(Physical Chemistry) IDEAL GAS

(EXERCISE O-I)
1. A container when is empty weighs 50 gm. After certain liquid of density 25 gm/dm3 is filled its
mass becomes equal to 100 gm. The volume of the container will be :
(A) 0.25 dm3 (B) 0.5 dm3 (C) 1 dm3 (D) 2 dm3
2. 10 g of a gas at 1 atm, 273 K occupies 5 litres. The temperature at which the volume becomes
double for the same mass of gas at the same pressure is ?
(A) 273K (B) –2730C (C) 2730C (D) 5460C
3. The density of gas A is twice that of B at the same temperature the molecular weight of gas B is
thrice that of A. The ratio of pressure of gas A and gas B will be
(A) 1 : 6 (B) 7 : 8 (C) 6 : 1 (D) 1 : 4
4. 4.0 g of argon has pressure P and temperature T K in a vessel. On keeping the vessel at 50°
higher temperature, 0.8 g of argon was given out to maintain the pressure P. The original
temperature was :
(A) 73 K (B) 100 K (C) 200 K (D) 510 K
5. A rigid container containing 10 gm gas at some pressure and temperature. The gas has been
allowed to escape from the container due to which pressure of the gas becomes half of its initial
pressure and temperature become (2/3)rd of its initial. The mass of gas (in gm) escaped is
(A) 7.5 (B) 1.5 (C) 2.5 (D) 3.5
6. At constant temperature 200 cm3 of N2 at 720 mm and 400 cm3 of O2 at 750 mm pressure are
put together in a one litre flask. The final pressure of mixture is
(A) 111 mm (B) 222 mm (C) 333 mm (D) 444 mm
7. In a rigid container NH3 is kept at certain temperature, if on doubling the temperature it is
completely dissociated into N2 and H2. Find final pressure to initial pressure ratio :
1 1
(A) 4 (B) 2 (C) (D)
2 4
8. The total pressure exerted by a number nonreacting gases is equal to the sum of partial
pressure of the gases under the same conditions is known as :
(A) Boyle's law (B) Charle's law (C) Avogadro's law (D) Dalton's law
9. Dalton's law cannot be applied for which gaseous mixture at normal temperatures:
(A) O2 and N2 (B) NH3 and HCl (C) He and N2 (D) CO2 and O2
10. A closed vessel contains helium and ozone at a pressure of P atm. The ratio of He and oxygen
atoms is 1 : 1. If helium is removed from the vessel, the pressure of the system will reduce to :
(A) 0.5 P atm (B) 0.75 P atm (C) 0.25 P atm (D) 0.33 P atm

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(Physical Chemistry) IDEAL GAS
11. Which of the following graphs represent boyle's law :

(A) (B)

(C) (D)

12. V versus T curves at constant pressure P1 and P2 for an ideal gas are shown in Fig. Which is
correct

(A) P1 > P2 (B) P1 < P2 (C) P1 = P2 (D) All

13. At constant pressure of 0.821 atm ; log V vs log T is plotted as shown in-
Then number of moles present in experiment -

(A) 1 (B) 10 (C) 100 (D) 0.1

14. Gas A (1 mol) dissociates in a closed rigid container of volume 0.16 lit. as per following
reaction. 2A (g) ⎯→ 3B (g) + 2C (g)
If degree of dissociation of A is 0.4 and remains constant in entire range of temperature, then
the correct P vs T graph is [Given R = 0.08 lit-atm/mol/K]

(A) (B)

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(Physical Chemistry) IDEAL GAS

(C) (D)

15. A gaseous reaction,

3A ⎯→ 2B
is carried out in a 0.0821 litre closed container initially containing 1 mole of gas A.
After sufficient time a curve of P (atm) vs T (K) is plotted and the angle with x-axis was found to
be 42.95°. The degree of association of gas A is [Given : tan 42.95 = 0.8]
(A) 0.4 (B) 0.6 (C) 0.5 (D) 0.8
16. If saturated vapours are compressed slowly (temperature remaining constant) to half the initial
volume, the vapour pressure will :
(A) Become four times (B) become doubled
(C) Remain unchanged (D) Become half

17.

Total pressure at point (A) is

(A) 0.5 atm (B) 1 atm (C) 1.8 atm (D) 1.5 atm
18. A gas Ax having mass of 100 g is confined in a container of volume 16 L maintained at 300 K
and a manometer is attached as shown, value of x is :
(R = 0.08 atm-L/mole-K) (Atomic mass of A = 24)

(A) 2 (B) 8 (C) 4 (D) 5

19. A container of volume 2 litre contains H2 gas at 300K as shown (Patm = 76 cm of Hg)

The pressure (in cm Hg) of H2 in the container is -

(A) 82 cm (B) 85 cm (C) 80 cm (D) 81 cm

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(Physical Chemistry) IDEAL GAS
20. A box of 1L capacity is divided into two equal compartments by a thin partition which are filled

with 2g H2 and 16g CH4 respectively. The pressure in each compartment is recorded as

P atm. The total pressure when partition is removed will be:

(A) P (B) 2P (C) P/2 (D) P/4

21. Two vessels of volume 2V and 3V contain two gases A and B separately at 1.5 and 4 atm

respectively. If the vessels are connected through a tube (negligible volume) at constant

temperature, the total pressure of gaseous mixture is –

(A) 3 atm (B) 15/2 atm (C) 5 atm (D) 6 atm

22. A vessel of uniform cross-section of length 500 as shown figure is divided in two parts by a

weightless & frictionless piston one part contains 5 moles of N2 (g) and other part contains 2

moles of H2(g) & 1 mole of He (g) gaseous mixture at the same temperature and pressure.

What is the length of N2 compartment ?

(Assume volume of piston to be negligible)

(A) 187.5 cm (B) 300 cm (C) 312.5 cm (D) None of these

23. At 20°C, the vapour pressure of water is recorded as 22.57 mbar. What will be vapour pressure

of water in the apparatus shown after the piston is lowered, thereby decreasing the volume of

the gas above liquid to half of the original volume

(A) 45.14 mbar (B) 22.57 mbar

(C) 11.28 mbar (D) between 11.28 and 22.57 mbar

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24. Two containers at same temperature are connected through a nozzle as shown, if one container
have O2 gas and some liquid H2O at total pressure of 840 mm at 27ºC.

Find pressure when valve between two containers is opened.

