FINAL JEE–MAIN EXAMINATION – JANUARY, 2024

(Held On Monday 29th January, 2024) TIME : 3 : 00 PM to 6 : 00 PM

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 3. Let P(3, 2, 3), Q (4, 6, 2) and R (7, 3, 2) be the
2 1 2  1 2 0  vertices of PQR. Then, the angle QPR is
1. Let A = 6 2 11 and P =  5 0 2  . The sum
    7
 3 3 2  7 1 5  (1) (2) cos1  
6  18 
of the prime factors of P 1AP  2I is equal to  1 
(3) cos1   (4)
(1) 26 (2) 27 (3) 66 (4) 23  18  3
Ans. (1) Ans. (4)
1 1 1
Sol. P AP  2I  P AP  2P P Sol. P(3, 2, 3)

= P 1 (A  2I)P 

= P 1 A  2I P Q(4, 6, 2) R(7, 3, 2)
Direction ratio of PR = (4, 1, -1)
= |A-2I|
01 2 Direction ratio of PQ = (1, 4, -1)
 6 0 11 = 69 4  4 1
Now, cos  
3 3 0 18. 18

So, Prime factor of 69 is 3 & 23 


So, sum = 26 3
2. Number of ways of arranging 8 identical books 4. If the mean and variance of five observations are
into 4 identical shelves where any number of 24 194
shelves may remain empty is equal to and respectively and the mean of first
5 25
(1) 18 (2) 16 (3) 12 (4) 15
7
Ans. (4) four observations is , then the variance of the
2
Sol. 3 Shelf empty : (8, 0, 0, 0)  1way
first four observations in equal to
(7,1,0,0) 
4 77 5 105
(6, 2,0,0)  (1) (2) (3) (4)
2 shelf empty :  4ways 5 12 4 4
(5,3,0,0) 
 Ans. (3)
(4, 4,0,0) 
24 2 194
(6,1,1,0) (3,3, 2,0)  Sol. X ; 
5 25
1 shelf empty : (5, 2,1,0) (4, 2, 2,0)   5ways
Let first four observation be x1, x2, x3, x4
(4,3,1,0) 
x1  x 2  x 3  x 4  x 5 24
(1, 2,3, 2) (5,1,1,1)  Here,  ......(1)
5 5
(2, 2, 2, 2) 
0 Shelf empty :   5ways x1  x 2  x 3  x 4 7
(3,3,1,1)  Also, 
 4 2
(4, 2,1,1) 
 x1  x 2  x 3  x 4  14
Total = 15 ways
 Now from eqn -1 6. Let r and  respectively be the modulus and
x5 = 10 amplitude of the complex number
194  5 
Now, 2  z  2  i  2 tan  , then (r, ) is equal to
25  8 
x12  x 22  x 32  x 24  x 52 576 194
   3 3 
5 25 25 (1)  2sec , 
 8 8 
 x12  x22  x32  x42  54
 3 5 
Now, variance of first 4 observations (2)  2sec , 
 8 8 
2
4
 4 
 x i2   xi   5 3 
(3)  2sec , 
Var = i 1
  i 1   8 8 
4  4 
   11 11 
  (4)  2sec ,
 8 8 
54 49 5
  =
4 4 4 Ans. (1)
2
 5 
5. The function f(x) = 2x  3(x) 3 ,x  , has Sol. z = 2  i  2 tan  = x + iy (let)
 8 
(1) exactly one point of local minima and no
y
point of local maxima r= x 2  y 2 &   tan 1
x
(2) exactly one point of local maxima and no
2
point of local minima  5 
r = (2)2   2 tan 
 8 
(3) exactly one point of local maxima and
exactly one point of local minima 5  3 
= 2sec  2sec    
(4) exactly two points of local maxima and 8  8 
exactly one point of local minima 3
Ans. (3) = 2 sec
8
2
Sol. f (x)  2x  3(x) 3  5 
 2 tan
&   tan 1  8 
1 
f '(x)  2  2x 3  2 
 
 1 
= 2 1  1    5  
  = tan 1  tan     
 x3    8 

 13  3
 x 1 =
= 2 1  8
 x3 
  7. The sum of the solutions x  of the equation
+ – +
3cos2x  cos3 2x
–1 0 = x3 – x2 + 6 is
cos6 x  sin 6 x
M m
So, maxima (M) at x = -1 & minima(m) at x = 0 (1) 0 (2) 1
(3) –1 (4) 3
Ans. (3) Ans. (1)
3cos2x  cos3 2x Sol. logea, logeb, logec are in A.P.
Sol. = x3 – x2 + 6  b2 = ac …..(i)
cos x  sin x
6 6

Also
cos2x (3  cos2 2x)
 = x 3 – x2 + 6  a   2b   3c 
cos2x (1  sin 2 x cos2 x) loge   ,loge   ,loge   are in A.P.
 2b   3c   a 
4(3  cos2 2x)
 = x3 – x2 + 6 2
(4  sin 2 2x)  2b  a 3c
 3c   2b  a
 
4(3  cos2 2x)
 = x3 – x2 + 6 b 3
(3  cos2 2x) 
c 2
x3 – x2 + 2 = 0  (x + 1)(x2 – 2x + 2) = 0
2b
so, sum of real solutions = –1 Putting in eq. (i) b2 = a ×
3
8. Let OA  a,OB  12a  4b and OC  b, where O
a 3
is the origin. If S is the parallelogram with adjacent 
b 2
sides OA and OC, then a :b:c=9:6:4
area of the quadrilateral OABC 10. If
is equal to ___
area of S 3 3
sin 2 x  cos 2 x
(1) 6 (2) 10  sin 3 x cos3 x sin(x  )
dx  A cos  tan x  sin   B cos   sin  cot x  C,

(3) 7 (4) 8 where C is the integration constant, then AB is

Ans. (4) equal to
B (1) 4 cosec(2) (2) 4sec 
A
Sol. (3) 2sec  (4) 8cosec(2)
12a + 4b
a Ans. (4)
3 3
sin 2 x  cos 2 x
Sol.  sin 3 x cos3 x sin(x  )
dx

O C 3 3
b
sin 2 x  cos 2 x
Area of parallelogram, S  a  b I=  sin 3 x cos3 x (sin x cos   cos x sin )
dx

