Prolems Solutions
Prolems Solutions
1. Surge drums are often used as intermediate storage for gas streams: that are
transferred between chemical process units. Consider a drum depicted in Figure 1,
where qi is the inlet molar flow rate of gas and q is the outlet molar flow rate of
the gas.
Required:
1. Develop a model that describes how the pressure in the tank varies with time.
2. State your assumptions
qi q
(mole/ time) P (mole/ time)
Figure:2
Answer the problem (1)
qi q
(mole/ time) P (mole/ time)
1- Basis:
Total continuity equation
2- Assumptions:
• Isothermal ( no temperature mentioned)
• Constant area (C. S. A)
• Behaves as an ideal gas
3- Mathematical model:
[ mass flow into the system] – [mass flow out of the system]= [time rate of
the change]
Molar flow rate= (mass flow rate/Molecular weight)
∵ n•= [m•/M]
∴m•= n• *M
∵n• =q
∴ m•= q * M
∵ m=Ꝭ *V
qi *M – q*M = d((P*M/R*T)*V)/dt
M*(qi– q)= [V*M/R*T] d(P)/dt ÷M
1- Basis:
Energy balance equation
2- Assumptions:
• Constant Cp
• Neglect kinetic energy
• Neglect potential energy
• Neglect shaft-work
• Perfect mixing
• Constant Ꝭ, V
• No phase change(Liquid)
3- Mathematical model:
w: mass flow rate of feed
Q: heat loss to surrounding is governed by the equation
Q= U*A(T-Ta)
∵Q= U*A(T-Ta)