(Volume of liquid is negligible)
(Vapour pressure of H2O = 40 mm Hg at 27ºC)
(A) 210 mm (B) 200 mm (C) 240 mm (D) 800 mm
25. Equal mass of three gases He, O2 & SO2 are present in a container initially as shown -

If mechanical stoppers are removed and movable pistons are allowed to attain equilibrium -
Choose the correct statement -
(A) Position of piston A from the left end of the container is 15 cm
(B) Position of piston B from the left end of the container is 7cm
(C) Final pressure of O2 gas is 10 atm
(D) Final pressure of He gas is 20 atm.
26. Find length of column having He gas if it is kept in the following manner at same T

(A) 65  20 cm (B) 85  20 cm
75 75
85  20 85  20
(C) cm (D) cm
 10   10 
 75 −   75 + 
 2  2
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(Physical Chemistry) IDEAL GAS
Graham’s Law of Diffusion and Effusion

27. Rate of diffusion of a gas is :

(A) directly proportional to its density
(B) directly proportional to its molecular weight
(C) directly proportional to the square of its molecular weight
(D) inversely proportional to the square root of its molecular weight
28. Since the atomic weights of carbon, nitrogen and oxygen are 12, 14 and 16 respectively, among
the following pairs of gases, the pair that will diffuse at the same rate is :
(A) CO2 and N2O (B) CO2 and N2O3 (C) CO2 and CO (D) CO2 and NO

29. The increasing order of effusion among the gases, H2, O2, NH3 and CO2 is –
(A) H2, CO2, NH3, O2 (B) H2, NH3, O2, CO2
(C) H2, O2, NH3, CO2 (D) CO2, O2, NH3, H2
30. Consider the following pairs of gases A and B.
A B
(a) CO N2
(b) O2 O3
(c) 235UF6 238UF6

Relative rates of effusion of gases A to B under similar condition is in the order:

(A) a < b < c (B) a < c < b (C) a > b > c (D) a > c > b
31. The rate of diffusion of hydrogen is about–
1
(A) that of Helium (B) 1.4 times that of Helium
2
(C) twice that of Hydrogen atom (D) Four times that of Helium
32. A football bladder contains equimolar proportions of H2 and O2. The composition by mass of
the mixture effusing out of punctured football is in the ratio (H2 : O2)
(A) 1 : 4 (B) 2 2 : 1 (C) 1 : 2 2 (D) 4 : 1
33. The rate of diffusion of methane at a given temperature is twice that of a gas X. The molecular
weight of X is :
(A) 64 (B) 32 (C) 4.0 (D) 8.0
34. A 4 : 1 molar mixture of He & CH4 kept in a vessel at 20 bar pressure. Due to a hole in the vessel,
gas mixture leaks out. What is the composition of mixture effusing out initially -
(A) 8 : 1 (B) 4 : 1 (C) 1 : 4 (D) 4 : 3

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(Physical Chemistry) IDEAL GAS
35. A gas X diffuses three times faster than another gas Y the ratio of their vapour densities i.e., Dx :
Dy is
(A) 1/3 (B) 1/9 (C) 1/6 (D)1/12
36. Calculate the ratio of rate of effusion of O2 and H2 from a container containing 16gm O2 and
2gm H2
(A) 1 : 8 (B) 8 : 1 (C) 1 : 4 (D) 4 : 1
37. The number of effusion steps required to convert a mixture of H2 and O2 from 240 : 1600 (by
mass) to 3072 : 20 (by mass) is
(A) 2 (B) 4 (C) 5 (D) 6

38. For the reaction

2NH3(g) ⎯→ N2(g) + 3H2(g),
what is the % of NH3 converted if the mixture diffuses twice as fast as that of SO2 under similar
conditions.
(A) 3.125 % (B) 31.25 % (C) 6.25 % (D) 62.5 %

Kinetic Theory of Gaseous

39. Which of the following is not a postulate of kinetic molecular theory of gases :
(A)The actual volume of gas particles is negligible in comparison to the empty space between
them
(B) Particles of gas are in constant random motion and move in all possible directions in
straight line
(C) Particle collide with each other and with container wall and the total energy of particles
before and after the collision remains same
(D) Different particles travel with different speeds which remains constant with time
40. Which is not one of the postulates of the kinetic molecular theory
(A) At a constant temp. all of the particle have the same speed
(B) There are no force of attraction between molecules
(C) Gas particles move in a straight line between collisions
(D) The molecules are in a state of constant random motion
41. If a gas is expands at constant temperature then :
(A) No. of gaseous molecule decreases (B) kinetic energy of molecule decreases
(C) K.E. remain same (D) K.E. increases

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42. Average K.E. of CO2 at 270C is E. The average kinetic energy of N2 at the same temperature will
be
(A) E (B) 22E (C) E/22 (D) E/ 2
43. The total KE of an ideal monoatomic gas at 270C is
(A) 900 cal/mol (B) 1800 cal/mol (C) 300 cal/mol (D) None
44. The average kinetic energy of an ideal gas per molecule in SI units at 250C will be :
(A) 6.17 × 10–21 kJ (B) 6.17 × 10–21 J (C) 6.17 × 10–20 J (D) 7.16 × 10–20 J
45. At what temperature will be total kinetic energy (KE) of 0.30 mole of He be the same as the
total KE of 0.40 mole of Ar at 400 K :
(A) 400 K (B) 373 K (C) 533 K (D) 300 K
Maxwell Distribution of Speeds
46. Most probable speed, average speed and RMS speed are related as :
(A) 1 : 1.128 : 1.224 (B) 1 : 1.128 : 1.424
(C) 1 : 2.128 : 1.224 (D) 1 : 1.428 : 1.442
47. Four particles have speed 2, 3, 4 and 5 cm/s respectively. Their rms speed is :
 27   
(A) 3.5 cm/s (B)   cm/s (C) 54 cm/s (D)  54  cm/s
 2   
 2 

48. A flask has 10 molecules out of which four molecules are moving at 7ms–1 & the remaining are
moving at same speed of X ms–1. If Urms of the gas is 5 ms–1. The value of 'X' will be
(A) 5 (B) 3 (C) 9 (D) 16
49. At STP, the order of root mean square speed of molecules H2, N2, O2 and HBr is :
(A) H2 > N2 > O2 > HBr (B) HBr > O2 > N2 > H2
(C) HBr > H2 > O2 > N2 (D) N2 > O2 > H2 > HBr
50. Which one of the following gases would have the highest R.M.S. velocity at 250C ?
(A) Oxygen (B) Carbon dioxide (C) Sulphur dioxide (D) Carbon monoxide
51. If the average velocity of N2 molecules is 0.3 m/sec. at 270C, then the velocity of 0.6 m/sec will
take place at :
(A) 273 K (B) 927 K (C) 1000 K (D) 1200 K
52. Which of the following expression does not give root mean square velocity –
1 1 1 1
 3RT  2  3P  2  3P  2  3PV  2
(A)   (B)   (C)   (D)  
 Mw   DM w  D  nM w 
53. At what temperature would the rms speed of a gas molecule have twice its value at 100°C ?
(A) 4192 K (B) 1492 K (C) 9142 K (D) 2491 K

