Safety Data Sheet

according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 1 of 7

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

2928V3 Divinol CAF

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Calibration oil for calibrating injection pumps, injectors and other diesel injection components.
1.3. Details of the supplier of the safety data sheet
Company name: Zeller+Gmelin GmbH & Co. KG
Street: Schlossstr. 20
Place: D-73054 Eislingen
Telephone: +49 (0) 7161 / 802-0 Telefax: +49 (0) 7161 / 802-290
e-mail: [email protected]
Contact person: Uwe Allmendinger Telephone: +49 (0) 7161 / 802-297
e-mail: [email protected]
Internet: www.zeller-gmelin.de
Responsible Department: Produktsicherheit / Product Safety
1.4. Emergency telephone Germany: +49 (0) 7161 / 802-400
number: In England and Wales: NHS Direct: 0845 4647 or 111 In Scotland: NHS 24 -
08454 24 24 24 In Republic of Ireland: 01 809 2166

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008
Hazard categories:
Aspiration hazard: Asp. Tox. 1
Hazard Statements:
May be fatal if swallowed and enters airways.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labelling
hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics
hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30%)
Signal word: Danger

Pictograms:

Hazard statements
H304 May be fatal if swallowed and enters airways.
Precautionary statements
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P331 Do NOT induce vomiting.
Special labelling of certain mixtures
EUH066 Repeated exposure may cause skin dryness or cracking.
2.3. Other hazards
Results of PBT and vPvB assessment: not applicable.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Hydrocarbon-based mixture.
Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016
 Safety Data Sheet
according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 2 of 7

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics 25 - < 100 %
926-141-6 01-2119456620-43
Asp. Tox. 1; H304 EUH066
hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30%) 25 - < 100 %
920-360-0 01-2119448343-41
Asp. Tox. 1; H304 EUH066
Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
When in doubt or if symptoms are observed, get medical advice. If unconscious place in recovery position and
seek medical advice. Remove contaminated, saturated clothing immediately.
After inhalation
Remove casualty to fresh air and keep warm and at rest.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap.
After contact with eyes
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then consult an
ophthalmologist immediately.
After ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Let water be drunken in little sips (dilution
effect). Call a physician immediately. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
When in doubt or if symptoms are observed, get medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
No information available.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
alcohol resistant foam, Extinguishing powder, Carbon dioxide (CO2).
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products: Carbon monoxide Carbon dioxide (CO2). Do not inhale explosion and
combustion gases.
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.
Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Do not
allow to enter into soil/subsoil.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See protective measures under point 7 and 8.

Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016

 Safety Data Sheet
according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 3 of 7

6.2. Environmental precautions

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Clean contaminated
articles and floor according to the environmental legislation.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the
recovered material as prescribed in the section on waste disposal.
6.4. Reference to other sections
See protective measures under point 7 and 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Use personal protection equipment. Do not eat, drink or smoke when using this product. Provide fresh air.
Handle and open container with care. Conditions to avoid: generation/formation of aerosols.
Advice on protection against fire and explosion
No special measures are necessary.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Protect against: Frost. Keep away from heat. Protect against direct sunlight. Keep container tightly closed in a
cool, well-ventilated place.
7.3. Specific end use(s)
Observe technical data sheet.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.2. Exposure controls
Appropriate engineering controls
See chapter 7. No additional measures necessary.
Protective and hygiene measures
When using do not eat, drink, smoke, sniff.
Eye/face protection
Eye glasses with side protection.
Hand protection
Wear suitable gloves. Recommended glove articles: DIN EN 374. Suitable material: NBR (Nitrile rubber).
Breakthrough time (maximum wearing time): > 480 min (Thickness of the glove material: 0.4 mm).
Breakthrough times and swelling properties of the material must be taken into consideration. For special
purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above
together with the supplier of these gloves. Barrier creams can help protecting exposed skin areas. In no case
should they be used after contact.
Skin protection
Protective clothing.
Respiratory protection
With correct and proper use, and under normal conditions, breathing protection is not required. When splashes
or fine mist form, a permitted breathing apparatus suitable for these purposes must be used. Suitable
respiratory protection apparatus: Filtering Half-face mask (DIN EN 149), e.g. FFA P / FFP3.
Environmental exposure controls
Do not allow to enter into surface water or drains.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: liquid
Colour: yellowish
Odour: characteristic
Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016
 Safety Data Sheet
according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 4 of 7

