MATERIAL SAFETY DATA SHEET

CHEMLOK 205

1.1 PRODUCT NAME: CHEMLOK 205

1.2 COMPANY

LORD CHEMICAL PRODUCTS (AUSTRALIA) PTY. LTD.

ACN 085 209 712
21 Beverage Drive
Tullamarine
Victoria 3043
Australia

Phone: 03 - 9335 6620

Fax: 03 - 9335 6570

1.3 EMERGENCY

Telephone: 1800 033 111 - ANYTIME AUSTRALIA WIDE

1.4 RECOMMENDED USE

Elastomer Adhesive

2 COMPOSITION

Hazardous CAS No %(w/v) Hazardous Risk Phases

Ingredients Category
Carbon Black 1333-86-4 1 Non-hazardous -
Ethyl Benzene 100-41-4 3 Non-hazardous -
Methyl Ethyl Ketone 78-93-3 2 Xi R10, R20, R36/R37
Methyl Isobutyl Ketone 108-10-1 60 Xn R11, R20, R36/R37
Xylene 1330-20-7 15 Xn R10, R20/R21

3 HAZARDOUS IDENTIFICATION

Classified as hazardous according to the criteria of Worksafe Australia.

Hazard Category: Xn (HARMFUL)

UN Number 1133
Proper Shipping Name ADHESIVES containing flammable liquid
Dangerous Goods Class 3
Subsidiary Risk -
Hazchem Code 3[Y]E
Packing Group II
IERG Number 14
Poisons Schedule 5

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CHEMLOK 205

4 FIRST AID MEASURES

Swallowed: Immediately rinse mouth with water. DO NOT INDUCE

vomiting. Give plenty water or milk to drink, then raw egg. Seek immediate
medical assistance.

Eye: Immediately irrigate with copious quantities of water for at least 15

minutes. Eyelids to be held open. Remove clothing if contaminated and
wash contaminated skin. Seek immediate medical assistance.

Skin: Immediately wash contaminated skin with plenty of soap and water.
Remove contaminated clothing and wash before re-use. If irritation occurs
seek medical advice.

Inhalation: Remove victim from exposure – avoid becoming a casualty.

Remove contaminated clothing and loosen remaining clothing. Allow patient
to assume most comfortable position and keep warm. Keep at rest until full
recovered. If breathing laboured and patient cyanotic (blue), ensure airways
are clear and have qualified person give oxygen through a facemask. If
breathing has stopped apply artificial respiration at once. In the event of
cardiac arrest, apply external cardiac massage. Seek immediate medical
advice.

Poisons Information Centres in each State capital city can provide

additional assistance for scheduled poisons.

Advice to Doctor: Treat symptomatically as for exposure to aromatic

hydrocarbon solvents. Do not give epinephrine or related drugs. Aspiration
can result in pulmonary oedema. Liquid paraffin BP may slow gastric
absorption. Gastric lavage should only be undertaken after endotracheal
intubation.

5 FIRE - FIGHTING MEASURES

Flammable liquid, (Class 3).

May form flammable vapour mixtures with air. Avoid all ignition sources.
Flameproof equipment necessary in area where this chemical is being
used. Nearby equipment must be earthed. Keep containers tightly closed.
Heating can cause expansion or decomposition leading to violet rupture of
containers. If safe to do so, remove containers from path of fire. Keep
containers cool with water spray. Fire fighters to wear self contained
breathing apparatus if risk of exposure to vapour or products of
combustion/decomposition. During a fire, thermal decomposition or
combustion may generate irritating and/or toxic gases and particulate.

EXTINGUISHING MEDIA: Water fog, foam, dry agent (carbon dioxide, dry
chemical powder).

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6 ACCIDENTAL RELEASE MEASURES

Shut off possible sources of ignition. Avoid inhalation of vapours. Use

self-contained breathing apparatus. Clear area of all unprotected
personnel. Slippery when split. Avoid accidents, clean up immediately.
Use absorbent (soil, sand or other inert materials). Wear protective
equipment to prevent skin and eye contamination and inhalation of
vapours. Contain – prevent run off into drains and waterways. For large
spills notify Emergency Services. If contamination of sewers or waterways
has occurred advise local Emergency Services.