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(Physical Chemistry) IDEAL GAS
54. Temperature at which most probable speed of O2 becomes equal to root mean square speed of
N2 is [Given : N2 at 427°C]
(A) 732 K (B) 1200 K (C) 927 K (D) 800 K
55. Two flasks X and Y have capacity 1L and 2L respectively and each of them contains 1 mole of a
gas. The temperature of the flask are so adjusted that average speed of molecules in X is twice
as those in Y. The pressure in flask X would be
(A) same as that in Y (B) half of that in Y (C) twice of that in Y (D) 8 times of that in Y

56. Which of the gas have highest fraction of molecules at 27ºC in most probable speed region -
(A) H2 (B) N2 (C) O2 (D) CO2
57. For ideal gas observation as per Maxwell distribution

(A) U rms = 1.5  400 m / sec

(B) Fraction of molecules moving between 400 to 401 m / sec are equal with fraction of
molecules moving between 452 to 453 m/ sec

(C) U rms = 20  400 m / sec

(D) U avg = 1.5 U mps

58. The ratio of fraction of molecules present in the range Umps ± 0.02 (m/sec.) for N2 at 100 K &
C4H8 at 200 K is
(A) Greater than 1 (B) less than 1 (C) 1 (D) None of these
Collisions Among Gaseous Molecules
59. A vessel contains mono atomic 'He' at 1 bar and 300 K, determine its number density -
(A) 2.4 × 1025 m–3 (B) 6.8 × 1023 m–3
(C) 4.8 × 1026 m–3 (D) 9.2 × 1027 m–3
60. At constant volume Z11 is directly proportional to -
(A) P (B) P (C) T2 (D) T
61. Which of the following changes will double the mean free path of gas in closed container
(A) Increasing temperature two times at constant volume
(B) Increasing temperature four times at constant volume
(C) Increasing temperature two times at constant pressure
(D) Increasing temperature four times at constant pressure
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(Physical Chemistry) IDEAL GAS
(EXERCISE S-I)
1. A fix amount of gas by absorbing heat volume increases two times & pressure also increases to
4 times. How many times absolute temperature of gas would increase.
2. 3.6 gm of an ideal gas was injected into a bulb of internal volume of 8.21 L at pressure P atm
and temp T-K. The bulb was then placed in a thermostat maintained at (T+ 15) K.0.6 gm of the
gas was let off to keep the original pressure. Find P and T if mol weight of gas is 36.
3. A toy balloon originally held 1.0 gm of He gas and had a radius 10 cm. During the night,
0.875 gm of the gas effused from the balloon. Assuming ideal gas behaivour, under these
constant P and T conditions, what was the radius of the balloon the next morning.
4. Density of ideal gas at 2.46 atm and 300 K is 0.8 gm/l. Hence molar mass of gas is
[R = 0.082L-atm/mol-K]
5. While resting, the average human male use 0.2 dm3 of O2 per hour at 1 atm & 300 K for each kg
of body mass. Assume that all this O2 is used to produce energy by oxidising glucose in the
body. What is the mass of glucose required per hour by a resting male having mass 60 kg.
L − atm
What volume, at 1 atm & 300 K of CO2 would be produced (R = 0.08 )
mol − K
6. Automobile air bags are inflated with N2 gas which is formed by the decomposition of solid
sodium azide (NaN3). The other product is Na - metal. Calculate the volume of N2 gas at 27°C
and 1atm formed by the decomposing of 130 gm of sod azide.
7. 1.0×10–2 kg of hydrogen and 6.4×10–2 kg of oxygen are contained in a 10×10–3 m3 flask at
473 K. Calculate the total pressure of the mixture. If a spark ignities the mixture. What will be
the final pressure.
8. Calculate the mole fraction of N2 gas in a mixture of N2 and O2. If the partial pressure of O2 is 63
cm of Hg and the total pressure of the mixture is 90 cm of Hg.
9. A polythene bag of 3 litre capacity is filled by Helium gas (Occupying 1L at 0.3 atm & 300K).
Subsequently enough Ne gas is filled to make total pressure 0.4 atm at 300K. Calculate ratio of
moles of Ne to He in container.
10. 16 gm of O2 was filled in a container of capacity 8.21 lit. at 300 K. Calculate
(i) Pressure exerted by O2
(ii) Partial pressure of O2 and O3 if 50 % of oxygen is converted into ozone at same
temperature.
(iii) Total pressure exerted by gases if 50% of oxygen is converted into ozone (O3)
at temperature 50 K.

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(Physical Chemistry) IDEAL GAS
11. An ideal gas is at a temperature of 200 K & at a pressure of 8.21 atm. It is subjected to change in
volume by changing amount of the gas & a graph of n2 vs V2 (litre2) is plotted. Is slope constant?
If yes, calculate its value else justify why it is not constant.
12. Consider the following graph

Graph is plotted for 1 mol of gas at 400K, find slope of curve. [ Take : R=0.08 L − atm ]
mol − K
(A) (32)2 (B) (16)2 (C) (8)2 (D) (D)2

13. In the following arrangement find the pressure of gas (in cm of Hg).
(Assume that atmospheric pressure Patm = 75 cm of Hg)

xz
14. A manometer attached to a flask contains NH3 gas have no difference in mercury level initially
as shown in diagram. After the sparking into the flask, it have difference of 19 cm in mercury
level in two columns. Calculate % dissociation of ammonia.

Patm =760 mm

NH3gas

15. At 300, two gases are filled in two equal sized containers as given.
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(Physical Chemistry) IDEAL GAS

What will be the pressure of A(g) (in mm of Hg).

16. An iron cylinder contains helium at a pressure of 250 k pa and 27°C. The cylinder can
withstand a pressure of 1 × 106 pa . The room in which cylinder is placed catches fire. Predict
whether the cylinder will blow up before it metls or not. [melting point of cylinder = 1800 k]
17. Two glass bulbs A and B are connected by a very small tube having a stop cock. Bulb A has a
volume of 100 ml and contained the gas, while bulb B was empty on opening the stop cock, the
pressure fell down to 40% at constant temperature. Find out the volume of bulb B in mL.
18. Determine final pressure after the valve is left opened for a long time in the apparatus
represented in figure. Assume that the temperature is fixed at 300 K. Under the given
conditions assume no reaction of CO & O2.
I Closed
II
Value
CO O2

2L 1L

2.463 atm 4.926 atm

7
19. If in below diagram after opening valve, final pressure is MPa, than calculate P1 (in MPa)
6

P1MPa 2MPa

O2(g) O2(g)

2l,300 K 0.4l,300 K

20. There are n connected container having volume V, 2V, 3V, ......., nV separated by stopcock.
All container have same moles of gas at same temperature. If pressure of first container is P,
then final pressure when all stop cocks are opened is -
21. A vertical cylinder closed from both ends is equipped with an easily moving piston dividing the
volume into two parts, each containing one mole of air. In equilibrium at 320 K, the volume of
the upper part is 4.0 times greater than that of the lower part. At what temperature (in kelvin)
the volume of upper part becomes 3.0 times than that of lower part?