Area of quadrilateral =Area(OAB)+Area (OBC) 3 3

= sin 2 x cos 2 x
dx =
=
1
2
a  (12a  4b)  b  (12a  4b)   3
sin x cos x tan x cos   sin 
2 2
dx   3
sin x cos x cos   cot xsin 
2 2

sec2 x cosec2 x
= 8 (a  b)  tan x cos   sin 
dx  
cos   cot xsin 
dx

8 (a  b) I = I1 + I2 …… {Let}
Ratio = =8
(a  b) For I1, let tan x cos  – sin  = t2
2t dt
9. If loge a, loge b, loge c are in an A.P. and loge a – sec 2 x dx 
cos 
loge2b, loge2b – loge3c, loge3c – loge a are also in
For I2 , let cos   cot xsin   z2
an A.P, then a : b : c is equal to
2z dz
(1) 9 : 6 : 4 (2) 16 : 4 : 1 cosec 2 x dx 
sin 
(3) 25 : 10 : 4 (4) 6 : 3 : 2
 I = I 1 + I2 Ans. (1)
2t dt 2z dz Sol. Differential equation :–
=  cos  t   sin  z y dy y
x cos  y cos  x
2t 2z x dx x
= 
cos  sin  y  dy 
cos x  y   x
x  dx 
= 2sec  tan xcos   sin   2cosec cos   cot xsin 
Divide both sides by x2
Comparing
 dy 
AB = 8 cosec2 x y
y  dx 1
cos  2 
11. The distance of the point (2, 3) from the line 2x – x x  x

3y + 28 = 0, measured parallel to the line  
y
3x  y  1  0, is equal to Let t
x
(1) 4 2 (2) 6 3
 dt  1
cos t   
(3) 3  4 2 (4) 4  6 3  dx  x
Ans. (4) 1
cos t dt  dx
x
Sol. r P Integrating both sides
A
(2, 3) sin t = ln | x | + c
y
sin  ln x  c
2x – 3y + 28 = 0 x
Writing P in terms of parametric co-ordinates 2 + r  3
Using y(1) = , we get c =
3 2
cos , 3 + r sin  as tan = 3
So,   3  2  3
r 3r
P(2  ,3  ) 13. If each term of a geometric progression a1, a2, a3,…
2 2
P must satisfy 2x – 3y + 28 = 0 1
with a1  and a 2  a1 , is the arithmetic mean of
8
r 3r
So, 2(2  )  3(3  )  28  0 the next two terms and Sn = a1 + a2 + …+an, then
2 2
S20 – S18 is equal to
We find r = 4  6 3
(1) 215 (2) –218
y  (3) 218 (4) –215
12. If sin    loge | x |  is the solution of the
x
  2 Ans. (4)
 y  dy y Sol. Let r’th term of the GP be arn–1. Given,
differential equation x cos    ycos    x
 x  dx x 2ar = ar+1 + ar+2
 2arn–1 = arn + arn+1
and y(1) = , then  2 is equal to
3 2
1 r
(1) 3 (2) 12 r
(3) 4 (4) 9 r2 + r – 2 = 0
 Hence, we get, r = – 2 (as r  1) So, the quadratic equation becomes 2x2 – 3x + 1 =
So, S20 – S18 = (Sum upto 20 terms) – (Sum upto 1
0 whose roots are   1,  
18 terms) = T19 + T20 2
T19 + T20 = ar18 (1 + r)  1
1  1, 2  lies on 5x + 8y = 9
Putting the values a = and r = – 2;  
8 x
we get T19 + T20 = –2 15 16. The function f(x) = ,x  –{–2, 8}
x  6x  16
2

14. Let A be the point of intersection of the lines 3x + (1) decreases in (–2, 8) and increases in
2y = 14, 5x – y = 6 and B be the point of (, 2)  (8, )
intersection of the lines 4x + 3y = 8, 6x + y = 5.
(2) decreases in (, 2)  (2,8)  (8, )
The distance of the point P(5, –2) from the line
(3) decreases in (, 2) and increases in (8,  )
AB is
13 5 (4) increases in (, 2)  (2,8)  (8, )
(1) (2) 8 (3) (4) 6
2 2 Ans. (2)
Ans. (4) x
Sol. f(x) =
Sol. Solving lines L1 (3x + 2y = 14) and L2 (5x – y = 6) x  6x  16
2

to get A(2, 4) and solving lines L3 (4x + 3y = 8) Now,

1  (x2  16)
and L4 (6x + y = 5) to get B  ,2  . f '(x) 
2  (x2  6x  16)2
Finding Eqn. of AB : 4x – 3y + 4 = 0 f '(x)  0
Calculate distance PM Thus f(x) is decreasing in
4(5)  3(2)  4 (,–2)  (2,8)  (8, )
 6
5
 1  x2  1
m 17. Let y = log e   , –1 < x < 1. Then at x = ,
1 x
2
15. Let x = (m, n are co-prime natural numbers) be  2
n
the value of 225(y ' y") is equal to
1
 1