7 HANDLING and STORAGE

Handling: Avoid skin and eye contact and inhalation of vapours. Wear
overalls, chemical goggles and impervious gloves. Use with adequate
ventilation. If inhalation risk exists wear organic vapour respirator meeting
the requirements of AS1715 and AS1716. Do not handle until all safety
precautions have been read and understood. Keep closure tight and
container upright to prevent leakage. Empty containers should not be re-
used. Because empty containers may retain product residue and
flammable vapours, keep away from heat, sparks and flame; do not cut,
puncture or weld on or near the empty container. Do not smoke where this
product is used or stored. Always wash hands before smoking, eating,
drinking or using the toilet. Wash contaminated clothing and other
protective equipment before storage or reuse.

Storage: Store only in well-ventilated area. Store away from

organic/combustible materials/oxidising agents/foodstuffs. Keep containers
closed at all times – check regularly for leaks. Avoid thermal shock. Store in
cool place and out of direct sunlight. Store away from sources of heat or
ignition. Keep container closed when not in use.

8 EXPOSURE CONTROLS and PERSONAL PROTECTION

TWA TWA STEL STEL

NOTICES
ppm mg/m3 ppm mg/m3
Carbon Black - 3 - - -
Ethyl Benzene 100 434 125 543 -
Methyl Ethyl -
150 445 300 890
Ketone
Methyl
Isobutyl 50 205 75 307 -
Ketone
Xylene 80 350 150 655 -

As published by the National Occupational Health and Safety Commission (Worksafe

Australia).

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8 EXPOSURE CONTROLS and PERSONAL PROTECTION - continued

Exposure Standard (TWA) is the time weighted average airborne

concentration over an eight-hour working day, for day working week over an
entire working life. According to current knowledge this concentration should
neither impair the health of, nor cause undue discomfort to, nearly all
workers.

STEL (Short Term Exposure Limits) – the average airborne concentration

over a 15 minute period which should not be exceeded at any time during a
normal eight-hour workday. According to current knowledge this
concentration should neither impair the health of, nor cause undue discomfort
to, nearly all workers.

‘Sen’ notice – sensitiser. The substance can cause a specific immune

response in some people. An affected individual may subsequently react to
minute levels of that substance.

These Exposure Standards are guides to be used in the control of

occupational heath hazards. All atmospheric contamination should be kept
as low a level as is workable. These exposure standards should not be used
as fine dividing lines between safe and dangerous concentrations of
chemicals. They are not a measure of relative toxicity.

Skin Protection: Use neoprene, nitrile or rubber gloves to prevent skin

contact.

Eye Protection: Use safety eyewear including safety glasses with side
shields and chemical goggles where splashing may occur.

Other Protective Equipment: Use disposable or impervious clothing if

work clothing contamination is likely. Remove and wash contaminated
clothing and other protective equipment before storage or reuse. If
inhalation risk exists wear organic vapour respirator meeting the
requirements of AS1715 and AS1716.

Hygienic Practices: Always wash hands before smoking, eating, drinking or

using the toilet. Food or beverages should not be consumed anywhere this
product is handled or stored. Wash thoroughly after handling.

9 PHYSICAL and CHEMICAL PROPERTIES

Appearance Grey liquid

Odour Solvent
Specific Gravity 0.94
Vapour Pressure (kPa) Not determined
Flash Point (C) 19
Flammability Limits (v/v%) 1.0 – 11.4
Solubility Limits Insoluble in H2O
Boiling Range (C) 79 – 139

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9 PHYSICAL and CHEMICAL PROPERTIES - continued

Freeze Point (C) Not determined

pH Not applicable
% Volatile by volume 86.9
% Volatile by weight 75.5
Viscosity Not available
Odour Threshold Not determined

10 STABILITY and REACTIVITY

Stability: This product is stable under normal storage conditions.

Reactivity: Reacts with strong oxidising gents/acid/alkalis/water/moisture

liberating flammable/toxic gas.

Hazardous decomposition products are carbon dioxide, carbon monoxide,

chlorine, and hydrogen chloride. Phosgene. (1)

11 HEALTH HAZARDS and TOXICOLOGICAL INFORMATION

HEALTH EFFECTS

No adverse health effects expected if the product is handled in accordance

with this Safety Data Sheet and the product label. Symptoms or effects that
may arise if the product is mishandled are:

ACUTE EFFECTS

Swallowed: Harmful if swallowed. Swallowing can result in nausea,

vomiting and central nervous system depression. If the victim is
uncoordinated there is greater likelihood of vomit entering the lungs and
causing subsequent complications.