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Graham’s Law of Diffusion and Effusion
22. H2 and O2 are kept in mass ratio 1 : 8 respectively at 6 atm. If small orifice is made then relative
rate of effusion of H2 with respect to O2 initially is.
23 A gas mixture contains equal number of molecules of N2 and SF6, some of it is passed through a
gaseous effusion apparatus. Calculate how many molecules of N2 are present in the product gas
for every 100 molecules of SF6.
24. One litre of gaseous mixture of CH4 and H2 effuses in 200 seconds while one litre of gas
'X' take 10 minutes to effuse in identical conditions. If molar ratio of CH4 : H2 in mixture is
1 : 2. Find molar mass of gas 'X' in (g mol–1) units ?
25. Pure O2 diffuses through an aperture in 224 sec, whereas mixture of O2 and another gas containing
75 % O2 Takes 336 sec to effuse out same volume What is molecular weight of the gas?
26. Two gases NO and O2 were introduced at the two ends of a one meter long tube simultaneously
(tube of uniform cross- section). At what distance from NO gas end , Brown fumes will be seen.
27. At 20ºC two balloons of equal volume and porosity are filled to a pressure of 2 atm, one with 14
1
kg N2 & other with 1 kg H2 . The N2 balloon leaks to a pressure of atm in one hour. How long
2
1
will it take for H2 balloon to leaks to a pressure of atm.
2
28. Calculate relative rate of effusion of SO2 to CH4 under given condition
(i) Under similar condition of pressure & temperature
(ii) Through a container containing SO2 and CH4 in 3:2 mass ratio
(iii) If the mixture obtained by effusing out a mixture ( n SO 2
/ n CH 4 = 8/1 ) after three effusing steps.

29. Find the number of diffusion steps required to separate the isotopic mixture initially containing
some amount of H2 gas and 1 mol of D2 gas in a container of 3 lit capacity maintained at

 WD 
24.6 atm & 27 °C to the final mass ratio  2
 WH  equal to 1 .
 2  4

Kinetic Theory of Gaseous

30. Average translational kinetic energy of an ideal gas molecule at 27ºC is 3.88 × 10–x eV.
Hence x is

Maxwell Distribution of Speeds

31. At what temperature in °C, the Urms of SO2 is equal to the average velocity of O2 at 27°C.

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32. Calculate the root mean square speed of H2 molecules under following conditions.
(a) 2 mole of H2 at 27ºC
(b) 3 mole of H2 in a 5 L container at 105 Pa
(c) 4 mole of H2 at the density of 1g/ml at 105 Pa
33. Calculate Urms of molecules of H2 at 1 atm if density of H2 is 3 × 10–4 g/cc. (1 atm = 105 Pa)
34. Three ideal gases H2, CH4 and SO2 are filled in three rigid containers A, B and C respectively.

the ratio of most probable speeds of molecules in all containers is x : y : z then calculate the

x+y
value of  .
 z 
35. Root mean square speed of an unknown gas at 727°C is 105 cm/second. Calculate molar mass of

unknown gas(in gram/mole) [ Take R = 25 J /mole-K]

3
Collisions Among Gaseous Molecules
36. If the mean free path is 10 cm at one bar pressure then its value at 5 bar pressure, if
temperature is kept constant.
37. Calculate the mean free path in CO2 at 27°C and a pressure of 10–6 mm Hg.
(molecular diameter = 460 pm)
38. Two flask A and B have equal volume at 100K and 200K and have pressure 4 atm and 1 atm
respectively. The flask A contains H2 gas and B contains CH4 gas. The collision diameter of CH4
is twice that of H2 Calculate ratio of mean free path of CH4 to H2

(EXERCISE O-II)

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(Physical Chemistry) IDEAL GAS
1. An open ended mercury manometer is used to measure the pressure exerted by a trapped gas
as shown in the figure. Initially manometer shows no difference in mercury level in both
columns as shown in diagram.
P = 76 cm
gas A

Hg

After sparking 'A' dissociates according to following reaction

2A(g) ⎯→ 3B(g) + 2C(g)
If pressure of Gas "A" decreases to 0.8 atm. Then (Assume temperature to be constant and is
300 K)
(A) total pressure increased by 1.3 atm
(B) total pressure increased by 0.3 atm
(C) total pressure increased by 22.3 cm of Hg
(D) difference in mercury level is 228 mm.
2. Select the correct option for an ideal gas undergoing a process as shown in diagram.
(A) If 'n' is changing, 'V' must also be changing.
P B
(B) If 'n' is constant, 'V' must be constant.
A
(C) If 'n' is constant, 'V' must be changing.
T
(D) If 'n' is changing, 'V' must be constant.
3. Select the correct option(s):
Container-I Container-II
Valve

300 K 400 K

2 mol H2 1 mol H2

16.42 lit. 8. 21 lit.

(A) Pressure in container-I is 3 atm before opening the valve.

(B) Pressure after opening the valve is 3.57 atm.
(C) Moles in each compartment are same after opening the valve.
(D) Pressure in each compartment are same after opening the valve.
4. When an equimolar mixture of two gases A and B [MA > MB] is allowed to effuse through a Pin hole-
(A) B comes out at a faster rate

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(Physical Chemistry) IDEAL GAS
(B) Relative rate of effusion of A increases with time
(C) Rate of effusion of B will always be greater
(D) Initially, with equal molar ratio rate of effusion of B is greater than rate of effusion of A.
5. A closed vessel at temperature T contain a mixture of two diatomic gases A and B. Molar mass
of A is 16 times that of B and mass of gas A contained in the vessel is 2 times that of B.
Which of the following statements are correct-
(A) Average kinetic energy per molecule of A is equal to that of B.
(B) Root mean square velocity of B is four times that of A
(C) Pressure exerted by B is eight time of that exerted by A
(D) Number of molecules of B, in the cylinder, is eight time that of A
6. Choose the correct statement(s) among the following
(A) Average molecular speed of gases increases with decrease in fraction of molecules moving
slowly
(B) Rate of effusion of gases increases with increase in collision frequency at constant volume.
(C) Rate of effusion is proportional to molecular weight of gas
(D) Mean free path does not change with change in temperature at constant pressure
7. The graph below shows the distribution of molecular speed of two ideal gases X and Y at 200K.
on the basis of the below graph identify the correct statements –
Fraction of gas particle

Y
X
250 500 750 1000 1250 speed(m/s)

