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10-05-2024 - SR - Super60 - Elite, Target & LIIT-BTs - EAPCET - EGT-16 - KEY & SOL'S

This document contains a key and solutions for a mathematics exam. It provides the answers to 160 multiple choice questions across mathematics, physics, and chemistry sections. Formulas and working steps are included for several questions.
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0% found this document useful (0 votes)
33 views12 pages

10-05-2024 - SR - Super60 - Elite, Target & LIIT-BTs - EAPCET - EGT-16 - KEY & SOL'S

This document contains a key and solutions for a mathematics exam. It provides the answers to 160 multiple choice questions across mathematics, physics, and chemistry sections. Formulas and working steps are included for several questions.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.

Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S

Sri Chaitanya IIT Academy.,India.


 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite,Target&LIIT-BTs EAPCET Date: 10-05-2024
Time: 09 A.M TO 12 NOON GTE-16 Max. Marks: 160
KEY SHEET
MATHEMATICS

1) 4 2) 2 3) 1 4) 1 5) 1 6) 3 7) 3 8) 4 9) 4 10) 3

11) 1 12) 3 13) 3 14) 2 15) 2 16) 3 17) 2 18) 1 19) 3 20) 1

21) 2 22) 3 23) 2 24) 3 25) 2 26) 2 27) 3 28) 1 29) 1 30) 1

31) 3 32) 2 33) 1 34) 4 35) 2 36) 3 37) 4 38) 4 39) 3 40) 4

41) 4 42) 2 43) 3 44) 4 45) 1 46) 1 47) 3 48) 3 49) 1 50) 2

51) 3 52) 4 53) 2 54) 1 55) 1 56) 1 57) 4 58) 3 59) 2 60) 1

61) 1 62) 3 63) 2 64) 4 65) 4 66) 3 67) 2 68) 2 69) 1 70) 4

71) 2 72) 3 73) 4 74) 1 75) 2 76) 4 77) 2 78) 1 79) 2 80) 3

PHYSICS
81) 1 82) 1 83) 4 84) 2 85) 4 86) 3 87) 1 88) 1 89) 2 90) 3

91) 1 92) 1 93) 1 94) 4 95) 3 96) 1 97) 3 98) 1 99) 2 100) 1

101) 2 102) 3 103) 3 104) 2 105) 1 106) 1 107) 3 108) 1 109) 2 110) 3

111) 4 112) 2 113) 1 114) 2 115) 3 116) 3 117) 4 118) 1 119) 3 120) 1
CHEMISTRY
121) 3 122) 4 123) 3 124) 4 125) 3 126) 2 127) 1 128) 4 129) 2 130) 4

131) 4 132) 1 133) 4 134) 1 135) 3 136) 3 137) 2 138) 2 139) 2 140) 3

141) 1 142) 2 143) 1 144) 1 145) 4 146) 4 147) 2 148) 1 149) 4 150) 4

151) 1 152) 4 153) 3 154) 2 155) 1 156) 3 157) 4 158) 3 159) 1 160) 4

Sec: Sr.Super60_Elite,Target&LIIT-BTs Page 1


SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
SOLUTIONS 3 5

56
MATHEMATICS  4 2 
3 5 33
1 .
1. x  1  x 2  0  x  1  x2  0 4 12

x2  1  x2 1  x2  0 6. tan 3  period is
3
1
x2  x2  1  0
2 2  k  2    k  2 2  4  k  3
7. sin x 
1 2
x2   0  x  1 x  1  0
2 sin 2 x  k  3  2sin 2 x  1
1
x2  0 1  x  1  0  k  3  1  3  k  2
2
1
 1  1 8. sin 1  cos 1 x  sin 1 1
 x   x    0 5
 2  2
 1
1 1  cos 1 x   sin 1
x or x   Req Domain is 2 5
2 2
1
 1   cos 1 x  cos 1
x ,1 5
 2 
1
x x
e 5
2. y  y. 1   x   e  x  0
1   x  1  1  sin 2  
9. log    log  1  cos    
  log  cot 
 y  0 if 1   x   0 and y  0 is 

sin  

 sin    2

1   x  0 1
4. .b2c 2 sin 2 A
16. 2
10.  4  sin 2 A
 y  R  0 2 2
4b c 2 2
b c
5 k2 k 1 2
   22.5  s s  c   s  s  a   3b
3.  11. a.   c 
4k 2  ab   bc  2
k 1
s 3b
 sin 9o cos9o   sin 27o cos 27 o    s  c  s  a    2s  3b
4.      b 2
 cos9o sin 9o   cos 27o sin 27o 
     a  c  2b
2 2  a, b, c are in A.P
  4
sin18o sin 54o
tan      tan    
5. tan 2  12.  A  B  C    cot  A  B   cot   c 
1  tan     tan    
cot A cos B  1
   cot c
cot B  cot B