Eye: May be an eye irritant.

Skin: Contact with skin may result in irritation. Will have a degreasing
action on the skin. Repeated or prolonged skin contact may lead to irritate
contact dermatitis.

Inhalation: Possible irritation of the respiratory system can occur causing

a variety of symptoms such as dryness of the throat, tightness of the chest,
and shortness of breath. May cause central nervous system depression
characterised by the following progressive steps: headache, dizziness,
staggering gait, confusion, unconsciousness or coma. May cause
respiratory sensitisation. (1)

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11 HEALTH HAZARDS and TOXICOLOGICAL INFORMATION - continued

CHRONIC EFFECTS

May cause liver or kidney damage. Repeated or prolonged solvent over

exposure may result in permanent central nervous system damage. May
affect the gastrointestinal system. May effect the blood and blood forming
organs. Formaldehyde (gas), entrapped in this product, may be released
during heating or mixing. NTP, IARC and OSHA have identified it as a
potential human carcinogen. Chronic skin contact may cause dermatitis.
IARC has designated carbon black as Group 2B – inadequate evidence for
carcinogenicity in humans, but sufficient evidence in experimental animals.
(1)

TOXICITY EFFECTS

No product toxicological information is available.

For the individual components based on 100% the following toxicological

information has been recorded:

Carbon Black (2)

IARC Evaluation Possibly carcinogenic to humans (Group 2B)

Ethyl Benzene (3)

Oral LD50 (rat) 3500 mg/kg
Inhalation LC50 (rat) 4000 ppm/4 hrs

Methyl Ethyl Ketone (4)

Oral LD50 (rat) 2737 mg/kg
Inhalation LCLo (rat) 2000 ppm/4 hr
Inhalation LC50 (mouse) 40 g/m³/2 hr
Skin LD50 (rabbit) 13 g/kg
Skin (rabbit) 500 mg/24 hr: moderate irritation effects
Skin (rabbit) 13780 ug/24 hr open: mild irritation
Inhalation (rat) dose 412, 1002, 3005 ppm: kidney, cranium,
face development including teratogenicity
effects. Dose 400, 1000 or 3000 ppm: skeleton,
development effects

Methyl Isobutyl Ketone (5)

Oral LD50 (rat) 2080 mg/kg
Oral LD50 (mouse) 2671 mg/kg
Eye LC50 (mouse) 23300 mg/m³
Skin (rabbit) 500 mg/24 hr: mild irritation effects
Eye (rabbit) 500 mg/24 hr: mild irritation effects

Xylene (6)
Oral LD50 (rat) 4300 mg/kg
Inhalation LC50 (rat) 5000 ppm/4 hrs

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12 ECOLOGICAL INFORMATION

No environmental impact data found for this material, however for:

Carbon Black
No data found.

Ethyl Benzene (7)

96 hr LC50 (minnow, sheepshead, juvenile) (static): 280 mg/l
24 – 96 hr LC50 (bass, stripped, juvenile) (static): 4.3 mg/l
96 hr LC50 (mysidopsis) (static): 87.6 mg/l
96 hr LC50 (sunfish, bluegill) (static): 130 - 200 mg/l
48 hr LC50 (daphnia magna, <24 HR) (static): 50 - 120 mg/l

Methyl Ethyl Ketone

No data found.

Methyl Isobutyl Ketone

No data found.

Xylene (8)
24 – 96 hr LC50 (guppy) (static): 34.73 mg/l
24 – 96 hr LC50 (goldfish) (static): 36.81 mg/l
24 - 48 hr LC50 (sunfish, bluegill) (static): 24 mg/l
24 – 96 hr LC50 (minnow, flathead) (static): 28.77 mg/l
24 hr LC50 (daphnia magna, juvenile 24 HR) (static): 150 mg/l

13 DISPOSAL CONSIDERATIONS

Refer to appropriate authority in your State. Dispose of material through a

licensed waste contractor. Advise flammable nature. Normally suitable for
disposal by approved agent.