(A) If gas X is methane, then gas Y can be CO2

(B) Fraction of molecules of X must be greater than Y in any range of speed at 200K
(C) Under identical conditions rate of effusion of Y is greater than that of X
(D) The molar kinetic energy of gas X at 200K is equal to the molar kinetic energy of Y at 200K
8. Identify the correct statements when a fixed amount of ideal gas is heated in a container fitted
with a movable piston always operating at constant pressure.
(A)Average distance travelled between successive collisions will decreases.
(B) Collisions frequency increases since speed of the molecules increases with increase in
temperature.
(C) Average relative speed of approach remains unaffected.
(D)Average angle of approach remains unaffected.
APNI KAKSHA 243
(Physical Chemistry) IDEAL GAS

9. Select the correct option(s) for an ideal gas

(A) Most probable speed increases with increase in temperature
(B) Fraction of particles moving with most probable speed increases with increase in
temperature
(C) Fraction of particles moving with most probable speed are more for Cl2 than H2 under
similar condition of T, P & V.
(D) Most probable speed is more for Cl2 than H2 at same temperature
Paragraph for Question 10 to 12
On the recently discovered 10th planet it has been found that the 1 atm
gases follow the relationship PeV/2 = nCT where C is constant P
other notation are as usual (V in lit., P in atm and T in Kelvin).
V (lit)
A curve is plotted
between P and V at 500 K & 2 moles of gas as shown in figure

10. The value of constant C is

(A) 0.01 (B) 0.001 (C) 0.005 (D) 0.002
11. Find the slope of the curve plotted between P Vs T for closed container of volume 2 lit. having
same moles of gas
e e
(A) (B) 2000 e (C) 500 e (D)
2000 1000e
12. If a closed container of volume 200 lit. of O2 gas (ideal gas) at 1 atm & 200 K is taken to planet.
Find the pressure of oxygen gas at the planet at 821 K in same container
10 20
(A) (B) (C) 1 atm (D) 2 atm
e100 e50
Paragraph for Question 13 to 15
The constant motion and high velocities of gas particles lead to some important practical
consequences. One such consequence is that as minimum rapidly when they come in contact.
The mixing of different gases by random molecular motion and with frequent collisions is
called diffusion A similar process in which gas molecules escape through a tiny hole into a
vacuum is called effusion.

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(Physical Chemistry) IDEAL GAS
13. Helium gas at 1 atm and SO2 at 2 atm pressure, temperature being the same, are released
separately at the same moment into 1 m long evacuated tubes of equal diameters. If helium
reaches the other end of the tube in t sec, what distance SO2 would traverse in the same time
interval in the other tube ?
(A) 25 cm (B) 50 cm (C) 60 cm (D) 75 cm
14. 4 g of H2 effused through a pinhole in 10 sec at constant temperature and pressure. The amount
of oxygen effused in the same time interval and at the same conditions of temperature and
pressure would be :
(A) 4 g (B) 8 g (C) 16 g (D) 32 g
15. For 10 min. each at 27°C, from two identical bulbs helium and an unknown gas X at equal
pressures are leaked into a common vessel of 3 L capacity. The resulting pressure is 4.1 atm
and the mixture contains 0.4 mol of helium. The molar mass of gas X is :
(A) 16 (B) 32 (C) 64 (D) 80
Paragraph for Question 16 to 17
Initially, flask A contained oxygen gas at 27°C and 950 mm of Hg, and flask B contained neon
gas at 27°C and 900 mm. Finally, the two flasks were joined by means of a narrow tube of
negligible volume equipped with a stopcork and gases were allowed to mixup freely. The final
pressure in the combined system was found to be 910 mm of Hg.
A B
O2 Ne

16. What is the correct relationship between volumes of the two flasks ?
(A) VB = 3VA (B) VB = 4VA (C) VB = 5VA (D) VB = 4.5VA
17. How many moles of gas are present in flask A in the final condition, if volume of flask B is 304 L?
(R = 0.08 atm L mol–1 K–1)
(A) 7.58 (B) 3.79 (C) 15.16 (D) None of these
18. Match the entries in column I with entries in Column II and then pick out correct options.
Column I Column II

1
(A) vs P for ideal gas at (P)
V2

constant T and n.

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(Physical Chemistry) IDEAL GAS

(B) V 1 vs for ideal gas at (Q)

T

constant P and n

(C) log P vs log V for ideal gas (R)

at constant T and n.

1
(D) V vs for ideal gas (S)
P2

at constant T and n.

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(Physical Chemistry) IDEAL GAS
EXERCISE (S-II)
1
1. One mole of an ideal gas is subjected to a process in which P = V where P is in atm & V in
8.21
litre. If the process is operating from 1 atm to finally 10 atm (no higher pressure achieved
during the process) then what would be the maximum temperature obtained.

2. Calculate the number of moles of gas present in the container of volume 10 L at 300 K. If the
manometer containing glycerin shows 5m difference in level as shown in diagram.
Given: dglycerin = 2.72 g/ml, dmercury = 13.6 g/ml.
3. Fixed mass of a gas is subjected to the changes as shown is diagram, calculate T3, T4, P1, P2 and
V1 as shown is diagram. Considering gas obeys PV = nRT equation.

4. A balloon containing 1 mole air at 1 atm initially is filled further with air till pressure increases
to 3 atm. The initial diameter of the balloon is 1 m and the pressure at each state is proportion
to diameter of the balloon. Calculate
(a) No. of moles of air added to change the pressure from 1 atm to 3 atm.
(b) balloon will burst if either pressure increases to 7 atm or volume increases to 36m3.
Calculate the number of moles of air that must be added after initial condition to burst
the balloon.
5. The composition of the equilibrium mixture (Cl2 2Cl) which is attained at 1200ºC is
determined by measuring the rate of effusion through a pin hole. It is observed that at 1.8 mm
Hg pressure, the mixture effuses 1.16 times as fast as Kr effuses under the same conditions.
Calculate the fraction of chlorine molecules dissociated into atoms. [Kr = 84 a. m. u.]

6. One mole of NH4Cl (s) is kept in an open container & then covered with a lid. The container is
now heated to 600 K where all NH4Cl (s) dissociates into NH3 & HCl(g). If volume of the
APNI KAKSHA 247
(Physical Chemistry) IDEAL GAS
container is 24.63 L, calculate what will be the final pressure of gases inside the container. Also
find whether the lid would stay or bounce off if it can withstand a pressure difference of 4.5
atm. Assume that outside air is at 300 K and 1 atm pressure.
7. A compound exists in the gaseous state both as a monomer (A) and dimer (A2). The molecular
weight of the monomer is 48. In an experiment, 96 g of the compound was confined in a vessel
of volume 33.6 litres and heated to 273° C. Calculate the pressure developed, if the compound
exists as a dimer to the extent of 50 per cent by weight, under these conditions. (R = 0.082)
8. H2 gas is kept inside a container A and container B, each having volume 2 litre under different
conditions which are described below. Determining the missing values with proper unit.
[R = 8 J mol–1 K–1 and NA = 6 × 1023 , N = No. of molecules]
Parameter Container A Container B
P (i) ----- 1 atm
T 300 K 600 K
N 6×1020 (ii) -----
Total Average KE (iii) ----- (iv) -----
Ratio Umps (v) ----------------------
Ratio Z11 (vi) ----------------------

9. The mean free path of the molecule of a certain gas at 300 K is 2.6 × 10–5 m. The collision
diameter of the molecule is 0.23 nm. Calculate
(a) Pressure of the gas, and
(b) number of molecules per unit volume of the gas.