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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
cot A.cot B  cot B.cot C  cot c.cot A  1 2
 9  a  b  c  9
13. A2  O ,  A is nill potent 18. Given OA  a OB  b OC  c
14.
OP  a  b  c
0 0 0
2 1 0 v   a b c 

F   
1
2 1  1 0 0 
2  AP BP CP   2  a b c  = 2.V
0 1 2    
0 0 2
2 1 0 19.  a.c  b   a.b  .c  12 .b

2 1  2
2
0 0 0


1
  a.c   b  a.b c
2
 
1 
 k  13  k  2 3   k  3
3
 a.c  , a.b  0   
2 2
15. k 1 k2   k  3  0  k  2
1 1 1 20. Given U  a  b,V  a  b, a  b  2 then

 
1 1 2 2 2 2
16. AL  AB  BL  AB  BC  AB  AD U V  U .V  U .V
2 2
1
AM  AD  DM  AD  DC 
   
2 2 2 2 2
 U V  U . V  U .V  8.8  4 a.b 0
1
AD 
 
AB 2
2  2. 16  a.b

3 21. Given a  i  j  k , b   i  3 j  k
AL  AM   AB  AD 
2
 b.a  a  3

3
2
 AB  AD  
2 4
l  j  k 
a
3
  AB  BC     3 1 
2 
 3
 3
. i  j  k  i  j  k
 4
  
3
 AC  2
2
2 2 2 22. PA2  PM 2  x 2  y 2  8 x  8 y  2 xy  0
17. a b  bc  ca
 0,h 2  ab

 2 a b c 2 2 2
  2  a.b  bc  c.a  X Y X Y
23. x , y  2x2  y2  1
 2.3  2  a.b  b.c  c.a  2 2

 2
 6   a  b  c   a 2  b2  c2  24. l  0 is the er bisector of the line segment
joining the points (-2, 6), (4, 2)
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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S

25.
k2
 4  k  8  2 x  4 y  8  0 39. Area 

y12  1  m 2  2 3
16
2m
m  tan 
26. Slope   3  3 x  y  5
1  m tan  11
40. f 1 c  0  c 
27.   0   2 8

 
41. m:n = 1:2
28. 2c 2  a 2 1  m2  2a 2  4.2  a  2
 m  n 2 
b2
29. AB  AC   0,1, 1 mn ac
42. tanA+tanB = b, tanA tanB = c
30. Plane is llel to x-axis it is er to YOZ plane.
b
31. AB  2 DE tan(A+B) =
1 c
BC  2 EF
43. z12  z22  z32  z1z2  z2 z3  z3 z1, z3  0
2 2 2
CA  2 DF AB  BC  CA
z1  z2  1, z1z2  b / 3
 2
= 4. DE  EF  DF 2
 2

44. sin 1  z   cos 1  z  
 4. m2  n2  n2  l 2  l 2  m2 
2
zz
 8  l 2  m2  n 2   Im  z   0 & Re (z)   1,1

  
sin10 x 1  cos10 x  tan 1 z    , 
32. Lt . 5 k 2  4 4
x  0 x10 xk
1
45. 5  1,1     2   3   4  0
33. using L-H rule  Ans 
2 46. a  b  c  0, a3  b3  c3  3abc
34. Using L – H rule  a  0
a2 b2 c2
a b b 1   3
35.    bc ac ab
2 4
x 1 x 1 x 1
1 x
 sin  2 A  B  C   0
Put x = 0  a  2b  1
47. given f  1  14
36. Put t  tan 
k  14  14  k  0
37. r = 10 cm  r  0.02
48. Decrease each root by -1
V
 100  3 x  0.2   0.6
V 49.  26  149  26 K  1
1  log x  26 K  13  12
38. f 1  x  0 xe
x2  13  2 K  1  12
1
Maximum 
e
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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
P  x,0  is mid point of
 