a solution of the equation cos 2sin x  and let
9
(1) 732 (2) 746
(3) 742 (4) 736
, (  ) be the roots of the equation mx2 – nx –
Ans. (4)
m + n = 0. Then the point (, ) lies on the line
 1  x2 
(1) 3x + 2y = 2 (2) 5x – 8y = –9 Sol. y = log e  2 
1 x 
(3) 3x – 2y = –2 (4) 5x + 8y = 9
Ans. (4) dy 4x
 y' 
Sol. Assume sin–1 x =  dx 1  x4
Again,
1
cos(2)  d2 y 4(1  3x 4 )
9  y" 
2 dx2 (1  x 4 )2
sin   
3 Again
as m and n are co-prime natural numbers, 4x 4(1  3x 4 )
y' y"  
2 1  x 4 (1  x 4 )2
x
3 1
at x  ,
i.e. m = 2, n = 3 2
 736  
y ' y"  20. Let a unit vector û  xiˆ  yjˆ  zkˆ make angles ,
225 2 3
736 2 1 ˆ 1 ˆ 1 ˆ 1 ˆ
Thus 225 (y' y") = 225 × = 736 and with the vectors i k, j k
225 3 2 2 2 2
18. If R is the smallest equivalence relation on the set 1 ˆ 1 ˆ
and i j respectively. If
{1, 2, 3, 4} such that {(1,2), (1,3)}  R, then the 2 2
number of elements in R is ______
1 ˆ 1 ˆ 1 ˆ
v i  j  k , then û  v is equal to
2
(1) 10 (2) 12
2 2 2
(3) 8 (4) 15
11 5
Ans. (1) (1) (2)
2 2
Sol. Given set {1, 2, 3, 4}
(3) 9 (4) 7
Minimum order pairs are
Ans. (2)
(1, 1), (2, 2), (3, 3), (4, 4), (3, 1),(2, 1), (2, 3),(3,2),
(1, 3), (1, 2) Sol. Unit vector û  xiˆ  yjˆ  zkˆ
Thus no. of elements = 10 1 ˆ 1 ˆ 1 ˆ 1 ˆ
p1  i k,p2  j k
19. An integer is chosen at random from the integers 1, 2 2 2 2
2, 3, …, 50. The probability that the chosen integer 1 ˆ 1 ˆ
p3  i j
is a multiple of atleast one of 4, 6 and 7 is 2 2
8 21
(1) (2) 
25 50 Now angle between û and p1 
2
9 14
(3) (4) x z
50 25 û  p1  0   0
2 2
Ans. (2)
Sol. Given set = {1, 2, 3, …….. 50}  x  z  0 ….(i)
P(A) = Probability that number is multiple of 4 
Angle between û and p 2 
P(B) = Probability that number is multiple of 6 3
P(C) = Probability that number is multiple of 7 
uˆ  p2  uˆ  p 2 cos
Now, 3
12 8 7 y z 1 1
P(A)  , P(B)  , P(C)     yz ….(ii)
50 50 50 2 2 2 2
again 2
Angle between ûand p3 
4 1 1 3
P(A  B)  ,P(B  C)  ,P(A  C) 
50 50 50
2
P(A  B  C)  0 uˆ  p3  uˆ  p3 cos
3
Thus x 4 1 1
   xy …. (iii)
12 8 7 4 1 1 2 2 2 2
P(A  B  C)       0
50 50 50 50 50 50
from equation (i), (ii) and (iii) we get
21
= 1 1
50 x y=0 z=
2 2
 1 ˆ 1 ˆ 1 ˆ 1 ˆ 1 ˆ Ans. 113
Thus û  v  i k i j k
2 2 2 2 2 Sol. a, b, c and in A.P
2 ˆ 1 ˆ  2b = a + c a – 2b + c = 0
û  v  i j
2 2
 ax + by + c passes through fixed point (1, -2)
2
2  4 1 5  P = (1, - 2)
 û  v    
 2 2  2
  For infinite solution,
SECTION-B D = D1 = D2 = D3 = 0
21. Let ,  be the roots of the equation 11 1
x  6x  3  0 such that Im () > Im (). Let a, b
2
D: 2 5   0
be integers not divisible by 3 and n be a natural 12 3

99 98 n =8
number such that    3 (a  ib),i  1 . Then

61 1
n + a + b is equal to _______. D1 :  5   0   = 6
Ans. 49 4 2 3

Sol. x 2  6x  6  0   Q = (8,6)
6 i 6 6  PQ2 =113
x  (1  i)
2 2
23. Let P(,) be a point on the parabola y2 = 4x. If P
 
i i
  3(e ) ,   3(e
4 4
) also lies on the chord of the parabola x2 = 8y
99    5
  98   98   1 whose mid point is 1,  . Then (-28) (-8) is
    4

98 (  )  i99   equal to ___________.

= = 349  e 4   2
   Ans. 192
49
= 3 (-1+i) Sol. Parabola is x2 = 8y
= 3n (a+ib)
Chord with mid point (x1,y1) is T = S1
 n = 49, a = -1, b = 1
 xx1 – 4(y+y1) = x12-8y1
 n + a + b = 49 – 1 + 1 = 49
 5
22. Let for any three distinct consecutive terms a, b, c  (x1, y1) = 1, 
 4
of an A.P, the lines ax + by + c = 0 be concurrent
at the point P and Q (,) be a point such that the  5 5
 x  4  y    1  8   9
system of equations  4 4

x + y + z = 6,  x-4y + 4 = 0  (i)

2x + 5y + z =  and (,) lies on (i) & also on y2 = 4x

x + 2y + 3z = 4, has infinitely many solutions.   - 4 + 4 = 0  (ii)

Then (PQ)2 is equal to ________. & 2 = 4(iii)
 Solving (ii) & (iii) Ans. 164
y = x2 + 2 y
2 = 4(4-4)  2-16 + 16 = 0 (2, 6)
Sol.
  = 8 4 3 and  = 4 - 4 = 28 16 3

 (, ) = ( 28  16 3,8  4 3 ) & (0, 2)

x
 28 16 
(3, 0)
3,8  4 3
y = 2x + 2
 (  28)(  8)   16 3  4 3 
2 3
A   (x 2  2)dx   (2x  2)dx
0 2
= 192
41

A=
3
3
24. If 

1  sin 2xdx     2   3 , where ,  12A = 41 × 4 = 164
6 26. Let O be the origin, and M and N be the points on
x 5 y4 z 5
and  are rational numbers, then 3+4-  is equal the lines   and
4 1 3
to _______. x  8 y  2 z  11
  respectively such that MN is
12 5 9
Ans. 6
the shortest distance between the given lines. Then

3 OM. ON is equal to _____.
Sol. = 

1  sin 2x dx
Ans. 9
6
x 5 y4 z 5
 Sol. L1 :    drs (4,1,3) = b1
3
4 1 3
=  sin x  cos x dx

M (4+5,  + 4, 3 + 5)
x  8 y  2 z  11
  
6
L2 :
 
12 5 9
4 3
N(12 – 8, 5 -2, 9-11)
=   cos x  sin x  dx   sin x  cos x  dx
  MN   4  12  13,   5  6,3  9  16  ..(1)
6 4
Now
= 1  2 2  3 ˆi ˆj kˆ

=   2   3 b1  b2  4 1 3 = 6iˆ  8kˆ …(2)

12 5 9
  1,   2,   1
Equation (1) and (2)
3  4   = 6 4  12  13   5  6 3  9  16
 = =
6 0 8
25. Let the area of the region {(x, y): 0  x  3,0  y 
I and II
2
min{x + 2, 2x + 2}}be A. Then 12A is equal to  – 5 + 6 = 0 ….(3)
_____. I and III
 – 3 + 4 = 0 ….(4)
 Solve (3) and (4) we get 2
 c  1 
 = –1,  = 1 e