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(Physical Chemistry) IDEAL GAS
EXERCISE (JEE-MAINS)
1. According to the kinetic theory of gases, in an ideal gas, between two successive collisions a gas
molecule travels [AIEEE-2003]
(A) In a straight line path (B) with an accelerated velocity
(C) In a circular path (D) In a wavy path
2. What volume of hydrogen gas, at 273K and 1 atm, pressure will be consumed in obtaining
21.6g of elemental boron (atomic mass = 10.8) from the reduction of boron trichloride by
hydrogen ? [AIEEE-2003]
(A) 44.8 L (B) 22.4 L (C) 89.6 L (D) 67.2 L
3. As the temperature is raised from 20°C to 40°C, the average kinetic energy of neon atoms
changes by factor of which of the following ? [AIEEE-2004]

(A) 1/2 (B) (313 / 293) (C) 313/298 (D) 2

4. Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of
the total pressure exerted by oxygen is - [AIEEE-2008]
1 273 1 1
(A) 2/3 (B)  × (C) (D)
3 298 3 2
5. The molecular velocity of any gas is :- [AIEEE-2011]
(A) inversely proportional to the square root of temperature
(B) inversely proportional to absolute temperature
(C) directly proportional to square of temperature
(D) directly proportional to square root of temperature
6. a, v and u represent most probable velocity, average velocity and root mean square velocity
respectively of a gas at a particular temperature. The correct order among the following is
[JEE(Main)-2012]
(A) a > u > v (B) v > u > a (C) u > v > a (D) u > a > v
2
7. An open vessel at 300 K is heated till th of the air in it is expelled. Assuming that the volume
5
of the vessel remains constant, the temperature to which the vessel is heated is:
[JEE(Main-online)-2012]
(A) 750 K (B) 400 K (C) 500 K (D) 1500K
8. For 1 mol of an ideal gas at constant temperature T, the plot of (log P) against(log V) is a (P :
Pressure, V : Volume) : [JEE(Main-online)-2012]
(A) Straight line parallel to x-axis (B) Curve starting at origin
(C) Straight line with a negative slope (D) Straight line passing through origin

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(Physical Chemistry) IDEAL GAS
9. The relationship among most probable velocity, average velocity and root mean square velocity
is respectively :- [JEE(Main-online)-2012]

(A) 2 : 8/  : 3

(B) 2 : 3: 8/ 

(C) 3: 8/  : 2

(D) 8/  : 3: 2
10. Which one of the following is the wrong assumption of kinetic theory of gases ?
[JEE(Main-online)-2013]

(A) All the molecules move in straight line between collision and with same velocity.
(B) Molecules are separated by great distances compared to their sizes.
(C) Pressure is the result of elastic collision of molecules with the container's wall.
(D) Momentum and energy always remain conserved.
11. By how many folds the temperature of a gas would increase when the root mean square
velocity of the gas molecules in a container of fixed volume is increased from 5 × l04 cm/s to l0
× l04 cm/s ? [JEE(Main-online)-2013]
(A) Four (B) three (C) Two (D) Six
12. For gaseous state, if most probable speed is denoted by C, average speed by C and mean square
speed by C, then for a large number of molecules the ratios of these speeds are :-
[JEE(Main-offline)-2013]
(A) C : C : C = 1.225 : 1.128 : 1 (B) C : C : C = 1.128 : 1.225 : 1
(C) C : C : C = 1 : 1.128 : 1.225 (D) C : C : C = 1 : 1.225 : 1.128
13. A gaseous compound of nitrogen and hydrogen contains 12.5%(by mass) of hydrogen. The
density of the compound relative to hydrogen is 16. The molecular formula of the compound is:
[JEE(Main-online)-2014]
(A) NH2 (B) NH3 (C) N3H (D) N2H4
14. The initial volume of a gas cylinder is 750.0 mL. If the pressure of gas inside the cylinder
changes from 840.0 mm Hg to 360.0 mm Hg, the final volume the gas will be
[JEE(Main-online)-2014]
APNI KAKSHA 250
(Physical Chemistry) IDEAL GAS
(A)1.750 L (B) 7.50 L (C) 3.60 L (D) 4.032 L
15. The temperature at which oxygen molecules have the same root mean square speed as helium
atoms have at 300 K is : (Atomic masses : He = 4 u, O = 16 u) [JEE(Main-online)-2014]
(A) 1200 K (B) 600 K (3) 300 K (4) 2400 K
16. Which of the following is not an assumption of the kinetic theory of gases ?
[JEE-Mains (online)-2015]
(A) Gas particles have negligible volume.
(B) A gas consists of many identical particles which are in continual motion.
(C) At high pressure, gas particles are difficult to compress.
(D) Collisions of gas particles are perfectly elastic.
17. Initially the root mean square (rms) velocity of N2 molecules at certain temperature is u. If this
temperature is doubled and all the nitrogen molecules dissociate into nitrogen atoms, then the
new rms velocity will be : [JEE(Main-online)-2016]
(A) u/2 (B) 4u (C) 14u (4) 2u
18. Two closed bulbs of equal volume(V) containing an ideal gas initially at pressure pi and
temperature T1 are connected through a narrow tube of negligible volume as shown in the
figure below. The temperature of one of the bulbs is then raised to T2. The final pressure pf is :-
[JEE-Mains-2016]
T1 T1 T1 T1
Pi, V Pi, V  Pf, V Pf, V

   TT   T1   T2 
(A) 2pi 2pi  T1T2  (B) pi  1 2  (C) 2pi   (D) 2pi  
 T1 + T2   T1 + T2   T1 + T2   T1 + T2 

19. An open vessel at 27°C is heated until two fifth of the air (assumed as an ideal gas) in it has
escaped from the vessel. Assuming that the volume of the vessel remains constant, the
temperature at which the vessel has been heated is : [JEE-Mains-2019 (Jan)]
(A) 500°C (B) 500 K (C) 750° C (D) 750 K
20. The volume of gas A is twice than that of gas B. The compressibility factor of gas A is thrice than
that of gas B at same temperature. The pressures of the gases for equal number of moles are :
[JEE-Mains-2019 (Jan.)]
(A) PA = 3PB (B) 3PA = 2PB (C) 2PA = 3PB (D) PA = 2PB

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(Physical Chemistry) IDEAL GAS
21. 0.5 moles of gas A and x moles of gas B exert a pressure of 200 Pa in a container of volume 10
m3 at 1000 K. given R is the gas constant in JK–1 mol–1, x is : [JEE-Mains-2019 (Jan.)]