14 TRANSPORT INFORMATION

SHIPPING NAME ADHESIVES containing flammable liquid

Packing Group II

Mode Regulations Class Packing Group Notes

- UN 1133 II
Sea IMDG Class 3 II
Road/Rail ADG Code Class 3 II
Air IATA/ICAO Class 3 II

Classified as a Class 3 (FLAMMABLE LIQUID) Dangerous Substance for the

purpose of transport. Refer to relevant regulations for storage and transport
requirements.

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14 TRANSPORT INFORMATION - continued

Not to be loaded with explosives (Class 1), spontaneously combustible

substances (Class 4.2), oxidising agents (Class 5.1), organic peroxides
(Class 5.2), foodstuff or foodstuff empties, however exemptions may apply.

This material is a Scheduled Poison (S5) and must be stored, maintained

and used in accordance with the relevant regulations.

15 REGULATORY INFORMATION

Classification and labelling according to Worksafe Australia’s Code of Practice

for Labelling Workplace Substances [NOHSC –2012 (1994)]

Hazard Symbol: Xn (HARMFUL)

R11 Highly flammable.

R20/R21 Harmful by inhalation and in contact with skin
R36/R37 Irritating to eyes and respiratory system.

S26 In case of contact with eyes, rinse immediately with plenty of

water and contact a doctor or Poisons Information Centre.
S36/S37 Wear suitable protective clothing and gloves.
S44 If you feel unwell, contact a doctor or Poisons Information
Centre immediately.
S51 Use only in well ventilated areas.

16 OTHER INFORMATION

Exposure Limits: Worksafe Australia has not established A Workplace

Exposure Standard for Atmospheric Contaminants in
the Occupational Environment.

The information contained in this Safety Data Sheets does not replace any of
the user’s statutory duties in respect of performing an adequate assessment
of any potential workplace risk which may occur as a result of the way in
which the product is used. The user must carry out such assessments as are
required by other health and safety legislation.

Principal References:

(1) Material Safety Data Sheet – CHEMLOK 205, LORD Corporation Inc. USA, 11
February 2009.

(2) ECDIN, 0037800 Carbon Black - 1333864, Human Health Effects,

Carcinogenicity Summary, Occupational Poisoning Reports.

(3) Dangerous Properties of Industrial Materials, 8th Edition – Ethyl Benzene, 1994.

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(4) ECDIN, 0000388 Butone (Methyl Ethyl Ketone) - 78933, Effects on experimental
animals – Data, Effects on experimental animals – Summary, Teratogenicity –
Animal Data.

(5) ECDIN, 0030522 4-Methylpentan-2-one (Methyl lsobutyl Ketone) – 108101,

Effects on experimental animals – Summary.

(6) Material Safety Data Sheet – Xylene, BP Chemicals, July 1996, Infosafe No.
BP062.

(7) ECDIN, 0000440 Benzene, Ethyl - 100414, Aquatic Toxicity.

(8) ECDIN, 0000503 Benzene, Dimethyl – 1330207, Aquatic Toxicity.

The customer is advised to consult the product Technical Data Sheets for further
information including advice on suitable equipment.

Information used in the compilation of this product SDS obtained from

investigations conducted at outside laboratories.

Lord Chemical Products (Australia) Pty. Ltd has prepared this Material Safety
Data Sheet.

Issue Date 2 March 2010

Supersedes 6 November 2008

Reason for Revision Review of Risk phrases, deletion of formaldehyde.

‘CHEMLOK’ is a registered trademark of Lord Corporation Inc. Erie PA, USA

The information contained in this document is intended to describe the product only in terms of health, safety and environmental requirements for the purposes of its safe handling, use and disposal and is
to the best of Lord’s knowledge and belief correct. Lord will be pleased to give further advice and assistance, but customers must satisfy themselves (by appropriate testing if necessary) that the product
is suitable for their purposes and conditions of use and that their facilities and arrangements are suitable for handling or using the product. Accordingly Lord disclaims any liability for loss, injury or
damage, which may result from the use of the product, this information, or from such advice and assistance save as may be expressly agreed under its terms of sale.

This information does not comprise a technical or performance specification for the product and customers are referred to any relevant product technical information or specification issued by Lord.

Customers are also reminded that there may be uses or application for the product which are protected by Lord's or third parties patent rights and nothing herein may be construed as an authority or
encouragement to use or apply the product in contravention of such rights.

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