 M (1, 3, 2)  2 
ev  1   x   1  v  0
N (4, 3, –2)  e 

 OM.ON = 4 + 9 – 4 = 9 
y
2  y
e  1   x   1   0
x

 e  x

 2r (f (r))  f (x)f (r)  3 r 
2 2 f (r)

27. Let f (x)  lim  r e  2
r x
 r x
2 2
 x = a, y = 0  a 
  e
be differentiable in (,0)  (0, ) and f(1) = 1. ae = 2
Then the value of ea, such that f(a) = 0, is equal to 32
28. Remainder when 6432 is divided by 9 is equal to
_____.
____.
Ans. 2
Ans. 1
Sol. f(1)=1, f(a) = 0
Sol. Let 3232 = t
 2r 2 (f 2 (r)  f (x)f (r)) 3 f (r)  32

f 2 (x)  Lim  r e r  6432 = 64t = 82t = (9 – 1)2t

r x
 r x
2 2

= 9k + 1
 2r f (r) (f (r)  f (x))
2 f (r)
 Hence remainder = 1
 Lim  r e 3 r

r x
 rx rx 
29. Let the set C   x, y  | x 2  2 y  2023, x, y  .
2 f (x)
2x f (x)
f 2 (x)  f '(x)  x e 
3 x
Then (x  y) is equal to _______.
2x (x,y)C

y
dy
y  xy  x e
2 3 x Ans. 46
dx
Sol. x2 – 2y = 2023
y dy x 2 xy  x  45, y  1
  e
x dx y

(x,y)C
(x  y)  46.
dy dv
Put y  vx   vx
dx dx 30. Let the slope of the line 45x + 5y + 3 = 0 be
9r2
v vx
dv x v
 e 27r1  for some r1, r2  R. Then
dx v 2

 
dv e v x 
  e  v vdv  dx 8t 2
dx v Lim   dt  is equal to ____.
 3 3r2 x  r2 x 2  r1x 3  3x 
x 3

Integrating both side  2 

ev (x + c) + 1 + v = 0
f (1)  1  x  1, y  1
Ans. 12
Sol. According to the question ,
9r
27r1  2  9
2
x

 8t dt
2

3
lim
x 3 3r2 x
 r2 x 2  r1x 3  3x
2
8x 2
= lim 2 (using LH’ Rule)
x 3 3r
2
 2r2 x  3r1x  3
2

2
72
=
3r2
 6r2  27r1  3
2
72
=
9r2
  27r1  3
2
72
=  12
93
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A Sol.
31. Two sources of light emit with a power of 200 W. A A A.B
The ratio of number of photons of visible light
B Output = A.B + A B
emitted by each source having wavelengths 300
nm and 500 nm respectively, will be : A
(1) 1 : 5 (2) 1 : 3 A
(3) 5 : 3 (4) 3 : 5 B
B A.B
Ans. (4)
Y = A.B + A.B
hc
Sol. n1   200
1  
= A  A .B

hc Y = 1.B
n2   200
2 Y=B
33. A physical quantity Q is found to depend on
n1 1 300
  a 4 b3
n 2  2 500 quantities a, b, c by the relation Q  . The
c2
n1 3
 percentage error in a, b and c are 3%, 4% and 5%
n2 5
respectively. Then, the percentage error in Q is :
32. The truth table for this given circuit is : (1) 66% (2) 43%
A (3) 34% (4) 14%
Ans. (3)
a 4 b3
Y Sol. Q
c2
B Q a b c
4 3 2
Q a b c
A B Y A B Y
Q  a   b   c 
0 0 1 0 0 0  100  4   100   3   100   2   100 
Q  a   b   c 
(1) (2)
0 1 1 0 1 1 % error in Q = 4 × 3% + 3 × 4% + 2 × 5%
= 12% + 12% + 10%
1 0 1 1 0 0 = 34%
1 1 0 1 1 1 34. In an a.c. circuit, voltage and current are given by :
V = 100 sin (100 t) V and
A B Y A B Y 
I = 100 sin (100 t + ) mA respectively.
0 0 0 0 0 1 3
(3) (4) The average power dissipated in one cycle is :
0 1 0 0 1 0 (1) 5 W (2) 10 W
1 0 0 1 0 1 (3) 2.5 W (4) 25 W
Ans. (3)
1 1 1 1 1 0
Ans. (2)
Sol. Pavg  Vrms I rms cos() 900 9
m = 900 gm = kg  kg
1000 10
100 100  103  
   cos   r = 1m
2 2 3
2N 2(10) 
10 4 1    rad / sec
   10 3 60 60 3
2 2
T – mg = mr2
10
  2.5 W
4 T = mg + mr2
25
35. The temperature of a gas having 2.0 × 10 9 9 
2

molecules per cubic meter at 1.38 atm (Given, k = =  9.8   1 

10 10  3 
1.38 × 10–23 JK–1) is :
9 2
(1) 500 K (2) 200 K = 8.82  
10 9
(3) 100 K (4) 300 K
= 8.82 + 0.98
Ans. (1)
Sol. PV = nRT = 9.80 N

N 37. The bob of a pendulum was released from a

PV  RT
NA horizontal position. The length of the pendulum is
N = Total no. of molecules 10m. If it dissipates 10% of its initial energy
N against air resistance, the speed with which the bob
P kT
V arrives at the lowest point is : [Use, g : 10 ms–2]
5 25 –23
1.38 × 1.01 × 10 = 2 × 10 × 1.38 × 10 × T (1) 6 5 ms–1 (2) 5 6 ms–1
1.01 × 105 = 2 × 102 × T –1 –1
(3) 5 5 ms (4) 2 5 ms
1.01  103
T  500 K Ans. (1)
2
36. A stone of mass 900g is tied to a string and moved Sol.  = 10 m,
in a vertical circle of radius 1m making 10 rpm.
Initial energy = mg 
The tension in the string, when the stone is at the
lowest point is (if 2 = 9.8 and g = 9.8 m/s2) 9 1
So, mg  mv2
(1) 97 N (2) 9.8 N 10 2 
(3) 8.82 N (4) 17.8 N 9 1
Ans. (2)   10  10  v2
10 2
Sol. Given that v2 = 180
v  180  6 5 m / s
38. If the distance between object and its two times
magnified virtual image produced by a curved
T
mirror is 15 cm, the focal length of the mirror must
v be :
(1) 15 cm (2) –12 cm
mg (3) –10 cm (4) 10/3 cm
Ans. (3)
Sol. 40. In Young’s double slit experiment, light from two
\ identical sources are superimposing on a screen.
The path difference between the two lights