6 62.
1 x 6  1 
 
6
50.    1  x 6 1  x 6 A  a,1
 x 1 
 
P  x,0 

Coeff = 11C6  6 C1 B  h, k 

51.  
2 x  1  A x 2  2   Bx  C  x  1 A(a,1) B(h,k)
ah k 1
Compare coefficients x 0
2 2
52. 8 C 8 C
4 4 h=2x-a k=-1 sub in equ
53.  n  1! 3  4  5  6  (2x-a)(2x-2a)-1(-2)=0
4x2 – 6ax+(2a2+2)=0
54. n  S   6  6, n  E   2
2x2 -3ax+(a2+1) = 0
P A  B
55. P  A / B  0
P B
63. Two lines are parallel and other is 
3
=
3 3
 6, 4  4,6  6,6  No of circles = 2
64. Conceptual
1
56. P  E1   P  E2   65. S-S1 = 0 slope = -a/b
2 66. t1t2 = -1
2  A  1
P  A / E1   P  at12 .at22  2at1.2at2
5  E2  6
67. a=2 2at=8  t= 2
E  2/5
P 1  
 
3/2
 A  2 / 5 1/ 6 4a 1  t 2
Length =
57.    0.001 2000  2 t2

3 68. Product of perpendiculars = b2


e 2  2 
P  X  3  69. e4  e2  1  0
3!
58. np  5 npq  4 5 1
e2   2sin180
2
59. Median remains same even the observations
70. Centre = (-3,4)
after the median in creases
Sub in equation
60. Sum of 9 items = 135
2 x 2 .xdx , 2 x 2  t
Sum of 10 items =160 71. e
10th item = 160-135
x  1  sin x  dx
61. lines 6x-8y+8=0, 6x-8y-7=0 72. e  
 2cos2 x / 2 
1  c1  c2 
r   1 
2  a 2  b 2    e x  sec 2 x / 2  tan x / 2  dx
2 

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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S

73.
2 cos 2 2 x
 cos2 x  sin 2 x dx
79.   2 y  f  dy    ax  3 dx
y2 ax 2
cos x sin x 2  fy   3x  c
2 2
cos 2 2 x.sin 2 x
 dx ax 2
cos 2 x  y 2  fy  3 x  c  0
2
1
2
 sin 4 xdx a
  1  a  2
2
74. By Leibnitz rule
d2y dy
x 80.   1   2   1 2 y  0
g1  x   x 2  f  u  du 1  0 dx 2 dx
1 Where 1  2,  2  5
1
PHYSICS
g1 1  12  f  u  du  0
1 81. When two quantities are added
(orsubtracted) they must have the same
x
dimensions. Therefor,
g11  x   2 x  f  u  du  x 2 f  x 1 dimensionally
1
1
 At    Bt 2  i.e, LT 1T 1   B  T 2  or
g 1  2 f  u  du  1. f 1
11
 L
 B   2   LT 2    M 0 L1T 2 
1 T
=0+3=3 1 2 1
82. u  at0 ; h  at0 for packet h  gt 2  ut
4  y  2   1 sin  y  2 
2 2 2
 
75.  2
2  y  2  3
dy 1 2 1 2 1  1
at  gt  at0t  g  t 2   at0  t  at02  0
2 0 2 2  2
0
Let y-2=t Solving the quadrant equation, we get
at  g
 /2
 cos x  2019
 t  0 1  1  
76.  2019 2019
dx 
4
2  a
0  cos x    sin x 
u
1 
77. Area = 4  ab   2ab
2  h

Vel  0

b
83. R
u 2 sin 2
andR1  u 2 
sin 300  2


u2 3 / 2  
a g g g

R

u 2 sin 600  2   u2 sin 1200   u 2  3/2 
78. If=sinx g g g

sin x  R1  R2
e  cot xdx  eloge
84. Mass of man M=80Kg
Sec: Sr.Super60_Elite,Target&LIIT-BTs Page 6
SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S

