47 (2) (3) Q48 (1) (2) (3) (4)
Q49 (2) (3) (4) Q50 (1) (2) (4) Q51 (25) Q52 (3)
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