\\\
\ \\\\
7
reaching at a point on the screen is . The ratio

\\\\\\\\\\\ \
f 4
u of intensity of fringe at this point with respect to
v = 15 – u
\ \ \\ the maximum intensity of the fringe is :
(1) 1/2 (2) 3/4 (3) 1/3 (4) 1/4
15 cm
Ans. (1)
v 7
m=2= Sol. x 
u 4
(15  u) 2 2 7 7
2  x   
u   4 2
2u = 15 –u 
I  I max cos2  
3u = 15  u = 5 cm 2
v = 15 – u = 15 – 5 = 10 cm I   7   7 
 cos2    cos2    cos2  
I max 2  22   4 
1 1 1
   
f v u  cos2  2  
 4
1 1 1  2 1
    
10 (5) 10 10  cos2
4
f = –10 cm 1
39. Two particles X and Y having equal charges are 
2
being accelerated through the same potential 41. A small liquid drop of radius R is divided into 27
difference. Thereafter they enter normally in a identical liquid drops. If the surface tension is T,
then the work done in the process will be :
region of uniform magnetic field and describes
(1) 8R2T (2) 3R2T
circular paths of radii R1 and R2 respectively. The 1
(3) R 2 T (4) 4R2T
mass ratio of X and Y is : 8
R 
2
R 
2 Ans. (1)
(1)  2  (2)  1  Sol. Volume constant
 R1   R2  4 3 4
R  27   r 3
R  R  3 3
(3)  1  (4)  2  R3 = 27r3
 R2   R1 
R = 3r
Ans. (2) R
r
mv p 2m(KE) 2mqV 3
Sol. R    R2
qB qB qB qB r2 
9
R m Work done = T.A
2 2
m  R2 = 27 T(4r ) – T 4R
2 R2
m1  R1  = 27T4   4 R 2 T
  9
m2  R2 
= 8R2T
42. A bob of mass ‘m’ is suspended by a light string of stress
Sol. Y
length ‘L’. It is imparted a minimum horizontal strain
velocity at the lowest point A such that it just F
completes half circle reaching the top most 
Y r
2

(K.E.)A L
position B. The ratio of kinetic energies
(K.E.)B
F  Yr 2  ….(i)
is : L
VH B F/2
Y  r / 4
2
Vm
mg 
L
O C
 r 2
FY 2
L L 4

VL From (i)
A mg  r 2
Yr 2 Y
(1) 3 : 2 (2) 5 : 1 L L 2

(3) 2 : 5 (4) 1 : 5  = 2
Ans. (2)
44. A planet takes 200 days to complete one revolution
Sol. Apply energy conservation between A & B
around the Sun. If the distance of the planet from
1 1 Sun is reduced to one fourth of the original
mVL2  mVH2  mg(2L)
2 2
distance, how many days will it take to complete
VL  5gL one revolution ?
So, VH  gL (1) 25 (2) 50
(3) 100 (4) 20
1
 
2

(K.E)A 2 m 5gL
5 Ans. (1)
 
(K.E)B 1
 1

2
Sol. T  r
2 3
m gL
2
T12 T22
43. A wire of length L and radius r is clamped at one  3
r13 r2
end. If its other end is pulled by a force F, its
(200)2 T22
length increases by l. If the radius of the wire and  3
r3 r
the applied force both are reduced to half of their 4
 
original values keeping original length constant,
200  200
the increase in length will become.  T22
444
(1) 3 times (2) 3/2 times
200
(3) 4 times (4) 2 times T2 
42
Ans. (4)
T2 = 25 days
45. A plane electromagnetic wave of frequency V 10
i   2A
35 MHz travels in free space along the X-direction. Re q 5
At a particular point (in space and time)
 4 
E  9.6ˆjV / m . The value of magnetic field at this Current in resistance R3 = 2   
44
point is :
4
ˆ  2
(1) 3.2  10 8 kT (2) 3.2  10 8 ˆiT 8
(3) 9.6ˆjT ˆ
(4) 9.6  10 8 kT = 1A
Ans. (1) 47. A particle is moving in a straight line. The
E variation of position ‘x’ as a function of time ‘t’ is
Sol. C
B given as x = (t3 – 6t2 + 20t + 15) m. The velocity of
E the body when its acceleration becomes zero is :
 3  108
B (1) 4 m/s (2) 8 m/s
E 9.6 (3) 10 m/s (4) 6 m/s
B 
3  108 3  108
Ans. (2)
B = 3.2 × 10–8 T
Sol. x = t3 – 6t2 + 20t + 15
ˆ  vˆ  Eˆ
B
dx
 v = 3t – 12t + 20
2
= ˆi  ˆj = k̂ dt
So, dv
 a = 6t –12
B  3.2  108 kˆ T dt
46. In the given circuit, the current in resistance R3 is : When a = 0
R2 6t – 12 = 0; t = 2 sec
4 At t = 2 sec
R1 1
v = 3(2)2 – 12(2) + 20
2 R4
v = 8 m/s
4 R3 48. N moles of a polyatomic gas (f = 6) must be mixed
with two moles of a monoatomic gas so that the
mixture behaves as a diatomic gas. The value of N
10 V
(1) 1 A (2) 1.5 A is :
(3) 2 A (4) 2.5 A (1) 6 (2) 3 (3) 4 (4) 2
Ans. (1) Ans. (3)
Sol. n1f1  n2f2
Sol. feq 
R2 n1  n2
1A
2 4 1 For diatomic gas feq = 5
R1 2A R4 (N)(6)  (2)(3)
R3 5
2A 1A N2
4
5N + 10 = 6N + 6
N=4
2A
10 V
Req = 2 + 2 + 1 = 5
49. Given below are two statements : Stress F / A F
Sol. Y  
Statement I : Most of the mass of the atom and all Strain  / A
its positive charge are concentrated in a tiny
F
nucleus and the electrons revolve around it, is  
AY
Rutherford’s model.
Statement II : An atom is a spherical cloud of V
VA  
positive charges with electrons embedded in it, is a A
special case of Rutherford’s model. FV
In the light of the above statements, choose the  
A2 Y
most appropriate from the options given below.
(1) Both statement I and statement II are false Y & V is same for both the wires
(2) Statement I is false but statement II is true F
 