Acceleration of lift, a  5ms 2 88. When the radius of the earth is decreased to
half its initial value, the value of moment of
When lift is moving upwards the reading of th
weighing scale will be equal to R. The  1
inertia reduces to   of the initial value.
equation of motion gives  4
R  Mg  Ma or R  Mg  Ma  M  g  a This causes the increase in angular speed by
 R  80 10  5  80  15  1200 N the same degree in order to maintain the
angular momentum,
L  1 , is constant. There fore,
2 2 T 1
 2  41  4  2
T2 T1 T1 4
T1  24hr  T2  6hr
89. The system of two given particles of masses
m1 and m2 are shown in figure. Initially the
85. Block can be pulled when the horizontal centre of mass
component of the force is greater than the m r  m2 r2
force of friction. The vertical component rCM  1 1
m1  m2
will decrease the weight as well as the
normal reaction. m1 m2
 Mg sin     Mg  Mg cos  
r1 r2
  -------- (i)
2sin cos    sin 2
2 2 2 When mass m1 moves towards centre of
 mass by adistanced, then let mass m2 moves
i.e.cot  adistance d’ away from CM to keep the CM
2
in its initial position.
md 
86. P  F 
dt
  m d   Pdt
So, rCM 

m1  r1  d   m2 r2  d '  ...ii
m1  m2
m 2 dx 2 Pt 2P 12 Equating Eqs, (i) and (ii), we get
  Pt     dx  t dt 
2 dt m m m1r1 m r m1  r1  d   m2 r  d 
22  2
2 2P 3 2
on integration x  t m1  m2 m1  m2
3 m
90. The total energy aparticle executing
87. We have h1  He2 , h2  He4 , h3  He6 ..... 1
SHM  m 2 A2
 Total distance 2
 H  2 He 2  2 He 4  2 He 6  ....  H 1  2e 2  2e 4  2e6  .... The PF of the particle at a distance x from
 
1
 the equilibrium position m 2 x 2
2e2   A  2
 H 1    S 
2
 1  e   1  r  From the question,
1  e 2  1 11  A2 A
m 2 x 2   m 2 A2   x 2  x
H  2 
2 2  2 2
1  e2 
91. Let 0 be orbital speed and r is radius of
orbit of a geo stationary satellite. So,time
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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
4
period of satellite E T  E  546 
 ET 4  2   2   2  
4
4
   2  E2  16 E1  16 E

E1  T1  E1 273
2 r GM gR 2  GM 
T

As, 0 
r

r  g  2 
R
96. The rate of cooling d / dt  K    0 
3 where  0 is the temperature of the
2 r 2 r 2 2 surroundings.
T   But T 
 gR2 / r  gR 2 
For the first 10 minutes
60  50
3  K  60   0 
2 r 2 2 10  60
 
gR 2  For the next 10 minutes
50  42
1  K  50   0 
 gR 2  3 10  60
Hence r
3 gR 2 gR 2
2 or r 3  or r   
 2  2  Solving these equations, we get  0  100 C

92. Extension of wire e  FL  e  FL 97. Q  nC p t


2 AY r Y U CV 1 1 3
U  nCV t     
Since, F and Y are same for all wires Q C p   5 / 3 5
L
e 
r2 98. m  8 RT ; r  3RT ;  p  2 RT
100 200 M M M
ea   2500eb   1250
0.2  0.2 0.4  0.4 5
99. Second overtone of the closed pipe  ;
300 4l
ec   833.4
0.6  0.6 
400 First overtone of the open pipe 
ed   625 l
0.8  0.8
5   1  
93. When two drops merge let R be the radius, But    100     100
4l l 4l 2  2l 
4 4  1
then  R3  2   r 3   R  2 3 r Funcdamental frequency of the open pipe
3 3 

  200 HZ
2 T r2 2l
T   radius    ,
1T 2
2 3 r2
100. The driver will listen two sounds. Direct
sound of the horn and sound reflected from
1 1
1T  4 3 T  4 3  2  3.17ms 1 the wall. For the reflected sound, the wall
acts assource (virtual source). When the car
4 moves towards the wall the virtual source
94. W  8 2T Now V   r 3 also appears to move towards the car with
3
the same speed. Relative velocity of the car
Hence with respect to the wall (virtual source)is
2 2
2  1
 3V 
W  8T   3  W V 3
 4 
W
W1