(A) 2R
(B) 2R
(C) 4 − R (D) 4 + R
4 + 12 4 − 12 2R 2R
22. Points I,II and III in the following plot respectively correspond to (Vmp :most probable velocity)
[JEE-Mains-2019 (Apr.)]

(A) Vmp of O2 (400 K) ; Vmp of N2 (300 K); Vmp of H2 (300 K)

(B) Vmp of N2 (300 K) ; Vmp of H2 (300 K); Vmp of O2 (400 K)
(C) Vmp of H2 (300 K) ; Vmp of N2 (400 K); Vmp of O2 (300 K)
(D) Vmp of N2 (300 K) ; Vmp of O2 (400 K); Vmp of H2 (300 K)
23. A spherical balloon of radius 3 cm containing helium gas has a pressure of 48 × 10–3 bar. At the
same temperature, the pressure, of a spherical balloon of radius 12 cm containing the same
amount of gas will be ………….. ×10–6 bar. [JEE Main, 2020]
24. Which one of the following graphs is not correct for ideal gas ? [JEE Main, 2020]

d d d d

T T 1/T P
I II III IV

d = Density, P = Pressure, T = Temperature

(A) IV (B) II (C) III (D) I
25. Geraniol, a volatile organic compound, is a component of rose oil. The density of the vapour is
0.46 gL–1 at 257°C and 100 mm Hg. The molar mass of geraniol is ___________ (Nearest Integer)
[Given R = 0.082 L atm K–1 mol–1]
[JEE Main, June 2022]
26. Which amongst the given plots is the correct plot for pressure (p) vs density (d) for an ideal
gas? [JEE Main, June 2022]

APNI KAKSHA 252

(Physical Chemistry) IDEAL GAS

(A) (B)

(C) (D)

27. 'x' g of molecular oxygen (O2) is mixed with 200 g of neon (Ne). The total pressure of the
nonreactive mixture of O2 and Ne in the cylinder is 25 bar. The partial pressure of Ne is 20 bar
at the same temperature and volume. The value of 'x' is
[Given: Molar mass of O2 = 32 g mol–1. Molar mass of Ne = 20 g mol–1]
[JEE Main, July 2022]

EXERCISE (JEE-ADVANCED)
1. Calculate the total pressure in a 10 litre cylinder which contains 0.4 g He, 1.6 g oxygen and
1.4 g of nitrogen at 27ºC. Also calculate the partial pressure of He gas in the cylinder. Assume
ideal behavious for gases. [JEE 1997]
rA
2. According to Graham's law, at a given temperature the ratio of the rates of diffusion of
rB
ga gases A and B is given by : [JEE 1998]

APNI KAKSHA 253

(Physical Chemistry) IDEAL GAS
1/ 2 1/ 2 1/ 2 1/ 2

(A) PA  M A  (B)  M A   PA  (C) PA  M B  (D) M A  PB 

PB  M B   M B   PB  PB  M A  M B  PA 

3. An evacuated glass vessel weighs 50.0 g when empty, 148.0 gm when filled with a liquid of
density 0.98 g /mL and 50.5 g when filled with an ideal gas at 760 mm Hg at 300 k . Determine
the molecular weight of the gas . [JEE 1998]
4. The pressure exerted by 12 g of an ideal gas at temperature t ºC in a vessel of volume V is one
atmp. When the temperature is increased by 10 degrees at the same volume, the pressure
increases by 10 %. Calculate the temperature 't' and volume 'V'. [molecular weight of
gas = 120] [JEE 1999]
5. One mole of N2 gas at 0.8 atm takes 38 sec to diffuse through a pin hole, whereas one mole of an
unknown compound of Xenon with F at 1.6 atm takes 57 sec to diffuse through the same hole.
Calculate the molecular formula of the compound.(At. wt. Xe = 138, F = 19) [JEE 1999]

6. The rms velocity of hydrogen is 7 times the r. m. s. velocity of nitrogen. If T is the temperature
of the gas : [JEE 2000]

(A) T(H2) = T(N2) (B) T(H2) > T(N2) (C) T(H2) < T(N2) (D) T(H2) = 7 T(N2)
7. Statement-1 : The pressure of a fixed amount of an ideal gas is proportional to its temperature.
Statement-2 : Frequency of collision and their impact both increase in proportion to the
square root of temperature. True / False. [JEE 2000]
8. The root mean square velocity of an ideal gas at constant pressure varies with density as
[JEE 2001]
(A) d2 (B) d (C) d1/2 (D) 1/d1/2

9. Which one of the following V, T plots represents the behaviour of one mole of an ideal gas at
one atmp? [JEE 2002]

V(L) 38.8 L V(L) 28.6 L

373 K 373 K
22.4 L
  20.4 L
 
273 K 273 K
 
T(K)  
T(K)
(A) (B)
   

 

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(Physical Chemistry) IDEAL GAS

V(L) 30.6 L V(L) 14.2 L

373 K 373 K
22.4 L
  22.4 L
 
273 K 273 K
 
T(K)  
T(K)
(C) (D)

 velocity of gas molecules is 400 m/sec. Calculate
 
10. The average its (rms) velocity at the same

temperature.  [JEE 2003]
11. The root mean square velocity of one mole of a monoatomic gas having molar mass M is urms.
The relation between the average kinetic energy (E) of the gas and urms is [JEE-2004]

3E 2E 2E E
(A) urms = (B) urms = (C) urms = (D) urms =
2M 3M M 3M
12. 20% surface sites have adsorbed N2. On heating N2 gas evolved from sites and were collected at
0.001 atm and 298 K in a container of volume is 2.46 cm3. Density of surface sites is
6.023×1014/ cm2 and surface area is 1000 cm2, find out the no. of surface sites occupied per
molecule of N2. [JEE 2005]
13. The ratio of the rate of diffusion of helium and methane under identical condition of pressure
and temperature will be [JEE 2005]
(A) 4 (B) 2 (C) 1 (D) 0.5
14. At 400 K, the root mean square (rms) speed of a gas X (molecular weight = 40) is equal to the
most probable speed of gas Y at 60 K. The molecular weight of the gas Y is [JEE 2009]
15. To an evacuated vessel with movable piston under external pressure of 1 atm., 0.1 mol of He
and 1.0 mol of an unknown compound (vapour pressure 0.68 atm. at 0°C) are introduced.
Considering the ideal gas behaviour, the total volume (in litre) of the gases at 0°C is close to
[JEE 2011]