(3) Statement I is true but statement II is false A2
(4) Both statement I and statement II are true
 F1 A 22
Ans. (3) 1
 
Sol. According to Rutherford atomic model, most of  2 A12 F2
mass of atom and all its positive charge is  
1 2
concentrated in tiny nucleus & electron revolve
around it. F1A22  F2 A12
According to Thomson atomic model, atom is 2
spherical cloud of positive charge with electron F1 A12  4 
   16
embedded in it. F2 A22  1 
Hence,
52. A horizontal straight wire 5 m long extending from
Statement I is true but statement II false.
50. An electric field is given by (6iˆ  5jˆ  3k) ˆ N/C. east to west falling freely at right angle to
horizontal component of earth’s magnetic field
The electric flux through a surface area 30iˆ m2
lying in YZ-plane (in SI unit) is : 0.60 × 10–4 Wbm–2. The instantaneous value of emf
(1) 90 (2) 150 induced in the wire when its velocity is 10 ms–1 is
(3) 180 (4) 60 _________ × 10 V.
–3

Ans. (3)
Ans. (3)
Sol. E  6iˆ  5jˆ  3kˆ
Sol. BH = 0.60 × 10–4 Wb/m2
A  30iˆ
  E.A Induced emf e  BH v

  (6iˆ  5jˆ  3k).(30i)

ˆ ˆ = 0.60 × 10–4 × 10 × 5
  6  30  180 = 3 × 10–3 V
SECTION-B 53. Hydrogen atom is bombarded with electrons
51. Two metallic wires P and Q have same volume and accelerated through a potential different of V,
are made up of same material. If their area of cross which causes excitation of hydrogen atoms. If the
sections are in the ratio 4 : 1 and force F1 is applied
experiment is being formed at T = 0 K. The
to P, an extension of l is produced. The force
which is required to produce same extension in Q minimum potential difference needed to observe
is F2. any Balmer series lines in the emission spectra will
F1 
The value of is_______ . be V , where  = ________.
F2 10
Ans. (16) Ans. (121)
Sol. For minimum potential difference electron has to From phasor diagram particle has to move from P
make transition from n = 3 to n = 2 state but first
to Q in a circle of radius equal to amplitude of
electron has to reach to n = 3 state from ground
state. So, energy of bombarding electron should be SHM.
equal to energy difference of n = 3 and n = 1 state.
 1 3A
E  13.6 1  2  e  eV 3
 3  cos   2 
A 2
13.6  8
V
9 

V  12.09 V  12.1 V 6
So,  121 
Now,  t
54. A charge of 4.0 C is moving with a velocity of 6
6 –1
4.0 × 10 ms along the positive y-axis under a
 2
 
magnetic field B of strength 2kˆ T. The force 
6 T
t

acting on the charge is x iˆ N . The value of x is __.  2

 t
Ans. (32) 6 6
Sol. q = 4 C, v  4  106 ˆj m/s 
t
ˆ
B  2kT 2

F  q vB 
So, x = 2

= 4  10 6 4  106 ˆj  2kˆ 
56. In the given figure, the charge stored in 6F
= 4  10 6  8  106 ˆi
F  32iˆ N capacitor, when points A and B are joined by a
x = 32 connecting wire is _______C.
55. A simple harmonic oscillator has an amplitude A
9V
and time period 6 second. Assuming the
oscillation starts from its mean position, the time
3
required by it to travel from x = A to x  A
2
 6µF
will be s, where x = _______ : 6
x
Ans. (2)
Sol. A B
P
3µF 3
A
Q
A 

Ans. (36)
Sol. At steady state, capacitor behaves as an open
circuit and current flows in circuit as shown in the A
diagram.
9V 9V B y3

y1
i 3
6F b 1
6 6

A B A B
 D
3 3
3F

B  1st minima, A  3rd minima

3D D
y3  , y1 
R eq  9  b b
2 D
y  y 3  y1 
9V b
i  1A
9 2  6000  10 10  0.5
3  10 –3 
b
V6  1 6  6 V
2  6000  10 10  0.5
b
VA = 3 V 3  10 3
–4
b = 2 × 10 m
So, potential difference across 6F is 6 V.
x=2
Hence Q = CV 58. In the given circuit, the current flowing through the
–6
= 6 × 6 × 10 C resistance 20 is 0.3 A, while the ammeter reads
0.9 A. The value of R1 is ______ .
 36 C R1
57. In a single slit diffraction pattern, a light of
wavelength 6000 Å is used. The distance between
the first and third minima in the diffraction pattern 20 
is found to be 3 mm when the screen in placed 50 A
cm away from slits. The width of the slit is ______
× 10–4 m. 15 
Ans. (2)
Ans. (30)
Sol. For nth minima R1
bsin = n i3
 ( is small so sin  is small, hence sin  tan ) 20 
 btan = n Sol. A
A i1 B
y
 b  n 15 
D
i2
nD
 yn  (Position of nth minima) Given, i1 = 0.3 A, i1 + i2 + i3 = 0.9 A
b So, VAB = i1 × 20 = 20 × 0.3 V = 6 V
 6V 2 4 ds
i2 =  A v 
15 5 1  8t dt
9 t
dt
s
i1 + i2 + i3  A 4
1  8t 0
10  ds
0
 2 9
  i3  (r = 0.5 m
10 5 10
s = 2r = 
7 9
 i3   n 1  8t  
t