Test method
pH-Value: not applicable
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: not determined
Pour point: not determined
Flash point: > 90 °C EN ISO 2719
Lower explosion limits: 0,5 vol. %
Upper explosion limits: 6,0 vol. %
Ignition temperature: not determined
Decomposition temperature: No information available.
Vapour pressure: not determined
Density (at 15 °C): 0,82 g/cm³ DIN 51757
Water solubility: insoluble
Partition coefficient: not determined
Viscosity / dynamic: not determined
Viscosity / kinematic: 2,5 mm²/s DIN 51562
(at 40 °C)
Flow time: not determined
Vapour density: not determined
Evaporation rate: not determined
9.2. Other information
No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No information available.
10.2. Chemical stability
No information available.
10.3. Possibility of hazardous reactions
No hazardous reaction when handled and stored according to provisions.
10.4. Conditions to avoid
Heat.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
No information available.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.

Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016

 Safety Data Sheet
according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 5 of 7

CAS No Chemical name

Exposure route Dose Species Source
hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics
oral LD50 >5000,0 Rat
mg/kg
dermal LD50 >5000,0 Rabbit
mg/kg
hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30%)
oral LD50 > 4150 mg/kg Rat ECHA Dossier
dermal LD50 > 2000,0 Rabbit ECHA Dossier
mg/kg
inhalative (4 h) aerosol LC50 > 5,28 mg/l Rat ECHA Dossier

Irritation and corrosivity

Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Repeated exposure may cause skin dryness or cracking.
Aspiration hazard
May be fatal if swallowed and enters airways.
Practical experience
Other observations
Keeping to the general worker's protection rules and the industrial hygienics, there is no risk in handling this
product through the personnel.

SECTION 12: Ecological information

12.1. Toxicity
There are no data available on the mixture itself.
12.2. Persistence and degradability
There are no data available on the mixture itself.
CAS No Chemical name
Method Value d Source
Evaluation
hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics
Biodegradation 69,0 % 28
Readily biodegradable (according to OECD criteria).
Biodegradation 69,0 % 28
Readily biodegradable (according to OECD criteria).
hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30%)
OECD 301F/ ISO 9408/ EEC 92/69/V, C.4-D 60,7% 28 ECHA Dossier
Readily biodegradable (according to OECD criteria).

12.3. Bioaccumulative potential

There are no data available on the mixture itself.
Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30%) > 3,50

Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016

 Safety Data Sheet
according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 6 of 7

12.4. Mobility in soil

No data available
12.5. Results of PBT and vPvB assessment
No data available
12.6. Other adverse effects
No data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe
way. Waste disposal according to EC directives 75/442/EEC and 91/689/EEC in the corresponding versions,
covering waste and dangerous waste.
Waste disposal number of waste from residues/unused products
070604 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease,
soaps, detergents, disinfectants and cosmetics; other organic solvents, washing liquids and mother
liquors
Classified as hazardous waste.
Contaminated packaging
Non-contaminated packages may be recycled. Consult the appropriate local waste disposal expert about waste
disposal.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Marine transport (IMDG)
14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Marine pollutant: NO
Air transport (ICAO)
14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
No data available

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2010/75/EU (VOC): 0%

Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016

 Safety Data Sheet
according to Regulation (EC) No 1907/2006

Divinol CAF
Print date: 14.09.2016 Article No.: 2928V3 Page 7 of 7

National regulatory information

Water contaminating class (D): 1 - slightly water contaminating
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes
This data sheet contains changes from the previous version in section(s): 9,11,15.
Abbreviations and acronyms
ADR: Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement concernant le transport international ferroviaire des marchandises dangereuses (Regulations
concerning the International Carriage of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
CAS: Chemical Abstracts Service (a division of the American Chemical Society)
DNEL/DMEL: Derived No-Effect Level / Derived Minimal Effect Level
PNEC: Predicted No Effect Concentration
WEL (UK): Workplace Exposure Limits
TWA (EC): Time-Weighted Average
STEL (EC): Short Term Exposure Limit
ATE: Acute Toxicity Estimate
LD50: Lethal Dose, 50% (median lethal dose)
LC50: Lethal Concentration, 50% (median lethal concentration)
EC50: half maximal Effective Concentration
ErC50: EC50 in terms of reduction of growth rate
VwVwS: Verwaltungsvorschrift wassergefährdende Stoffe
Relevant H and EUH statements (number and full text)
H304 May be fatal if swallowed and enters airways.
EUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 1,5 - Replaces version: 1 GB - EN Revision date: 13.04.2016