V3
2

1
1
 W1   4 3  W
 
 R  2 s  2  5  10ms 1
 2V  3 4 3  
    350 
E V' V   v  v but
95. According to Stefan’s law   AT 4   R   350  10 
t

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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
350 Q q Q
v  v  5 v  v  5  v  170 Hz
340 d d
101. For 2 2
sin  A  A / 2 A
1, D  A  n   2cos  3  A  600
sin  A / 2 2 1 q
105. V  volume of bigger drop =
For 4 0 r
volume of 1000 small drop i.e.,
 2 , D'  300 , A  600

 n' 

sin 600  300 / 2   sin 450  n  1 / 2   4 3
3
4 
 R  1000   r 3   R  10 r also
3 
sin  60 / 2
2
0 sin 300 1 / 2
Q  1000q
102. The equivalent focal length of the  potential of bigger drop
combination 1 Q 1 1000 q
V   
1 1 1 1 1 4 0 R 4 0 10r
    but
feq f1 f 2 f    f / 2 
 1 q
11 1 V '    .100 i.eV '  102V
   4 0 r 
 u f eq
106. T1  300 K , T2  300  0.2  300  300  60  240 K
1 2 1
    orf eq   f
f f f  k2  T1  300 
 K  1  T  1   240  1  100  0.25
For a parallel bean of rays, u   1 2
susceptibility increase by 25%
1 1
     f (virtual image at a
  feq 107. l  0.3m, N1  2000, A  1.2  103 m2
distance   f ) N 2  300, di  2   2  4 amp , dt  0.25sec e 
Mdi
dt
 N N A
,M  0 1 2
l

103. If n is the number off ringes off ringe with  N N A di


e 0 1 2  4  107
 and l is the length of field of view, then l dt
l  n  n11  n2 2 2000  300  1.2  103
 D   D 2  n 
n1  1   n2  n   n2 2  n2  1 1 0.3
 d   d  1 1 2 2
Number of fringes (when  2 is used)   e  6  102 v
0.1
visible in the field of view is given by
108.
n11 5893  1010 6000 1 r
n2 
2
 60 
 10
 60 
4200
 60 
0.7
 85 cos    1  r  Z  X L  XC
4200  10 R
1
f 
104. For equilibrium, 2 LC
Q2 Qq C 
1

1
 20 F
K K  0  Q 2  4qQ  0 4 2 f 2 L 2
d2 d
2 4  3.14  50 2  0.5
  109. Momentum of the incident light
2
U
q 
Q   U   AT 
4 C

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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
h 1 R
110.  , so   Here R
2mE m After connecting in parallel Rnet  5 
ma  mn  m p  me 5 25

117. (1) E  0, B  0 then F = 0 so V is constant
deBroglie wavelength in increasing order   
will be  a ,  n ,  p , e (2) E  0, B  0 if V ll B then V is constant

11 1  (3) E  0, B  0 then V = constant is not
111. We have  R    or possible
 12 22    
1  1  1 3R (4) E  0, B  0 if FB   FE then V =
 R 1   or  wave number
  4  4 constant is possible
3R 118.

4
112. 3 Li 7  H 1  2  He24 Energy
E   2 EHe  Eli 
Eli  7  5.6V  39.2MeV
EHe  4  7.06 MeV  28.24 MeV
E   2  28.24  39.2 MeV  17.26MeV B  B1  B2
113. The electron and hole concentration in a
 I 
semi conductor in thermal equilibrium is B  0  0I
given by ne nh  n 2 2 r 2 r
1  I
B2 0
n 2
ne  i 
3  10 
16 2

 2  1010 m 3
2 r
B  16  105 T 160T
nh 4.5  10 22
119. R  R0 A1/3
114. In amplitude modulation, the frequency of
the modulated wave is equal to the 1
 R / 2   A 3
frequency of the carrier wave.  
R  192 
115. In meter bridge
192
RLEFT l A  24
 8
RRIGHT 100  l
120. In forward biasing the diffusion current
4.5 60 4.5  4 increases and drift current remains constant
 R
R 100  60 6 so net current is due to the diffusion.
 3 In reverse biasing diffusion becomes more
difficult so net current (very small) is due to
 