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(Physical Chemistry) IDEAL GAS
Paragraph for Question 16 & 17
X and Y are two volatile liquids with molar weights of 10g mol–1 and 40g mol–1 respectively.
Two cotton plugs, one soaked in X and the other soaked in Y, are simultaneously placed at the ends of a
tube of length L = 24 cm, as shown in the figure. The tube is filled with an inert gas at 1 atmosphere
pressure and a temperature of 300K. Vapours of X and Y react to form a product which is first
observed at a distance d cm from the plug soaked in X. Take X and Y to have equal molecular diameters
and assume ideal behaviour for the inert gas and the two vapours. [JEE 2014]

16. The value of d in cm (shown in the figure), as estimated from Graham's law, is -
(A) 8 (B) 12 (C) 16 (D) 20
17. The experimental value of d is found to be smaller than the estimate obtained using Graham's
law. This is due to -
(A) Larger mean free path for X as compared to that of Y
(B) Larger mean free path for Y as compared to that of X
(C) Increased collision frequency of Y with the inert gas as compared to that of X with the inert gas
(D) Increased collision frequency of X with the inert gas as compared to that of Y with the inert gas
18. The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed.
The absolute temperature of an ideal gas is increased 4 times. As a result, the diffusion
coefficient of this gas increases x times. The value of x is [JEE-2016]
19. A closed tank has two compartments A and B, both filled with oxygen (assumed to be ideal
gas). The partition separating the two compartments is fixed and is a perfect heat insulator
(Figure 1). If the old partition is replaced by a new partition which can slide and conduct heat
but does NOT allow the gas to leak across (Figure 2), the volume (in m3) of the compartment A
after the system attains equilibrium is ____. [JEE Advance 2018]

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(Physical Chemistry) IDEAL GAS

20. Which of the following statement(s) is(are) correct regarding the root mean square speed
(Urms) and average translational kinetic energy (av) of a molecule in a gas at equilibrium ?
[JEE Advance 2019]
(A) av is doubled when its temperature is increased four times
(B) Urms is doubled when its temperature is increased four times
(C) Urma is inversely proportional to the square root of its molecular mass
(D) av at a given temperature does not depend on its molecular mass
21. If the distribution of molecular speeds of gas is as per the figure shown below, then the ratio of
the most probable, the average, and the root mean square speeds, respectively, is
[JEE Advance 2020]

(A) 1 : 1 : 1 (B) 1 : 1 : 1.224

(C) 1 : 1.128 : 1.224 (D) 1 : 1.128 : 1

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(Physical Chemistry) IDEAL GAS
Answer key
(EXERCISE O-I)
1. (D) 2. (C) 3. (C) 4. (C) 5. (C) 6. (D) 7. (A)
8. (D) 9. (B) 10. (C) 11. (B) 12. (B) 13. (C) 14. (B)
15. (B) 16. (C) 17. (D) 18. (D) 19. (B) 20. (A) 21. (A)
22. (C) 24. (C) 25. (D) 26. (B) 27. (D) 28. (A) 29. (D)
30. (B) 31. (B) 32. (A) 33. (A) 34. (A) 35. (B) 36. (A)
37. (C) 38. (C) 39. (D) 40. (A) 41. (C) 42. (A) 43. (A)
44. (B) 45. (C) 46. (A) 47. (D) 48. (B) 49. (A) 50. (D)
51. (D) 52. (B) 53. (B) 54. (B) 55. (D) 56. (D) 57. (A)
58. (C) 59. (A) 60. (A) 61. (C)
(EXERCISE S-I)
1. (8) 2. (P=0.075 atm, T=75 K) 3. (5 cm) 4. (8)
5. (15 gm ; 12 dm3) 6. (73.9 litre)
7. (Ptotal = 27.54 ×105 N/m2 , Pfinal = 19.66 ×105N/m2)
8. (0.3) 9. (3) 10. ( (i) 1.5 atm; (ii) O2=0.75 atm, O3 = 0.5 atm; (iii) 0.208 atm)
1
11. ( ) 12. (32)2 13. (5) 14. (25 %)
6

2P
15. (820) 16. (Yes) 17. (150) 18. (3.284 atm) 19. (1 MPa) 20. ( )
(n + 1)
21. (450) 22. (8) 23. (228) 24. (60) 25. (192)
1 3 1
26. (50.8 cm) 27. (16 min) 28. ( (i) ; (ii) , (iii) )
2 16 2
29. (4) 30. (2) 31. (𝟐𝟑𝟔. 𝟑𝐨 𝐂)
32. ( (a) 1934.24 m/sec , (b) 500 m/sec , (c) 17.32 m/sec.)
33. (1000 m/sec) 34. (3) 35. (25) 36. (2 cm)37. (3.3 × 103) 38. (2)
(EXERCISE O-II)
1. (B,D) 2. (A,B) 3. (A,D) 4. (A,B,D) 5. (A,B,C,D) 6. (A,B)
7. (C.D) 8. (D) 9. (A,C) 10. (B) 11. (D) 12. (A) 13. (B)
14. (C) 15. (C) 16. (B) 17. (B)
18. ( (A)→R, (B)→S, (C)→P, (D)→Q )

(EXERCISE S-II)
1. (10,000 K) 2. (0.94 mole)
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(Physical Chemistry) IDEAL GAS
3. ((i) P1 = 5 atm; (ii) T3 = 360 K; (iii) V1 = 16 lit.; (iv) P2 = 1.5 atm ; (v) T4 = 90 K)
1atm
4. (P  d; P= kd & k = ; (a) 80; (b) 1295 moles) 5. (0.137)
1meter
6. (6 atm, will bounce) 7. (2 atm)
1
8. ((i) 0.012 atm; (ii) 2.5 ×1022; (iii) 3.6 J; (iv) 300 J; (v) ; (vi) 0.4 × 10–3 : 1)
2
9. ( (a) 530.6 Pa, (b) 1281 × 1020 m–3)
(EXERCISE JEE-MAIN)
1. (A) 2. (D) 3. (C) 4. (C) 5. (D) 6. (C) 7. (C)
8. (C) 9. (A) 10. (A) 11. (A) 12. (C) 13. (D) 14. (A)
15. (D) 16. (C) 17. (D) 18. (D) 19. (B) 20. (C) 21. (C)
22. (D) 23. (750) 24. (2) 25. (152) 26. (B) 27. (80)
(EXERCISE JEE-ADVANCED)
1. (0.492 atm; 0.246 atm) 2. (C) 3. (123) 4. (-173oC, 0.82 litre)
5. (XeF6) 6. (C) 7. (Both statement are correct) 8. (D) 9. (C)
10. (434.17 m/sec) 11. (C) 12. (2) 13. (B) 14. (4)
15. (7) 16. (C) 17. (D) 18. (4) 19. (2.22 or 2.23) 20. (B,C,D)
21. (B)

APNI KAKSHA 259