4 
10 10 0

i3 = 0.2 A 8
So, i3 × R1 = 6 V n 1  8t   2
(0.2)R1 = 6
6 1 – 8t = e–2
R1   30 
0.2

t  1  e 2   81 s
59. A particle is moving in a circle of radius 50 cm in
such a way that at any instant the normal and So,  = 8
tangential components of its acceleration are equal. 60. A body of mass 5 kg moving with a uniform speed
If its speed at t = 0 is 4 m/s, the time taken to
1 3 2 ms1 in X – Y plane along the line y = x + 4.
complete the first revolution will be 1  e2  s,
 The angular momentum of the particle about the
where  = ______. origin will be ______ kg m2s–1.
Ans. (8) Ans. (60)
Sol. a C  a t Sol. y – x – 4 = 0
dl is perpendicular distance of given line from
v 2 dv
 origin.
r dt
v t 4
dv dt dl  2 2 m
 2  1  12
2
4
v 0
r
v So, L  mvdl  5  3 2  2 2 kg m2/s
 1  t
  
 v 4 r = 60 kg m2/s
1 1
   2t
v 4
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 63. Match List I with List II
61. The ascending acidity order of the following H List I List II
atoms is (Compound) (pKa value)
H3C
HC C H H2C CH H3C C H H3C CH2 H
A. Ethanol I. 10.0
H
H3C B. Phenol II. 15.9
A B C D C. m-Nitrophenol III. 7.1
(1) C < D < B < A D. p-Nitrophenol IV. 8.3
(2) A < B < C < D Choose the correct answer from the options given
(3) A < B < D < C below :-
(4) D < C < B < A (1) A-I, B-II, C-III, D-IV
Ans. (1) (2) A-IV, B-I, C-II, D-III
CH3 (3) A-III, B-IV, C-I, D-II
 
Sol. CH  C > CH 2  CH > H3C – CH 2 > CH3 C (4) A-II, B-I, C-IV, D-III
CH3
Ans. (4)
Stability of conjugate base  acidic strength Sol. Ethanol  15.9
C<D<B<A Phenol  10
M-Nitrophenol  8.3
62. Match List I with List II P-Nitrophenol  7.1
List I (Bio Polymer) List II (Monomer)
A. Starch I. nucleotide 64. Which of the following reaction is correct ?
(1) CH3CH2CH2 NH2 
HNO ,0ºC
CH3CH2OH  N2  HCl
B. Cellulose II. -glucose
2
HO 2

C. Nucleic acid III. -glucose CH3 CH3

D. Protein IV. -amino acid (2) + HI I

Choose the correct answer from the options given
Br
below :- 
(3) + Br2
UV light
(1) A-II, B-I, C-III, D-IV Br
(2) A-IV, B-II, C-I, D-III (4) C2H5CONH2  Br2  NaOH

(3) A-I, B-III, C-IV, D-II  C2H5CH 2 NH 2  Na 2CO3  NaBr  H 2O

(4) A-II, B-III, C-I, D-IV Ans. (2)