2
RA (3) r 2 3 7 10
4

Re sistivity  S    2
 66 107 the drift
L L 10 10

R
116. Resistance of each part is
5

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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
CHEMISTRY 127. Conceptual
121. E  hCV AgCl  Ag   Cl 
128.
0.529 2 0.529 2 S 0.1
122. rn  n A  r1  1 A
z z
Ksp   S   0.1
 0.529  2
r4   A   4 
 z  Ksp of AgCl  1.2  1010

 0.529  Ksp  S .S
r4  16  A 
 z  1.2  1010  S  0.1  S 
1.2  1010
 12  1010  1.2 109
0.1
r4  16r1
Kf
129. KC 
123. IE decreases in group and increases in Kb
periods
162 162
81   Kb  2
Nb  N a Kb 81
124. Bond order 
2
130. Conceptual
 
N 2 14e   B.O 
10  4
2
3 131. Conceptual
132. Conceptual

O22  18e  B.O  
10  8
1
2 133. Tl is exhibit +1 oxidation state is stable
134. Conceptual
NO 
14e  
 B.O 
10  4
2
3
135. Conceptual

  10  8 136. According to Huckels’ rule, the aromatic


F2 18e   B.O  1
2 nature is due to the presence of


N 22 16e   BO   10  6
2
2  4n  2   electrons. III and IV structure

do not obey’s Huckel’s rule


 
O2 17e  B.O 
10  7
 1.5
2
137. Double bond carbon posses two different
groups
 
CO 14e   B.O 
10  4
2
3
138.
aq KOH
125. PN 2  PO2  PH 2O  640 mm CCl4
CH 2  CH 2  Br2   H 2C  CH 2 
2 KBr
H 2C  CH 2

Br Br OH OH
PN 2  PO 2  640  40  600mm ethylene glycol

3 139. For P  0 , pairing will start only from


PN 2   600  450 mm
4 3
sixth electron, so, 3d 4 will be t2g eg1 or
126. CaCO3  Cao  CO2
100 gr  56 gr t111 1
2g eg .

50 gr  28 gr
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SRI CHAITANYA IIT ACADEMY, INDIA 10-05-2024_ Sr.Super60_Elite,Target&LIIT-BTs _EAPCET_GTE-16_KEY & SOL’S
OH
COC6 H5
150. He  O2
Zn dust


C H COCl
6 5

AlCl3
151.   1.7 BM means it contain one unpaired

140. (A) Benzophenone electron.

141. 152. Conceptual

OH 153.  Ni  CO 4   Diamagnetic,

H3C  CH  CH  CH  CH  CH3 sp 3 hybridisation and no of unpaired


6 5 4 3 2 1
CH 3 electrons =0

142. Conceptual  NiCl4 2  paramagnetic, sp3


143. i  1    n  1 hybridisation and no of unpaired
v K  1000 electrons =2
144.   , we know that  v 
 M 154.
4
10  S 3
C6H12O6 COOH
HNO
 

 CHOH4 saccharic acid
 1 
145. Conceptual  x m  P n 
  COOH

x y 155. Due to –I effect iii is acidic and order will


146. Rate  K  A  B 
be iii>iv>ii>i
On doubling the concentration of B, rate
CHO CH 2OH COO  Na 

does not change, so order w.r.t B is zero.


conc NaOH (Cannizaro reaction)

 +

On doubling the concentration of ‘A’ rate
156 Benzyl alcohol Sodium benzoate
doubles. So order w.r.t A is one
157. 3 alkyl halide is hydrolysed by
dC
 Rate   K  A
dt SN 1 mechanism
147. K 2O  Al2O3 158. Conceptual

148. Conceptual 159. CH 3  CH  CH  CH3  O3 


electrolysis
149. 2 NaCl  2 Na   2Cl  o
At anode : 2Cl   Cl2  2e  CH3 CH CH CH3

At cathode : 2 H 2O  2 H   2OH  O O
2CH 3CHO  H 2O2
2 H   2e  H 2  2H O / Zn

Acetaldehyde
 
2 Na  2OH  2 NaOH 160. Conceptual

Sec: Sr.Super60_Elite,Target&LIIT-BTs Page 12

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