CH3 CH3
Ans. (4)
Sol. HI I
Sol. A-II, B-III, C-I, D-IV
Markovnikov addition
Fact based.
65. According to IUPAC system, the compound 69. Match List I with List II
OH List I List II
is named as (Spectral Series (Spectral Region/Higher
for Hydrogen) Energy State)
(1) Cyclohex-1-en-2-ol (2) 1-Hydroxyhex-2-ene
A. Lyman I. Infrared region
(3) Cyclohex-1-en-3-ol (4) Cyclohex-2-en-1-ol
B. Balmer II. UV region
Ans. (4)
Cyclohex-2-en-1-ol C. Paschen III. Infrared region
D. Pfund IV. Visible region
66. The correct IUPAC name of K2MnO4 is Choose the correct answer from the options given
(1) Potassium tetraoxopermanganate (VI) below :-
(2) Potassium tetraoxidomanganate (VI) (1) A-II, B-III, C-I, D-IV
(3) Dipotassium tetraoxidomanganate (VII) (2) A-I, B-III, C-II, D-IV
(4) Potassium tetraoxidomanganese (VI) (3) A-II, B-IV, C-III, D-I
Ans. (2) (4) A-I, B-II, C-III, D-IV
Sol. K2MnO4
Ans. (3)
2+x–8=0
Sol. A – II, B – IV, C – III, D – I
 x = +6
Fact based.
O.S. of Mn = +6
IUPAC Name =
Potassium tetraoxidomanganate(VI) 70. On passing a gas, ‘X’, through Nessler’s reagent, a
brown precipitate is obtained. The gas ‘X’ is
67. A reagent which gives brilliant red precipitate with (1) H2S (2) CO2
Nickel ions in basic medium is (3) NH3 (4) Cl2
(1) sodium nitroprusside Ans. (3)
(2) neutral FeCl3 Sol. Nessler’s Reagent Reaction :
(3) meta-dinitrobenzene 2K 2HgI4  NH3  3KOH  HgO. Hg  NH2  I  7KI  2H2O
(4) dimethyl glyoxime
 Nessler 's Reagent 
Iodine of Millon 's base
Brown precipitate 
Ans. (4) 71. The product A formed in the following reaction is:
Sol. Ni2+ + 2dmg–  [Ni(dmg)2] NH2
NaNO2, HCl, 0ºC
Rosy red/Bright Red precipitate A
then Cu2Cl2
+ –
68. Phenol treated with chloroform in presence of NH2 NH 3Cl
sodium hydroxide, which further hydrolysed in (1) (2)
presence of an acid results Cl
(1) Salicyclic acid Cl Cl
(2) Benzene-1,2-diol (3) (4)
(3) Benzene-1, 3-diol Cl
(4) 2-Hydroxybenzaldehyde Ans. (3)
+
Ans. (4)
–
N2Cl Cl
OH OH NH2
Sol. + CHCl3 + NaOH CHO Sol. NaNO2 HCl Cu2Cl2
0° C
-hydroxy-benzaldehyde
It is Reimer Tiemann Reaction
72. Identify the reagents used for the following conversion 75. Which of the following statements are correct
O CH3
CHO
about Zn, Cd and Hg?
A. They exhibit high enthalpy of atomization as
CHO
O A B
CHO
OH OH OH
CHO
C
the d-subshell is full.
B. Zn and Cd do not show variable oxidation
state while Hg shows +I and +II.
(1) A = LiAlH4, B = NaOH(aq), C = NH2–NH2/KOH, C. Compounds of Zn, Cd and Hg are
ethylene glycol paramagnetic in nature.
D. Zn, Cd and Hg are called soft metals.
(2) A = LiAlH4, B = NaOH(alc), C =Zn/HCl
Choose the most appropriate from the options
(3) A = DIBAL-H, B= NaOH(aq), given below:
C = NH2–NH2/KOH, ethylene glycol (1) B, D only (2) B, C only
(4) A = DIBAL-H, B = NaOH(alc), C = Zn/HCl (3) A, D only (4) C, D only
Ans. (4) Sol. Ans. (1)
Sol. (A) Zn, Cd, Hg exhibit lowest enthalpy of
OCH3 atomization in respective transition series.
CHO
O CHO
(C) Compounds of Zn, Cd and Hg are diamagnetic
(A) DIBAL–H HO
HO
{Selective
in nature.
CHO
reduction (B)
NaOH
76. The element having the highest first ionization
of ester}
(alc.) enthalpy is
Intramolecular
Aldol
(1) Si (2) Al
(3) N (4) C
CHO
Ans. (3)
(C) Zn/HCl Sol. Al < Si < C < N ; IE1 order.
(Clemmensen
reduction) OH
77. Alkyl halide is converted into alkyl isocyanide by
73. Which of the following acts as a strong reducing
reaction with
agent? (Atomic number : Ce = 58, Eu = 63,
(1) NaCN (2) NH4CN
Gd = 64, Lu = 71) (3) KCN (4) AgCN
(1) Lu3+ (2) Gd3+ Ans. (4)
(3) Eu2+ (4) Ce4+ Sol. Covalent character of AgCN.
Ans. (3)
Sol. Eu+2   Eu+3 + 1e– 78. Which one of the following will show geometrical
isomerism?
[Xe]4f76s0 [Xe] 4f66s0
CHBr
CH 2
74. Chromatographic technique/s based on the
principle of differential adsorption is/are (1) (2)
A. Column chromatography
B. Thin layer chromatography Br Br
C. Paper chromatography CH 2
Choose the most appropriate answer from the CHBr
options given below:
(3) (4)
(1) B only (2) A only
(3) A & B only (4) C only
Ans. (3) Br Br
Ans. (3)
Sol. Memory Based
Sol. Due to unsymmetrical.
79. Given below are two statements: M 1000
Statement I: Fluorine has most negative electron Sol. m
dsol 1000  M  Molar masssolute
gain enthalpy in its group.
815 × 10–3 m
Statement II: Oxygen has least negative electron
gain enthalpy in its group. 85. If 50 mL of 0.5 M oxalic acid is required to
In the light of the above statements, choose the neutralise 25 mL of NaOH solution, the amount of
most appropriate from the options given below. NaOH in 50 mL of given NaOH solution is
(1) Both Statement I and Statement II are true _____g.
(2) Statement I is true but Statement II is false Ans. (4)
(3) Both Statement I and Statement II are false Sol. Equivalent of Oxalic acid = Equivalents of NaOH
(4) Statement I is false but Statement II is true 50 × 0.5 × 2 = 25 × M × 1
Ans. (4) MNaOH = 2M
Sol. Statement-1 is false because chlorine has most WNaOH in 50ml = 2 × 50 × 40 × 10–3 g = 4g
negative electron gain enthalpy in its group.
80. Anomalous behaviour of oxygen is due to its 86. The total number of ‘Sigma’ and Pi bonds in 2-
(1) Large size and high electronegativity formylhex-4-enoic acid is ____.
(2) Small size and low electronegativity Ans. (22)
H H H O
(3) Small size and high electronegativity
(4) Large size and low electronegativity Sol. H C C C C C C O H
Ans. (3)
H H H H C H
Sol. Fact Based.
SECTION-B O
81. The total number of anti bonding molecular 22 bonds
orbitals, formed from 2s and 2p atomic orbitals in a 87. The half-life of radioisotopic bromine - 82 is 36
diatomic molecule is _____________. hours. The fraction which remains after one day is
Ans. (4) ___________ ×10–2.
Sol. Antibonding molecular orbital from 2s = 1 (Given antilog 0.2006 = 1.587)
Antibonding molecular orbital from 2p = 3 Ans. (63)
Total = 4 Sol. Half life of bromine – 82 = 36 hours
82. The oxidation number of iron in the compound 0.693
t1/2 
formed during brown ring test for NO3 ion is _____. K
Ans. (1) 0.693
Sol. [Fe(H2O)5(NO)]2+, K = 0.01925 hr–1
36
Oxidation no. of Fe = +1 1st order rxn kinetic equation
83. The following concentrations were observed at 2.303 a
500 K for the formation of NH3 from N2 and H2. At t log
equilibrium :[N2] = 2 × 10–2 M, [H2] = 3 ×10–2 M and K ax
[NH3] = 1.5 ×10–2M. Equilibrium constant for the a tK
log  (t = 1day = 24hr)
reaction is _______. a  x 2.303
Ans. (417) a 24hr  0.01925hr 1
log 
 NH3  ax
2
2.303
Sol. KC 
 N2  H2  a
3
log  0.2006
ax
KC 
1.5 10 
2 2
a
 anti log  0.2006 
 2 10   3 10 
2 2 3 ax
a
KC = 417  1.587
ax
If a = 1
84. Molality of 0.8 M H2SO4 solution (density 1.06 g cm–3) 1
is _____×10–3 m.  1.587  1 – x = 0.6301 = Fraction remain
Ans. (815) 1 x
after one day
88. Standard enthalpy of vapourisation for CCl4 is 89. A constant current was passed through a solution
–1
30.5 kJ mol . Heat required for vapourisation of of AuCl 4 ion between gold electrodes. After a
period of 10.0 minutes, the increase in mass of
284g of CCl4 at constant temperature is ____kJ. cathode was 1.314 g. The total charge passed
(Given molar mass in g mol–1 ; C = 12, Cl = 35.5) through the solution is _________ × 10-2 F.
(Given atomic mass of Au = 197)
Ans. (56)
Ans. (2)
Sol. H 0vap CCl4  30.5 kJ / mol W ch arg e
Sol. 
Mass of CCl4 = 284 gm E 1F

Molar mass of CCl4 = 154 g/mol 1.314 Q


197 1F
284
Moles of CCl4 = = 1.844 mol 3
154
Q = 2 × 10–2 F
Hvapº for 1 mole = 30.5 kJ/mol 90. The total number of molecules with zero dipole
Hvapº for 1.844 mol = 30.5 × 1.844 moment among CH4, BF3, H2O, HF, NH3, CO2 and
SO2 is _________.
= 56.242 kJ
Ans. (3)
Sol. Molecules with zero dipole moment = CO2, CH4,
BF3